A comprehensive assessment of the economic and technical viability of a zero liquid discharge (ZLD) hybrid desalination system for water and salt recovery.

Brine, a by-product of desalination and industrial facilities, is becoming more and more of an environmental issue. This comprehensive techno-economic assessment (TEA), focusing on the technical and economic aspects, investigates the performance and viability of a novel hybrid desalination brine treatment system known as zero liquid discharge (ZLD). Notably, this research represents the first instance of evaluating the feasibility and effectiveness of integrating three distinct desalination processes, namely brine concentrator (BC), high-pressure reverse osmosis (HPRO), and membrane-promoted crystallization (MPC), within a ZLD framework. The findings of this study demonstrate an exceptional water recovery rate of 97.04%, while the energy requirements stand at a reasonable level of 17.53 kWh/m3. Financially, the ZLD system proves to be at least 3.28 times more cost-effective than conventional evaporation ponds and offers comparable cost efficiency to alternatives such as land application and deep-well injection. Moreover, the ZLD system exhibits profitability potential by marketing both drinking water and solid salt or solely desalinated water. The daily profit from the sale of generated water varies from US$194.08 to US$281.41, with Greece and Cyprus attaining the lowest and highest profit, respectively. When considering the sale of both salt and water, the profit rises by 8% across all locations.

Evaluation of enhanced nanofiltration membranes for improving magnesium recovery schemes from seawater/brine: Integrating experimental performing data with a techno-economic assessment.

The global demand for valuable metals and minerals necessitates the exploration of alternative, sustainable approaches to mineral recovery. Seawater mining has emerged as a promising option, offering a vast reserve of minerals and an environmentally friendly alternative to land-based mining. Among the various techniques, Nanofiltration (NF) has gained significant attention as a preliminary treatment step in Minimum Liquid Discharge (MLD) and Zero Liquid Discharge (ZLD) schemes. This study focused on the potential of two underexplored commercial polyamide based NF membranes, Synder NFX and Vontron VNF1, with enhanced divalent over monovalent separation factors, in optimizing the extraction of magnesium hydroxide (Mg(OH)2) from seawater and seawater reverse osmosis (SWRO) brines. The research encompassed a thorough characterization of the membranes utilizing advanced physic-chemical analytical techniques, followed by rigorous experimental assessments using synthetic seawater and SWRO brine in concentration configuration. The findings highlighted the superior selectivity of NFX for magnesium recovery from SWRO brine and the promising concentration factors of VNF1 for seawater treatment. Cross-validation of experimental data with a mathematical model demonstrated the model's reliability as a process design tool in predicting membrane performance. A comprehensive techno-economic evaluation demonstrates the potential of NFX, operating optimally at 23 bar pressure and 70% permeate recovery rate, to yield an estimated annual revenue of 5.683 M€/yr through Mg(OH)2 production from SWRO brine for a plant with a nominal capacity of 0.8 Mm3/y. This research shed light on the promising role of NF membranes in enhancing mineral recovery taking benefit of their separation factors and emphasizes the economic viability of leveraging NF technology for maximizing magnesium recovery from seawater and SWRO brines.

Reclaimed seawater discharge - Desalination brine treatment and resource recovery system.

With the proliferation of reverse osmosis technology, seawater reverse osmosis desalination has been heralded as the solution to water scarcity for coastal regions. However, the large volume of desalination brine produced may pose an adverse environmental impact when directly discharged into the sea and result in energy wastage as the seawater pumped out is dumped back into the sea. Recently, zero liquid discharge has been extensively studied as a way to eliminate the aquatic ecotoxicity impact completely, despite being expensive and having a high carbon footprint. In this work, we propose a new strategy towards the treatment of brine to seawater level for disposal, dubbed reclaimed seawater discharge (RSD). This process is coupled with existing resource recovery techniques and waste alkali CO2 capture processes to produce an economically viable waste treatment process with minimal CO2 emissions. In this work, we placed significant focus on the electrolysis of brine, which simultaneously lowers the salinity of the desalination brine (56.0 ± 2.1 g/L) to seawater level (32.0 ± 1.4 g/L), generates alkali brine from seawater (pH 13.6) to remove impurities in brine (Mg2+ and Ca2+ to below ppm level), and recovers magnesium hydroxide, calcium carbonate, chlorine, bromine, and hydrogen gas as valuable resources. The RSD is further chemically dechlorinated and neutralised to pH 7.3 to be safe to discharge into the sea. The excess alkali brine is used to capture additional CO2 in the form of bicarbonates, achieving net abatement in climate change impact (9.90 CO2 e/m3) after product carbon abatements are accounted.

