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1.
Environ Geochem Health ; 46(8): 279, 2024 Jul 03.
Artigo em Inglês | MEDLINE | ID: mdl-38958829

RESUMO

The present study focused on to determine the concentration and health risk of heavy metals (Cu, Pb, Zn, Cd, Hg, Cr) in e-waste contaminated soils collected from different provinces of Pakistan. Further, the impact of heavy metals on soil enzyme activities and microbial community was also investigated. The concentration (mg/kg) of Hg, Zn, Fe, Cu, Pb, Cd, and Cr ranged between 0-0.258, 2.284-6.587, 3.005-40.72, 8.67-36.88, 12.05-35.03, 1.03-2.43, and 33.13-60.05, respectively. The results revealed that Lahore site of Punjab province indicated more concentration of heavy metals as compared to other sites. The level of Cr at all sites whereas Hg at only two sites exceeds the World Health Organization standards (WHO) for soil. Soil enzyme activity exhibited dynamic trend among the sites. Maximum enzyme activity was observed for urease followed by phosphatase and catalase. Contamination factor (Cf), Pollution load index (PLI), and geo-accumulation index (Igeo) results showed that all the sites are highly contaminated with Cu, Cd, and Pb. Hazard index (HI) was less than 1 for children and adults suggesting non-carcinogenic health risk. Principle component analysis results depicted relation among Cr, Fr, catalase, and actinomycetes; Cd, OM, urease, and bacteria, and Pb, Cu, Zn, Hg, and phosphatase, suggesting soil enzymes and microbial community profiles were influenced by e-waste pollution. Therefore, there is a dire need to introduce sustainable e-waste recycling techniques as well as to make stringent e-waste management policies to reduce further environmental contamination.


Assuntos
Resíduo Eletrônico , Metais Pesados , Microbiologia do Solo , Poluentes do Solo , Metais Pesados/análise , Paquistão , Poluentes do Solo/análise , Medição de Risco , Humanos , Monitoramento Ambiental/métodos , Instalações de Eliminação de Resíduos , Solo/química
2.
Environ Sci Pollut Res Int ; 31(28): 41208-41220, 2024 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-38849616

RESUMO

Reasonable treatment of large amounts of sludge excavated from landfills has gained increasing attention due to the diminishing availability of landfill space in China. In this study, five landfill sludge (LS) treatment technologies using life cycle assessment (LCA) and life cycle cost (LCC) were investigated, i.e., co-incineration in coal-fired power plants (CFPP) and waste incineration power plant (WIPP), co-processing in cement kiln, bricks production, and sintering ceramsite. The LCA results demonstrate that sintering ceramsite outperforms other technologies and LCC results indicate sintering ceramsite also provides the highest economic benefit ($869.94). To further enhance environmental and economic performances of the LS treatment, the substitution of coal with natural gas and biomass can reduce Energy Conservation and Emission Reduction (ECER) index by 74% and 98%, respectively. This substitution can increase economic returns by 24% and 26%, respectively. Furthermore, national-level economic benefit and carbon emission reduction potential of different LS treatment technology alternative scenarios were assessed. Results display that a combination of 50% CFPP, 25% bricks, and 25% ceramsite (biomass) offers the highest economic gain, which is 3.02 times that of 50% CFPP and 50% cement (original case). Conversely, the replacement of 25% brick with 25% cement in the above combination result in the lowest carbon reduction, which is 9.35 times that of the original case.


Assuntos
Esgotos , Instalações de Eliminação de Resíduos , China , Incineração , Carvão Mineral
3.
Waste Manag ; 184: 109-119, 2024 Jul 15.
Artigo em Inglês | MEDLINE | ID: mdl-38810396

