ABSTRACT
In the last decades, the world suffers from the wastes those results from unprecedented growth in the food industry. This context investigated the characteristics and suitability of utilizing cocoa shell (CS), an agro-industrial residual biomass waste from the chocolate industry, without any chemical and/or physical treatment. It is an abundant, low-cost, and green adsorbent that can be utilized for the effective removal of basic blue (BB41) as an example of cationic dye from aqueous solutions. The CS showed high adsorption potential (90.04%) with the mild operating condition, 45 min adsorption time, pH 6, CS dose 4 g/L, BB41 concentration 10 mg/L, stirring speed 400 rpm at 295 K. The kinetic, equilibrium, isotherms and mechanism studies revealed that the BB41 adsorption onto CS was attained mainly by electrostatic interaction, π-π stacking interaction, hydrogen bonding, covalent bond, and physical mechanisms. Besides, the organic functional groups played an important role during the adsorption process. The thermodynamic parameters suggested that the adsorption of BB41 dye was the non-spontaneous endothermic process with an activation energy 18.28 kJ/mol. From the industrial point of view, this work offers an economical push in waste management and also a green approach for the effective removal of toxic dyes from textile wastewater.
ABSTRACT
Polyolefins are formed by the polymerization of olefin monomer units such as ethylene, styrene, and vinyl chloride. Polyolefins composites are a mixture of polyolefins with different types of other polymers, reinforcements, or fillers. Blending neat polyolefins with composites widens its uses in various applications that require high efficiency in the areas of environmental degradation, impact resistance, fire and chemical resistance, or strength. In this review, the effects of blending neat polyolefin with other types of polymers or wood fibers on the properties of neat polymers have been represented. Moreover, this review reveals the importance of a coupling agent or compatibilizer in the improvement of the polyolefin's compatibility with the other added components.