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1.
Environ Res ; 253: 119176, 2024 Jul 15.
Artigo em Inglês | MEDLINE | ID: mdl-38768887

RESUMO

This study investigates spatiotemporal dynamics in metal sedimentation in the North American Great Lakes and their underlying biogeochemical controls. Bulk geochemical and isotope analyses of n = 72 surface and core sediment samples show that metal (Cu, Zn, Pb) concentrations and their isotopic compositions vary spatially across oligotrophic to mesotrophic settings, with intra-lake heterogeneity being similar or higher than inter-lake (basin-scale) variability. Concentrations of Cu, Zn, and Pb in sediments from Lake Huron and Lake Erie vary from 5 to 73 mg/kg, 18-580 mg/kg, and 5-168 mg/kg, respectively, but metal enrichment factors were small (<2) across the surface- and core sediments. The isotopic signatures of surface sediment Cu (δ65Cu between -1.19‰ and +0.96‰), Zn (δ66Zn between -0.09‰ and +0.41‰) and Pb (206/207Pb from 1.200 to 1.263) indicate predominantly lithogenic metal sourcing. In addition, temporal trends in sediment cores from Lake Huron and Lake Erie show uniform metal concentrations, minor enrichment, and Zn and Pb isotopic signatures suggestive of negligible in-lake biogeochemical fractionation. In contrast, Cu isotopic signatures and correlation to chlorophyll and macronutrient levels suggest more differentiation from source variability and/or redox-dependent fractionation, likely related to biological scavenging. Our results are used to derive baseline metal sedimentation fluxes and will help optimize water quality management and strategies for reducing metal loads and enrichment in the Great Lakes and beyond.


Assuntos
Monitoramento Ambiental , Sedimentos Geológicos , Lagos , Poluentes Químicos da Água , Sedimentos Geológicos/química , Sedimentos Geológicos/análise , Lagos/química , Monitoramento Ambiental/métodos , Poluentes Químicos da Água/análise , Isótopos/análise , Great Lakes Region , Metais Pesados/análise
2.
BMC Public Health ; 23(1): 769, 2023 04 26.
Artigo em Inglês | MEDLINE | ID: mdl-37098511

RESUMO

BACKGROUND: The East North Central Census division (aka the Great Lakes region) experienced a decrease in life expectancy of 0.3 years from 2014 to 2016 - one of the largest declines across the nine Census divisions. Disadvantaged groups that typically have below-average life expectancy, including Black individuals and those without a college education, may have been disproportionately affected by this longevity shift. This investigation examines life expectancy changes among different sex, race, and education groups in the Great Lakes region, and how specific causes of death contributed to within-group longevity changes over time and across age. METHODS: We used 2008 to 2017 death counts from the National Center for Health Statistics and American Community Survey population estimates to measure within-group change in life expectancy at age 25 among non-Hispanic Black and white males and females by educational attainment. We decomposed life expectancy change over time for each subgroup by 24 causes of death and measured their contribution to longevity change across 13 age groups. RESULTS: Among persons with ≤ 12 years of education, white males and females experienced 1.3- and 1.7-year longevity declines respectively, compared to a 0.6-year decline among Black males and a 0.3-year decline among Black females. Life expectancy declined among all groups with 13-15 years of education, but especially Black females, who experienced a 2.2-year loss. With the exception of Black males, all groups with 16 + years of education experienced longevity gains. Homicide contributed 0.34 years to longevity decline among Black males with ≤ 12 years of education. Drug poisoning made large contributions to longevity losses among Black females with ≤ 12 years of education (0.31 years), white males and females with 13-15 years of education (0.35 and 0.21 years, respectively), and white males and females with ≤ 12 years of education (0.92 and 0.65 years, respectively). CONCLUSIONS: Public health efforts to reduce the risks of homicide among Black males without a college education and drug poisoning among all groups could improve life expectancy and reduce racial and educational longevity disparities in the Great Lakes region.