RESUMO

In recent years, construction and demolition waste (CDW) landfills landslide accidents have occurred globally, with consequences varying due to surrounding environmental factors. Risk monitoring is crucial to mitigate these risks effectively. Existing studies mainly focus on improving risk assessment accuracy for individual landfills, lacking the ability to rapidly assess multiple landfills at a regional scale. This study proposes an innovative approach utilizing deep learning models to quickly locate suspected landfills and develop risk assessment models based on surrounding environmental factors. Shenzhen, China, with significant CDW disposal pressure, is chosen as the empirical research area. Empirical findings from this study include: (1) the identification of 52 suspected CDW landfills predominantly located at the administrative boundaries within Shenzhen, specifically in the Longgang, Guangming, and Bao'an districts; (2) landfills at the lower risk of landslides are typically found near the northern borders adjacent to cities like Huizhou and Dongguan; (3) landfills situated at the internal administrative junctions generally exhibit higher landslide risks; (4) about 70 % of these landfills are high-risk, mostly located in densely populated areas with substantial rainfall and complex topographies. This study advances landfill landslide risk assessments by integrating computer vision and environmental analysis, providing a robust method for governments to rapidly evaluate risks at CDW landfills regionally. The adaptable models can be customized for various urban and broadened to general landfills by adjusting specific indicators, enhancing environmental safety protocols and risk management strategies effectively.


Assuntos
Deslizamentos de Terra , Instalações de Eliminação de Resíduos , China , Medição de Risco/métodos , Eliminação de Resíduos/métodos , Gerenciamento de Resíduos/métodos , Monitoramento Ambiental/métodos
4.
Environ Toxicol Pharmacol ; 108: 104460, 2024 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-38705363

RESUMO

Leachates from municipal landfills introduce toxic heavy metals into water, causing bioaccumulation. This study assesses metal levels and potential human health risks associated with consuming Anabas testudineus and Channa striata. Inductively coupled plasma mass spectrometry detected Cd, Cu, Cr, Ni, Pb, and Zn in both fish species. Leachate metal concentrations meet international discharge standards, Cd, Cr, and Pb in the fish exceed the international accepted values. Gastrointestinal tract+liver samples show significant variation between species, particularly in Cd and Pb. EDI, THQ/HI, and TR for the both species fall below TDIs, lower than the limit of 1, and within the acceptable range of the US-EPA permissible limit, respectively. Fish consumption appears safe regarding carcinogenic risk, but exceeding metal limits could impact heavy metals accumulation in the local food chain. Raising public awareness is crucial, and governmental agencies and environmental organizations should enhance waste treatment technologies and enact relevant health legislation.


Assuntos
Peixes , Metais Pesados , Instalações de Eliminação de Resíduos , Poluentes Químicos da Água , Metais Pesados/análise , Metais Pesados/toxicidade , Animais , Poluentes Químicos da Água/análise , Poluentes Químicos da Água/toxicidade , Medição de Risco , Humanos , Laos , Monitoramento Ambiental , Contaminação de Alimentos/análise
5.
Environ Pollut ; 352: 124147, 2024 Jul 01.
Artigo em Inglês | MEDLINE | ID: mdl-38735463

RESUMO

Continuous release and migration of heavy metals from coal-based solid waste (CSW) dumpsites often results in significant encroachment on ecological lands and pollution of natural environments. As a result, there is an urgent need for long-term and rapid monitoring, analysis, and assessment to control environmental risks associated with large CSW dumpsites. We constructed a new composite model (PLS-FL) that uses partial least squares regression (PLSR) and fuzzy logic inference (FLI) to accurately predict heavy metal concentrations in soils and assess pollution risk levels. The potential application of the PLS-FL was tested through a gully type CSW case study. We compared 20 modeling strategies using the PLS-FL: five types heavy metals (Cd, Zn, Pb, Cr and As) * four spectral transformation methods (first derivative (FD), second derivative (SD), reverse logarithm (RL), and continuum removal (CR)) * one variable selection method (competitive adaptive reweighted sampling (CARS)). The results showed that the combination of derivative transformation and CARS was recommended for estimation, with R2C > 0.80 and R2P > 0.50. When comparing the PLSR model with four traditional machine learning methods (Support Vector Machines (SVM), Random Forests (RF), Extreme Learning Machines (ELM), and KNN), the PLSR model demonstrated the highest average prediction accuracy. Additionally, the FLI process no longer relies on human perception and expert opinion, enhancing the model's objectivity and reliability. The evaluation results revealed that the heavy metal contamination areas of the CSW dumpsite are concentrated at the bottom of the gully, with more severe contamination in the north. Furthermore, a high-risk zone exists in the interim storage area for CSW to the east of the dump. These findings align with the initial detections at the sampling sites and highlight the need for targeted monitoring and control in these areas. The application of the model will empower regulators to quickly assess the overall situation of large-scale heavy metal pollution and provide scientific program and data support for continuous large-scale pollution risk monitoring and sustainable risk management.


