Air, land, and water pollutants and public health expenditures: Empirical data from selected EU countries in the transport sector.

The increase in economic activity, particularly in transport, leads to a significant increase in emissions of pollutants, such as ammonia, arsenic and cadmium, at the European Union (EU) level. This can seriously impact human health and, consequently, public health spending. Based on data from 15 European Union countries from 1992 to 2020, a panel co-integration approach is used to study these pollutants' short- and long-term co-movements and per capita health expenditure. The results show a long-term relationship between ammonia, arsenic and cadmium emissions and per capita health spending, as they are panel-cointegrated. Ammonia and cadmium emissions exert a statistically significant positive effect on health expenditure in the short run, and arsenic emissions have a statistically significant positive impact in the long run. The forecast assessment of reductions in health spending resulting from policies to reduce emissions of air, land and water pollutants, such as ammonia, arsenic and cadmium, from the transport sector supports investments in its policies that reduce pressure on health spending. The reduction in annual healthcare expenditure is greater when these reductions are made sooner and more severely. Indeed, varying the reduction in emissions for each pollutant by 10% and 100%, respectively, from the first year for all countries over a 3-year period results in an average annual reduction in health spending of 2.05% and 51.02%, respectively. However, if we wait until the third year, the annual reduction is only 0.77% and 17.63% respectively.

Distribution and ecological risk assessment of priority water pollutants in surface river sediments with emphasis on industrially affected areas.

Priority water pollutants comprising six plasticizers, 18 volatile organic compounds (VOCs), total petroleum hydrocarbon (TPH), 1,4-dioxane, epichlorohydrin, formaldehyde, acrylamide, and cyanides were determined in surface river sediments to assess their distribution patterns and ecological risks. Among these, di (2-ethylhexyl) phthalate (DEHP), toluene, TPH, and acrylamide were frequently found in sediments. The industrial sites had higher concentrations of ∑plasticizers (median 628 ng/g dry weight (dw)), ∑VOCs (median 3.35 ng/g dw), acrylamide (median 0.966 ng/g dw), and TPH (median 152 µg/g dw) in sediments than the mixed and non-industrial areas. The other pollutants did not show the significant differences in levels according to site types because of their relatively low detection frequencies. Volatile and soluble substances as well as hydrophobic pollutants were predominantly detected in surface sediments from industrial areas. Sediment contamination patterns were affected by the size and composition of the industrial zones around the sampling sites. The ecological risks determined using the sediment quality guidelines (DEHP, VOCs, and TPH) and the mean probable effect level quotients (DEHP) were mostly acceptable. However, the two most representative industrial regions (the largest industrial area and the first industrial city) showed risks of concern for DEHP and TPH.

Assessment of the water quality and toxicity effects on zebrafish (Danio rerio) of a stream near a phosphorus chemical plant in Guizhou Province, southwestern China.

To reveal the influence of the phosphorus chemical industry (PCI) on regional water environmental quality and safety, the water quality and ecotoxicological effects of a stream near a phosphorus chemical plant (PCP) in Guizhou Province, southwestern China, were investigated based on water samples collected from the stream. The results showed that the average concentrations of NH3-N, TN, P, F-, Hg, Mn, and Ni were 3.14 mg/L, 30.09 mg/L, 3.34 mg/L, 1.18 mg/L, 1.06 µg/L, 45.82 µg/L, and 11.30 µg/L, respectively. The overall water quality of the stream was in the heavily polluted category, and NH3-N, TN, P, F-, and Hg were the main pollution factors. The degree of pollution was in the order of rainy period > transitional period > dry period, and the most polluted sample site was 1100 m from the PCP. After 28 days of exposure to stream water, there was no significant change in the growth parameters of zebrafish. The gills of zebrafish showed a small amount of epithelial cell detachment and a small amount of inflammatory cell infiltration, and the liver tissue displayed a large amount of hepatocyte degeneration with loose and lightly stained cytoplasm. Compared with the control group, the %DNA in tail, tail length, tail moment, and olive tail moment were significantly increased (p < 0.05), indicating that the water sample caused DNA damage in the peripheral blood erythrocytes of zebrafish. The stream water in the PCI area was found to be polluted and exhibited significant toxicity to zebrafish, which could pose a threat to regional ecological security.

Assessment of toxicity potential of neglected Mithi River water from Mumbai megacity, India, in zebrafish using embryotoxicity, teratogenicity, and genotoxicity biomarkers.

