RESUMO
While several research studies considered the utilization of reclaimed asphalt pavement (RAP) aggregates for asphalt and concrete pavements, very few attempted its possible utilization for precast concrete applications like concrete paver blocks (CPBs). Moreover, few attempts made in the recent past to improve the strength properties of RAP inclusive concrete mixes by incorporating certain supplementary cementitious materials (SCMs) have reported an insignificant or marginal effect. The present study attempts to comprehensively investigate the utilization potential of some locally and abundantly available materials having suitable physicochemical properties to improve the performance of a zero-slump CPB mix containing 50% RAP aggregates. The studied filler materials, namely, wollastonite (naturally occurring calcium metasilicate mineral) and jarosite (hazardous zinc industry waste), were used to replace 5-15% and 10-20% by volume of Portland cement in the 50% RAP CPB mix. Apart from their individual effects, the efficacy of wollastonite-jarosite blends was also investigated. Considering the lack of indoor storage facilities and economic aspects of CPBs, the influence of water spray curing regime on the performance of the RAP CPB mixes was studied and compared to that of continuous water curing regime. Inclusion of the considered fillers was found to statistically and significantly enhance the flexural strength, tensile splitting strength, and abrasion resistance of the 50% RAP CPB mix; however, the compressive strength (in most cases), permeable voids, water absorption, and water permeability properties showed an insignificant improvement. Results of thermogravimetric analysis confirmed the occurrence of pozzolanic reactivity, and microstructure analysis revealed improvements in packing of concrete matrix and ITZ with filler inclusion qualitatively substantiating the improvements in strength and durability characteristics. The toxicity characteristics of heavy metals that may leach from the hazardous jarosite-based RAP CPB mixes were found to be within permissible limits. Based on the performance requirements specified by IS, IRC, and ASTM standards, all the RAP CPB mixes with filler inclusions fulfilled the acceptance criteria for heavy traffic applications, and water spray curing can enact as an alternate method for curing these mixes. However, to avail maximum performance benefits, it is recommended to use 5% wollastonite, 15% jarosite, and a combination of 10% wollastonite and 10% jarosite as a Portland cement substitute to produce sustainable eco-friendly RAP CPB mixes.
Assuntos
Compostos de Cálcio , Poeira , Compostos Férricos , Hidrocarbonetos , Silicatos , Sulfatos , Desenvolvimento Sustentável , Excipientes , Resíduos Perigosos , ÁguaRESUMO
Amid China's rapid economic expansion, the country's industrial solid waste (ISW) problem is escalating. As each sector generates distinct types of ISW, a multi-indicator assessment of each sector is essential to address China's New Solid Waste Policy. To investigate the ISW situation of each sector and perform a comprehensive assessment, we formulate an industrial solid waste ecological analysis framework based on ISW generation and ISW flow in the sector. Various indicators (i.e., solid waste utilization coefficient, solid waste threat coefficient, and solid waste threat intensity) are employed to assess the utilization of solid waste generated for each sector, as well as the threat of solid waste originating in each sector to society. Ecological network analysis probes the interrelationships between diverse sectors. Taking Shanghai in 2017 as an example, the study indicates that some sectors (e.g., production and supply of electric power and heat power (EH) and metal smelting and rolling processing sector (MS)) exhibit higher direct ISW generation and the direct industrial solid waste value-added coefficient (SVAC) for common industrial solid waste (CISW). Specifically, the direct CISW generation of EH and MS is 539.21Mt and 277.00Mt respectively. The direct SVAC of EH and MS is 157.06kg/103RMB and 126.27kg/103RMB respectively. These sectors should prioritize reducing emissions at the source. Additionally, the threats to society from various sectors are relatively insignificant for the CISW, while for the hazardous waste (HW), all sectors pose a considerable threat to Shanghai's society. Moreover, some sectors (e.g., mining industry) exhibit the highest mutualism relationships in the CISW and the HW. Enhancing mining sector technologies is a vital strategy for mitigating ISW sources. Specifically, MI has 9 pairs of mutualism relationships in the CISW and 8 pairs in the HW. These insights will provide empirical evidence for tackling the ISW problem in Shanghai.