Assuntos
Longevidade , Brancos , Masculino , Feminino , Humanos , Estados Unidos , Adulto , Causas de Morte , Expectativa de Vida , Escolaridade , Great Lakes Region
3.
Environ Sci Technol ; 55(4): 2411-2421, 2021 02 16.
Artigo em Inglês | MEDLINE | ID: mdl-33522786

RESUMO

Polychlorinated naphthalenes (PCNs) were measured in lake trout and walleye over the period 2004-2018, utilizing isotope dilution techniques with high-resolution gas chromatography/high-resolution mass spectrometry to assess concentrations and toxic equivalence (TEQ). An age-trend model was applied to mitigate the effect of a changing lake trout age structure. Most Great Lakes Fish Monitoring and Surveillance Program sampling sites demonstrated significant half-life and percent decreases for lake trout total PCNs and total TEQ over the 2004-2018 period, the exceptions being Lake Erie lake trout and walleye which illustrated increasing concentrations. Great Lakes total PCN concentrations ranged between 5701 and 100 pg/g ww, whereas total PCN TEQ concentrations ranged between 8.89 and 0.13 pg-TEQ/g ww. Based on the average number of chlorines per naphthalene, we determined that the overall lake trout and walleye PCN congener distribution has significantly shifted to a lower-chlorinated composition in the Great Lakes (5.33 to 4.48 Cl/CN) and has resulted in a substantial 59.1% reduction of the overall total PCN TEQ burden. A prominent PCN concentration trend breakpoint was observed in Lake Ontario lake trout over the 2012-2016 period likely associated with hazardous waste cleanups, channel dredging, and spoils disposal in the Detroit River and western-basin of Lake Erie.


Assuntos
Lagos , Poluentes Químicos da Água , Animais , Monitoramento Ambiental , Great Lakes Region , Naftalenos/análise , Ontário , Truta , Poluentes Químicos da Água/análise
4.
Glob Chang Biol ; 26(11): 6350-6362, 2020 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-32871618

RESUMO

Winter climate warming is rapidly leading to changes in snow depth and soil temperatures across mid- and high-latitude ecosystems, with important implications for survival and distribution of species that overwinter beneath the snow. Amphibians are a particularly vulnerable group to winter climate change because of the tight coupling between their body temperature and metabolic rate. Here, we used a mechanistic microclimate model coupled to an animal biophysics model to predict the spatially explicit effects of future climate change on the wintering energetics of a freeze-tolerant amphibian, the Wood Frog (Lithobates sylvaticus), across its distributional range in the eastern United States. Our below-the-snow microclimate simulations were driven by dynamically downscaled climate projections from a regional climate model coupled to a one-dimensional model of the Laurentian Great Lakes. We found that warming soil temperatures and decreasing winter length have opposing effects on Wood Frog winter energy requirements, leading to geographically heterogeneous implications for Wood Frogs. While energy expenditures and peak body ice content were predicted to decline in Wood Frogs across most of our study region, we identified an area of heightened energetic risk in the northwestern part of the Great Lakes region where energy requirements were predicted to increase. Because Wood Frogs rely on body stores acquired in fall to fuel winter survival and spring breeding, increased winter energy requirements have the potential to impact local survival and reproduction. Given the geographically variable and intertwined drivers of future under-snow conditions (e.g., declining snow depths, rising air temperatures, shortening winters), spatially explicit assessments of species energetics and risk will be important to understanding the vulnerability of subnivium-adapted species.


Assuntos
Ecossistema , Neve , Animais , Mudança Climática , Great Lakes Region , Ranidae , Estações do Ano
5.
Chemosphere ; 210: 1193-1206, 2018 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-30208545

