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1.
Environ Sci Pollut Res Int ; 31(24): 36052-36063, 2024 May.
Artigo em Inglês | MEDLINE | ID: mdl-38744768

RESUMO

Industrialization and the ever-increasing world population have diminished high-quality water resources for sustainable agriculture. It is imperative to effectively treat industrial effluent to render the treated water available for crop cultivation. This study aimed to assess the effectiveness of textile effluent treated with Trametes pubescens MB 89 in supporting maize cultivation. The fungal treatment reduced the amounts of Co, Pb and As in the textile effluent. The biological oxygen demand, total dissolved solids and total suspended solids were within the permissible limits in the treated effluent. The data indicated that the irrigation of maize with fungal-treated textile effluent improved the growth parameters of the plant including root, shoot length, leaf area and chlorophyll content. Moreover, better antioxidant activity, total phenol content and protein content in roots, stems and leaves of maize plants were obtained. Photosynthetic parameters (potential quantum yield, electron transport rate and fluorescence yield of non-photochemical losses other than heat) were also improved in the plants irrigated with treated effluent as compared to the control groups. In conclusion, the treatment of textile effluent with the immobilized T. pubescens presents a sustainable solution to minimize chemical pollution and effectively utilize water resources.


Assuntos
Têxteis , Trametes , Trametes/metabolismo , Zea mays , Eliminação de Resíduos Líquidos/métodos , Poluentes Químicos da Água , Águas Residuárias/química
2.
Anal Methods ; 16(21): 3372-3384, 2024 May 30.
Artigo em Inglês | MEDLINE | ID: mdl-38747244

RESUMO

Microfluidic channels fabricated over fabrics or papers have the potential to find substantial application in the next generation of wearable healthcare monitoring systems. The present work focuses on the fabrication procedures that can be used to obtain practically realizable fabric-based microfluidic channels (µFADs) utilizing patterning masks and wax, unlike conventional printing techniques. In this study, comparative analysis was used to differentiate channels obtained using different masking tools for channel patterning as well as different wax materials as hydrophobic barriers. Drawbacks of the conventional tape and candle wax technique were noted and a novel approach was used to create microfluidic channels through a facile and simple masking technique using PVC clear sheets as channel stencils and beeswax as the channel barriers. The resulting fabric based microfluidic channels with varying widths as well as complex microchannel, microwell, and micromixer designs were investigated and a minimum channel width resolution of 500 µm was successfully obtained over cotton based fabrics. Thereafter, the PVC clear sheet-beeswax based microwells were successfully tested to confine various organic and inorganic samples indicating vivid applicability of the technique. Finally, the microwells were used to make a simple and facile colorimetric assay for glucose detection and demonstrated effective detection of glucose levels from 10 mM to 50 mM with significant color variation using potassium iodide as the coloring agent. The above findings clearly suggest the potential of this alternative technique for making low-cost and practically realizable fabric based diagnostic devices (µFADs) in contrast to the other approaches that are currently in use.


Assuntos
Cloreto de Polivinila , Têxteis , Ceras , Ceras/química , Cloreto de Polivinila/química , Colorimetria/métodos , Colorimetria/instrumentação , Técnicas Analíticas Microfluídicas/instrumentação , Técnicas Analíticas Microfluídicas/métodos , Análise Custo-Benefício , Glucose/análise , Dispositivos Lab-On-A-Chip , Humanos , Desenho de Equipamento , Dispositivos Eletrônicos Vestíveis
3.
PLoS One ; 19(5): e0304578, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-38820452

RESUMO

The study explores the strategic pricing and quality improvement decisions under uncertain demand in a three-layer textile and garment supply chain. According to whether the fabric manufacturer (FM) invests in quality or not and whether the garment manufacturer (GM) or garment retailer (GR) is willing to share the costs or not, five game models are constructed to investigate the impact of different members' cost sharing on the optimal decisions and profits. By conducting a theoretical and numerical analysis, we find that: (1) The GM's or GR's cost sharing plays a positive effect on the quality improvement, as for whose cost sharing performs better in improving the quality depending on the proportion of cost sharing, and the quality improvement is highest with both members share the costs simultaneously. (2) The FM receives the highest profit when both members share the costs simultaneously, however, whose cost sharing is more profitable for the FM is also related to the proportion of cost sharing; in short, the FM always benefits from the cost sharing, no matter one member does this or two members do this. (3) The GM (GR) gains the highest profit when only the GR (GM) shares the costs, and the results indicate that if one member has shared the costs, whether the other member engaging in cost sharing could benefit the former depending on their proportions. Specifically, when the GM (GR) chooses to share the costs and the proportion is relatively low, the GR(GM) joining in cost sharing is beneficial to the former; otherwise, is harmful.


