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1.
Bull Environ Contam Toxicol ; 112(5): 75, 2024 May 11.
Artigo em Inglês | MEDLINE | ID: mdl-38733395

RESUMO

This study systematically investigated the pollution levels and migration trends of PBDEs in soils and plants around engineering plastics factory, and identified the ecological risks of PBDEs in the environment around typical pollution sources.The results showed that 13 kinds of PBDEs were widely detected in the surrounding areas, and the concentration level was higher than the general environmental pollution level. The total PBDE concentrations (∑13PBDEs) in soils ranged from 14.6 to 278.4 ng/g dry weight (dw), and in plants ranged from 11.5 to 176 ng/g dw. Both soil and plant samples showed that BDE-209 was the most important congener, the pollution level in soil and plant was similar, and the composition of PBDEs congener was similar. In the soil column (50 cm), the radial migration of PBDEs was mainly concentrated in the 0-30 cm section. Except for BDE-66, which was mainly located in the 20-30 cm soil layer, the concentration of PBDEs was the highest in the 0-10 cm region. Furthermore, the environmental risks of PBDEs in soil and plants were evaluated by hazard quotient method, and the HQ values were all < 1, which did not exhibit any ecological risk. The evaluation results also showed that the ecological risk of PBDEs in soil was higher than that of plants, especially penta-BDE, which should be paid more attention.


Assuntos
Monitoramento Ambiental , Éteres Difenil Halogenados , Plásticos , Poluentes do Solo , Solo , Éteres Difenil Halogenados/análise , Poluentes do Solo/análise , Medição de Risco , Solo/química , Plásticos/análise , Plantas , China
2.
Water Environ Res ; 96(5): e11033, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-38720414

RESUMO

The escalating issue of microplastic (MP) pollution poses a significant threat to the marine environment due to increasing plastic production and improper waste management. The current investigation was aimed at quantifying the MP concentration on 25 beaches on the Maharashtra coast, India. Beach sediments (1 kg) were collected from each site, with five replicates to evaluate the extent of MPs. The samples were homogenized, and three 20 g replicas were prepared for subsequent analysis. Later, the samples were sieved, and MPs were extracted using previously published protocols. The abundance of MPs found as 1.56 ± 0.79 MPs/g, ranges from 0.43 ± 0.07 to 3 ± 0.37 MPs/g. Fibers were found as the most abundant shape of MPs. Size-wise classification revealed dominance of <1 mm and 1-2 mm-sized MPs. Blue- and black-colored MPs were recorded dominantly. Polymer identification of MPs revealed polyurethane, polypropylene, polyvinyl chloride, acrylic or polymethyl methacrylate, and rubber. The findings revealed that MPs were found to be higher at highly impacted sites, followed by moderately impacted sites and low-impacted sites, possibly due to a different degree of anthropogenic pressure. The study recommended the urgent need for effective policy to prevent plastics accumulation in the coastal environment of Maharashtra State, India. PRACTITIONER POINTS: The study investigated the abundance and distribution of microplastics in the marine environment, specifically in sediments. The most common type of microplastic found was fibers, followed by fragments and films. Microplastics were found to pose a potential risk to the marine ecosystem, although further research is needed to fully understand their ecological impact. Future research should focus on expanding the sample size, assessing long-term effects, exploring sources and pathways, and considering size and shape of microplastics. The findings recommended urgent action to mitigate plastic pollution in Maharashtra coast.


Assuntos
Praias , Monitoramento Ambiental , Sedimentos Geológicos , Microplásticos , Índia , Microplásticos/análise , Sedimentos Geológicos/química , Poluentes Químicos da Água/análise , Poluentes Químicos da Água/química , Plásticos/química , Plásticos/análise
3.
J Contam Hydrol ; 263: 104339, 2024 04.
Artigo em Inglês | MEDLINE | ID: mdl-38564944