RESUMO

Polychlorinated biphenyl (PCB) contamination has historically posed constraints on the recreational and commercial fishing industry in the Great Lakes. Empirical evidence suggests that PCB contamination represents a greater health risk from fish consumption than other legacy contaminants. The present study attempts a rigorous assessment of the spatio-temporal PCB trends in multiple species across the Canadian waters of the Great Lakes. We applied a Bayesian modelling framework, whereby we initially used dynamic linear models to delineate PCB levels and rates of change, while accounting for the role of fish length and lipid content as covariates. We then implemented Bayesian hierarchical modelling to evaluate the temporal PCB trends during the dreissenid pre- and post-invasion periods, as well as the variability among and within the water bodies of the Great Lakes system. Our analysis indicates that Lake Ontario is characterized by the highest PCB levels among nearly all of the fish species examined. Historically contaminated local areas, designated as Areas of Concern, and embayments receiving riverine inputs displayed higher concentrations within each of the water bodies examined. The general temporal trend across the Great Lakes was that the high PCB concentrations during the early 1970s followed a declining trajectory throughout the late 1980s/early 1990s, likely as a result of the reductions in industrial emissions and other management actions. Nonetheless, after the late 1990s/early 2000s, our analysis provided evidence of a decline in the rate at which PCB concentrations in fish were dropping, accompanied by a gradual establishment of species-specific, steady-state concentrations, around which there is considerable year-to-year variability. The overall trends indicate that reduced contaminant emissions have brought about distinct beneficial changes in fish PCB concentrations, but past historical contamination along with other external or internal stressors (e.g., invasive species, climate change) continue to modulate the current levels, thereby posing potential risks to humans through fish consumption.


Assuntos
Bifenilos Policlorados/química , Poluentes Químicos da Água/química , Animais , Teorema de Bayes , Peixes , Great Lakes Region , Humanos , Bifenilos Policlorados/análise , Poluentes Químicos da Água/análise
6.
Risk Anal ; 38(10): 2029-2040, 2018 10.
Artigo em Inglês | MEDLINE | ID: mdl-29750842

RESUMO

The Chippewa Ottawa Resource Authority monitors fish contaminants in Anishinaabe (Great Lake Native American) tribal fisheries. This article updates previously reported trends in two persistent bioaccumulative toxic (PBT) substances that are the primary contributors to consumption advisory limits for these fish: methylmercury (MeHg) and polychlorinated biphenyls (PCBs). Also, we report, for the first time, an analysis of nutritional benefit bioindicators and metrics in these same Upper Great Lakes fish harvests: selenium (Se) and omega-3 fatty acids (PUFA-3s). A novel risk/benefit quantification originally presented by Ginsberg et al. is reported here to characterize the tradeoffs between fatty acid benefits and toxic MeHg health outcomes. We also report a Se benefit metric to characterize the possible protective value against MeHg neurotoxicity based on Ralston et al. Congruent with Anishinaabe cultural motivations to consume fish from their ancestral fisheries, nutritional content was high in locally caught fish and, in some respects, superior to farmed/store-bought fish. These Great Lakes fish still contained levels of PBTs that require careful education and guidance for consumers. However, the contaminant trends suggest that these fish need not be abandoned as important (both culturally and nutritionally) food sources for the Anishinaabe who harvested them.


Assuntos
Ácidos Graxos/análise , Peixes , Mercúrio/análise , Bifenilos Policlorados/análise , Medição de Risco/métodos , Selênio/análise , Animais , Contaminação de Alimentos/análise , Geografia , Great Lakes Region , Promoção da Saúde , Disparidades nos Níveis de Saúde , Humanos , Indígenas Norte-Americanos , Lagos , Especificidade da Espécie , Resultado do Tratamento , Poluentes Químicos da Água/análise
7.
PLoS One ; 12(2): e0172668, 2017.
Artigo em Inglês | MEDLINE | ID: mdl-28225817

RESUMO

Climate change is a global concern, requiring international strategies to reduce emissions, however, climate change vulnerability assessments are often local in scope with assessment areas restricted to jurisdictional boundaries. In our study we explored tools and impediments to understanding and responding to the effects of climate change on vulnerability of migratory birds from a binational perspective. We apply and assess the utility of a Climate Change Vulnerability Index on 3 focal species using distribution or niche modeling frameworks. We use the distributional forecasts to explore possible changes to jurisdictional conservation responsibilities resulting from shifting distributions for: eastern meadowlark (Sturnella magna), wood thrush (Hylocichla mustelina), and hooded warbler (Setophaga citrina). We found the Climate Change Vulnerability Index to be a well-organized approach to integrating numerous lines of evidence concerning effects of climate change, and provided transparency to the final assessment of vulnerability. Under this framework, we identified that eastern meadowlark and wood thrush are highly vulnerable to climate change, but hooded warbler is less vulnerable. Our study revealed impediments to assessing and modeling vulnerability to climate change from a binational perspective, including gaps in data or modeling for climate exposure parameters. We recommend increased cross-border collaboration to enhance the availability and resources needed to improve vulnerability assessments and development of conservation strategies. We did not find evidence to suggest major shifts in jurisdictional responsibility for the 3 focal species, but results do indicate increasing responsibility for these birds in the Canadian Provinces. These Provinces should consider conservation planning to help ensure a future supply of necessary habitat for these species.