Assuntos
Resíduos Industriais , Resíduos Sólidos , Resíduos Sólidos/análise , China , Indústrias , Mineração , Resíduos Perigosos , Dióxido de Carbono/análise , Desenvolvimento EconômicoRESUMO
Dealing with the current defaults of environmental toxicity, heating, waste management, and economic crises, exploration of novel non-edible, toxic, and waste feedstock for renewable biodiesel synthesis is the need of the hour. The present study is concerned with Buxus papillosa with seeds oil concentration (45% w/w), a promising biodiesel feedstock encountering environmental defaults and waste management; in addition, this research performed simulation based-response surface methodology (RSM) for Buxus papillosa bio-diesel. Synthesis and application of novel Phyto-nanocatalyst bimetallic oxide with Buxus papillosa fruit capsule aqueous extract was advantageous during transesterification. Characterization of sodium/potassium oxide Phyto-nanocatalyst confirmed 23.5 nm nano-size and enhanced catalytic activity. Other characterizing tools are FTIR, DRS, XRD, Zeta potential, SEM, and EDX. Methyl ester formation was authenticated by FTIR, GC-MS, and NMR. A maximum 97% yield was obtained at optimized conditions i.e., methanol ratio to oil (8:1), catalyst amount (0.37 wt%), reaction duration (180 min), and temperature of 80 °C. The reusability of novel sodium/potassium oxide was checked for six reactions. Buxus papillosa fuel properties were within the international restrictions of fuel. The sulphur content of 0.00090% signified the environmental remedial nature of Buxus papillosa methyl esters and it is a highly recommendable species for biodiesel production at large scale due to a t huge number of seeds production and vast distribution.
Assuntos
Buxus , Gerenciamento de Resíduos , Resíduos Perigosos , Biocombustíveis/análise , Ésteres , Catálise , Sódio , Óleos de PlantasRESUMO
Attention given to environmental pollution caused by environmental analytical (EA) laboratories is very poor in Sri Lanka (an economically developing country). This article discusses EA laboratory effluents and hazardous solid wastes, current environmental management practices, and the legislative requirements in Sri Lanka. Effluent quantities generated are low (29.99-63.09 L/week), but characterized with variable pH, high chemical oxygen demand (COD), total suspended solids (TSS) and heavy metals, and very high ecotoxicity. Quantities of chemical-contaminated solid wastes is 80-100 kg/year (excluding outdated and rejected chemicals). Most laboratories dispose chemical-contaminated solid wastes mixed with non-hazardous recyclables using the services of local authorities and some laboratories (particularly in areas where there is no municipal solid waste collection), practice backyard dumping or open burning, while a few laboratories employ private parties to dispose or burn these wastes elsewhere. Only one laboratory is disposing chemical-contaminated solid wastes through co-processing. Appropriate waste management strategies (including some cleaner production concepts) are discussed in this paper for selected streams of hazardous wastes.
Assuntos
Resíduos Perigosos , Eliminação de Resíduos , Laboratórios , Resíduos Sólidos , Países em Desenvolvimento , Sri Lanka , Monitoramento Ambiental , Análise da Demanda Biológica de OxigênioRESUMO
Globally, industrialisation and urbanisation have led to the generation of hazardous waste (HW). Sustainable hazardous waste management (HWM) is the need of the hour for a safe, clean, and eco-friendly environment and public health. The prominent waste management strategies should be aligned with circular economic models considering the economy, environment, and efficiency. This review critically discusses HW generation and sustainable management with the strategies of prevention, reduction, recycling, waste-to-energy, advanced treatment technology, and proper disposal. In this regard, the major HW policies, legislations, and international conventions related to HWM are summarised. The global generation and composition of hazardous industrial, household, and e-waste are analysed, along with their environmental and health impacts. The paper critically discusses recently adapted management strategies, waste-to-energy conversion techniques, treatment technologies, and their suitability, advantages, and limitations. A roadmap for future research focused on the components of the circular economy model is proposed, and the waste management challenges are discussed. This review stems to give a holistic and broader picture of global waste generation (from many sources), its effects on public health and the environment, and the need for a sustainable HWM approach towards the circular economy. The in-depth analysis presented in this work will help build cost-effective and eco-sustainable HWM projects.