The Mithi River begins at Vihar Lake and flows through the industrial hub of the city of Mumbai, India, and merges with the Arabian Sea at Mahim Creek. The current study was carried out to assess the ecotoxicological effects of the Mithi River surface water in zebrafish (Danio rerio) embryos. Water samples were collected from ten sampling sites (S1 to S10) located along the course of the Mithi River. The toxicity of water samples was assessed using a zebrafish embryo toxicity test (ZFET). Water samples were diluted from all sites at 1:0, 1:2, 1:4, 1:8, 1:16, 1:32, 1:64, and 1:128 times. The lowest and highest LDil 20 values for 96 h were estimated as 9.16 and 74.18 respectively for the S2 and S5 sites. The results of embryotoxicity and teratogenicity assays indicated a significant difference (p < 0.0001) between embryos exposed to control and sampling sites (except S1) for various endpoints such as mortality, egg coagulation, pericardial edema, yolk sac edema, tail bend, and skeletal deformities. The histopathological analysis revealed various lesions, ascertaining the toxic effects of water samples. The comet assay revealed significantly higher DNA damage (except S1) in embryos exposed to sites S5 and S6 with OTM values of 4.46 and 2.48 respectively. The results indicated that the Mithi River is polluted with maximum pollution load at the middle stretches. The study further indicated that the pollutants in the Mithi River (except S1) could potentially be hazardous to the aquatic organisms; therefore, continuous biomonitoring of the river is needed for its revival.

The nonlinear effect of new urbanization on water pollutant emissions: Empirical analysis based on the panel threshold model.

Rapid urbanization has led to a significant increase in water consumption and wastewater discharge. Balancing the relationship between urbanization development and water pollutants emissions is crucial for the sustainable development of the country. Given the uneven regional economic development and resource distribution in China, exploring the relationship between new urbanization and water pollution emissions cannot be limited to a single perspective such as population urbanization. This study developed a comprehensive evaluation index system for new urbanization level. Based on data from 30 provincial-level regions in China from 2006 to 2020, a Panel Threshold Regression Model (PTRM) was used to explore the nonlinear relationship between the new urbanization level and water pollution discharge. The research results show that China's new urbanization level (NUBL) and its subsystems, including population urbanization (P-NUBL), economic urbanization (E-NUBL), and spatial urbanization (SP-NUBL), all have a double threshold effect on chemical oxygen demand (COD) emissions. The promoting effect of NUBL and E-NUBL on COD emissions gradually increased in the later stage of the study. P-NUBL and SP-NUBL show a trend of inhibiting COD emissions after crossing the dual threshold values. Social urbanization (S-NUBL) and ecological urbanization (EL-NUBL) had no threshold effect, but they also had a promoting effect on COD emissions. In addition, the speed of new urbanization in eastern China was significantly faster than that in central and western China, with provinces such as Beijing, Shanghai, and Jiangsu being the first to enter the high threshold stage. The central region began to gradually enter the middle threshold stage, but provinces such as Hebei, Henan, and Anhui are still in the high pollution and high emission stage. The level of new urbanization in western China is relatively low, and future development should prioritize economic construction. Provinces with high thresholds and low water pollution emissions still need to be developed. The results of this study have important implications for promoting the harmonious development of water-saving and sustainable urban development in China.

A comprehensive review on sustainable clay-based geopolymers for wastewater treatment: circular economy and future outlook.

In the present era of significant industrial development, the presence and dispersal of countless water contaminants in water bodies worldwide have rendered them unsuitable for various forms of life. Recently, the awareness of environmental sustainability for wastewater treatment has increased rapidly in quest of meeting the global water demand. Despite numerous conventional adsorbents on deck, exploring low-cost and efficient adsorbents is interesting. Clays and clays-based geopolymers are intensively used as natural, alternative, and promising adsorbents to meet the goals for combating climate change and providing low carbon, heat, and power. In this narrative work, the present review highlights the persistence of some inorganic/organic water pollutants in aquatic bodies. Moreover, it comprehensively summarizes the advancement in the strategies associated with synthesizing clays and their based geopolymers, characterization techniques, and applications in water treatment. Furthermore, the critical challenges, opportunities, and future prospective regarding the circular economy are additionally outlined. This review expounded on the ongoing research studies for leveraging these eco-friendly materials to address water decontamination. The adsorption mechanisms of clays-based geopolymers are successfully presented. Therefore, the present review is believed to deepen insights into wastewater treatment using clays and clays-based geopolymers as a groundbreaking aspect in accord with the waste-to-wealth concept toward broader sustainable development goals.