Assuntos
Vestuário , Melhoria de Qualidade , Têxteis , Têxteis/economia , Vestuário/economia , Custos e Análise de Custo , Incerteza , Humanos , Indústria Têxtil/economia , Modelos Econômicos
4.
Waste Manag ; 182: 74-90, 2024 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-38643525

RESUMO

To understand which are the best strategies for textile waste management and to analyse the effects on the environment of applying circular economy practices to textile products, a review of 45 publications where life cycle assessment (LCA) is applied to these topics has been carried out. The separate collection of textiles, followed by reuse and recycling brings relevant environmental benefits, with impacts related to reuse resulting lower than those of recycling. At the opposite, when mixed municipal solid waste is addressed to energy recovery, the textile fraction is the second most impacting on climate change, right after plastics, while for landfill disposal impacts textiles directly follow the more biodegradable fractions. Textiles manufacturing using recycled fibres generally gives lower impacts than using virgin ones, with a few exceptions in some impact categories for cotton and polyester. The circular practices with the lowest impacts are those that ensure the extension of the textiles service life. Another aim of this review is to identify the main variables affecting the life cycle impact assessment (LCIA). These resulted to be the yield and material demand of recycling processes, the use phase variables, the assumptions on virgin production replaced by reuse or recycling, the substitution factor in reuse, and transportation data in business models based on sharing. Thus, in LCA modelling, great attention should be paid to these variables. Future research should address these aspects, to acquire more relevant data, based on industrial-scale processes and on people habits towards the circular economy strategies applied to textiles.


Assuntos
Reciclagem , Têxteis , Gerenciamento de Resíduos , Reciclagem/métodos , Gerenciamento de Resíduos/métodos , Indústria Têxtil , Resíduos Sólidos/análise
5.
ACS Appl Mater Interfaces ; 16(14): 18202-18212, 2024 Apr 10.
Artigo em Inglês | MEDLINE | ID: mdl-38551998

RESUMO

Textile-based sweat sensors display great potential to enhance wearable comfort and health monitoring; however, their widespread application is severely hindered by the intricate manufacturing process and electrochemical characteristics. To address this challenge, we combined both impregnation coating technology and conjugated electrospinning technology to develop an electro-assisted impregnation core-spinning technology (EAICST), which enables us to simply construct a sheath-core electrochemical sensing yarn (TPFV/CPP yarn) via coating PEDOT:PSS-coated carbon fibers (CPP) with polyurethane (TPU)/polyacrylonitrile (PAN)/poloxamer (F127)/valinomycin as shell. The TPFV/CPP yarn was sewn into the fabric and integrated with a sensor to achieve a detachable feature and efficiently monitor K+ levels in sweat. By introducing EAICST, a speed of 10 m/h can be realized in the continuous preparation of the TPFV/CPP yarn, while the interconnected pores in the yarn sheath enable it to quickly capture and diffuse sweat. Besides, the sensor exhibited excellent sensitivity (54.26 mV/decade), fast response (1.7 s), anti-interference, and long-term stability (5000 s or more). Especially, it also possesses favorable washability and wear resistance properties. Taken together, this study provides a crucial technical foundation for the development of advanced wearable devices designed for sweat analysis.