Assuntos
Gerenciamento de Resíduos , Gerenciamento de Resíduos/métodos , Resíduos Perigosos , Saúde Pública , Políticas , Gestão da Segurança , Reciclagem , Resíduos SólidosRESUMO
Sustainable valorization of tannery sludge (TS) is vital for achieving several sustainable development goals (SDGs) in the tannery industry. TS is considered a hazardous waste by-product posing a significant environmental challenge. However, TS can be utilized for energy or resource recovery by considering it as biomass and implementing the circular economy (CE) concept. Therefore, this study aims to develop an innovative DPSIR (Driver, Pressure, State, Impact, and Response) framework for promoting sustainable valorization of TS. Further, the study extends to quantify the importance of subjective DPSIR factors by offering interval-valued intuitionistic fuzzy number-based best worst method (IVIFN-BWM), which is relatively new in the literature and able to deal with the uncertainty, inconsistency, imprecise, and vagueness in the decision-making process. The study also investigates the most appropriate TS valorization technologies concerning identified DPSIR factors using a novel IVIFN-combined compromise solution (CoCoSo) approach. This research contributes to the literature by developing a comprehensive solution approach that combines the DPSIR framework, IVIFN-BWM, and IVIFN-CoCoSo method in addressing sustainability and resource recovery challenges for the tannery industry. The research findings highlight the potential of sustainable valorization of TS in reducing the waste amount and promoting sustainability and CE practices in the tannery industry. The findings indicated that response factors 'creation of national-level policies and awareness campaign' and 'facilitating financial support to adopt waste valorization technologies' received the highest priority among other DPSIR factors for managing and fostering sustainable valorization of TS. The IVIFN-CoCoSo analysis confirmed that the most promising TS valorization technology is 'gasification', which is followed by pyrolysis, anaerobic digestion, and incineration. The study's implications extend to policymakers, industrial practitioners, and researchers, who can leverage the research findings to develop more sustainable TS management practices in the tannery industry.
Assuntos
Resíduos Perigosos , Esgotos , Incineração , Incerteza , Desenvolvimento SustentávelRESUMO
The spread of antimony from mine wastes to the environment represents a matter of great concern due to its adverse effects on impacted ecosystems. There is an urgent need for developing and adopting sustainable and inexpensive measures to deal with this type of wastes. In this study the Sb leaching behavior of mine waste rocks and mine tailings derived from the exploitation of Sb ore deposits was characterized using standard batch leaching tests (TCLP and EN-12457-4) and column leaching essays. Accordingly, these mine wastes were characterized as toxic (>0.6 mg Sb L-1) and not acceptable at hazardous waste landfills (>5 mg Sb kg-1), showing also an ongoing Sb release under prolonged leaching conditions. Two industrial by-products were evaluated as amendments to stabilize them, namely deferrisation sludge (DFS) and a by-product derived from the treatment of aluminum salt slags (BP-Al). Mine wastes were amended with different doses (0-25%) of DFS or BP-Al and the performance of these treatments was evaluated employing also batch and column leaching procedures. The effectiveness of DFS to immobilize Sb was much higher than that exhibited by BP-Al. Thus, treatments with 25% BP-Al showed Sb immobilization levels of approximately 33-53%, whereas treatments with 5 and 25% DFS already attained Sb immobilization levels up to approximately 80-90 and 90-99%, respectively. Mine tailings amended with 5% DFS and mine waste rocks amended with 25% DFS decreased their leachable Sb contents below the limit for non-hazardous waste landfill acceptance (<0.7 mg Sb kg-1). Likewise, these DFS treatments were able to revert their toxic characterization. Moreover, the 25% DFS treatment showed to be a long-lasting stabilizing system, efficient at least during a leaching period equivalent to 10-year rainfall with a great Sb leaching reduction (close to 98%). After this long-term leaching process, DFS-treated mine wastes kept their non-hazardous and non-toxic characterization. The amorphous Fe (oxyhydr)oxides composing DFS were responsible for the important Sb removal capacity showed by this by-product. Thus, when DFS was applied to mine wastes mobile Sb was importantly fixed as non-desorbable Sb, showing also a considerable Sb removal capacity in presence of strong competing anions such as phosphate. The application of DFS as amendment presents a great potential to be used as a sustainable long-term stabilizing system of Sb mine wastes.