Assessment of selected pharmaceuticals in Riyadh wastewater treatment plants, Saudi Arabia: Mass loadings, seasonal variations, removal efficiency and environmental risk.

Despite increasing interest in pharmaceutical emissions worldwide, studies of environmental contamination with pharmaceuticals arising from wastewater discharges in Saudi Arabia are scarce. Therefore, this study examined occurrence, mass loads and removal efficiency for 15 pharmaceuticals and one metabolite (oxypurinol) from different therapeutic classes in three wastewater treatment plants (WWTPs), in Riyadh city in Saudi Arabia. A total of 144 samples were collected from the influents and effluents between March 2018 and July 2019 and analyzed using Solid Phase Extraction followed by triple quadrupole LC-MS/MS. The average concentrations in the influents and effluents were generally higher than their corresponding concentrations found either in previous Saudi Arabian or global studies. The four most dominant compounds in the influent were acetaminophen, ciprofloxacin, caffeine, and diclofenac, with caffeine and acetaminophen having the highest concentrations ranging between 943 and 2282 µg/L. Metformin and ciprofloxacin were the most frequently detected compounds in the effluents at concentrations as high as 33.2 µg/L. Ciprofloxacin had the highest mass load in the effluents of all three WWTPs, ranging between 0.20 and 20.7 mg/day/1000 inhabitants for different WWTPs. The overall average removal efficiency was estimated high (≥80), with no significant different (p > 0.05) between the treatment technology applied. Acetaminophen and caffeine were almost completely eliminated in all three WWTPs. The samples collected in the cold season generally had higher levels of detected compounds than those from the warm seasons, particularly for NSAID and antibiotic compounds. The estimated environmental risk from pharmaceutical compounds in the studied effluents was mostly low, except for antibiotic compounds. Thus, antibiotics should be considered for future monitoring programmes of the aquatic environment in Saudi Arabia.

A novel, efficient and economical alternative for the removal of toxic organic, inorganic and pathogenic water pollutants using GO-modified PU granular composite.

Multicomponent wastewater treatment utilising simple and cost-effective materials and methods is an important research topic. This study has reported the fabrication and utilisation of graphene oxide (GO) embedded granular Polyurethane (PU) (GOPU) adsorbent for the treatment of lead ion (Lead ion (Pb(II)), Methylene blue (MB), and E. coli. PU granules were wrapped with GO flakes to improve hydrophilicity, interaction with polluted water, cation-exchange reaction, and binding of pollutants on its surface. Synthesised GOPU granules were characterised by X-Ray Diffraction (XRD), Raman, Fourier transform infrared (FTIR) spectroscopy, and Scanning electron microscopy (SEM) analysis to ensure the successful synthesis of GO and fabrication of GOPU granules. Further, batch and continuous adsorption processes were studied in different operating conditions to evaluate the performance of GOPU granules in practical applications. The kinetic and isotherm analyses revealed that the adsorption of Lead (Pb(II)) ion and Methylene Blue (MB) dye followed the Freundlich and Langmuir isotherm models, respectively, and they showed good agreement with the Pseudo-second-order kinetic model. The adsorption capacities of GOPU granules for the elimination of Pb(II) and MB dye were about 842 mg/g and 899 mg/g, respectively. Additionally, investigations into the fixed bed column revealed that the adsorption column performed best at a flow rate of 5 mL/min and a bed height of 6 cm. Pb(II) adsorption had a bed uptake capacity (qbed) of 88 mg/g and percentage removal efficiency (%R) of 76%. Similarly, MB adsorption had a bed uptake capacity of 202 mg/g and a percentage removal efficiency of 71%. A systematic invention on antibacterial activity toward E. coli showed that The GOPU granules have a removal efficiency of about 100% at an exposure of 24 h. These findings indicated the possible use of GOPU granules as promising adsorbents for various water pollutants.

Interactive Allocation of Water Pollutant Initial Emission Rights in a Basin under Total Amount Control: A Leader-Follower Hierarchical Decision Model.