Assuntos
Técnicas Biossensoriais , Dispositivos Eletrônicos Vestíveis , Suor/química , Poliuretanos/química , Fibra de Carbono , Têxteis
6.
Environ Sci Pollut Res Int ; 31(19): 27817-27828, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38517631

RESUMO

Water and several chemicals, including dyestuffs, surfactants, acids, and salts, are required during textile dyeing processes. Surfactants are harmful to the aquatic environment and induce several negative biological effects in exposed biota. In this context, the present study aimed to assess acute effects of five surfactants, comprising anionic and nonionic classes, and other auxiliary products used in fiber dyeing processes to aquatic organisms Vibrio fischeri (bacteria) and Daphnia similis (cladocerans). The toxicities of binary surfactant mixtures containing the anionic surfactant dodecylbenzene sulfonate + nonionic fatty alcohol ethoxylate and dodecylbenzene sulfonate + nonionic alkylene oxide were also evaluated. Nonionic surfactants were more toxic than anionic compounds for both organisms. Acute nonionic toxicity ranged from 1.3 mg/L (fatty alcohol ethoxylate surfactant) to 2.6 mg/L (ethoxylate surfactant) for V. fischeri and from 1.9 mg/L (alkylene oxide surfactant) to 12.5 mg/L (alkyl aryl ethoxylated and aromatic sulfonate surfactant) for D. similis, while the anionic dodecylbenzene sulfonate EC50s were determined as 66.2 mg/L and 19.7 mg/L, respectively. Both mixtures were very toxic for the exposed organisms: the EC50 average in the anionic + fatty alcohol ethoxylate mixture was of 1.0 mg/L ± 0.11 for V. fischeri and 4.09 mg/L ± 0.69 for D. similis. While the anionic + alkylene oxide mixture, EC50 of 3.34 mg/L for D. similis and 3.60 mg/L for V. fischeri. These toxicity data suggested that the concentration addition was the best model to explain the action that is more likely to occur for mixture for the dodecylbenzene sulfonate and alkylene oxide mixtures in both organisms. Our findings also suggest that textile wastewater surfactants may interact and produce different responses in aquatic organisms, such as synergism and antagonism. Ecotoxicological assays provide relevant information concerning hazardous pollutants, which may then be adequately treated and suitably managed to reduce toxic loads, associated to suitable management plans.


Assuntos
Aliivibrio fischeri , Benzenossulfonatos , Daphnia , Tensoativos , Águas Residuárias , Poluentes Químicos da Água , Tensoativos/toxicidade , Poluentes Químicos da Água/toxicidade , Águas Residuárias/química , Aliivibrio fischeri/efeitos dos fármacos , Animais , Daphnia/efeitos dos fármacos , Ecotoxicologia , Têxteis
7.
Mar Pollut Bull ; 200: 116062, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-38290364

RESUMO

The present study aims to address the issue of oil in water pollution by application of a superhydrophobic cotton fabric. The superhydrophobic cotton fabric with a water contact angle of 158 ± 2°, is developed by a solution immersion technique using zirconium dioxide (ZrO2) nanoparticles and hexadecyltrimethoxysilane. The synthesis parameters such as concentration, curing temperature, and immersion time were optimized using Box-Behnken design method. With mechanical durability, chemical resilience and thermal stability, the coated fabric can separate different oil-water mixtures with an efficiency of 99.9 %. The coated fabric can also be reused for 50 separation cycles in acidic and neutral medium. Besides, droplet dynamic behavior of oil-water mixture has also been studied to ascertain the effect of mixture impact velocities on separation performance. Additionally, coated fabric possesses self-cleaning feature, which makes it viable for muddy oil-water separation. Prepared coated fabric holds tremendous potential for industrial use and oil-water separation in extreme conditions.


Assuntos
Indústrias , Têxteis , Água , Poluição da Água , Interações Hidrofóbicas e Hidrofílicas
8.
J Environ Manage ; 351: 119965, 2024 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-38171128

RESUMO

The textile industry in Bangladesh faces environmental and health challenges due to the disposal of solid waste from Effluent Treatment Plants (ETPs). To address this issue, a study was conducted using soil from a brick industry near Dhaka, amending it with varying amounts of dry sludge to create clay bricks. The original soil had a loam texture and medium plasticity. The research found that adding 9 wt% of sludge resulted in Grade A commercial bricks with a compressive strength of 15.33 MPa and water absorption of 13.33 wt%, meeting BDS 208 standards. However, these sludge-incorporated bricks experienced more shrinkage during the burning process due to organic content, requiring additional soil to maintain conventional dimensions. Also, to assess the health hazards of these sludge-incorporated bricks, a leaching test was performed, revealing that no toxic heavy metals (Pb, Cd, Cr, Cu, Ni, and Zn) in the leachate exceeded the limits set by the United States Environmental Protection Agency (USEPA). The study indicates that textile ETP sludge can serve as a sustainable raw material for bricks, potentially reducing the environmental burden caused by textile sludge disposal by 28.75%. This innovative approach offers a promising solution to both environmental and health concerns associated with textile waste in Bangladesh's industrial sector.