Assuntos
Antimônio , Ecossistema , Resíduos PerigososRESUMO
Biodiesel is considered the prospective substitute for non-renewable fossil fuel-derived sources of energy. However, the high costs of feedstocks and catalysts inhibit its large-scale industrial implementation. From this perspective, the utilization of waste as the source for both catalyst synthesis and feedstock for biodiesel is a rare attempt. Waste rice husk was explored as a precursor to prepare rice husk char (RHC). Sulfonated RHC was employed as a bifunctional catalyst for the simultaneous esterification and transesterification of highly acidic waste cooking oil (WCO) to produce biodiesel. The sulfonation process coupled with ultrasonic irradiation proved to be an efficient technique to induce high acid density in the sulfonated catalyst. The prepared catalyst possessed a sulfonic density and total acid density of 4.18 and 7.58 mmol/g, respectively, and a surface area of 144 m2/g. A parametric optimization was conducted for the conversion of WCO into biodiesel using the response surface methodology. An optimal biodiesel yield of 96% was obtained under the conditions of methanol to oil ratio (13:1), reaction time (50 min), catalyst loading (3.5 wt%), and ultrasonic amplitude (56%). The prepared catalyst showed higher stability up to five cycles with biodiesel yield greater than 80%.
Assuntos
Oryza , Óleos de Plantas , Resíduos Perigosos , Biocombustíveis/análise , Estudos Prospectivos , Esterificação , Catálise , CulináriaRESUMO
The healthcare sector is an ever-growing industry which produces a vast amount of waste each year, and it is crucial for healthcare systems to have an effective and sustainable medical waste management system in order to protect public health. Greek public hospitals in 2018 produced 9500 tons of hazardous healthcare wastes, and it is expected to reach 18,200 tons in 2025 and exceed 18,800 tons in 2030. In this paper, we investigated the factors that affect healthcare wastes. We obtained data from all Greek public hospitals and conducted a regression analysis, with the management cost of waste and the kilos of waste as the dependent variables, and a number of variables reflecting the characteristics of each hospital and its output as the independent variables. We applied and compared several models. Our study shows that healthcare wastes are affected by several individual-hospital characteristics, such as the number of beds, the type of the hospital, the services the hospital provides, the number of annual inpatients, the days of stay, the total number of surgeries, the existence of special units, and the total number of employees. Finally, our study presents two prediction models concerning the management costs and quantities of infectious waste for Greece's public hospitals and proposes specific actions to reduce healthcare wastes and the respective costs, as well as to implement and adopt certain tools, in terms of sustainability.