Assuntos
Migração Animal , Biodiversidade , Mudança Climática , Conservação dos Recursos Naturais/métodos , Ecossistema , Animais , Aves , Canadá , Great Lakes Region , Lagos
8.
Environ Manage ; 59(1): 154-173, 2017 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-27734087

RESUMO

The U.S. Army Corps of Engineers is conducting the Great Lakes and Mississippi River Interbasin Study to identify the highest risk aquatic nuisance species currently established in either the Mississippi River Basin or the Great Lakes Basin and prevent their movement into a new basin. The Great Lakes and Mississippi River Interbasin Study focuses specifically on aquatic nuisance species movement through the Chicago Area Waterway System, a multi-use waterway connecting the two basins. In support of Great Lakes and Mississippi River Interbasin Study, we conducted a qualitative risk assessment for 33 aquatic nuisance species over a 50-year period of analysis based on the probability of aquatic nuisance species establishing in a new basin and the environmental, economic, and sociopolitical consequences of their establishment. Probability of establishment and consequences of establishment were assigned qualitative ratings of high, medium, or low after considering the species' current location, mobility, habitat suitability, and impacts in previously invaded systems. The establishment and consequence ratings were then combined into an overall risk rating. Seven species were characterized as posing a medium risk and two species as posing a high risk to the Mississippi River Basin. Three species were characterized as posing a medium risk to the Great Lakes Basin, but no high-risk species were identified for this basin. Risk increased over time for some aquatic nuisance species based on the time frame in which these species were considered likely to establish in the new basin. Both species traits and the need to balance multiple uses of the Chicago Area Waterway System must be considered when identifying control measures to prevent aquatic nuisance species movement between the two basins.


Assuntos
Organismos Aquáticos/crescimento & desenvolvimento , Ecossistema , Monitoramento Ambiental/métodos , Espécies Introduzidas/tendências , Great Lakes Region , Lagos , Medição de Risco , Rios , Estados Unidos
9.
Ecol Appl ; 25(3): 717-28, 2015 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-26214917

RESUMO

Ecosystems often experience multiple environmental stressors simultaneously that can differ widely in their pathways and strengths of impact. Differences in the relative impact of environmental stressors can guide restoration and management prioritization, but few studies have empirically assessed a comprehensive suite of stressors acting on a given ecosystem. To fill this gap in the Laurentian Great Lakes, where considerable restoration investments are currently underway, we used expert elicitation via a detailed online survey to develop ratings of the relative impacts of 50 potential stressors. Highlighting the multiplicity of stressors in this system, experts assessed all 50 stressors as having some impact on ecosystem condition, but ratings differed greatly among stressors. Individual stressors related to invasive and nuisance species (e.g., dreissenid mussels and ballast invasion risk) and climate change were assessed as having the greatest potential impacts. These results mark a shift away from the longstanding emphasis on nonpoint phosphorus and persistent bioaccumulative toxic substances in the Great Lakes. Differences in impact ratings among lakes and ecosystem zones were weak, and experts exhibited surprisingly high levels of agreement on the relative impacts of most stressors. Our results provide a basin-wide, quantitative summary of expert opinion on the present-day influence of all major Great Lakes stressors. The resulting ratings can facilitate prioritizing stressors to achieve management objectives in a given location, as well as providing a baseline for future stressor impact assessments in the Great Lakes and elsewhere.