The initial emission rights allocation is the key measure to achieve the goal of total amount control and deepen the emission trading system. Although many studies have focused on the modeling of initial emission rights allocation, such as using game theory and multi-objective optimization methods, few studies have observed the hierarchical relationship of mutual interference and restriction between watershed management agency and local governments in each subarea during allocation. This relationship directly affects the rationality of the results of regional emission rights allocation. In this study, a leader-follower hierarchical decision model (LFHDM) for allocating initial emission rights in a basin is developed. Based on the bilevel programming approach, the model simulates the interactive decision-making process between the watershed management agency of the upper-level model (LFHDM-U) and the local government of the lower-level model (LFHDM-L) in the allocation under total amount control. A case study of China's Yellow River Basin is conducted to demonstrate the feasibility and practicality of the model. Findings reveal that, compared with the single-level model, the developed LFHDM has higher satisfaction with the allocation scheme. Under different scenarios, the overall satisfaction of the configuration schemes of COD and NH3-N in each province and autonomous region remains above 0.9. In addition, the allocation volumes of COD and NH3-N in each province of the Yellow River Basin in planning year increase with the enhancement of allowable assimilative capacity of water bodies, but the interval gap of satisfaction with allocation schemes gradually narrows. It shows that when the allowable assimilation capacity of a water body is low, the decision-making of the allocation scheme needs to be more cautious. Moreover, for the Yellow River Basin, apart from Qinghai and Sichuan, the task of reducing water pollutants in other provinces in the next few years is very arduous. The average reduction of total COD and NH3-N in the basin is about 48% and 46%, respectively.

The plight of Najafgarh drain in NCT of Delhi, India: assessment of the sources, statistical water quality evaluation, and fate of water pollutants.

The Najafgarh drain is the first major drain that joins the Yamuna River at Wazirabad in Delhi, India, and is known to contribute to the maximum pollution load to this river. The drain is originally an extension of the Sahibi River and was intentionally constructed as a canal to carry stormwater, but presently, it is carrying more of sewage, agricultural, and industrial effluents received through various small and large secondary drains. The present study has analyzed the water quality status of this interconnected system, i.e., the Najafgarh drain, its associated secondary drains, and the Yamuna River for physicochemical parameters (n = 16), microbiological parameter (n = 1), and heavy metal concentrations (n = 8). The analysis of the surface water samples collected during pre- and post-monsoon seasons showed that secondary drain discharges significantly impacted the water quality of the Najafgarh drain, which in turn affected the Yamuna River. Out of the eight selected secondary drains for this study, the Goyla dairy outlet came out as the most polluted site in terms of organic pollutants while the Basaidarapur drain was loaded with heavy metal contaminants. Statistical tools comprising hierarchical cluster analysis (HCA), Pearson's correlation, and principal component analysis (PCA) were further implemented on the water quality dataset for a better understanding of the possible sources of contamination for organic and inorganic pollutants in the selected sampling sites. The present study, thus, might help in providing key highlights to the policymakers for effective regulation and management of the point source discharges in Najafgarh drain, which will ultimately restrict its pollution loadings in Yamuna River, Delhi, and also help in the restoration of this important water body.

Open-source, low-cost, in-situ turbidity sensor for river network monitoring.

Fine sediment transport in rivers is important for catchment nutrient fluxes, global biogeochemical cycles, water quality and pollution in riverine, coastal and marine ecosystems. Monitoring of suspended sediment in rivers with current sensors is challenging and expensive and most monitoring setups are restricted to few single site measurements. To better understand the spatial heterogeneity of fine sediment sources and transport in river networks there is a need for new smart water turbidity sensing that is multi-site, accurate and affordable. In this work, we have created such a sensor, which detects scattered light from an LED source using two detectors in a control volume, and can be placed in a river. We compare several replicates of our sensor to different commercial turbidity probes in a mixing tank experiment using two sediment types over a wide range of typical concentrations observed in rivers. Our results show that we can achieve precise and reproducible turbidity measurements in the 0-4000 NTU or 0-16g/L range. Our sensor can also be used directly as a suspended sediment sensor and bypass an unnecessary calibration to Formazin. The developed turbidity sensor is much cheaper than existing options of comparable quality and is especially intended for distributed sensing across river networks.

Assessment of the effectiveness of a field-scale combined ecological treatment system at removing water pollutants, after optimization using a system dynamic model: a case study of rural inland ponds in China.