Assuntos
Eliminação de Resíduos de Serviços de Saúde , Gerenciamento de Resíduos , Atenção à Saúde , Grécia , Resíduos Perigosos , Hospitais Públicos , Humanos , Setor PúblicoRESUMO
This study proposed a decision support system (DSS) for optimizing transportation routing and disposal hub location for Thailand's local administrative organizations' hazardous waste management. The first step is to choose the origin and destination, as well as to collect data for each route. Each route's decision criteria were based on traffic quality and risk measures from the perspective of users. An analytic hierarchy process (AHP) was used to compute effective weights for decision criteria. To achieve optimal routing, AHP weights were combined with a zero-one goal programming technique. The DSS operates systematically and successfully, taking into account both transportation risk and socioeconomic factors, and provides appropriate routes. Overall, this waste management system may provide useful information to decision-makers for prioritizing disposal site alternatives and implementing feasible waste management actions. The zero-one location design was then used to determine the best hub location. Based on two scenarios of six and fifteen CoG hubs, the results revealed that the best model for managing a case company's hazardous waste was to establish 15 hubs scattered throughout the country for collecting points and then transporting them to the waste disposal plant in Phitsanulok province. Locating the hub near sink points would reduce transportation costs and backhaul issues, reducing the environmental impact of GHG emissions and increasing system efficiency.Implications: The problem of waste pollution has become increasingly serious all over the world, particularly in developing countries that face significant pollution control challenges. End-of-life wastes cause economic, health, and environmental problems if they are not properly managed. As the world's population and living standards rise, so does the amount of waste produced. The environmental impact is significant, with massive amounts of waste generated each year with only basic or minimal treatment to mitigate its impact. As a result, there is an urgent need for a method that can precisely optimize transportation routing and disposal hub location for Thailand's local administrative organizations' hazardous waste management (LAOs). The proposed decision support system (DSS) may provide useful information to decision-makers in prioritizing disposal site alternatives and implementing feasible waste management actions.
Assuntos
Eliminação de Resíduos , Gerenciamento de Resíduos , Resíduos Perigosos/análise , Eliminação de Resíduos/métodos , Tailândia , Meios de Transporte , Gerenciamento de Resíduos/métodosRESUMO
Hazardous waste pollutes the air, soil, and water and adversely affects human health if not disposed of safely. Analysis of the efficiency of hazardous waste disposal is essential to sustainable development. This paper uses the three-stage super-efficiency Data Envelopment Analysis model to measure the efficiency of 28 EU countries from 2004 to 2016. To ensure the reliability of the results, the article utilizes a one-way ANOVA statistical test to verify whether DEA results vary significantly across various EU countries. This article discusses "how inputs and outputs can be adjusted to eliminate inefficiencies" to suggest a targeted improvement. The third stage supper efficiency DEA results shows that the efficiency varies significantly across different EU countries. The main reasons for the low efficiency are high generated hazardous waste, management expenditure, greenhouse gas emissions, and inadequate waste disposal volume. Targeted proposals from three aspects are given for policymakers in EU countries: Build a resource recycling system to reduce hazardous waste. Establish a sound fee management system to reduce expenses. Optimization of disposal technology to improve incineration efficiency.
Assuntos
Eliminação de Resíduos , Gerenciamento de Resíduos , Resíduos Perigosos , Humanos , Incineração/métodos , Reciclagem , Eliminação de Resíduos/métodos , Reprodutibilidade dos Testes , Solo , Gerenciamento de Resíduos/métodosRESUMO
The industrial hazardous waste (IHW) generation to meet consumption is steadily increasing, resulting in environmental, health, and social problems around the world. To address IHW at the source, it is critical to understand the generation characteristics and key drivers on industrial hazardous waste generation (IHWG). This study analysed the generation characteristics of IHW of South Korea from 2008 to 2018 by decoupling and index decomposition analysis using Log Mean Divisia Index (LMDI) model. South Korea presented unstable decoupling of IHWG from economic growth, so more effective waste management regulations are needed to support a stable decoupling. One most critical finding was that the factors of industrial output and industrial characteristic of IHWG-to-energy were major driving factors influencing the increase of IHWG, whereas those of industrial structure and energy efficiency affect to the decrease of IHWG in most industries. In addition, the result clearly confirmed that the contribution of driving factors affecting the IHWG differs by industry. These results provide significant policy insights that the South Korean government needs institutional improvement and refinement of customised IHW management according to the characteristics of IHWG.