Assuntos
Ecossistema , Meio Ambiente , Atividades Humanas , Estresse Fisiológico , Poluentes da Água , Animais , Coleta de Dados , Great Lakes Region , Humanos , Espécies Introduzidas
10.
Environ Manage ; 55(6): 1446-56, 2015 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-25832344

RESUMO

Over 400 sites were sampled in the nearshore of the U.S. Great Lakes during the U.S. National Coastal Condition Assessment (NCCA) field survey in summer 2010. Underwater video images were recorded in addition to routine NCCA benthic assessment measures. This paper has two objectives: (1) to develop a process to evaluate video performance with acceptance criteria, exploring reasons for poor images, and (2) to use acceptable videos in an example application with invasive mussels, evaluating the enhancement potential of video to supplement traditional grab sampling. A standard hierarchical protocol was developed to rank video performance based on quality and clarity. We determined controllable and uncontrollable factors affecting video performance. Moreover, specific thresholds limiting video were identified: >0.5/m for light extinction and >3.5 µg/L for chlorophyll a concentration. To demonstrate the utility and enhancement potential of video sampling, observed dreissenid presence from excellent (221 of 362 videos) videos was compared with NCCA benthic taxonomy, in the context of the statistically based NCCA survey. Including video increased the overall area estimate of the U.S. Great Lakes nearshore with invasive mussels by about 15% compared to PONAR alone; 44% (7570 km(2)) of the surveyed region had mussels. The proportion of the nearshore area having mussels varied from low (3.5%) in Lake Superior to >50% in the lower lakes. PONAR and video have unique strengths and weaknesses as sampling tools in the Great Lakes nearshore environment, but when paired were complimentary and thus provided a more thorough benthic condition assessment at lake and regional scales.


Assuntos
Bivalves/crescimento & desenvolvimento , Clorofila/análise , Monitoramento Ambiental/métodos , Lagos/química , Gravação em Vídeo/métodos , Animais , Clorofila A , Great Lakes Region , Projetos de Pesquisa , Estados Unidos
11.
Int J Environ Res Public Health ; 12(4): 3600-14, 2015 Mar 31.
Artigo em Inglês | MEDLINE | ID: mdl-25837202

RESUMO

Many government, academic and research institutions collect environmental data that are relevant to understanding the relationship between environmental exposures and human health. Integrating these data with health outcome data presents new challenges that are important to consider to improve our effective use of environmental health information. Our objective was to identify the common themes related to the integration of environmental and health data, and suggest ways to address the challenges and make progress toward more effective use of data already collected, to further our understanding of environmental health associations in the Great Lakes region. Environmental and human health databases were identified and reviewed using literature searches and a series of one-on-one and group expert consultations. Databases identified were predominantly environmental stressors databases, with fewer found for health outcomes and human exposure. Nine themes or factors that impact integration were identified: data availability, accessibility, harmonization, stakeholder collaboration, policy and strategic alignment, resource adequacy, environmental health indicators, and data exchange networks. The use and cost effectiveness of data currently collected could be improved by strategic changes to data collection and access systems to provide better opportunities to identify and study environmental exposures that may impact human health.


Assuntos
Bases de Dados Factuais , Saúde Ambiental/métodos , Monitoramento Ambiental , Vigilância em Saúde Pública , Exposição Ambiental/efeitos adversos , Exposição Ambiental/análise , Política Ambiental , Great Lakes Region , Política de Saúde , Humanos , Armazenamento e Recuperação da Informação/métodos
12.
J Community Health ; 38(6): 1115-23, 2013 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-23821254

RESUMO

Contemporary American Indians and Alaska Natives (AIs/ANs) who live in urban areas today face the daunting task of navigating an urban landscape while maintaining the facets of their respective Native cultures. While AIs/ANs continue to grapple with the intergenerational trauma associated with forced assimilation, relocation movements, and boarding schools, these traumas have manifested themselves in elevated rates of psychopathology. AIs/ANs have elevated rates of domestic abuse, poverty, suicide, and substance misuse. Furthermore, AIs/ANs, like many other minority cultures often face discrimination in their everyday lives. In light of the aversive experiences they face, AI/AN people have followed the tenets of ritual and traditional healing to address imbalances in the body, mind, and spirit. For providers working with AI/AN clients, it is important to understand who is using traditional healing and why they are using alternative services. Secondary data analyses of survey data from 389 urban AIs/ANs were utilized in order to determine the relationship between experiences of discrimination and traditional healing use. Analyses indicated that experiences of discrimination in healthcare settings were significantly associated with participation in traditional healing. Analyses also indicated that nearly a quarter of the sample reported discrimination in a healthcare setting, roughly half of the sample had used traditional healing, and that the majority of those who had used traditional healing were women, and ages 35-44 (27%). This study calls attention to the socio-demographic factors implicated in traditional healing use by urban AI/AN people, in addition to the clinical and demographic characteristics of this sample.