On the evaluating membrane flux of forward osmosis systems: Data assessment and advanced intelligent modeling.

As an emerging desalination technology, forward osmosis (FO) can potentially become a reliable method to help remedy the current water crisis. Introducing uncomplicated and precise models could help FO systems' optimization. This paper presents the prediction and evaluation of FO systems' membrane flux using various artificial intelligence-based models. Detailed data gathering and cleaning were emphasized because appropriate modeling requires precise inputs. Accumulating data from the original sources, followed by duplicate removal, outlier detection, and feature selection, paved the way to begin modeling. Six models were executed for the prediction task, among which two are tree-based models, two are deep learning models, and two are miscellaneous models. The calculated coefficient of determination (R2 ) of our best model (XGBoost) was 0.992. In conclusion, tree-based models (XGBoost and CatBoost) show more accurate performance than neural networks. Furthermore, in the sensitivity analysis, feed solution (FS) and draw solution (DS) concentrations showed a strong correlation with membrane flux. PRACTITIONER POINTS: The FO membrane flux was predicted using a variety of machine-learning models. Thorough data preprocessing was executed. The XGBoost model showed the best performance, with an R2 of 0.992. Tree-based models outperformed neural networks and other models.

The potential of electrodialysis as a cost-effective alternative to reverse osmosis for brackish water desalination.

While electrodialysis (ED) demonstrates lower energy consumption than reverse osmosis (RO) in the desalination of low salinity waters, RO continues to be the predominant technology for brackish water desalination. In this study, we probe this skewed market share and project the potential for future disruption by ED through systematic assessment of the levelized cost of water (LCOW). Using rigorous process- and economic-models, we minimize the LCOW of RO and ED systems, highlighting important tradeoffs between capital and operating expenditure for each technology. With optimized current state-of-the-art systems, we find that ED is more economical than RO for feed salinities ≤ 3 g L-1, albeit to a minor extent. Considering that RO is a highly mature technology, we focus on predicting the future potential of ED by evaluating plausible avenues for capital and operating cost reduction. Specifically, we find that reduction in the price of ion-exchange membranes (i.e., < 60 USD m-2) can ensure competitiveness with RO for feed salinities up to 5 g L-1. For higher feed salinities (≥ 5 g L-1) we reveal that the LCOW of ED may effectively be reduced by decreasing ion-exchange membrane resistance, while preserving high current efficiency. Through extensive assessment of structure-property-performance relationships, we precisely identify target membrane charge densities and diffusion coefficients which optimize the LCOW of ED, thus providing novel guidance for future membrane material development. Overall, we emphasize that with a unified approach - whereby ion-exchange membrane price is reduced and performance is enhanced - ED can become the economically preferable technology compared to RO across the entire brackish water salinity range.

Energy behaviour and economic analysis of a photovoltaic-thermal (PV/T) collector coupled with a reverse osmosis (RO) desalination unit in Tunisian climatic conditions: a feasibility study.

Water scarcity affects about one billion people in the world. Around two billion people could be living in water-stressed areas by 2050. For this reason, the desalination is always evolving due to the importance of the water resources found in the seas and brackish water. As these systems are generally energy intensive, the use of a renewable energy source is among the most appropriate solution. In this paper, both experimental and numerical investigations have been conducted to evaluate the performances and the economic viability of a photovoltaic-thermal collector intended to supply a reverse osmosis (RO) unit. Experimental study is based on the input-output and dynamic system testing (DST) according to ISO 9459-5 standard method and computations use the energy and mass balances of the PV/T collector and the RO plant. Results of DST testing showed that the loss coefficient of the PV/T, the tank loss coefficient and the total tank heat capacity are 10.46 W.m-2.K-1, 1.596 W.K-1 and 388 MJ.K-1, respectively. The ability to couple the RO technology to PV/T systems has been demonstrated. The complete system has been simulated for a water salinity of 10,000 ppm and climatic data of Borj-Cedria (Tunisia) site (longitude 10° 25' 41″ E and latitude 36° 43' 04″ N). Numerical investigations showed that the electricity needs of a small off-grid desalination unit could be met by using a 6.48 m2 PV/T panel surface area. In this case, the purified water produced has a salinity of 1500 ppm and the flow rate is 24,000 l/day. For a grid connected site, the produced and auxiliary powers are found to be equal to 54% and 21%, respectively. Moreover, the economic cost of adding a PV/T system into an existing RO unit has been evaluated and the results showed that the payback period is 6 years.