Assuntos
Resíduos Perigosos , Gerenciamento de Resíduos , Dióxido de Carbono/análise , China , Desenvolvimento Econômico , Resíduos Industriais , IndústriasRESUMO
Improper healthcare waste (HCW) management poses significant risks to the environment, human health, and socio-economic sustainability due to the infectious and hazardous nature of HCW. This research aims at rendering a comprehensive landscape of the body of research on HCW management by (i) mapping the scientific development of HCW research, (ii) identifying the prominent HCW research themes and trends, and (iii) providing a research agenda for HCW management towards a circular economy (CE) transition and sustainable environment. The analysis revealed four dominant HCW research themes: (1) HCW minimization, sustainable management, and policy-making; (2) HCW incineration and its associated environmental impacts; (3) hazardous HCW management practices; and (4) HCW handling and occupational safety and training. The results showed that the healthcare industry, despite its potential to contribute to the CE transition, has been overlooked in the CE discourse due to the single-use mindset of the healthcare industry in the wake of the infectious, toxic, and hazardous nature of HCW streams. The findings shed light on the HCW management domain by uncovering the current status of HCW research, highlighting the existing gaps and challenges, and providing potential avenues for further research towards a CE transition in the healthcare industry and HCW management.
Assuntos
Gerenciamento de Resíduos , Atenção à Saúde , Resíduos Perigosos , Humanos , IncineraçãoRESUMO
We evaluated two types of automotive basecoats used in automotive refinishing (i.e., in auto body shops): waterborne and solventborne. The primary tool we used for this evaluation was the Alternatives Assessment Guide (version 1.0) developed by the Interstate Chemicals Clearinghouse (IC2). The term "solventborne," as used in this article, refers to products that contain relatively high concentrations of volatile organic compounds (referred to as "high-volatile organic compound [VOC] basecoats" in the industry). These products are distinct from the "low-VOC" solventborne products used widely in California and elsewhere. From a health and environmental hazard perspective, our evaluation found that waterborne basecoats contained fewer hazardous ingredients and at lower concentrations than their solventborne counterparts. Automotive painters who spray-painted vehicles with waterborne products experienced significantly lower exposures to several harmful solvents. Waterborne products are readily available and offer advantages with regard to social impacts. Some of these advantages include lower worker and community exposure to VOCs, reduced VOC release and smog formation, and reduced potential for generation of and exposure to hazardous waste. Based on our assessment in auto body shops, we consider waterborne basecoats to be safer alternatives from both a human health and environmental perspective. Integr Environ Assess Manag 2022;18:1101-1113. Published 2021. This article is a U.S. Government work and is in the public domain in the USA.
Assuntos
Exposição Ocupacional , Compostos Orgânicos Voláteis , Automóveis , Resíduos Perigosos , Humanos , Exposição Ocupacional/análise , Pintura , Solventes , Estados UnidosRESUMO
The rise in living standards and the continuous development in the global economy led to the depletion of resources and increased waste generation per capita. This waste might posture a significant threat to human health or the environmental matrices (water, air, soil) when inadequately treated, transported, stored, or managed/disposed of. Therefore, effective waste management in an economically viable and environmentally friendly way has become meaningful. Prominent technology is the need of the day for circular economy and sustainable development to reduce the speed of depletion in resources and produce an alternative means for the future demands in the different sectors of science and technology. In order to meet the potential requirements for energy production or producing secondary raw material, solid waste may be the prime source. The activities of living organisms convert waste products in one form or another in which electronic waste (e-waste) is a modern-day problem that is growing by leaps and bounds. The disposal protocols of the e-waste management need to be given proper attention to avoid its hazardous impacts. The e-waste is obtained from any equipment or devices that run by electricity or batteries like laptops, palmtops, computers, televisions, mobile phones, digital video discs (DVD), and many more. E-waste is one of the rapidly growing causes of world pollution today. Plenty of research is available in the scientific literature, which shows different approaches being set up and followed to manage and dispose of waste products. These strategies to manage waste products designed by the states all over the globe revolves around minimal production, authentic techniques for the management of waste produced, reuse and recycling, etc. The virtual survey of the available literature on waste management shows that it lacks specificity regarding the management of waste products parallel to ecological sustainability. The presented review covers the sources, potential environmental impacts, and highlights the importance of waste management strategies to provide the latest and updated knowledge. The review also put forward the countermeasures that need to be taken on national and International levels addressing the sensitive issue of waste management.