Assuntos
Carvão Mineral , Monitoramento Ambiental , Lógica Fuzzy , Metais Pesados , Poluentes do Solo , Poluentes do Solo/análise , Metais Pesados/análise , Medição de Risco , Análise dos Mínimos Quadrados , Monitoramento Ambiental/métodos , Resíduos Sólidos/análise , Instalações de Eliminação de Resíduos , Solo/química
6.
J Environ Manage ; 360: 121201, 2024 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-38796870

RESUMO

The explosive growth of China's express delivery industry has greatly increased plastic waste, with low-value plastics not effectively utilized, such as PE packaging bags, which are often not recycled and end up in landfills or incinerators, causing significant resource waste and severe plastic pollution. A gate -to- grave life cycle assessment was adopted to assess the impacts of express delivery plastic waste (EDPW) management models (S1, landfill; S2, incineration; S3, mechanical pelletization), with Suzhou, China as a case. Results showed that mechanical pelletization, was the most environmentally advantageous, exhibiting a comprehensive environmental impact potential of -215.54 Pt, significantly lower than that of landfill (S1, 78.45 Pt) and incineration (S2, -121.77 Pt). The analysis identified that the end-of-life disposal and sorting stages were the principal contributors to environmental impacts in all three models, with transportation and transfer stages of residual waste having minimal effects. In terms of all environmental impact categories, human carcinogenic toxicity (HTc) emerged as the most significant contributor in all three scenarios. Specifically, S1 exhibited the most detrimental effect on human health, while S2 and S3 showed positive environmental impacts. Based on these findings, it is recommended that the application and innovation in mechanical recycling technologies be enhanced, the promotion of the eco-friendly transformation of packaging materials be pursued, and a sustainable express delivery packaging recycling management system be established. These strategies are essential for achieving more eco-friendly management of EDPW, reducing its environmental pollution, and moving towards more sustainable express delivery management practices.


Assuntos
Incineração , Plásticos , Reciclagem , Instalações de Eliminação de Resíduos , Gerenciamento de Resíduos , China , Gerenciamento de Resíduos/métodos , Eliminação de Resíduos/métodos , Humanos
7.
Water Res ; 257: 121710, 2024 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-38728784

RESUMO

Sewage treatment involves a trade-off of land vs. energy and the location of installing Sewage Treatment Plants (STPs) strongly impacts the decisions regarding treatment technologies. In the wake of rapid urbanization, deteriorating freshwater quality and water scarcity, it is crucial to plan adequate and low-cost sewerage infrastructure that can improve the quality of life in rural and urban areas. The present work involves a novel life cycle analysis through six scenarios generated from a holistic perspective that can aid urban planners and urban local bodies in planning the sewage treatment facilities in their cities, towns or villages. Instead of planning sewerage infrastructure for a long-term period of thirty years, it is suggested to create and operate the STPs only for the upcoming decade. Further, owing to the drawbacks of mechanized and natural treatment systems, adopting a mix of these treatment approaches in planning infrastructure is suggested and the benefits of implementing the same are quantified and discussed. Implementing these strategies results in almost 30 % cost savings and 40 % reduction in greenhouse gas emissions, hence, investing in land for natural treatment systems is suggested instead of incurring heavy electricity bills for mechanized treatment systems. The land cost significantly affects the decision-making regarding treatment technology selection; hence, the variation in the life cycle cost of different sewage treatment approaches is assessed for varying land rates in India.