RESUMO

Plastic particles, measuring <5 mm in size, mainly originate from larger plastic debris undergoing degradation, fragmenting into even smaller fragments. The goal was to analyze the spatial diversity and polymer composition of microplastics (MPs) in North Chennai, South India, aiming to evaluate their prevalence and features like composition, dimensions, color, and shape. In 60 sediment samples, a combined count of 1589 particles were detected, averaging 26 particles per 5 g-1 of dry sediment. The water samples from the North Chennai vicinity encompassed a sum of 1588 particles across 71 samples, with an average of 22 items/L. The majority of MPs ranged in size from 1 mm to 500 µm. The ATR-FTIR results identified the predominant types of MPs as polystyrene, polyvinyl chloride, polyethylene, polyethylene terephthalate, and polypropylene in sediment and water. The spatial variation analysis revealed high MPs concentration in landfill sites, areas with dense populations, and popular tourist destinations. The pollution load index in water demonstrated that MPs had contaminated all stations. Upon evaluating the polymeric and pollution risks, it was evident that they ranged from 5.13 to 430.15 and 2.83 to 15,963.2, which is relatively low to exceedingly high levels. As the quantity of MPs and hazardous polymers increased, the level of pollution and corresponding risks also escalated significantly. The existence of MPs in lake water, as opposed to open well water, could potentially pose a cancer risk for both children and adults who consume it. Detecting MPs in water samples highlights the significance of implementing precautionary actions to alleviate the potential health hazards they create.


Assuntos
Monitoramento Ambiental , Sedimentos Geológicos , Microplásticos , Poluentes Químicos da Água , Microplásticos/análise , Índia , Poluentes Químicos da Água/análise , Sedimentos Geológicos/química , Sedimentos Geológicos/análise , Humanos , Medição de Risco , Plásticos/análise
4.
Environ Pollut ; 348: 123857, 2024 May 01.
Artigo em Inglês | MEDLINE | ID: mdl-38537794

RESUMO

Microplastics in drinking water captured widespread attention following reports of widespread detection around the world. Concerns have been raised about the potential adverse effects of microplastics in drinking water on human health. Given the widespread interest in this research topic, there is an urgent need to compile existing data and assess current knowledge. This paper provides a systematic review of studies on microplastics in drinking water, their evidence, key findings, knowledge gaps, and research needs. The data collected show that microplastics are widespread in drinking water, with large variations in reported concentrations. Standardized methodologies of sampling and analysis are urgently needed. There were more fibrous and fragmented microplastics, with the majority being <10 µm in size and composed of polyester, polyethylene, polypropylene, and polystyrene. Little attention has been paid to the color of microplastics. More research is needed to understand the occurrence and transfer of microplastics throughout the water supply chain and the treatment efficiency of drinking water treatment plants (DWTPs). Methods capable of analyzing microplastics <10 µm and nanoplastics are urgently needed. Potential ecological assessment models for microplastics currently in use need to be improved to take into account the complexity and specificity of microplastics.


Assuntos
Água Potável , Poluentes Químicos da Água , Humanos , Microplásticos/análise , Plásticos/análise , Água Potável/análise , Poluentes Químicos da Água/análise , Monitoramento Ambiental
5.
Environ Pollut ; 346: 123654, 2024 Apr 01.
Artigo em Inglês | MEDLINE | ID: mdl-38402933

RESUMO

The seafloor is recognised as a major sink for marine litter. However, studies conducted in this compartment addressing marine litter densities and its interactions with fauna are scarce, mainly due to sampling constraints. In this paper, we assess marine litter density, composition and interactions with marine communities and evaluate its relationship with fishing activities at the "Banco de la Concepción" seamount (Canary Islands, Spain). We took advantage of underwater video records taken with a Remotely Operated Towed Vehicle in the framework of the LIFE IP INTEMARES project. A total of 56 video transects were analysed covering about 9 km with 19 h of video recording. Transects were categorised as high, low, and null fishing effort based on the Vessel Monitoring System (VMS) positional data registered between 2009 and 2017. Litter items were recorded in 70% of the transects with a mean density of 2122 (±2464) items km-2. There were significant differences in litter densities over the three levels of fishing pressure, with a density decrease from stations of high to stations of null fishing pressure. Regarding categories, plastic was by far the most abundant category found (83.1%), mainly consisting of fishing lines, both monofilaments and entangled longlines. The study of the interactions of marine litter with fauna showed that less than 20% of the items presented an interaction with benthic organisms either by causing or not a visible impact. The sponge Asconema setubalense accounted for more than half (57.4%) of all interactions, but only 5% of all A. setubalense specimens showed physical damage.