Probabilistic human health risk assessment of trace elements in ballast water treated by reverse osmosis desalination plants.

Very few studies have paid attention to the transport of heavy and toxic metals via ballast water coming from different countries of the world. In the present study, ballast water samples (n = 83) were collected from ships, tankers and vessels of 21 different origins arriving at the two main ports of Qatar. Besides the basic physical parameters of pH, electrical conductivity (EC), and total organic carbon (TOC), concentrations of 24 elements (As, Sb, Al, Cd, Pb, Si, V, Ag, Zn, Cr, Mn, Ba, Co, Ni, Sr, Be, Cu, Tl, B, Fe, Se, Sn, Mo and U) were determined. In addition, the potential human health risks of drinking water treated by reverse osmosis (RO) were assessed using Monte Carlo simulations. Two scenarios were used to assess the risks to the general population, namely, seawater (baseline) and ballast water (worst-case scenario). Our results show significant differences among the tested elements, depending on the origin of the ballast water. The human health assessment showed that all hazardous quotients (HQs) were below the safety limits. However, for the ballast water scenario, thallium (Tl) HQs were 10 % above the safety level. Ballast water in Qatar does not pose risks for human health through drinking water, but ballast water discharges should take into consideration seawater catchments and potential toxic elements, especially Tl. Regular monitoring campaigns need to be performed.

Techno-economic assessment of a novel algal-membrane system versus conventional wastewater treatment and advanced potable reuse processes: Part II.

This study developed a comprehensive techno-economic assessment (TEA) framework to evaluate an innovative algae resource recovery and near zero-liquid discharge potable reuse system (i.e., the main system) in comparison with a conventional potable water reuse system (i.e., the benchmark system). The TEA study aims to estimate the levelized costs of water of individual units and integrated processes including secondary wastewater treatment, advanced water purification for potable reuse, and sludge treatment. This would provide decision-makers valuable information regarding the capital and operational costs of the innovative main system versus a typical potable water reuse treatment train, along with possible routes of cost optimization and improvements for the design of full-scale facilities. The main system consists of (i) a novel algal-based wastewater treatment coupled with a dual forward osmosis and seawater reverse osmosis (Algal FO-SWRO) membranes system for potable water reuse and hydrothermal liquefaction (HTL) to produce bioenergy and subsequent nutrients extraction from the harvested algal biomass. The benchmark system includes (ii) an advanced water purification facility (AWPF) that consists of a conventional activated sludge biological treatment (CAS), microfiltration (MF), brackish water reverse osmosis (BWRO), ultraviolet/advanced oxidation process (UV-AOP), and granular activated carbon (GAC), with anaerobic digestion for sludge treatment. Capital expenditures (CAPEX) and operational expenditures (OPEX) were calculated for each unit of both systems (i.e., sub-systems). Based on a 76% overall water recovery designed for the benchmark system, the water cost was estimated at $2.03/m3. The highest costs in the benchmark system were found on the CAS and the anaerobic digester, with the UV-AOP combined with GAC for hydrogen peroxide (H2O2) quenching as the driving factor in the increased costs of the system. The cost of the main system, based on an overall 88% water recovery, was estimated to be $1.97/m3, with costs mostly driven by the FO and SWRO membranes. With further cost reduction and optimization for FO membranes such as membrane cost, water recovery, and flux, the main system can provide a much more economically viable alternative in its application than a typical benchmark system.

Membrane-based water and wastewater treatment technologies: Issues, current trends, challenges, and role in achieving sustainable development goals, and circular economy.