Assuntos
Esgotos , Instalações de Eliminação de Resíduos , Eliminação de Resíduos Líquidos , Eliminação de Resíduos Líquidos/economia , Eliminação de Resíduos Líquidos/métodos , Custos e Análise de Custo , Urbanização , Recursos Hídricos/provisão & distribuição , Conservação dos Recursos Naturais , Índia , Humanos , População Rural , População Urbana , Gases de Efeito Estufa , Abastecimento de Água/estatística & dados numéricos , Instalações de Eliminação de Resíduos/economia , Instalações de Eliminação de Resíduos/estatística & dados numéricos
8.
Sci Total Environ ; 927: 171804, 2024 Jun 01.
Artigo em Inglês | MEDLINE | ID: mdl-38513865

RESUMO

Waste disposal in landfills remains a global concern. Despite technological developments, landfill leachate poses a hazard to ecosystems and human health since it acts as a secondary reservoir for legacy and emerging pollutants. This study provides a systematic and scientometric review of the nature and toxicity of pollutants generated by landfills and means of assessing their potential risks. Regarding human health, unregulated waste disposal and pathogens in leachate are the leading causes of diseases reported in local populations. Both in vitro and in vivo approaches have been employed in the ecotoxicological risk assessment of landfill leachate, with model organisms ranging from bacteria to birds. These studies demonstrate a wide range of toxic effects that reflect the complex composition of leachate and geographical variations in climate, resource availability and management practices. Based on bioassay (and other) evidence, categories of persistent chemicals of most concern include brominated flame retardants, per- and polyfluorinated chemicals, pharmaceuticals and alkyl phenol ethoxylates. However, the emerging and more general literature on microplastic toxicity suggests that these particles might also be problematic in leachate. Various mitigation strategies have been identified, with most focussing on improving landfill design or leachate treatment, developing alternative disposal methods and reducing waste volume through recycling or using more sustainable materials. The success of these efforts will rely on policies and practices and their enforcement, which is seen as a particular challenge in developing nations and at the international (and transboundary) level. Artificial intelligence and machine learning afford a wide range of options for evaluating and reducing the risks associated with leachates and gaseous emissions from landfills, and various approaches tested or having potential are discussed. However, addressing the limitations in data collection, model accuracy, real-time monitoring and our understanding of environmental impacts will be critical for realising this potential.


Assuntos
Inteligência Artificial , Ecotoxicologia , Instalações de Eliminação de Resíduos , Humanos , Monitoramento Ambiental/métodos , Política Ambiental , Eliminação de Resíduos/métodos , Medição de Risco , Poluentes Químicos da Água/análise , Poluentes Químicos da Água/toxicidade
9.
J Environ Manage ; 357: 120720, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38554451

RESUMO

Construction and demolition waste, along with discarded PET plastic bottles, have evolved into a widespread global resource. However, their current disposal in landfills poses a significant environmental pollution challenge. This research is centered on evaluating the performance of cement mortar composed by larger PET particles in conjunction with sand, construction and demolition waste, and lightweight expanded polystyrene aggregates. The primary objective of this study is to formulate a blend suitable for non-structural elements that can be easily manufactured for social housing construction. This modified blend extends upon the original certified mixture employed at CEVE for brick production, which encompasses cement and 3 mm-long PET particles. The experimental analysis revealed that blend containing 8 mm-long PET particles, in combination with fine aggregates of construction and demolition waste, attained a required mechanical strength of 2 MPa, while preserving the bulk density and hydric properties of the initial PET bricks developed at CEVE in Argentina.


Assuntos
Materiais de Construção , Reciclagem , Resíduos Industriais , Instalações de Eliminação de Resíduos , Argentina
10.
Environ Monit Assess ; 196(4): 397, 2024 Mar 26.
Artigo em Inglês | MEDLINE | ID: mdl-38530441

RESUMO

One of the main causes of contaminated groundwater in emerging nations is improper trash disposal in urban areas, which affects the level of groundwater contamination caused by contaminants of municipal solid waste (MSW) origin within the three local government headquarters in Akwa Ibom State, southeastern Nigeria. The main thrust of this research survey is to assess the level of groundwater contaminations and their consequences. The research used statistical data generated from the Electrical Resistivity Survey (ERS) in combination with hydrogeochemical investigations. Analysis of variance of resistivity between Uyo, Ikot Ekpene and Oron was carried out. The test result indicated significant difference in contamination among the three cities. This was followed by a t-test between each pair of dump and control sites in the three cities. The test results showed significant difference between each control and dumpsite. The results showed that leachate layer conductivity is always higher than that of the layer above it. All water samples from boreholes close to the dumpsites were identified by hydrogeochemical analysis to exhibit pH (3.70-4.15) lower than the permissible limit of the WHO; few water samples exhibit increased electrical conductivity (EC), cadmium and total dissolved solids (TDS). Similarly, the bacteriological analyses indicated a high level of microbial load due to the waste dump. Formations found in boreholes close to the dumpsite have litho-correlations which depict intercalations of comparatively impermeable and porous materials. The findings reveal that leachate (contaminate) travels slowly downward, allowing for physical, chemical and biological processes to filter out impurities before they get to the aquifer. It is recommended that no new water supply wells should be placed in areas of abnormally low resistivity and physicochemical and bacteriological parameters, until the reasons for these values are properly assessed.