Assuntos
Monitoramento Ambiental , Plásticos , Espanha , Plásticos/análise , Resíduos/análise , Gravação em Vídeo
6.
Environ Sci Pollut Res Int ; 31(6): 9031-9044, 2024 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-38182957

RESUMO

Polystyrene microplastics (PSMPs) have emerged as a ubiquitous environmental toxicant that affects different organs including testes. Ginkgetin (GNG) is a biflavonoid that shows antioxidant properties. The current research was undertaken to evaluate the ameliorative potential of GNG against PSMPs-instigated testicular damages. Forty-eight albino rats (male) were randomly divided into 4 equal groups: control, PSMPs-treated group (0.01 mgkg-1), GNG + PSMPs-exposed group (25 mgkg-1 + 0.01 mgkg-1), and only GNG-supplemented group (25 mgkg-1). After 56 days of treatment, it was revealed that PSMPs significantly reduced the activity of glutathione peroxidase (GPx), catalase (CAT), superoxide dismutase (SOD), and glutathione reductase (GSR), while concurrently augmented the levels of lipid peroxidation marker, i.e., malondialdehyde (MDA) along with reactive oxygen species (ROS). Rats administered with PSMPs showed a significant reduction in the spermatogenic indices (sperm count, viability, and motility), HOS coiled tail sperm along with increased sperm structural deformities, i.e., tail, head, and mid-piece. Additionally, PSMPs exposure decreased the levels of testosterone, luteinizing (LH), and follicle-stimulating hormones (FSH). Besides, administration of PSMPs reduced the steroidogenic enzymes (13ß-HSD, StAR, and 17ß-HSD) and Bcl-2 expression, while augmented the caspase-3 and Bax expression. PSMPs also elevated the levels of inflammatory markers (IL-6, IL-1ß, TNF-α, and NF-κB) and activity of COX-2 in the testes. Furthermore, PSMPs treatment induced various histopathological damages in the testes of rats. Therefore, findings of the current study suggested that GNG effectively mitigated the PSMPs-induced testicular toxicity owing to its chemoprotective potential possibly through its anti-inflammatory, antioxidant, anti-apoptotic, and androgenic properties.


Assuntos
Biflavonoides , Testículo , Ratos , Masculino , Animais , Antioxidantes/metabolismo , Biflavonoides/análise , Biflavonoides/metabolismo , Biflavonoides/farmacologia , Microplásticos/análise , Plásticos/análise , Poliestirenos/análise , Estresse Oxidativo , Ratos Wistar , Sêmen/metabolismo , Testosterona/metabolismo
7.
Sci Total Environ ; 913: 169739, 2024 Feb 25.
Artigo em Inglês | MEDLINE | ID: mdl-38163610

RESUMO

Microplastics (MPs) pollution in the marine environment has become a global problem. In this study, a number of 21 mollusk species (n = 2006) with different feeding habits were collected from 11 sites along the Bohai Sea for MPs uptake analysis. The MPs in mollusk samples were isolated and identified by micro-Fourier Transform Infrared Spectroscopy (µ-FTIR), and an assessment of the health risks of MPs ingested by mollusk consumption is also conducted. Approximately 91.9 % of the individuals among all the collected species inhaled MPs, and there was an average abundance of 3.30 ± 2.04 items·individual-1 or 1.04 ± 0.74 items·g-1 of wet weight. The shape of MPs was mainly fiber, and a total number of 8 polymers were detected, of which rayon had the highest detection rate (58.3 %). The highest abundance, uptake rate and polymer composition of MPs was observed in creeping types, suggesting that they might ingest these MPs from their food. The gastropod Siphonalia subdilatata contains the highest levels of MPs, which may increase the risk of human exposure if consumed whole without removing the digestive gland. The polymer risk level of MPs in these mollusks was Level III (H = 299), presenting harmful MPs such as polyvinyl chloride. In terms of human exposure risk, the average risk of human exposure to MPs through consumption of Bohai mollusks is estimated to be 3399 items·(capita·year)-1 (424-9349 items·(capita·year)-1). Overall, this study provides a basis for the ecological and health Risk assessment of MPs in mollusks collected from the coastline of China.