Membrane-based technologies are recently being considered as effective methods for conventional water and wastewater remediation processes to achieve the increasing demands for clean water and minimize the negative environmental effects. Although there are numerous merits of such technologies, some major challenges like high capital and operating costs . This study first focuses on reporting the current membrane-based technologies, i.e., nanofiltration, ultrafiltration, microfiltration, and forward- and reverse-osmosis membranes. The second part of this study deeply discusses the contributions of membrane-based technologies in achieving the sustainable development goals (SDGs) stated by the United Nations (UNs) in 2015 followed by their role in the circular economy. In brief, the membrane based processes directly impact 15 out of 17 SDGs which are SDG1, 2, 3, 5, 6, 7, 8, 9, 11, 12, 13, 14, 15, 16 and 17. However, the merits, challenges, efficiencies, operating conditions, and applications are considered as the basis for evaluating such technologies in sustainable development, circular economy, and future development.

Combined reverse osmosis and UV/H2O2 treatment of aqueous solutions of bisphenol A and 17α-ethinylestradiol: assessment of estrogenic activity.

Bisphenol-A (BPA) and 17α-ethinylestradiol (EE2) are considered endocrine disrupting compounds (EDC) and they may be harmful to the normal functioning of endocrine systems of humans and animals. Moreover, the presence of these compounds in superficial and groundwater may represent serious risks, even in low concentrations like ng·L-1. The objectives of this study were to remove BPA and EE2 from solutions containing a mixture of these compounds in ultrapure water at low concentrations through reverse osmosis (RO) membrane combined with a UV/H2O2 process. Furthermore, to assess the estrogenic activity reduction after such treatments, in vitro recombinant yeast-estrogen screen (YES) assay was used. The removal efficiencies of target micropollutants increased with the increase of H2O2 dosage. For RO permeate stream, they enhanced from 91% to 96% for EE2 and from 76% to 90% for BPA while, for the concentrate stream, from 70% to 81% for EE2 and 41% to 84% for BPA as the H2O2 concentration were increased from 100 to 1000 µg·L-1. The OH radicals' generation was the dominant factor in the degradation of EDC during the UV/H2O2 treatment since the photolysis itself was not enough to degrade BPA or EE2. The estrogenic activity reduction after UV/H2O2 treatment was high, ranging from 92% to 98% for the permeate stream and from 50% to 93% for the concentrate stream. The EE2 was responsible for the whole observed estrogenic activity since BPA does not present estrogenicity, by in vitro YES assay, in the concentrations observed.

Economic feasibility of solar-powered reverse osmosis water desalination: a comparative systemic review.

Due to disparities in the allocation of rainwater and drought, extreme exploitation of groundwater reservoirs has depleted water supplies in many locations. In addition, improper disposal of domestic and industrial waste leads to poor drainage and deterioration of water quality. According to studies, desalination methods are an effective solution for treating unconventional water, i.e., sea and brackish water, and making it usable in daily life. Solar-powered desalination has recently received a great deal of attention around the world. Herein, we summarized challenges and future perspectives associated with solar-powered desalination units. Some hybrid technologies are also discussed like solar-wind desalination and RO-ED crystallizer technology in Morocco and the Middle East and North Africa (MENA) region. Previously, most experimental studies focused on the use of solar energy in traditional desalination methods such as multistage flash and multi-effect distillation. Desalination with reverse osmosis has become popular due to membrane technology improvement and benefits like high recovery ratios and low energy consumption. Furthermore, it has been seen that solar energy is less expensive than the energy obtained from traditional fuels in the MENA area. This article aims to comparatively and systematically review the economic feasibility of the use of solar photovoltaic reverse osmosis in desalination in the MENA region.

Biofouling of reverse osmosis membranes: assessment by surface-enhanced Raman spectroscopy and microscopic imaging.

The decline in the performance of spiral-wound reverse osmosis (SWRO) membranes is frequently due to biofouling. This study focus on qualitative and quantitative diagnosis of SWRO membrane biofouling. Bacterial counts on the different surfaces of the fouled membranes were carried out. Surface enhanced Raman spectroscopy (SERS) was performed to highlight clogging materials as well as their natures and identity. The topography of the fouled membranes and the structures of biofilms were visualized by fluorescence microscopy (FM) and scanning electron microscopy (SEM). The results indicated the presence of bacteria in the different SWRO membrane areas. Those strongly adhered were significantly higher than those weakly. It varied between 26 × 105 and 262 × 105 CFU m-2. However, SERS mapping showed different fouling levels and the thickness of the fouling layer was 5 µm. Microscopic imaging revealed biotic and abiotic deposits. These data can together allow better management of the seawater desalination process.