Assuntos
Indígenas Norte-Americanos/psicologia , Inuíte/psicologia , Medicina Tradicional/estatística & dados numéricos , Discriminação Social/etnologia , Adolescente , Adulto , Idoso , Alaska/etnologia , Feminino , Great Lakes Region/etnologia , Humanos , Modelos Logísticos , Masculino , Pessoa de Meia-Idade , Pesquisa Qualitativa , Inquéritos e Questionários , Adulto Jovem
13.
Ecol Appl ; 23(3): 594-605, 2013 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-23734488

RESUMO

Sustainable management of exploited species is an ongoing challenge, particularly where populations have collapsed or been depleted by overharvest and habitat alteration. The walleye (Sander vitreus) population in Lake Superior's Black Bay historically supported more than 90% of the commercial walleye harvest from the entire lake, but collapsed in 1968 and has still not recovered despite long-term closure of the fishery. In an effort to rehabilitate this population, hatchery-origin walleye from exogenous sources were released into Black Bay between 2003 and 2005. We used individual-based analysis of genetic data collected between 2007 and 2010 to examine the contributions of different wild sources and hatchery stocking events to the contemporary walleye population in Black Bay. We found that 75% of the walleye in Black Bay originated from above- and below-barrier native populations in the Black Sturgeon River. The hatchery stocking events differed considerably in their effectiveness: the 2003 release of fry had no measurable contribution, whereas the 2004 and 2005 releases of fingerlings contributed 71% and 45% of the fish in their respective age classes. Hatchery and wild fish were similar in size, but hatchery fish rarely utilized the river habitat where Black Bay walleye historically spawned, and there was little genetic evidence of interbreeding or natural recruitment of stocked fish. Overall, our results suggest that restoring habitat connectivity to facilitate wild recruitment has greater potential than further exogenous stocking to contribute to the recovery of walleye in this system.


Assuntos
Ecossistema , Lagos , Perciformes/genética , Perciformes/fisiologia , Animais , Variação Genética , Great Lakes Region , Repetições de Microssatélites , Crescimento Demográfico
14.
Appetite ; 65: 58-67, 2013 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-23415978

RESUMO

Over the past 20 years, Asian carp have invaded rivers and lakes in the Midwest and southern United States, with large negative impacts, such as encroachment on the habitat of native fish and mass die-off. They also respond to boat motors by jumping out of the water, which can cause harm to boaters and fishermen. Policymakers in the Great Lakes region between the US and Canada are worried about possible expansion of the Asian carp to their region and its effects on their fishing industry. A potential solution to the problem is to harvest Asian carp for human consumption. This study analyzes the results of the first national survey on the attitudes of US fish consumers towards Asian carp. We find that this is a potentially promising strategy. Most respondents would be willing to try a free sample of Asian carp and would be willing to pay for it. Because of the negative connotation attached to carp in general, this figure is encouraging. Creating demand for Asian carp could be a market based, cost-effective solution for a problem (invasive species) that is typically dealt with through command and control policies, if it is coupled with appropriate policies and safeguards to ensure the fish is eventually eradicated and not cultivated for profit after removal from US rivers and lakes.


Assuntos
Atitude , Carpas , Dieta , Preferências Alimentares , Espécies Introduzidas , Marketing , Alimentos Marinhos , Adulto , Animais , Conservação dos Recursos Naturais , Feminino , Pesqueiros , Great Lakes Region , Humanos , Masculino , Pessoa de Meia-Idade , Estados Unidos
15.
Environ Pollut ; 161: 272-83, 2012 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-21705119