Assuntos
Gastrópodes , Poluentes Químicos da Água , Humanos , Animais , Microplásticos/análise , Plásticos/análise , Poluentes Químicos da Água/análise , Monitoramento Ambiental/métodos , Moluscos , Medição de Risco
8.
Mar Pollut Bull ; 199: 116007, 2024 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-38176161

RESUMO

Microplastics (MPs) have attracted global attention due to their ubiquity and potential impact on the environment. However, MPs are poorly documented along the Algerian coast. To address this data gap, this study investigated the presence of MPs on three recreational beaches in western Algeria (Stidia, Sablettes and Mersat El Hadjaj). The mean MP abundance for the three beaches was estimated at 55.47 ± 48.01 items/m2. Characterization of MPs shape revealed that fragments (79.81 %) were dominant, followed by pellets (10.58 %), filaments (5.57 %), and foam (3.85 %). An assessment of the Microplastic Pollution Index, the Pellet Pollution Index, and the Coefficient of Microplastic Impact, revealed the presence of very low to moderate levels of MPs on the beaches. This presence was associated with minimal beach pollution and moderate overall impact. The sector analysis approach results confirm that there are two different magnitudes of MPs presence that can negatively impact on the environmental quality of the studied beaches.


Assuntos
Microplásticos , Poluentes Químicos da Água , Microplásticos/análise , Plásticos/análise , Monitoramento Ambiental/métodos , Poluentes Químicos da Água/análise , Poluição Ambiental/análise
9.
Environ Pollut ; 344: 123321, 2024 Mar 01.
Artigo em Inglês | MEDLINE | ID: mdl-38185354

RESUMO

Microplastic (MP) pollution in lakes has received much attention as an increasing amount of plastic waste enters aquatic ecosystems. However, there is still a lack of comprehensive understanding of the global distribution patterns, environmental hazards, factors driving their presence, and the relationships between sources and sinks of MPs. In this study, we conducted a meta-analysis of drivers of lake MP pollution based on 42 articles on MP pollution from three different aspects: geographical distribution, driving factors and environmental risks. The results revealed differences in the MP pollution levels across the different sampling sites in the global lakes. Moreover, there is significant heterogeneity in the abundance of MPs among various lakes, whose distribution pattern is affected by geographical location, sampling method and extraction method. The size of the MPs differed significantly between water and sediment, and the proportion of small (<1 mm) MPs in sediment was significantly greater than that in water (72% > 46%). Environmental risk assessment reveals that the risk level of MP pollution in most lakes worldwide is low, and the environmental risk of pollution in lake water is higher than that in sediment. Based on the risk assessment and geographical location of the lake, the risk of MP pollution is related not only to human activities and economic development but also to local waste management practices, which directly impact the accumulation of MPs. Therefore, we suggest that the production of biodegradable low-risk polymer plastics instead of high-risk materials, and plastic solid waste recycling management should be strengthened to effectively mitigate the presence of MPs in the environment.


Assuntos
Plásticos Biodegradáveis , Poluentes Químicos da Água , Humanos , Microplásticos/análise , Plásticos/análise , Lagos , Ecossistema , Poluentes Químicos da Água/análise , Monitoramento Ambiental/métodos , Poluição da Água/análise , Água/análise , Medição de Risco
10.
Mar Pollut Bull ; 198: 115825, 2024 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-38029669

RESUMO

Transport of ballast water is considered a significant vector for dispersion of different pollutants, including microplastics (MPs), throughout the world's oceans. However, there is limited information on MPs in ballast water. Size distribution, polymer type, and ecological risks of MPs in ballast water were investigated for the first time in this study. The mean levels of MPs in ballast water and seawater samples were 12.53 and 11.80 items/L, respectively. MPs with a size category of 50-300 µm was the most abundant. Fiber, black, and polycarbonate (PC) were the predominant shape, color, and polymer type of identified MPs in ballast water and seawater, respectively. The pollution load index (PLI), hazard index (HI), and risk quotient (RQ) indicated high levels of MP pollution, potentially indicating an ecological risk. These findings increase our understanding of the major sources (such as ballast water), transportation routes, and related ecological risks of MPs to marine ecosystems.