Assuntos
Metais Pesados , Esgotos , Argila , Materiais de Construção , Bangladesh , Solo , Têxteis , Medição de Risco , Metais Pesados/análise
9.
Sci Total Environ ; 913: 169721, 2024 Feb 25.
Artigo em Inglês | MEDLINE | ID: mdl-38171461

RESUMO

The textile industry is one of the most chemical-intensive processes, resulting in the unquestionable pollution of more than a quarter of the planet's water bodies. The high recalcitrant properties of some these pollutants resulted on the development of treatment technologies looking at the larger removal efficiencies, due to conventional systems are not able to completely remove them in their effluents. However, safeguarding the environment also implies taking into account indirect pollution from the use of chemicals and energy during treatment. On the other hand, the emerged technologies need to be economically attractive for investors and treatment managers. Therefore, the costs should be kept under control. For this reason, the present study focuses on a comparative Life Cycle Assessment and Life Cycle Costing of four scale-up scenarios aiming at mono and di-azo reactive dyes removal from textile wastewater. Two reactors (sequencing batch reactor and two-phase partitioning) were compared for different reaction environments (i.e., single anaerobic and sequential anaerobic-aerobic) and conditions (different pH, organic loading rates and use of polymer). In accordance with the results of each scenario, it was found that the three technical parameters leading to a change in the environmental profiles were the removal efficiency of the dyes, the type of dye eliminated, and the pollutant influent concentration. The limitation of increasing organic loading rates related to the biomass inhibition could be overcame through the use of a novel two-phased partitioning bioreactor. The use of a polymer at this type of system may help restore the technical performance (84.5 %), reducing the toxic effects of effluents and consequently decreasing the environmental impact. In terms of environmental impact, this is resulting into a reduction of the toxic effects of textile effluents in surface and marine waters compared to the homologous anaerobic-aerobic treatment in a sequencing batch reactor. However, the benefits achieved for the nature comes with an economic burden related to the consumption of the polymer. It is expected that the cost of investment of the treatment with the two-phase partitioning bioreactor rises 0.6-8.3 %, depending on market prices, compared to the other analyzed sequential anaerobic-aerobic technologies. On the other side, energy and chemical consumption did not prove to be limiting factors for economic feasibility.


Assuntos
Águas Residuárias , Poluentes Químicos da Água , Humanos , Corantes , Compostos Azo , Polímeros , Reatores Biológicos , Têxteis , Eliminação de Resíduos Líquidos/métodos
10.
Waste Manag Res ; 42(2): 135-145, 2024 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-37313862

RESUMO

Clothing is one of the primary human needs, but today's business models turned most apparel into a disposable product. As a matter of fact, the rising demand results in the production of Millions of tons of textile waste every year which is either landfilled, incinerated or exported, with only small amounts being recycled. One promising recycling attempt towards a circular economy in the apparel sector is fibre-to-fibre recycling, where end-of-use clothes serve as input material for the production of new fibres and, eventually, new apparel. In this work, together with fashion brands and a textile research organisation, a mapping of the market situation and the economic boundary conditions regarding textile fibre recycling are presented. Generally, fibre-to-fibre recycling technologies need more public attention and intensive research, and development is necessary as well as legislative instruments that encourage interest in textile recycling. The market situation for recycled fibres is promising and will tend to an increased demand in recycled fibres in the future. Mandatory certification ensures a sustainable product and fast fashion should be held back. Textile waste landfilling, export regulations as well as sustainable lifestyle education shall be considered by EU legislature to ensure that recycling materials are actually used and create a market pull for textile waste back into the industry.


