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1.
J Environ Manage ; 324: 116329, 2022 Dec 15.
Article in English | MEDLINE | ID: mdl-36183527

ABSTRACT

Phosphorus losses from agriculture have long generated concern due to the ecological impact on surface waters. Here tile-drained agricultural catchments are a critical source for concentrating and transporting phosphorus bioavailable forms or dissolved reactive phosphorus (DRP). Hence, edge-of-field technologies have been introduced to reduce DRP loads. Filter systems have received special attention due to their targeted approach using a permeable filter material (FM) rich in DRP sorbents. This review explores the performance and applicability of FMs in the aforementioned context because of the growing number of studies. An overall analysis revealed that sorption is preferable to precipitation for DRP retention at the edge-of-field, and that FM pH and particle size affect sorption properties and subsequently DRP retention and lifetime. Thus, FMs with predominant amounts of iron and/or aluminium can be recommended. Such materials generally have an appreciable availability of DRP binding sites, strong bonds with DRP and short reaction times, as well as low desorption, which lead to good operation. On the other hand, FMs with predominant amounts of calcium and/or magnesium are restricted to catchments with favourable conditions unless they have optimal reactivity for DRP. The review also found that hydraulic retention time plays a key role in the performance and applicability of FMs, especially in those dependent on precipitation reactions. Therefore, it is crucial that FMs are designed, constructed and managed according to the catchment conditions-including normally varying flow rates and DRP concentrations-in order to ensure successful operation. This reflects in long-term, high and steady net DRP retention along with low costs, thus improving the FM cost-effectiveness, besides discharging non-harmful effluents to aquatic ecosystems.


Subject(s)
Phosphorus , Water Movements , Ecosystem , Agriculture , Particle Size
2.
Water Res ; 247: 120792, 2023 Dec 01.
Article in English | MEDLINE | ID: mdl-37925858

ABSTRACT

Phosphorus (P) losses from tile-drained agricultural fields may degrade surface water quality by accelerating eutrophication. Among the different edge-of-field technologies, compact filter systems using different filter materials have been identified as potentially effective solutions for removing P from drainage water before discharge downstream. This study investigated the long-term (>696 days) P removal efficiency of 5 different filter materials in a column setup, using artificial drainage water (pH 6). Filter materials included two iron-based granulates (calcinated diatomaceous earth (CDE), ferric hydroxide granules (CFH)), and three calcium-based granulates (seashells, limestone, calcinated silicate/calcium oxide (Filtralite-P)). Experiments were performed under variable flow rates (0.037 and 1.52 L h-1; hydraulic retention time of 26-43 min and 18-30 h) and inlet P concentrations (0.14 and 0.7 mg L-1). An overall analysis revealed that the Fe-based materials achieved higher P retention than Ca-based materials. In particular, CFH was capable of retaining 99 and 98 % of the high and low inlet P concentrations, respectively. Conversely, limestone retained only 25 % of the high P load. CDE performed moderately well, independently of the inlet P concentration. Filtralite-P and Seashells performed well at high inlet P concentration but relatively poorly at low P concentration. The sensitivity of filter material P removal efficiency to variations in P loading was generally lowest for CFH and highest for limestone.


Subject(s)
Bays , Phosphorus , Iron , Calcium Carbonate , Silicates
3.
Water Sci Technol ; 64(5): 1122-9, 2011.
Article in English | MEDLINE | ID: mdl-22214060

ABSTRACT

In this paper the nitrogen elimination rates of different constructed wetland (CW) designs reported in literature are compared with those obtained for outdoor and indoor 2-stage vertical flow (VF) systems. The outdoor system is located about 150 km west of Vienna. Both stages are planted with Phragmites australis and the system has been operated for 4 years continuously. During this period the average value of the nitrogen elimination rate was 3.30 g N m(-2) d(-1). The indoor system comprises three parallel operated 2-stage VF systems and is located in the technical lab hall at BOKU University. The design of the indoor system resembles the outdoor system. However, there are a few differences: (1) the indoor systems are not planted, and (2) different filter media have been used for the main layer of the first stages. With the indoor system the highest nitrogen elimination rate achieved was 2.24 g N m(-2) d(-1) for the system with zeolite and impounded drainage layer. Similar results have been found in France for treating raw wastewater with VF and horizontal flow (HF) beds in series with nitrogen elimination rates of 1.89 and 2.82 g N m(-2) d(-1) for differently designed HF beds. The highest nitrogen elimination rates of 15.9 g N m(-2) d(-1) reported were for pilot-scale VF CWs treating high-strength synthetic wastewater (total nitrogen of 305 mg L(-1) in the influent) in Thailand. It has been shown that the outdoor two-stage VF CW system has one of the highest nitrogen elimination rates of CWs treating domestic wastewater.


Subject(s)
Nitrogen/isolation & purification , Wetlands , Waste Disposal, Fluid/methods , Water Purification/methods
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