Assuntos
Microplásticos , Poluentes Químicos da Água , Microplásticos/análise , Plásticos/análise , Água/análise , Ecossistema , Oceano Índico , Navios , Poluentes Químicos da Água/análise , Monitoramento Ambiental , Polímeros/análise , Medição de Risco
11.
Environ Res ; 241: 117666, 2024 Jan 15.
Artigo em Inglês | MEDLINE | ID: mdl-37984787

RESUMO

Over the past few years, it has become increasingly evident that microplastic pollutant heavily contaminates water sources, posing a potential threat to both human and wildlife. These plastic pollutants do not get degraded efficiently by natural processes and the existing traditional treatment methods are incapable of fully eradicating them. In this regard, degradation of microplastic contaminants through photocatalytic methods has emerged as a powerful technique. Unfortunately, only a limited number of investigations have been reported in the field of photocatalytic degradation of microplastics. This comprehensive assessment focuses on the detailed analysis of the latest cutting edge engineered technologies aimed at efficiently separating, identifying microplastic contaminants present in food samples and degrading them through photocatalysis. Moreover, detailed information on various instrumental techniques that can be adopted to analyze the isolated micro sized plastic particles has been discussed. The assessment and degradation of these micro contaminants through photocatalytic methods is still in juvenile stage and there are lot of rooms to be explored. The need for profound contemplation on methods to degrade them through photocatalytic approaches as well as their possible health risks to humans motivated us to bring out this review.


Assuntos
Poluentes Ambientais , Poluentes Químicos da Água , Humanos , Microplásticos , Plásticos/análise , Poluentes Químicos da Água/análise , Poluentes Ambientais/análise , Medição de Risco , Monitoramento Ambiental
12.
Environ Pollut ; 343: 123158, 2024 Feb 15.
Artigo em Inglês | MEDLINE | ID: mdl-38123117

RESUMO

Estuaries, which serve as vital links between land and coastal ecosystems, play a significant part in facilitating the transfer of plastic waste from the land to the ocean. In this research, we examined the prevalence, characteristics, and ecological risks of microplastics (MPs) in the extensively urbanized Cochin Estuarine System (CES), India. Additionally, it represents one of the initial evidence-based examinations of MPs ingestion by jellyfish in Indian waters, focusing on Acromitus flagellatus, Blackfordia virginica, and Pleurobrachia pileus species. The abundance of MPs found in the surface water of the Cochin Estuarine System (CES) varied between 14.44 ± 9 to 30 ± 15.94 MP/m3, with an average of 21.6 ± 11 MP/m3. In both surface waters and jellyfish from the Cochin Estuarine System (CES), fibers were the most prevalent type of MPs, with polyethylene (PE), polypropylene (PP), and polyamide (PA) being the most common polymer varieties. To evaluate the current levels of MPs and their effect on the CES, the Pollution Load Index (PLI), Potential Ecological Risk Index (PERI), and Polymeric Risk Index (H) were utilized. The high PLIestuary values (20.33), high Hestuary values (234.02), and extreme PERIestuary value (1646.06) indicate that the CES is facing an extreme ecological risk. Among the 280 jellyfish individuals examined, 118 (42.14%) were recognized to contain MPs with an average of 1.54 ± 2.68 MPs/individual. Pearson bivariate analysis revealed a significant correlation between the jellyfish bell size and number of plastics per individual. Comparison between jellyfish species revealed, the majority (66%) of the MPs identified in jellyfish were from A. flagellatus and 44 among the 50 jellyfish examined (88%) had MPs. These findings suggest that A. flagellatus may be a potential sink for MPs and may be utilized to be a bioindicator for monitoring MPs contamination in estuarine systems, aiding in future plastic pollution mitigation efforts.


