Visible light induced regioselective C-3 thiocyanation of imidazoheterocycles through naphthalimide dye based photoredox catalysis.

A visible light induced C-3 thiocyanation of imidazo[1,2-a]pyridines by using a naphthalimide based photoredox catalyst has been reported. Tolerance of electron withdrawing and donating groups at different positions of the imidazo[1,2-a]pyridine ring led to a wide substrate accessibility of this method. This methodology is further reproducible with other heterocycles like benzo[d]imidazo[2,1-b]thiazoles, indoles, azaindoles, and anilines.

Superior electrocatalytic hydrogen evolution activity of a triply bridged diruthenium(II) complex on a carbon cloth support.

This article describes the structural authentication of a unique triply bridged [1](ClO4)2 and monomeric [2]ClO4/[3]ClO4. Electrochemical HER on a carbon cloth support demonstrated the superior performance of [1](ClO4)2 with high TON (>105) and its long-term stability. The primary kinetic isotope effect of [1](ClO4)2 revealed the involvement of PCET in the rate-determining step.

4f-2p-3d orbital overlap in a metal-organic framework-derived CeO2/CeCo-LDH heterostructure promotes water oxidation.

Herein, we have demonstrated a facile method for the synthesis of CeO2/Ce-Co-LDH heterostructures using zeolitic imidazolate framework-67 as the precursor. The Ce-incorporation in Co-LDH results in 4f-2p-3d orbital overlap to tune the electronic structure whereas the oxygen-deficient CeO2 controls the interface charge transfer. This results in excellent water oxidation activity to attain 500 mA cm-2 current density at 320 overpotential.

Nitrogen substitution induced lattice contraction in nickel nanoparticles for electrochemical hydrogen evolution from simulated seawater.

Herein, we demonstrate a facile method for the introduction of nitrogen in the lattices of nickel nanoparticles to form NiNx (x = 0.13, 0.20, 0.27). X-ray absorption spectroscopy reveals the contraction of the Ni-Ni bond and modulated coordination environment after nitrogen introduction. The NiN0.20 required 87 mV overpotential for -10 mA cm-2 cathodic current density in simulated seawater. The density functional theory calculations revealed favorable EH2Oads and ΔGHads after N-introduction.