Assuntos
Reciclagem , Gerenciamento de Resíduos , Humanos , Têxteis , Indústrias , Gerenciamento de Resíduos/métodos
11.
NanoImpact ; 33: 100488, 2024 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-37940075

RESUMO

A nanomaterial life-cycle risk assessment (Nano LCRA) of a graphene-enabled textile used in the construction of heat and fire-resistant personal protective equipment (PPE) was conducted to develop, analyze, and prioritize potential occupational, health and environmental risks. The analysis identifies potential receptors and exposure pathways at each product life-cycle stage and makes a qualitative evaluation of the potential significance of each scenario. A literature review, quality evaluation, and database were developed as part of the LCRA to identify potential hazards associated with graphene-based materials (GBMs) throughout the product life-cycle. Generally, risks identified from graphene-enabled textiles were low. Of the developed exposure scenarios, occupational inhalation exposures during raw material and product manufacturing ranked highest. The analysis identifies the key potential human and environmental hazards and exposures of the products across the product life-cycle of graphene enabled textiles. Priority research gaps to reduce uncertainty include evaluating long-term, low dose graphene exposures typical of the workplace, as well as the potential release and hazard characterization of graphene-acrylic nanocomposites.


Assuntos
Grafite , Nanocompostos , Exposição Ocupacional , Humanos , Exposição Ocupacional/prevenção & controle , Medição de Risco , Têxteis
12.
Environ Res ; 242: 117731, 2024 Feb 01.
Artigo em Inglês | MEDLINE | ID: mdl-38007080

RESUMO

The determination of hexavalent chromium in textiles and clothes is challenging since during extraction, the original oxidation state should not be altered. Since, as a matter of fact, current analytical methods are focused only on total chromium determination, the purpose of this research is to develop a reliable analytical method for the determination of Cr(VI) in textiles and tissues of daily use for a reliable application of risk analysis models, which are usually based on total Cr data. After optimization, a 0.0025 M Na3PO4 extraction solution was selected for the extraction of Cr(VI) from textiles. This solution minimizes possible interconversion redox reactions and interference, and provides good extraction recoveries (88.4 ± 2.5% - 105.5 ± 0.6 %, according to Cr(VI) concentration) and quantitation limits (0.017 mg/kg), fully complying the current limits set for Cr(VI) in textiles in contact with skin, and for leachable Cr(VI). The developed method was validated investigating intra-day repeatability (n = 10) and inter-day repeatability (n = 30) which were below 12%, and matrix effect which was below 6% confirming the precision of the method and the negligibility of a matrix interference during the whole analysis. The method, which was proved to be suited also for bioaccessibility studies in saliva and sweat, was applied to the analysis of tank top, coloured paper napkin, polyamide tights, panties, highlighting Cr(VI) content in the panties only at very low concentration (0.028 mg/kg). As verified by ECHA and US EPA approaches, this amount does not pose a non-carcinogenic risk for human health. As regards carcinogenic risk, considering both adult and child exposure, the dermal contact with the panties poses an acceptable risk (R ≤ 10-6).


Assuntos
Cromatografia , Cromo , Adulto , Criança , Humanos , Cromo/análise , Medição de Risco , Carcinógenos/análise , Têxteis
13.
Environ Res ; 242: 117716, 2024 Feb 01.
Artigo em Inglês | MEDLINE | ID: mdl-37995999

RESUMO

The textile industry is a major contributor to global waste, with millions of tons of textiles being discarded annually. Material and energy recovery within circular economy offer sustainable solutions to this problem by extending the life cycle of textiles through repurposing, recycling, and upcycling. These initiatives not only reduce waste but also contribute to the reduction of the demand for virgin materials (i.e. cotton, wool), ultimately benefiting the environment and society. The circular economy approach, which aims to recreate environmental, economic, and societal value, is based on three key principles: waste reduction, material circulation, and ecological restoration. Given these difficulties, circularity incorporates the material recovery approach, which is focused on the conversion of waste into secondary raw resources. The goal of this notion is to extract more value from resources by prolonging final disposal as long as feasible. When a textile has outlived its functional life, material recovery is critical for returning the included materials or energy into the manufacturing cycle. The aim of this paper is to examine the material and energy recovery options of main raw materials used in the fashion industry while highlighting the need of close observation of the relation between circularity and material recovery, including the investigation of barriers to the transition towards a truly circular fashion industry. The final results refer to the main barriers of circular economy transition within the industry and a framework is proposed. These insights are useful for academia, engineers, policy makers and other key stakeholders for the clear understanding of the industry from within and highlight beyond circular economy targets, SDGs interactions with energy and material recovery of textile waste (SDG 7, SDG 11, SDG 12 etc.).