Assuntos
Microplásticos , Poluentes Químicos da Água , Humanos , Microplásticos/análise , Plásticos/análise , Estuários , Ecossistema , Poluentes Químicos da Água/análise , Monitoramento Ambiental , Polímeros , Medição de Risco
13.
Environ Pollut ; 334: 122167, 2023 Oct 01.
Artigo em Inglês | MEDLINE | ID: mdl-37437763

RESUMO

The contamination of microplastics (MP) in freshwater environments represent a major way for the MP transport in the environment. The assessment of MP pollution in freshwater compartments is then important to visualize the pressure and the impacts on medium, and to set up necessary measures. In this context, this study focused on the influence of anthropogenic activities of a medium French city (Angers) on MP levels in samples collected from the Loire River, the longest river in France. Abiotic and biotic matrices were collected upstream and downstream Angers. A first analysis was performed based on microscopy to determine the size, colour and shape of suspected MP and a complementary analysis by µ-FTIR (micro-Fourier Transform InfraRed) was conducted to determine the composition of plastic particles. Three organisms belonging to different trophic levels were studied: when the MP level was expressed per individual, the lowest abundance of MP was found in Tubifex sp. Followed by Corbicula fluminea, while the highest was measured in Anguilla anguilla. To establish the relationship with their habitat, the presence of MP in sediment and water was also analysed. Therefore, this works constitutes a complete overview of the MP levels in freshwater abiotic and biotic matrices. Overall, the presence of MP in analysed samples did not follow a particular pattern, neither in the sites nor matrices: the characteristics depending on a multifactorial outcome (feeding mode, organism size …). However, correlation of MP pattern between clams and sediment was quite evident, while the one between worms and their habitat was not. This demonstrates the relevance of investigating plastic contamination both in biotic and abiotic matrices. Finally, a standardisation of sampling and analytical analysis protocols would be helpful to make comparisons between studies more robust.


Assuntos
Corbicula , Poluentes Químicos da Água , Animais , Microplásticos , Plásticos/análise , Poluentes Químicos da Água/análise , Monitoramento Ambiental/métodos , Água Doce/análise , França
14.
Sci Total Environ ; 892: 164712, 2023 Sep 20.
Artigo em Inglês | MEDLINE | ID: mdl-37301381

RESUMO

Emerging contaminants and their pervasive presence in freshwater ecosystems have been widely documented, but less is known about their prevalence and the harm they cause in marine ecosystems, particularly in developing countries. This study provides data on the prevalence and risk posed by microplastics, plasticisers, pharmaceuticals and personal care products (PPCPs), and heavy metal(loid)s (HMs) along the Maharashtra coast of India. The sediment and coastal water samples were collected from 17 sampling stations, processed, and subjected to FTIR-ATR, ICP-MS, SEM-EDX, LC-MS/MS, and GC-MS for further analysis. Higher MPs abundance, combined with the pollution load index, indicates that the northern zone is a high-impact zone with pollution concerns. Plasticisers in extracted MPs and HMs adsorption on MPs surface from surrounding waters reveal their roles as a source and vector for contaminants, respectively. The mean concentration of metoprolol (53.7-306 ng L-1), tramadol (16.6-198 ng L-1), venlafaxine (24.6-234 ng L-1), and triclosan (211-433 ng L-1) in Maharashtra's coastal waters were several folds higher than in other water systems, raising major health concerns. The hazard quotient (HQ) scores revealed that >70 % of study sites pose a high to medium (1 > HQ > 0.1) ecological risk to fish, crustaceans and algae, indicating serious concern. Fish and crustaceans (35.3 % each) show a higher level of risk than algae (29.5 %). Metoprolol and venlafaxine could represent greater ecological risks than tramadol. Similarly, HQ suggests that bisphenol A has larger ecological risks than bisphenol S along the Maharashtra coast. To the best of our knowledge, this is the first in-depth investigation into emerging pollutants in Indian coastal regions. This information is crucial for better policy formulation and coastal management in India in general, and Maharashtra in particular.


Assuntos
Cosméticos , Metais Pesados , Tramadol , Poluentes Químicos da Água , Animais , Microplásticos/análise , Ecossistema , Água/análise , Plásticos/análise , Sedimentos Geológicos , Cromatografia Líquida , Metoprolol , Cloridrato de Venlafaxina , Poluentes Químicos da Água/análise , Índia , Espectrometria de Massas em Tandem , Metais Pesados/análise , Medição de Risco , Cosméticos/análise , Preparações Farmacêuticas , Monitoramento Ambiental
15.
Mar Pollut Bull ; 192: 115131, 2023 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-37290300