Assuntos
Resíduos Perigosos , Gerenciamento de Resíduos , Humanos , Reciclagem , Solo , Resíduos SólidosRESUMO
In this study, wastes originating at each production station during refrigerator manufacturing were identified and classified based on a waste tree. A mass balance study revealed a total waste production factor of 0.046 kg/kg of a product of which 75.3%, 23.9%, and 0.8% were non-hazardous wastes (NHWs), packaging wastes (PWs), and hazardous wastes (HWs), respectively. Wastes produced during refrigerator manufacturing were grouped under 35 different waste codes. Waste codes that contributed more than 5% by weight were 15 02 02 (contaminated absorbent material), 15 01 10 (contaminated packaging), 16 02 13 (electronic cards), 07 02 14 (polyol) and 08 05 01 (isocyanates), 19 08 13 (treatment sludge), 16 02 15 (capacitors), and 13 01 13 (hydraulic oil) for HWs, 12 01 01 (ferrous metal), and 16 02 16 (components) for NHWs, and, finally, 15 01 03 (wooden), 15 01 01 (paper&cardboard), and 15 01 02 (plastic) for PWs over 5 years. Scrap costs were used as a surrogate to determine production stages that generated high amounts of metal and plastic wastes. Logarithmically, increasing and decreasing trends were observed for PWs and NHWs over the study period, respectively. HW amounts did not exhibit a statistically significant trend. Twenty-eight BATs (best available techniques) were identified that could be applied in refrigerator manufacturing for waste minimization and management. Among those, 8 of them were proposed for further improvement for waste management in the facility.
Assuntos
Árvores , Gerenciamento de Resíduos , Resíduos Perigosos/análise , Instalações Industriais e de Manufatura , PlásticosRESUMO
A total of 214 sampling sites of a hazardous waste disposal center were surveyed in a two-stage pollution investigation, including soil boreholes and groundwater monitoring wells. Results showed that chemical oxygen demand (COD) (4.00-2930.00 mg/L), fluoride (0.07-9.08 mg/L), chromium (0.12-1.20 µg/L), nickel (0.15-459.00 µg/L), lead (0.10-10.20 µg/L), cadmium (Cd) (0.05-16.40 µg/L), and beryllium (0.06-3.48 µg/L) were detected in groundwater samples. For soils, Cd in soil (78.7 mg/kg) exceeded the risk screening value (65 mg/kg) for soil contamination of the second type of development land (GB36600-2018), and there remained the risk of leakage in the landfill detection investigation. Then, a health risk assessment was carried out. Based on the definitions of the groundwater exposure pathway (HJ 25.3-2019) and the pollution investigation of groundwater, the carcinogenic and non-carcinogenic risks of groundwater were generally considered to be negligible. The carcinogenic risk and non-carcinogenic risk of the concerned pollutant in soil for risk assessment (Cd) under the condition of reutilization exceeded the corresponding acceptable levels (1E-06 and 1). The (non-)carcinogenic risk of Cd mainly came from oral intake of soil and inhalation of soil particles under two conditions of reutilization and non-utilization, so on-site workers and surrounding residents should be properly protected from the mouth and nose to minimize the intake of pollutants from the soil and soil particles. The area of soil contaminated by Cd was about 630.58 m2, and the amount of pollution was about 1261.16 m3. The heavy metal pollution was only distributed in the depth range of 0-2 m, and the suggested risk control value of soil pollutants under the condition of reutilization for Cd was 56 mg/kg. Based on different pollution characteristics of soil, groundwater, and the landfill, targeted control measures were proposed.