Assuntos
Reciclagem , Gerenciamento de Resíduos , Animais , Têxteis , Indústrias , Indústria Têxtil
14.
Biomed Tech (Berl) ; 69(1): 17-26, 2024 Feb 26.
Artigo em Inglês | MEDLINE | ID: mdl-37650423

RESUMO

OBJECTIVES: The aim of this study was to investigate the potential of tuning the topography of textile surfaces for biomedical applications towards modified cell-substrate interactions. METHODS: For that purpose, a supercritical Nitrogen N2 jet was used to spray glass particles on multi-filament polyethylene terephthalate (PET) yarns and on woven fabrics. The influence of the jet projection parameters such as the jet pressure (P) and the standoff distance (SoD) on the roughness was investigated. RESULTS: The impact of the particles created local filament ruptures on the treated surfaces towards hairiness increase. The results show that the treatment increases the roughness by up to 17 % at P 300 bars and SoD 300 mm while the strength of the material is slightly decreased. The biological study brings out that proliferation can be slightly limited on a more hairy surface, and is increased when the surface is more flat. After 10 days of fibroblast culture, the cells covered the entire surface of the fabrics and had mainly grown unidirectionally, forming cell clusters oriented along the longitudinal axis of the textile yarns. Clusters were generated at yarn crossings. CONCLUSIONS: This approach revealed that the particle projection technology can help tuning the cell proliferation on a textile surface.


Assuntos
Fibroblastos , Polietilenotereftalatos , Têxteis
15.
ACS Appl Mater Interfaces ; 16(1): 1428-1438, 2024 Jan 10.
Artigo em Inglês | MEDLINE | ID: mdl-38150614

RESUMO

Smart wearable technology has been more and more widely used in monitoring and prewarning of human health and safety, while flexible yarn-based strain sensors have attracted extensive research interest due to their ability to withstand greater external strain and their significant application potential in real-time monitoring of human motion and health signals. Although several strain sensors based on yarn structures have been reported, it remains challenging to strike a balance between high sensitivity and wide strain ranges. At the same time, visual signal sensing is expected to be used in strain sensors thanks to its intuitiveness. In this work, thermoplastic polyurethane (TPU) and tetraphenylethylene (TPE) were wet-spun to fabricate flexible fluorescent fibers used as the substrate of the sensor, followed by the drop addition of polydimethylsiloxane (PDMS) beads and curing to produce a heterogeneous structure, which were further twisted into a plied yarn. Finally, a visualizable flexible yarn strain sensor based on solidified liquid beads and crack structure was obtained by loading polydopamine (PDA) and polypyrrole (PPy) in situ. The sensor exhibited high sensitivity (the GF value was 58.9 at the strain range of 143-184%), a wide working strain range (0-184%), a low monitoring limit (<0.1%), a fast response (58.82 ms), reliable responses at different frequencies, and excellent cycle durability (over 2000 cycles). At the same time, the yarn strain sensor also had excellent photothermal characteristics and a fluorescence crack visualization effect. These attractive advantages enabled yarn strain sensors to accurately monitor various human activities, showing great application potential in health monitoring, personalized medical diagnosis, and other aspects.