RESUMO

Microplastics (MPs) have become a global concern due to their widespread distribution in marine ecosystems. The present study was aimed to assess MPs contamination in 21 muddy shores sites situated in the Gulf of Khambhat. From each site, five samples (1 kg each) were collected. In the laboratory, the replicates were homogenated, out of which a 100 g sample was used for analysis. The total number of MPs, shape, colour, size and polymer composition of MPs were assessed. The MPs abundance ranged from 0.32 ± 0.18 particles/g (Jampore) to 2.81 ± 0.50 particles/g (Uncha Kotda) among different study sites. Moreover, threads were recorded maximum followed by films, foams and fragments. In case of MPs colour, black and blue coloured MPs occurred dominantly, with sizes ranging from 1 mm to 5 mm. FTIR analysis identified seven different types of plastic polymers, out of which polypropylene was the dominant plastic polymer (32.46 %) followed by polyurethane (32.16 %), acrylonitrile butadiene styrene (14.93 %), polystyrene (9.62 %), polyethylene terephthalate (4.61 %), polyethylene (3.71 %) and polyvinyl chloride (2.51 %). Based on the results of the Contamination factor (CF) value, Alang, Mahua, Ghogha and Uncha Kotda were identified as very high contaminated sites (CF ≥ 6). Pollution Load Index (PLI) value of entire study area revealed the Gulf of Khambhat as a polluted area with MPs contamination (PLI > 1). While value of Hazardous Index (H) identified 12 study sites as class-V risk category (H value > 10,000). Moreover, Pollution Risk Index (PRI) value revealed fifteen sites as very high contaminated sites (PRI > 1200). Pollution indices can be useful in predicting the level of MPs contamination at the study site. Overall, the present study provides the information on MPs contamination in the coastal region of the Gulf of Khambhat that can be used as a baseline data for future studies on the ecotoxicity of MPs on marine biota.


Assuntos
Monitoramento Ambiental , Microplásticos , Poluentes Químicos da Água , Ecossistema , Monitoramento Ambiental/métodos , Índia , Microplásticos/análise , Plásticos/análise , Poluentes Químicos da Água/análise
16.
Sci Total Environ ; 892: 164549, 2023 Sep 20.
Artigo em Inglês | MEDLINE | ID: mdl-37269998

RESUMO

Microplastic fibers have been found to be a dominant form of microplastics in water matrixes, and textile industry and domestic washing of synthetic textiles as one of its main sources. Additionally, there is a lack of knowlidge about microplastic fiber release during mechanically drying clothes and textiles due to differences in the isolation of microplastic fiber methods. Limited information available in the literature in terms of the isolation of microplastic fibers from organic-rich samples after using different household equipment represents one of the main challenges leading us to our main goal, to optimise an effective, simple, and low-cost method for the isolation of microplastic fibers from textile fibers of different origins without damaging their structure. This is achieved by primarily removing mineral matter by using density separation with a saturated solution of ZnCl2 followed by removal of organic matter by using hydrogen peroxide (H2O2) and FeCl3 as a catalyst. Identification of microplastic fibers was obtained by optical microscope, Fourier-transform infrared spectroscopy and Thermogravimetric analysis. Clear microscope (both optical and SEM) images, high percentage of obtained FTIR spectra overlap with Polymer Sample laboratory, clear TGA of isolated samples confirmed that this method can be used as a simple and effective method for isolation of microplastic fibers from organic components rich samples of different origin.


Assuntos
Microplásticos , Poluentes Químicos da Água , Plásticos/análise , Peróxido de Hidrogênio/análise , Poluentes Químicos da Água/análise , Têxteis/análise , Monitoramento Ambiental
17.
Environ Int ; 177: 108010, 2023 07.
Artigo em Inglês | MEDLINE | ID: mdl-37307603

RESUMO

Organophosphate esters (OPEs) are widely used as plasticizers in plastic food packaging; however, the migration of OPEs from plastic to food is largely unstudied. We do not even know the specific number of OPEs that exist in the plastic food packaging. Herein, an integrated target, suspect, and nontarget strategy for screening OPEs was optimized using ultrahigh-performance liquid chromatography-high-resolution mass spectrometry (UHPLC-HRMS). The strategy was used to analyze 106 samples of plastic food packaging collected in Nanjing city, China, in 2020. HRMS allowed full or tentative identification of 42 OPEs, of which seven were reported for the first time. Further, oxidation products of bis(2,4-di-tert-butylphenyl) pentaerythritol diphosphite (AO626) in plastics were identified, implying that the oxidation of organophosphite antioxidants (OPAs) could be an important indirect source of OPEs in plastics. The migration of OPEs was examined with four simulated foods. Twenty-six out of 42 OPEs were detected in at least one of the four simulants, particularly isooctane, in which diverse OPEs were detected at elevated concentrations. Overall, the study supplements the list of OPEs that humans could ingest as well as provides essential information regarding the migration of OPEs from plastic food packaging to food.