Decarbonized and circular brine management/valorization for water & valuable resource recovery via minimal/zero liquid discharge (MLD/ZLD) strategies.

Brine (saline wastewater/water) from desalination, salt lakes, and industrial activities (e.g., pharmaceutical industries, oil & gas industries) has received a lot of attention around the world due to its adverse impact on the environment. Currently, several disposal methods have been applied; however, these methods are nowadays unsustainable. To tackle this problem, brine treatment and valorization is considered a promising strategy to eliminate brine discharge and recover valuable resources such as water, minerals, salts, metals, and energy. Brine valorization and resource recovery can be achieved via minimal and zero liquid discharge (MLD & ZLD) desalination systems. Commercially successful technologies such as reverse osmosis (RO) and distillation cannot be adopted as standalone technologies due to restrictions (e.g., osmotic pressure, high-energy/corrosion). Nonetheless, novel technologies such as forward osmosis (FO), membrane distillation (MD) can treat brine of high salinity and present high recovery rates. The extraction of several ions from brines is technically feasible. The minerals/salts composed of major ions (i.e., Na+, Cl-, Mg2+, Ca2+) can be useful in a variety of sectors, and their sale prices are reasonable. On the other hand, the extraction of scarce metals such as lithium, rubidium, and cesium can be extremely profitable as their sale prices are extremely higher compared to the sale prices of common salts. Nonetheless, the extraction of such precious metals is currently restricted to a laboratory scale. The MLD/ZLD systems have high energy consumption and thus are associated with high GHGs emissions as fossil fuels are commonly burned to produce the required energy. To make the MLD/ZLD systems more eco-friendly and carbon-neutral, the authors suggest integrating renewable energy sources such as solar energy, wind energy, geothermal energy, etc. Besides water, minerals, salts, metals, and energy can be harvested from brine. In particular, salinity gradient power can be generated. Salinity gradient power technologies have shown great potential in several bench-scale and pilot-scale implementations. Nonetheless, several improvements are required to promote their large-scale feasibility and viability. To establish a CO2-free and circular global economy, intensive research and development efforts should continue to be directed toward brine valorization and resource recovery using MLD/ZLD systems.

Identification of cost and energy effective seawater membranes for use under hot climate conditions.

Seawater desalination using a cost-effective reverse osmosis system is crucial for hot climate countries suffering from water scarcity. The most favorable seawater membrane characteristics were identified under typical Egyptian operating conditions. Twelve different commercially available membrane elements were investigated. A reverse osmosis system was designed and simulated using available software (e.g., ROSA and IMSDesign). The characteristics of the most promising membranes were identified for operation at Matruh (Mediterranean Sea) and Sharm El-Sheikh (Red Sea). The present work shows that the lowest cost of seawater desalination is obtained with membranes having high salt rejection, high permeate flow, high membrane active area, and permeate flux greater than 0.914 m3 /(d·m2 ). Moreover, the cost of seawater desalination in summer is lower than in winter by 5% for Matruh and 2.7% for Sharm El-Sheikh. However, the impact of water salinity on the cost and specific energy consumption is higher than that of the seawater temperature. The cost of Mediterranean seawater desalination is lower than that of the Red Sea by 10.6%. Cost analysis at five different locations in Egypt shows that the highest cost takes place at Suez (Gulf of Suez), and the lowest cost occurs at Matruh (Mediterranean Sea). PRACTITIONER POINTS: Twelve different membranes were investigated for use under typical hot climate conditions. The cost of seawater reverse osmosis (RO) desalination is lower in summer by 2.7%-5% compared with winter. RO desalination costs up to 10.6% less for the Mediterranean Sea compared with the Red Sea. The optimum membrane element performance characteristics were identified for use under hot climate conditions.

Possibility assessment of ultrafiltration membrane pre-treatment efficiency for brackish water reverse osmosis-based wastewater reuse: Lab and demonstration.