Assuntos
Polímeros , Poliuretanos , Estilbenos , Humanos , Poliuretanos/química , Têxteis , Pirróis
16.
Environ Res ; 245: 118041, 2024 Mar 15.
Artigo em Inglês | MEDLINE | ID: mdl-38160973

RESUMO

In recent years, there has been a growing focus on treating textile wastewater due to its escalating threat to aquatic ecosystems and exposed communities. The present study investigates the adsorption efficacy of biopolymer functionalized nanoscale zero-valent iron (CS@nZVI) composite for the treatment of textile wastewater using the RSM-CCD model. The structure and morphology of CS@nZVI were characterized using XRD, FTIR, FESEM, and EDX. CS@nZVI was then evaluated for its adsorption potential in removing COD, color, and other physico-chemical parameters from textile wastewater. The results showed the high efficacy of CS@nZVI for COD and color removal from textile wastewater. Under optimal conditions (pH 6, contact time 60 min, and 1.84 g CS@nZVI), COD removal reached a maximum of 85.53%, and decolorization efficiency was found to be 89.73%. The coefficient of determination R2 (0.98) and AIC (269.75) values suggested quadratic model as the best-fitted model for optimizing the process parameters for COD removal. Additionally, the physico-chemical parameters were found to be within permissible limits after treatment with CS@nZVI. The influence of coexisting ions on COD removal followed the order PO43- > SO42- > Cl- >Na+ > Ca2+. The kinetics data fitted well with the pseudo-first-order reaction, indicating physisorption as the primary mechanism. The thermodynamic study revealed the endothermic nature of the removal process. Reusability tests demonstrated that great regeneration capacity of spent CS@nZVIafter five consecutive cycles. Furthermore, toxicological studies showed reduced toxicity in treated samples, leading to improved growth of Vigna radiata L. These findings suggest that CS@nZVI bionanocomposites could serve as an efficient, cost-effective, and eco-friendly remediation agent for the treatment of textile effluents, presenting significant prospects for commercial applications.


Assuntos
Quitosana , Poluentes Químicos da Água , Águas Residuárias/toxicidade , Quitosana/química , Ecossistema , Poluentes Químicos da Água/análise , Têxteis , Adsorção
17.
Sensors (Basel) ; 23(22)2023 Nov 16.
Artigo em Inglês | MEDLINE | ID: mdl-38005593

RESUMO

The development of smart wearable solutions for monitoring daily life health status is increasingly popular, with chest straps and wristbands being predominant. This study introduces a novel sensorized T-shirt design with textile electrodes connected via a knitting technique to a Movesense device. We aimed to investigate the impact of stationary and movement actions on electrocardiography (ECG) and heart rate (HR) measurements using our sensorized T-shirt. Various activities of daily living (ADLs), including sitting, standing, walking, and mopping, were evaluated by comparing our T-shirt with a commercial chest strap. Our findings demonstrate measurement equivalence across ADLs, regardless of the sensing approach. By comparing ECG and HR measurements, we gained valuable insights into the influence of physical activity on sensorized T-shirt development for monitoring. Notably, the ECG signals exhibited remarkable similarity between our sensorized T-shirt and the chest strap, with closely aligned HR distributions during both stationary and movement actions. The average mean absolute percentage error was below 3%, affirming the agreement between the two solutions. These findings underscore the robustness and accuracy of our sensorized T-shirt in monitoring ECG and HR during diverse ADLs, emphasizing the significance of considering physical activity in cardiovascular monitoring research and the development of personal health applications.


Assuntos
Atividades Cotidianas , Têxteis , Humanos , Frequência Cardíaca/fisiologia , Eletrocardiografia , Monitorização Fisiológica/métodos
18.
J Environ Manage ; 347: 119040, 2023 Dec 01.
Artigo em Inglês | MEDLINE | ID: mdl-37751666

RESUMO

Microfiber from textiles is one of the new anthropogenic pollutants which attracted a wide range of researchers. Domestic laundry, being the most common cause of microfiber release from textiles, is widely studied. Studies exhibit a broad range of quantities of microfibers owing to the distinct quantification methodologies employed due to their convenience and resource availability. Out of several such estimation processes, reporting microfiber quantity in numbers or mass (mg or g) is quite common with respect to the unit area or weight of the textile used. However, results reported by different literature vary significantly. Hence, this study aims to analyze the microfiber release from knitted polyester fabric using count- and mass-based methods. Four different fabrics were used for this study with three different counting processes from literature along with direct weight difference estimation. The results of the direct counting method showed that the average microfiber release of selected fabrics is 13.28-33.16 microfibers per sq.cm, whereas, the direct weight estimation showed an average weight of 0.0664 ± 0.0289 mg/sq.cm. The subsequent conversion showed a release of 887.89 ± 633.49 microfibers/sq.cm of the fabric. Further, the microfiber mass was also estimated using the number of microfiber count and found that a sq.cm of fabric releases up to 0.0010-0.0024 mg of microfibers. While comparing the results, the weight-based estimation showed a significantly higher microfiber release (41.3-42.9 times) than the direct counting method. The deposition of surfactants in detergents, contaminants from the water, atmospheric contaminants, and finishes released from the fabric can be the sources of additional weights noted in the direct mass estimation. As the weight-based method is quite simple and the fastest way to quantify the microfibers, future studies must focus on this area to reduce the error percentage in quantification.