Assuntos
Retardadores de Chama , Plásticos , Humanos , Plásticos/análise , Embalagem de Alimentos , Ésteres/análise , Retardadores de Chama/análise , Monitoramento Ambiental , Organofosfatos/análise , China , Suplementos Nutricionais/análise
18.
Mar Pollut Bull ; 192: 115073, 2023 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-37245322

RESUMO

A common method for characterizing microplastics (MPs) involves capturing the plastic particles on a filter after extraction and isolation from the sediment particles. Microplastics captured on the filter are then scanned with Raman spectroscopy for polymer identification and quantification. However, scanning the whole filter manually using Raman analysis is a labor-intensive and time-consuming process. This study investigates a subsampling method for Raman spectroscopic analysis of microplastics (operationally defined here as 45-1000 µm in size) present in sediments and isolated onto laboratory filters. The method was evaluated using spiked MPs in deionized water and two environmentally contaminated sediments. Based on statistical analyses, we found quantification of a sub-fraction of 12.5 % of the filter in a wedge form was optimal, efficient, and accurate for estimating the entire filter count. The extrapolation method was then used to assess microplastic contamination in sediments from different marine regions of the United States.


Assuntos
Microplásticos , Poluentes Químicos da Água , Microplásticos/análise , Plásticos/análise , Análise Espectral Raman , Poluentes Químicos da Água/análise , Monitoramento Ambiental , Sedimentos Geológicos/química
19.
Mar Pollut Bull ; 192: 115058, 2023 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-37210987

RESUMO

Spatial and temporal distribution of microplastics along the nearshore surface waters of Kerala after the floods of 2018 was studied. Results indicated a seven-fold increase in its mean concentration (7.14 ± 3.03 items/m3) post deluge. The average abundance was highest during pre-monsoon (8.27 ± 3.09 items/m3). Fibres were the dominant group, with blue and black being the most prevalent colours. Polyethylene and polypropylene were the most commonly found polymers, possibly gaining entry through sewage waste or land-based plastic litter. Highest abundance of microplastic was recorded off Kochi categorising it at Hazard Level I under Pollution Load Index assessment. Similarly high levels of Pollution Hazard Index and Potential Ecological Risk Index were also reported due to the presence of hazardous polymers PVC and PU that can cause concern to marine life. The differential weathering pattern and surface morphology analysis suggested microplastics to be relatively old that had undergone substantial mechanical and oxidative weathering.


Assuntos
Microplásticos , Plásticos , Plásticos/análise , Monitoramento Ambiental , Polímeros , Índia , Medição de Risco
20.
Mar Pollut Bull ; 191: 114906, 2023 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-37060890

RESUMO

This paper proposes and applies a multicriteria decision analysis framework tailored to assess measures for reducing the concentration of microplastics and macroplastics in seas, by implementing ground-breaking clean-up technologies and addressing different types of pollutant sources. Environmental, socio-economic and financial impacts are considered to provide a ranking of these measures for better-informed decision making. The data required to evaluate the performance of the technologies in different locations and scales are analyzed to understand the consequences of the different measures in terms of plastic pathways and sites, and the amounts accumulated, using innovative simulation models. The framework is applied to the Mediterranean Sea, providing insights for designing measures to respond to the challenges of cleaning seas and fulfill the EU marine strategy. The results for the best ranked alternatives show that dealing with microplastics is much more expensive (by one order of magnitude) than dealing with macroplastics.


Assuntos
Microplásticos , Poluentes Químicos da Água , Plásticos/análise , Monitoramento Ambiental/métodos , Poluentes Químicos da Água/análise , Mar Mediterrâneo
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