RESUMO

Three sets of model predicted values for speciated mercury concentrations and dry deposition fluxes over the Great Lakes region were assessed using field measurements and model intercomparisons. The model predicted values were produced by the Community Multiscale Air Quality Modeling System for the year 2002 (CMAQ2002) and for the year 2005 (CMAQ2005) and by the Global/Regional Atmospheric Heavy Metals Model for the year 2005 (GRAHM2005). Median values of the surface layer ambient concentration of gaseous elemental mercury (GEM) from all three models were generally within 30% of measurements. However, all three models overpredicted surface-layer concentrations of gaseous oxidized mercury (GOM) and particulate bound mercury (PBM) by a factor of 2-10 at the majority of the 15 monitoring locations. For dry deposition of GOM plus PBM, CMAQ2005 showed a clear gradient with the highest deposition in Pennsylvania and its surrounding areas while GRAHM2005 showed no such gradient in this region; however, GRAHM2005 had more hot spots than those of CMAQ2005. Predicted dry deposition of GOM plus PBM from these models should be treated as upper-end estimates over some land surfaces in this region based on the tendencies of all the models to overpredict GOM and PBM concentrations when compared to field measurements. Model predicted GEM dry deposition was found to be as important as GOM plus PBM dry deposition as a contributor to total dry deposition. Predicted total annual mercury dry deposition were mostly lower than 5 µg m(-2) to the surface of the Great lakes, between 5 and 15 µg m(-2) to the land surface north of the US/Canada border, and between 5 and 40 µg m(-2) to the land surface south of the US/Canada border. Predicted dry deposition from different models differed from each other by as much as a factor of 2 at regional scales and by a greater extent at local scales.


Assuntos
Poluentes Atmosféricos/análise , Mercúrio/análise , Modelos Químicos , Poluição do Ar/estatística & dados numéricos , Atmosfera/química , Monitoramento Ambiental , Great Lakes Region , Ontário , Quebeque
16.
Ecotoxicology ; 20(7): 1500-11, 2011 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-21861165

RESUMO

While mercury (Hg) releases to air and water within the Great Lakes states have declined significantly, concentrations of mercury in fish remain a cause for concern regarding human and ecosystem health in the Great Lakes Basin. This paper assesses the priority that Hg source reduction ought to have in relation to some other environmental concerns, and explores the relative costs of various Hg reduction policies. Long-range transport of atmospheric mercury creates a collective action problem for states, since most of the mercury emitted within any given state deposits outside that state's borders, and since most of the mercury deposited within a state originated outside that state. This paper discusses some of the mechanisms that policy makers in the Great Lakes states employed to get beyond the collective action problem, including: providing an example for others to follow; using cross-jurisdiction cooperation to leverage the benefits of leadership on Hg reduction and control; and, promoting voluntary actions. Recommendations for future opportunities include: focusing reduction efforts on sources with the highest total mass of emissions rather than solely focusing on reduction of local deposition and utilizing all tools available in the clean air and clean water acts.


Assuntos
Poluição do Ar/análise , Monitoramento Ambiental/métodos , Lagos , Mercúrio/análise , Poluição Química da Água/análise , Poluição do Ar/economia , Animais , Ecossistema , Peixes , Great Lakes Region , Humanos , Políticas , Poluentes Químicos da Água/análise , Poluição Química da Água/economia
17.
Ecotoxicology ; 20(7): 1520-9, 2011 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-21735124

RESUMO

While mercury is a health hazard to humans and wildlife, the biogeochemical processes responsible for its bioaccumulation in pelagic food webs are still being examined. Previous studies have indicated both "bottom-up" control of piscivorous fish Hg content through methylmercury.(MeHg) supply, as well as site-specific trophic factors. We evaluated ten studies from the western Great Lakes region to examine the similarity of MeHg trophic transfer efficiency within the pelagic food web, and assessed regional-scale spatial variability. Analyses of bioaccumulation and biomagnification factors between water, seston, zooplankton, and preyfish indicated that the largest increases in MeHg occurred at the base of the food web, and that the relative extent of trophic transfer was similar between sites. Positive correlations were observed between aqueous unfiltered MeHg, total Hg, and dissolved organic carbon, and measures of the efficiency of MeHg trophic transfer were consistent across widely disparate systems (both natural and experimentally manipulated) throughout North America. Such similarity suggests that the aqueous supply of MeHg is largely controlling bioaccumulation in pelagic food webs, while local, lake-specific variability can result from an array of trophic (biological) factors.