Assuntos
Lavanderia , Poluentes Químicos da Água , Plásticos , Têxteis , Lavanderia/métodos , Poliésteres , Poluentes Químicos da Água/análise
19.
Environ Res ; 234: 116545, 2023 10 01.
Artigo em Inglês | MEDLINE | ID: mdl-37429404

RESUMO

Although biological treatment of textile effluent is a preferred option for industries avoiding toxic chemical sludge production and disposal, requirement of several extra pre-treatment units like neutralization, cooling systems or additives, results in higher operational cost. In the present study, a pilot scale sequential microbial-based anaerobic-aerobic reactor technology (SMAART) was developed and operated for the treatment of real textile effluent in the industrial premises in continuous mode for 180 d. The results showed an average ∼95% decolourization along with ∼92% reduction in the chemical oxygen demand establishing the resilience against fluctuations in the inlet parameters and climate conditions. Moreover, the pH of treated effluent was also reduced from alkaline range (∼11.05) to neutral range (∼7.76) along with turbidity reduction from ∼44.16 NTU to ∼0.14 NTU. A comparative life cycle assessment (LCA) of SMAART with the conventional activated sludge process (ASP) showed that ASP caused 41.5% more negative impacts on environment than SMAART. Besides, ASP had 46.15% more negative impact on human health, followed by 42.85% more negative impact on ecosystem quality as compared to SMAART. This was attributed to less electricity consumption, absence of pre-treatment units (cooling and neutralization) and less volume of sludge generation (∼50%) while using SMAART. Hence, integration of SMAART within the industrial effluent treatment plant is recommended to achieve a minimum waste discharge system in pursuit of sustainability.


Assuntos
Esgotos , Eliminação de Resíduos Líquidos , Humanos , Animais , Eliminação de Resíduos Líquidos/métodos , Anaerobiose , Ecossistema , Reatores Biológicos , Tecnologia , Têxteis , Estágios do Ciclo de Vida , Resíduos Industriais/análise , Indústria Têxtil
20.
Sci Justice ; 63(4): 509-516, 2023 07.
Artigo em Inglês | MEDLINE | ID: mdl-37453783

RESUMO

Knowledge of the number of fibres transferred during a particular activity is essential for the interpretation of findings in similar criminal cases. In this regard, violent contacts and physical assaults still present a challenge, due to a lack of robust published data. Hereby, we present the outcome of an empirical study where different assault activities were simulated by a Jiu Jitsu team and participants were asked to play either the role of an aggressive 'assailant' or a defensive 'victim', wearing cotton garments (i.e., Gi's). Four different scenarios were simulated in replicates (n = 5), each of them involving different intensity levels (low and high) and duration times (30 and 60 s). Results showed that approximately 1,000 to 44,000 fibres were cross-transferred between the participants' garments, with noticeable differences between the different scenarios. These values were significantly larger than those published in previous studies and, therefore, suggested the possibility of a current underestimation of the number of fibres transferred in physical assaults. Furthermore, statistical analysis by ANOVA indicated that the all the variables tested (i.e., intensity level, duration time, and participants role) had a significant effect on the number of transferred fibres (p < 0.001) and, consequently, that some knowledge of the case circumstances may be important to make more educated estimations. This is the first time that such a methodology has been applied for the quantitative assessment of fibre transfer between participants in assault activities. Data are expected to help practitioners with the interpretation of findings in real casework and lead to a more robust evidential assessment.


Assuntos
Vítimas de Crime , Têxteis , Humanos
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