Field-scale combined ecological treatment systems (FCETS) are designed to remove nutrients from aquaculture wastewater in ponds according to the characteristics of the nutrients present. We designed and established a numerical model based on the system dynamic (SD) method, to optimize the parameters of FCETS. Results showed that the mean removal rates of TSS, TN, NO3--N, NH4+-N, TP, DP, and CODMn ranged from 83.3 to 125.8%, 41.1 to 49.1%, 44.8 to 56.2%, 49.3 to 55.6%, 80.0 to 88.2%, 52.6 to 65.0%, and 52.0 to 61.5%, respectively. The SD model provided satisfactory estimates of water quality at the outlet throughout both the validation and calibration periods. In addition, we conducted a sensitivity analysis to determine the key parameters of the SD model. This also involved optimization of the N and P removal capacity of FCETS, and their corresponding discharge (Q), and concentration (C) at the inlet. This made it possible to use R and MATLAB to simulate seasonal differences in the removal of N and P. Our results indicate that a FCETS can be used to efficiently remove nutrients from rural wastewater in ponds. In addition, we demonstrated that the SD-based numerical model is a useful management support tool to ensure that decisions are made which result in the stable operation of a FCETS. This illustrates that contamination-free aquaculture from rural inland ponds is a feasible goal.

GIS-based impact assessment and spatial distribution of air and water pollutants in mining area.

Mining is a significant part of the transforming economy, which is generally considered as essential as well as social evil at the same time. It is one of the potential contributors to air and water pollution and possesses long-term impact on their quality. Keeping in view the exponential mining activities, we have selected an iron mine area in Bailadila, Chhattisgarh, India, as a sampling site and investigated the impact of mining activities on the air as well as water quality by setting up seven air quality and thirty water quality monitoring stations. From the results obtained, it was observed that concentration of air pollutants such as SO2, NO2, PM2.5 and PM10 for the year 2015 lies in the range of 11.5-13.0 µg/m3, 11.5-13.0 µg/m3, 24.9-33.4 ppm and 61.6-74.2 ppm, respectively, while for the year 2018, it lies in the range of 10.3-11.7 µg/m3, 10.5-14.7 µg/m3, 18.3-50.8 ppm and 23.7-60.7 ppm, respectively. Furthermore, results obtained revealed that air pollutants such as SO2, NO2, PM2.5 and PM10 were within the permissible limits but they contributed towards the light air pollution (air pollution index: 25-50) at all the air monitoring stations. Moreover, PM10 was considered as criterion pollutant in the Bailadila, Chhattisgarh region. On the other hand, it was observed that groundwater quality was deteriorated in the subsequent years. Most of the water quality parameters were in the permissible limits except iron (Fe). Moreover, on the basis of water quality indexing, water quality was classified as "poor" in ~ 30% of the sites and "very poor" in ~ 34% sites. The water quality was "unhealthy for drinking" in 3% and 6% sites in the year 2015 and 2018, respectively.

Water pollutant discharge permit allocation based on DEA and non-cooperative game theory.

Against the background of the ecological civilization system reform in the new era, the appropriate allocation of water pollutant discharge permits is an important policy for controlling the amount of wastewater discharge. Traditional allocation methods have disadvantages, such as high additional costs, an unfair allocation scheme, and market distortion. In the present study, a fixed-cost allocation model based on data envelopment analysis (DEA) and the Nash non-cooperative game theory is employed to allocate water pollutant discharge permits of totally 31 provinces in China from 2008 to 2017. The allocation scheme considers environmental efficiency. The results demonstrate regional differences in the allocation of water pollutant discharge permits. The eastern region has abundant allocations. The northeastern and central regions have insufficient allocations. Besides, the western region has a significant shortage of allocations. It indicates the higher the utilization efficiency of the water pollutant discharge permits, the higher the region's sustainable development is. Based on the analysis, we propose guidelines for industrial wastewater discharge reduction.

Polymer composition assessment suggests prevalence of single-use plastics among items ingested by loggerhead sea turtles in the western mediterranean sub-region.