Assuntos
Água Subterrânea , Poluentes Químicos da Água , Resíduos Sólidos/análise , Monitoramento Ambiental/métodos , Nigéria , Poluentes Químicos da Água/análise , Água Subterrânea/análise , Instalações de Eliminação de Resíduos , Água/análise
11.
Waste Manag ; 177: 177-181, 2024 Apr 01.
Artigo em Inglês | MEDLINE | ID: mdl-38330513

RESUMO

Assessments of greenhouse gas (GHG) emissions in managed areas are facing various challenges. A non-flow-through, non-steady-state (NFT-NSS) chamber coupled to a frame permanently inserted into the landfilled substrates is a standard method for quantifying GHG emissions in managed areas, such as pulp and paper mill sludge (PPMS) landfill sites. Frequent measurements are needed to minimize uncertainties on GHG emission factors at the landfill site scale. However, maintaining a frame inserted into the substrates for a long time period is often impossible due to landfilling management operations. Therefore, GHG measurements using NFT-NSS chambers placed directly on substrates' surface could be an interesting option. Our objectives were to determine the relationships between CO2, CH4, and N2O fluxes measured with (F + ) and without (F-) a frame inserted in the substrates' surface and to develop correction factors for fluxes measured without a frame. Measurements were made at different PPMS landfill sites in the province of Québec, Canada. Stronger GHG flux relationships were observed at the provincial (across sites) than the specific site scale: the variance in GHG fluxes from F- chambers explained up to 80 % of variance in fluxes from F + chambers. The measured CO2, CH4, and N2O fluxes in F- chambers were on average 53, 78, and 63 % lower, respectively, than those estimated by the models at provincial scale. The correction factors developed with this approach could greatly extend the number of sites where in situ GHG measurements can be done and would help refining GHG inventories at the provincial and national levels.


Assuntos
Dióxido de Carbono , Gases de Efeito Estufa , Esgotos , Canadá , Instalações de Eliminação de Resíduos
12.
Environ Sci Pollut Res Int ; 31(9): 14156-14177, 2024 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-38277108

RESUMO

This study aimed to assess the suitability of the potential solid waste landfill sites in seven provinces (Samsun, Ordu, Giresun, Trabzon, Gümüshane, Bayburt and Artvin) in the Eastern Blacksea Region of Türkiye. The earthquake hazard analysis for two major earthquakes which occurred in the region was first carried out. Then, the geophysical methods including seismic refraction tomography (SRT), electrical resistivity tomography (ERT) and Multichannel Analysis of Surface Waves (MASW) were conducted to find out the structural and physical properties of the subsurface which include the layering, soil classification based on VS30 and the groundwater content at 25 locations of 13 in target provinces. The integrated interpretation of whole data sets demonstrates that Isiktepe, Esence, Çamburnu and Kazantas which are characterized by VP > 1200 m/s, VS30 ≥ 400 m/s, ρ > 70 Ohm-m, low earthquake hazard and seismicity are more suitable among others. Vezirköprü, Sebinkarahisar, Yenice, Bayburt-Center, Balkaynak and Murgul will be suitable after a geotechnical reclamation due to moderate seismic velocities and electrical resistivity which are 900 < VP ≤ 1200 m/s, 200 < VS30 < 400 m/s and 10 < ρ ≤ 70 Ohm-m representing stiff and wet soils. In addition, Bafra, Agalik and Ovacik were considered to be unsuitable due to the presence of thick, water-saturated soft soil and extremely weathered rocks. Finally, this study shows that the joint interpretation of seismicity and geophysical data in potential waste landfill sites, extremely important for the planning and development of a city, can provide the valuable information which will enable to prevent possible deformations, environmental problems and economic losses after waste landfill.