Assuntos
Água Subterrânea , Metais Pesados , Monitoramento Ambiental , Resíduos Perigosos/efeitos adversos , Humanos , Metais Pesados/análise , Medição de RiscoAssuntos
Teste para COVID-19/economia , COVID-19/diagnóstico , Resíduos Perigosos/prevenção & controle , SARS-CoV-2/patogenicidade , Biomarcadores/sangue , COVID-19/terapia , COVID-19/virologia , Teste para COVID-19/instrumentação , Teste para COVID-19/métodos , Análise Custo-Benefício , Resíduos Perigosos/economia , Humanos , Testes Imediatos/economia , Testes Imediatos/organização & administração , Guias de Prática Clínica como Assunto , SARS-CoV-2/genética , SARS-CoV-2/imunologiaRESUMO
Nowadays, together with the economic development, public health activities have gained substantial attention with increasing number of hospitals during the past decades. A multi-method approach involving site visits, questionnaires, and interviews, in combination with secondary data revealed that the healthcare waste (HCW) generation, varied with different specialties (general or pediatric/obstetric hospitals) and different level of hospitals (central, provincial, district levels). The HCW generation from different kinds of surveyed hospitals varied from 0.8 to 1.0 kg/bed/day for domestic waste, 0.15 to 0.25 kg/bed/day for infectious and hazardous waste, and less than 0.1 kg/bed/day for recycled waste. Only 94.3% of central hospitals, 92% of provincial hospitals, and 82% of district hospitals complied with national regulation in hazardous medical waste treatment. For healthcare wastewater treatment, the actual operating rates were 91%, 73%, and 50% for central, provincial, and district hospitals, respectively. The cost for HCW management accounted for only 10-15% of the total budget allocated for the medical facilities. Most of the provincial hospitals spent about $0.2-$0.4/bed/year for HCW management. This is the root cause of ineffective HCW management.
Assuntos
Eliminação de Resíduos de Serviços de Saúde , Resíduos de Serviços de Saúde , Gerenciamento de Resíduos , Criança , Atenção à Saúde , Resíduos Perigosos , Humanos , VietnãRESUMO
Industrial waste management generated by different petrochemical complexes at Pars Special Economic Energy Zone, located in the south of Iran, was investigated. All 10 active petrochemical complexes were visited and generated wastes were identified by a checklist. Petrochemical plants were classified regarding feeds, process, and products and nine representative wastes were sampled. Physicochemical characteristics were analyzed and appropriate management approaches were proposed according to the literature review and the results of waste characterization. The generated wastes were classified as hazardous and non-hazardous according to the Basel Convention and Environmental Protection Agency lists of waste classification. Also, the concentrations of organic compounds and heavy metals were measured to classify wastes characteristically. Comparing concentrations of the most important heavy metals in sampled wastes illustrated that sandblast with Cu concentration of 4295 mg kg-1, spent activated carbon with Hg concentration of 127 mg kg-1, and spent catalyst with 25% Ni content can be categorized as hazardous wastes, due to the exceeding Total Threshold Limit Concentration levels. Based on laboratory results, all industrial waste generated in the petrochemical complexes were categorized into three groups, namely Organic Waste with High Calorific Value, Non-organic Recyclable Waste, and Non-organic Non-recyclable Waste. Finally, management approaches, including material recycling, energy recovery (through incineration), and landfilling, were proposed and a conceptual model was suggested in order to show different routes and final destination for each kind of waste generated in all similar petrochemical complexes.