The ingestion of plastic is becoming a major concern for various species and particularly for marine turtles across the globe. The loggerhead sea turtle (Caretta caretta) was recently chosen by the European Commission as a bio-indicator for plastic pollution within the Mediterranean basin. We further investigated which items this key species is more prone to ingest, following the standardised Marine Strategy Framework Directive protocols. Moreover, we integrated to this protocol the Fourier Transform Infrared Spectroscopy, which allowed us to determine the polymer type of each item. We analysed samples from 226 sea turtles from 2008 to 2017 in two areas of the western Mediterranean sub-region (sensu MSFD). In the Lazio area we found a frequency of occurrence of plastic ingestion of 78.33%, while in Sardinia 41.79%. The analysis of the litter categories, among all individuals, highlights a prevalence of user-sheet (Use-She; 69.13%) and user-fragment plastics (Use-Fra; 20.84%). In addition, the polymer analysis showed a dominance of polyethylene (65.98%) and polypropylene (26.23%). As a result, by looking at other works that have investigated polymer types and items sources, we are able to infer that 77.25% of the objects ingested by the C. caretta individuals are attributable to disposable daily-life objects managed in an improper way. Therefore, C. caretta apart from being an efficient bio-indicator for plastic pollution, highlighting spatial and temporal concentration differences, it could also be used to verify the effectiveness of the Single-use Plastic Directive (EU 2019/904).

Medio ambiente y cambio climático: un enfoque basado en los derechos humanos

La Región de las Américas constituye un territorio extremadamente rico desde el punto de vista de la diversidad cultural, en la cual se presentan una variedad de desafíos relacionados con el reconocimiento y el respeto de los derechos humanos de los miembros de los pueblos indígenas, los afrodescendientes, los romaníes, así como de otros grupos étnicos. A lo largo del curso de la vida, estas personas experimentan discriminación estructural y poca representatividad e inclusión en los procesos de toma de decisiones, lo cual dificulta su acceso a los servicios de salud, afecta la calidad de la atención que reciben y tiene un efecto general en sus condiciones de vida. Por tanto, la protección y la promoción de su salud y seguridad socioeconómica es una cuestión no solo de política pública, sino también de protección y ejercicio de los derechos humanos. En esta publicación se presentan los instrumentos internacionales y regionales de derechos humanos y los sistemas de protección de esos derechos instaurados por las Naciones Unidas y el Sistema Interamericano de Derechos Humanos, así como medidas para hacerlos efectivos, con especial hincapié en el derecho a la salud, al medio ambiente sano y otros derechos relacionados con el cuidado del planeta.

Protein nanofibrils for next generation sustainable water purification.

Water scarcity is rapidly spreading across the planet, threatening the population across the five continents and calling for global sustainable solutions. Water reclamation is the most ecological approach for supplying clean drinking water. However, current water purification technologies are seldom sustainable, due to high-energy consumption and negative environmental footprint. Here, we review the cutting-edge technologies based on protein nanofibrils as water purification agents and we highlight the benefits of this green, efficient and affordable solution to alleviate the global water crisis. We discuss the different protein nanofibrils agents available and analyze them in terms of performance, range of applicability and sustainability. We underline the unique opportunity of designing protein nanofibrils for efficient water purification starting from food waste, as well as cattle, agricultural or dairy industry byproducts, allowing simultaneous environmental, economic and social benefits and we present a case analysis, including a detailed life cycle assessment, to establish their sustainable footprint against other common natural-based adsorbents, anticipating a bright future for this water purification approach.

Occurrence, distribution, and pollution indices of potentially toxic elements within the bed sediments of the riverine system in Pakistan.