Assuntos
Eliminação de Resíduos , Resíduos Sólidos , Eliminação de Resíduos/métodos , Monitoramento Ambiental/métodos , Mar Negro , Turquia , Instalações de Eliminação de Resíduos , Solo
13.
Ecotoxicol Environ Saf ; 271: 115968, 2024 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-38218107

RESUMO

The physicochemical properties, chemical fractions of six metals (Cu, Zn, Pb, Cd, Cr, and Mn), and microbial communities of soil around a typical sanitary landfill were analyzed. The results indicate that soils around the landfill were from neutral to weak alkalinity. The contents of organic matter (OM), total nitrogen (TN), total phosphorous (TP), and activities of catalase, cellulase, and urease were significantly higher in landfill soils than those in background soils. Negative correlations were found between pH and metals. Cr was the dominant metal. Cu, Pb, Cr, and Mn were accumulated in the nearby farmland soils. Cd had the highest percentage of exchangeable fraction (33.7%-51.8%) in landfill and farmland soils, suggesting a high bioavailability to the soil environment affected by the landfill. Pb, Cr, and Mn existed mostly in oxidable fraction, and Cu and Zn were dominant in residual fraction. There was a low risk of soil metals around the landfill based on the RI values, while according to RAC classification, Cd had high to very high environmental risk. The MisSeq sequencing results showed that Actinobacteria, Proteobacteria, Chloroflexi, and Acidobacteria were the dominant phyla of bacteria, and the most abundant phylum of fungi was Ascomycota. The NMDS analysis revealed that the landfill could influence soil fungal communities more intensely than bacterial communities. TN, cellulase, and bioavailable metals (Pb-Bio and Cr-Bio) were identified to have main influences on microbial communities. Pb-Bio was the most dominant driving factor for bacterial community structures. For fungi, Pb-Bio was significantly negatively related to Olpidiomycota and Cr-Bio had a significantly negative correlation with Ascomycota. It manifests that bioavailable metals play important roles in assessing environmental risks and microbial community structures of soil around landfill.


Assuntos
Celulases , Metais Pesados , Microbiota , Poluentes do Solo , Solo/química , Metais Pesados/toxicidade , Metais Pesados/análise , Cádmio/análise , Chumbo/análise , Poluentes do Solo/toxicidade , Poluentes do Solo/análise , Bactérias/genética , Fungos , Instalações de Eliminação de Resíduos , Medição de Risco , China , Monitoramento Ambiental
15.
Waste Manag ; 174: 203-217, 2024 Feb 15.
Artigo em Inglês | MEDLINE | ID: mdl-38061188

RESUMO

Medical waste (MW) is exploding due to the COVID-19 pandemic, posing a significant environmental threat, and leading to the urgent requirement for affordable and environmentally friendly MW disposal technologies. Prior research on individual MW disposal plants is region-specific, applying these results to other regions may introduce bias. In this study, major MW disposal technologies in China, i.e., incineration technologies (pyrolysis incineration and rotary kiln incineration), and sterilization technologies (steam sterilization, microwave sterilization, and chemical disinfection) with residue landfill or incineration were analyzed from an industry-level perspective via life cycle assessment (LCA), life cycle costing (LCC) and net present value (NPV) methods. Life cycle inventories and economic cost data for 4-5 typical companies were selected from 128 distinct enterprises and academic sources for each technology. LCA results show that microwave sterilization with residue incineration has the lowest environmental impact, emitting only 480 kg CO2 eq. LCC and NPV analyses indicate that steam sterilization with landfilling is the most economical, yielding revenues of 1,210 CNY/t and breaking even in the first year. Conversely, pyrolysis and rotary kiln incineration break even between the 4th and 5th years. Greenhouse gas emissions from the MW disposal in ten cities with the largest MW production in 2020 increased by 7% over 2019 to 43,800 tons and other pollutants increased by 6% to 12%. Economically, Shanghai exhibits the highest cost-effectiveness, while Nanjing delivers the lowest. It can be observed that the adoption of optimal environmental technologies has resulted in a diminution of greenhouse gas emissions by 279,000 tons and energy conservation of 1.76 billion MJ.