Ultrafiltration (UF) membranes are considered a pre-treatment for brackish water reverse osmosis (BWRO) membranes because of the high rejection rate of particulates and the productivity of the final water quantity. This study presents the performance and membrane surface property analysis of UF membranes for commercial membrane manufacturers, and their structural strength and chemical resistance were evaluated. Moreover, the pilot-scale UF-BWRO process was operated for two months using real wastewater based on the results of this study. Although the overall properties were similar, the poly (ether-sulfone) UF membrane showed higher tensile strength than the polyvinylidene difluoride and polyacrylonitrile UF membranes. The UF membrane showed a high removal rate of particulates (over 90%) but low rejection rate of organic compounds, such as humic acid and sodium alginate (below 30%). After exposure to high concentrations of chemicals, the contact angle of the membranes was reduced by approximately 15% compared to that of the virgin membranes. In addition, despite the exposure to low-and high-concentration chemicals, UF membranes were relatively stable in terms of tensile strength. During the operation period of the pilot-scale UF-RO process, the UF membrane showed a high turbidity removal of over 93%, and the UF-BWRO process presented a high salt rejection of over 92%. The UF membrane showed potential for the pre-treatment of BWRO membranes.

Exploring energy-saving potentials in seawater desalination engineering from the energy-water nexus perspective.

With the rapid population growth and economic development, the necessity to explore energy-saving potentials in typical seawater desalination project is increasingly essential. Taking the Reverse Osmosis (RO) seawater desalination project in Hebei Province, China as a case, this study performed systematic accounting framework combining the direct and indirect energy consumption from the energy-water nexus perspective, and carried out the energy-saving potential assessment and systematical optimization configuration. From the results, the total direct energy consumption of the project was 2.23 × 106 kWh, and the total embodied energy consumption was 2.18 × 107 kWh. Define the embodied energy consumption (ESE) as an evaluation index of energy saving potentials, the energy consumption degree before optimization is 79.54%, which could be reduced to 26.30% after optimization. The results showed that the systematic accounting framework in this study can greatly improve the accuracy of energy consumption measurement in the project, and the systematical optimization configuration can significantly reduce energy consumption and improve the energy-saving design under the minimum investment in the seawater desalination projects.

Membrane biorreactor, reverse osmosis and UV/H2O2 process integration for ethinylestradiol removal: A cost-benefit analysis.

The presence of 17α-ethinylestradiol (EE2) in water bodies and its potential risks to human health and the environment have been frequently described in the literature, in addition to its limited removal in conventional wastewater treatment plants. Many studies have evaluated this removal by advanced processes, including photodegradation and membrane separation. A significant number of studies also assess the economic analysis of these technologies. However, few works articulate both perspectives: the specificity involved in estrogen removal and economic analysis. Given this gap, this work evaluates the synergies involved in the integration of reverse osmosis (RO) and advanced oxidative processes by UV/H2O2 (AOP) in the post-treatment of membrane bioreactor (MBR) effluents. To this end, the integrated plant possibilities were represented through a superstructure that integrated EE2 removal and cost models of each process. The use of a Hook and Jeeves optimizer considering these processes standard operating conditions made it possible to determine the percentage of stream division for each equipment and even the absence of any of these in an integrated plant with lower cost and EE2 concentration output below the recommended limit by the European Union (0.035 ng.L-1). For EE2 feed content up to 3 ng.L-1, the lowest cost configuration is to route 20% of the MBR effluent to the AOP, 30% to the RO, and the remainder to a final mixer. For concentrations above 15 ng.L-1, the sufficient and lowest cost configuration is the MBR-RO-AOP series. Intermediate values have a more advantageous integrated process configuration with the parallel and series configurations combined, with a stream distribution dependent on the feed concentration. Moreover, a parameter sensitivity analysis was performed, clarifying paths for design improvements and acting as a systematic guide for future work in this area. This analysis highlights that EE2 removal is more sensitive to temperature (1.04%), feed substrate concentration (-1.18%), solid retention time in the MBR (0.32%), and irradiance in AOP (-0.46%). Investment costs also proved to be decisive in the composition of the total cost, enhancing the relevance of the maturation process of these technologies in light of simple changes in operating parameters.

Techno-economic assessment of decentralized polishing schemes for municipal water reclamation and reuse in the industrial sector in costal semiarid regions: The case of Barcelona (Spain).