Potentially toxic elements (PTEs) are a major source of pollution due to their toxicity, persistence, and bio-accumulating nature in riverine bed sediments. The sediment, as the largest storage and source of PTEs, plays an important role in transformation of mercury (Hg), lead (Pb), nickel (Ni), chromium (Cr), copper (Cu), zinc (Zn), and other toxic PTEs. Several important industrial hubs that contain a large population along the banks of different rivers, such as Kabul, Sutlej, Ravi, Jhelum, and Chenab in Pakistan, are acting as major sources of PTEs. In this study, 150 bed sediment samples (n=30 from each river) were collected from different sites. Total (acid extracted) PTE (Hg, Cu, Cr, Ni, Zn, and Pb) concentrations in bed sediments were determined using inductively coupled plasma mass spectrometry (ICP-MS). Sediment pollution indices were calculated in the major rivers of Pakistan. The results demonstrated high levels of Hg and Ni concentrations which exceeded the guideline standards of river authorities in the world. The contamination factor (CF) and contamination degree (CD) indices for Hg, Ni, and Pb showed a moderate to high (CF≥6 and CD≥24) contamination level in all the selected rivers. The values of geo-accumulation index (Igeo) were also high (Igeo≥5) for Hg and Pb and heavily polluted for Ni, while Cr, Cu, and Zn showed low to unpolluted (Igeo) values. Similarly, the enrichment factor (EF) values were moderately severe (5≤EF≤10) for Hg, Pb, and Ni in Sutlej, Ravi, and Jhelum, and severe (10≤EF≤25) in Kabul and Jhelum. Moreover, Hg and Ni showed severe to very severe enrichment in all the sampling sites. The ecological risk index (ERI) values represented considerable, moderate, and low risks, respectively, for Hg (The ERI value should not be bold. Please unbold the  ERI in the whole paper. It should be same like RI, CD and EF. [Formula: see text]≥160), Pb and Ni (40≤[Formula: see text]≤80), and Cr, Cu, and Zn ([Formula: see text]≤40). Similarly, potential ecological risk index (PERI) values posed considerable (300≤RI≤600) risk in Ravi and moderate (150≤RI≤300) in Kabul and Jhelum, but low (RI≤150) risk in Ravi and Chenab. On the basis of the abovementioned results, it is concluded that bed sediment pollution can be dangerous for both ecological resources and human beings. Therefore, PTE contamination should be regularly monitored and a cost-effective and environmentally friendly wastewater treatment plant should be installed to ensure removal of PTEs before the discharge of effluents into the freshwater ecosystems.

Spatio-temporal assessment, sources and health risks of water pollutants at trace levels in public supply river using multivariate statistical techniques.

The Joanes River is located in the northeast of Brazil, crosses the Camaçari Petrochemical Complex, the largest integrated industrial complex in the Southern Hemisphere, which has over 90 companies in the chemical and petrochemical industry. The present study aims to evaluate spatial distribution, seasonal variation and identify possible sources of trace metal contamination in surface water samples of the Joanes River. Samples were collected in the dry (December 2018) and rainy (August 2019) seasons. Analysis of trace elements (As, Cd, Cr, Cu, Ni, Mn and Pb) were performed by ICP-MS. A total of 60 water samples were obtained. Samples were analyzed using exploratory techniques such as principal component analysis (PCA) and cluster analysis (CA). It was possible to characterize the samples according to the seasonal variation. The formation of two groups was observed. Among these, samples from the rainy season presented the higher levels of metals in relation to the samples of the dry season. Natural and anthropic sources of metal contamination were identified using CA. Similarity was shown in the relationship between the metals As-Pb and Ni-Cd-Cr-Cu in the dry season, and Cd-Ni and Pb-As-Cr-Cu in the rainy season. Dermal absorption (HQderm) and ingestion hazard quotients (HQing) routes exhibited values of less than one for all the elements analyzed for adults and children, in both rainy and dry seasons. This indicated that the pollutants analyzed posed little or no health risk over a lifetime of exposure. According to international guidelines (US EPA), the values of Cu, Pb and Cr were above the limit established.

Development of an efficient remediation system with a low cost after identification of water pollutants including phenolic compounds in a tannery built-up area in Bangladesh.

Water pollution caused by tannery wastewater is an important issue in developing countries. Most studies have focused on inorganic chemicals represented by chromium as a tannery-related main pollutant. This is the first study in which pollution of water by tannery-related organic chemicals was assessed by a combination of qualitative and quantitative analyses. Our quantitative analysis showed that the maximum concentration of total phenolic compounds (phenols), consisting of phenol, bisphenol F, p-cresol and chlorocresol, in canal water in a tannery built-up area in Bangladesh was >67-fold higher than the Environmental, Health and Safety (EHS) guideline value. Mapping of our results indicated tanneries as the sources of phenols pollution. Our original depurative, a hydrotalcite-like compound consisting of magnesium and iron (MF-HT), could adsorb all kinds of phenols and exhibited the highest phenol adsorption ability (115.8 mg/g) among reported hydrotalcite-like compounds. The levels of phenols in canal water samples were reduced to levels below the guideline value by using MF-HT with assistance of a photocatalytic reaction. Moreover, the mean level of chromium (112.2 mg/L) in canal water samples was decreased by 99.7% by using the depurative. Thus, the depurative has the potential for solving the problem of tannery-related water pollution by phenols and chromium.