Assuntos
Monitoramento Ambiental/métodos , Cadeia Alimentar , Lagos , Mercúrio/análise , Mercúrio/farmacocinética , Animais , Peixes , Great Lakes Region , Invertebrados , Modelos Lineares , Compostos de Metilmercúrio/análise , Compostos de Metilmercúrio/farmacocinética , Cifozoários , Poluentes Químicos da Água/análise , Poluentes Químicos da Água/farmacocinética , Zooplâncton
18.
Bioresour Technol ; 102(2): 1087-94, 2011 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-20833541

RESUMO

A bioenergy production and delivery system built around the Great Lakes St. Lawrence Seaway (GLSLS) transportation corridor was assessed for its ability to mitigate energy security and climate change risks. The land area within 100 km of the GLSLS and associated railway lines was estimated to be capable of producing at least 30 Mt(dry) yr(-1) of lignocellulosic biomass with minimal adverse impacts on food and fibre production. This was estimated to be sufficient to displace all of the coal-fired electricity in Ontario plus more than 620 million L of green diesel (equivalent to 5.3% of diesel consumption in GLSLS provinces). Lifecycle greenhouse gas emissions were 88% and 76% lower than coal-fired power and conventional diesel, respectively. Production costs of $120 MWh(-1) for power and up to $30 GJ(-1) ($1.1 L(-1)) for green diesel were higher than current market prices, but a value for low-carbon energy would narrow the price differential.


Assuntos
Biocombustíveis/análise , Agricultura , Biocombustíveis/economia , Biomassa , Carbono/economia , Produtos Agrícolas/crescimento & desenvolvimento , Estudos de Viabilidade , Combustíveis Fósseis , Great Lakes Region , Efeito Estufa , Meios de Transporte/economia , Árvores
19.
J Fam Hist ; 35(4): 329-45, 2010.
Artigo em Inglês | MEDLINE | ID: mdl-21105493

RESUMO

The industrial and transportation revolutions of nineteenth-century America separated work from home (at least for the growing middle class) and intensified the development of masculine and feminine spheres devoted to success and domesticity, respectively. This development tended to reduce the husband's traditional patriarchal roles to that of provider only, while leaving the wife and mother with enhanced authority over household management and child rearing, a development with consequences for feminism. This article examines two extreme cases of separation of work from home: absent husbands, respected professional men, who left their wives alone for months or years and, while they provided financial support, surrendered all household authority to "single" wives.


Assuntos
Emprego , Características da Família , Relações Familiares , Zeladoria , Mudança Social , Cônjuges , Características Culturais/história , Emprego/economia , Emprego/história , Emprego/psicologia , Características da Família/etnologia , Características da Família/história , Relações Familiares/etnologia , Pai/educação , Pai/história , Pai/psicologia , Feminismo/história , Great Lakes Region/etnologia , História do Século XIX , Zeladoria/história , Masculinidade/história , Mudança Social/história , Cônjuges/educação , Cônjuges/etnologia , Cônjuges/história , Cônjuges/psicologia , Migrantes/educação , Migrantes/história , Migrantes/psicologia , Viagem/história , Viagem/psicologia , Estados Unidos/etnologia
20.
J Air Waste Manag Assoc ; 60(7): 884-90, 2010 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-20681436

RESUMO

This paper applies a geospatial network optimization model to explore environmental, economic, and time-of-delivery tradeoffs associated with the application of marine vessels as substitutes for heavy-duty trucks operating in the Great Lakes region. The geospatial model integrates U.S. and Canadian highway, rail, and waterway networks to create an intermodal network and characterizes this network using temporal, economic, and environmental attributes (including emissions of carbon dioxide, particulate matter, carbon monoxide, sulfur oxides, volatile organic compounds, and nitrogen oxides). A case study evaluates tradeoffs associated with containerized traffic flow in the Great Lakes region, demonstrating how choice of freight mode affects the environmental performance of movement of goods. These results suggest opportunities to improve the environmental performance of freight transport through infrastructure development, technology implementation, and economic incentives.


Assuntos
Comércio , Poluição Ambiental/prevenção & controle , Veículos Automotores , Navios , Poluentes Atmosféricos/análise , Dióxido de Carbono/química , Comércio/economia , Monitoramento Ambiental , Great Lakes Region , Fatores de Tempo , Emissões de Veículos/análise
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