Assuntos
Gases de Efeito Estufa , Eliminação de Resíduos de Serviços de Saúde , Resíduos de Serviços de Saúde , Eliminação de Resíduos , Gerenciamento de Resíduos , Humanos , Eliminação de Resíduos de Serviços de Saúde/métodos , Cidades , Vapor , Análise Custo-Benefício , Pandemias , China , Incineração/métodos , Instalações de Eliminação de Resíduos , Eliminação de Resíduos/métodos , Gerenciamento de Resíduos/métodos
16.
Waste Manag ; 174: 646-665, 2024 Feb 15.
Artigo em Inglês | MEDLINE | ID: mdl-38159503

RESUMO

Environmental management of solar photovoltaic (PV) modules is attracting attention as a growing number of field-operated PV modules approach end of life (EoL). PV modules may contain small amounts of toxic metals, and the procedures for assessing and regulating the toxic metal content and release of such materials at EoL differ widely across nations. This paper provides an overview of the metal composition of PV modules and common procedures for toxicity assessment through extensive research and review of technical literature and legislative documents. This review focuses on three primary aspects: first, it explores the distribution of toxic elements within current and emerging PV module designs, with a specific focus on obtaining representative samples for proportional toxicity testing within different module laminate areas. Second, it examines a sampling standard and the diverse toxicity testing methods and regulations employed in various regions, encompassing standards like the Environmental Protection Agency (EPA) Test Method 1311 (Toxicity Characteristic Leaching Procedure, TCLP) in the U.S., Restriction of Hazardous Substances (RoHS) in Europe, and the Waste Extraction Test (WET) in California. Third, the review examines the sources of variability in toxicity testing outcomes, including techniques for securing homogeneous samples from non-uniform PV modules, selecting particle sizes representative of landfill conditions in extracted samples, determining appropriate leachate characteristics such as leaching agents and pH levels, and considering factors like test duration and temperatures. In summary, this review summarizes relevant regulations and offers a comprehensive overview of the strengths and limitations associated with several toxicity assessment procedures currently in practice.


Assuntos
Substâncias Perigosas , Metais , Instalações de Eliminação de Resíduos , Europa (Continente)
17.
Waste Manag ; 175: 1-11, 2024 Mar 01.
Artigo em Inglês | MEDLINE | ID: mdl-38103434

RESUMO

Pharmaceutical packaging waste has increased due to a higher global demand for pharmaceutical products, leading to more waste generation and associated environmental impacts. The main goal of this article is to present a cradle-to-grave life cycle assessment of pharmaceutical packaging, evaluating end-of-life (EoL) alternatives, aiming to identify hotspots and opportunities for improvement. A life cycle model was implemented for three types of pharmaceutical packaging (blisters, sachets, bottles; 23 packaging). The functional unit is the storage and delivery of medicines containing the same active pharmaceutical ingredient, dosage, and amount of medicines. Two EoL analyses were performed: 1) compare take-back (recycling and incineration) with domestic waste collection (landfill or incineration); and 2) assess different EoL situations of pharmaceutical packaging in Europe. A life cycle impact assessment was performed for 13 categories. Analysis 1 shows that take-back presents lower environmental impacts than domestic waste collection for seven out of 13 categories due to paper and glass recycling benefits. Analysis 2 shows that in the take-back, higher amounts of packaging are recycled or incinerated, which leads to lower EoL impacts. A sensitivity analysis was performed to evaluate the influence of parameters and assumptions in packaging EoL impacts. Packaging production contributes significantly to life cycle impacts, followed by transportation, EoL, and packing process. Ecodesign initiatives are recommended, such as packaging with less material and volume, using materials with lower impacts to significantly reduce the impacts of pharmaceutical packaging.