This study demonstrates the techno-economic reliability of an innovative fit-for-use treatment train to boost municipal reclaimed water reuse fore industrial uses in the Barcelona Metropolitan Area (BMA). The relatively high conductivity (2090 µS/cm) and hardness (454 mg/L) of reclaimed water in the BMA (e.g. Water Reclamation Plant (WRP) of El Baix Llobregat, Barcelona, Spain), together with the restrictive water quality demands in industrial uses, claims for the implementation of advanced reclamation schemes based on desalination technologies such as reverse osmosis (RO). The study assesses the benefits of two potential pre-treatments of the RO stage: (i) ultrafiltration (UF) or (ii) an innovative high-performance nano-structured polymeric adsorbent (CNM); in which a permeability decline of 5% was observed when CNM was used as a pre-treatment, while a stable permeability of RO was found when was fed by the UF effluent. On the other hand, generic cost curves have been calculated for the technologies evaluated and were applied to estimate capital and operational expenditures (CAPEX and OPEX) for the scale-up in three different industrial sites (e.g., chemical, waste management and electro-coating industries). The economic assessment indicates that the use of municipal reclaimed water is economically competitive in front of the use of tap water in the BMA, providing savings between 0.13 and 0.52 €/m3 for the waste management industry and between 0.49 and 0.98 €/m3 for the electrocoating industry. On the other hand, the use of groundwater in one of the industrial sites and its relatively low cost implied that, although it is necessary a RO, the current cost of water is significantly lower.

Assessment of fouling mechanisms on reverse osmosis (RO) membrane during permeation of 17α-ethinylestradiol (EE2) solutions.

Fouling mechanisms are mainly caused by the deposition of organic compounds that reduce the removal efficiency on reverse osmosis (RO) membranes. It can be described by mathematical models. The aim of this study was to evaluate the membrane fouling and rejection mechanisms when aqueous solutions containing 17α-ethinylestradiol (EE2) in different concentrations are permeated at 5 and 10 bar in a bench-scale dead-end RO system. Adsorption tests were performed and the fouling mechanism was assessed by Hermia's model for solutions of EE2 at concentrations typically found in the environment (µg L-1). Fourier transform infrared spectroscopy (FTIR) has indicated the presence of EE2 on the fouled membrane surface. Membrane rejection of EE2 ranged from 90% to 98% and the main rejection mechanism was size exclusion at all experimental conditions. However, for the higher concentration of EE2 permeated at 5 and 10 bar, adsorption of 7 and 32 mg m-2, respectively, also took place. The rejection was influenced by fouling and concentration polarisation. Fouled membranes present higher rejection of hydrophobic neutral compounds and the concentration polarisation reduces rejection. Hermia's model demonstrated that the permeation values fitted better the standard blocking filtration and cake filtration equations for describing fouling mechanism. This study showed that fouling also occurs in the TFC RO membrane after permeation of EE2, which corroborates with studies using other pollutants.

Membrane distillation crystallization technology for zero liquid discharge and resource recovery: Opportunities, challenges and futuristic perspectives.

Water resources are getting limited, which emphasises the need for the reuse of wastewater. The conventional waste(water) treatment methods such as reverse osmosis (RO) and multi-effect distillation (MED) are rendered limited due to certain limitations. Moreover, the imposition of stringent environmental regulations in terms of zero liquid discharge (ZLD) of wastewater containing very high dissolved solids has assisted in developing technologies for the recovery of water and useful solids. Membrane distillation crystallization (MDCr) is an emerging hybrid technology synergising membrane distillation (MD) and crystallization, thus achieving ZLD. MDCr technology can be applied to desalinate seawater, treat nano-filtration, and RO reject brine and industrial wastewater to increase water recovery and yield useful solids. This manuscript focuses on recent advances in MDCr, emphasizing models that account for application in (waste)water treatment. MDCr has dual benefits, first the environmental conservation due to non-disposal of wastewater and second, resources recovery proving the proverb that waste is a misplaced resource. Limitations of standalone MD and crystallization are discussed to underline the evolution of MDCr. In this review, MDCr's ability and feasibility in the treatment of industrial wastewater are highlighted. This manuscript also examines the operational issues, including crystal deposition (scaling) on the membrane surface, pore wetting phenomenon and economic consequences (energy use and operating costs). Finally, opportunities and future prospects of the MDCr technology are discussed. MDCr technology can amplify natural resources availability by recovering freshwater and useful minerals from the waste stream, thus compensating for the relatively high cost of the technology.