Assuntos
Eliminação de Resíduos , Gerenciamento de Resíduos , Animais , Preparações Farmacêuticas , Reciclagem , Instalações de Eliminação de Resíduos , Incineração , Embalagem de Produtos , Estágios do Ciclo de Vida
18.
Waste Manag ; 172: 320-325, 2023 Dec 01.
Artigo em Inglês | MEDLINE | ID: mdl-37939603

RESUMO

In this study, we simulated the actual landfill disposal process using accelerated carbonization experiments, based on the leaching characteristics of heavy metals from "alkaline" fly ash, and used the LandSim-HELP coupling model to assess the environmental risk of the leaching. The results showed that the leaching data of "alkaline" fly ash before carbonization showed the illusion of admission to landfill with only a small amount of chemical addition or even without curing/stabilization. The leached concentrations of Zn and Cd from "alkaline" fly ash after carbonation were significantly higher. The risk assessment of the leakage of heavy metals in the case of a single artificial composite liner system showed that the exposure concentrations of Pb, Zn, and Cd in samples exceeded Standard for groundwater quality (GB/T 14848-2017) the Class III permissible limits after carbonation; exposure risk for Cd was exceeded in all samples. However, although the use of a double-layer artificial composite liner to improve the level of impermeability effectively reduced the risk of Cd leaching, so that none of the non-carcinogenic risks exceeded the standard, the carcinogenic risk of Cd in the carbonized samples exceeded the factor of 1.1-4.5 of the acceptable hazard quotient, and the contamination characteristics of the alkaline fly ash still need to be kept in view.


Assuntos
Metais Pesados , Eliminação de Resíduos , Cinza de Carvão , Cádmio , Incineração , Medição de Risco , Instalações de Eliminação de Resíduos , Carbono , Material Particulado , Eliminação de Resíduos/métodos
19.
Environ Sci Pollut Res Int ; 30(60): 125965-125976, 2023 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-38008831

RESUMO

The main aim of this study is to investigate the material and monetary flows of CDW management and to characterize the distribution of illegally dumped CDW in Hanoi. Construction and demolition waste management has become a source of much concern to the urban authorities and citizens of big cities in Vietnam. It is estimated that 3000 t of CDW were generated per day from construction and demolition activities in Hanoi, but only 45% of the CDW was received at official landfills, while 55% of the CDW was disposed of elsewhere. The consequences of improper waste management are potentially alarming. The study conducted interviews to identify the material and cash flow associated with licensed and unlicensed contractors in CDW classification, transportation, treatment, and disposal, to characterize the distribution of illegally dumped CDW in two districts in Hanoi (urban and suburban districts), and to assess the composition of dumped CDW and environmental assessment of illegally dumped CDW by chemical analyses such as leaching and content tests. The study concluded that illegal dumping was performed mostly by unlicensed private companies. The illegally dumped CDW was mostly composed of mixed materials such as concrete, bricks, stones, and some hazardous materials such as asbestos and gypsum were found. The environmental concern of illegally dumped CDW was mostly dust, blockage of water ways, and inundation of increased suspended solids, whereas the heavy metal leaching concentration of all samples was below the environmental standards in Vietnam.


Assuntos
Indústria da Construção , Metais Pesados , Gerenciamento de Resíduos , Materiais de Construção/análise , Instalações de Eliminação de Resíduos , Metais Pesados/análise , Reciclagem , Resíduos Industriais/análise
20.
J Environ Manage ; 348: 119300, 2023 Dec 15.
Artigo em Inglês | MEDLINE | ID: mdl-37862889

RESUMO

Landfill mining has received major attention in recent years for the reclamation of waste disposal sites, including in developing countries such as India where significant efforts are being made to manage sites in this way. The bulk of the material obtained from landfill mining consists of fine-grained soil-like material (SLM) but its direct reuse in off-site applications is restricted due to the presence of harmful heavy metals, soluble salts and other pollutants. In this study, appropriate techniques for managing SLM to permit recovery and reuse are assessed. As a result, experimental investigation explores the efficacy of two remediation techniques considered appropriate for SLM management: electrokinetic remediation and phytoremediation. These were applied to SLM from a recently mined landfill and their ability to reduce heavy metal and other soluble salt burdens assessed. Electrokinetic remediation has shown considerable potential to mobilise and transport heavy metals and soluble salts through and from the SLM over an eight-week period. Phytoremediation experiments also demonstrated mobilisation and uptake of metals from the SLM over a similar duration although relatively low amounts were recovered as a result of the low biomass produced over this period. Both technologies have demonstrated potential for recovery of metals from SLM, as well as recovering the SLM itself as a potential resource.


Assuntos
Metais Pesados , Poluentes do Solo , Solo , Sais , Instalações de Eliminação de Resíduos , Mineração , Biodegradação Ambiental
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