Development of a Cu/MoS2/Ni Self-Lubricating Composite Clad through Laser Additive Approach over a Ti6Al4V Substrate and Its Characterizations.

Solid lubricant coatings play a critical role in enhancing the tribological properties of engineering materials, particularly in aerospace and biomedical applications. Ti6Al4V is widely used in aerospace and defense industries due to its excellent mechanical properties and high strength-to-weight ratio. In this regard, a solid lubricant metal matrix composite (MMC) clad was successfully fabricated over Ti6Al4V. A full factorial (L16) was successfully implemented to investigate the interaction of process parameters for laser power and scanning speed with response outputs, such as the clad layer thickness and microhardness. The microstructural study of the clad confirmed the presence of dark and bright phases of the microstructure with cylindrical, elliptical, and lamellar structures. This showed the presence of molybdenum and sulfide phases (MoS2, TiS, CuS) and the presence of a nickel phase (TiNi, NiS, CuNi), confirmed through X-ray diffraction (XRD) analysis and energy-dispersive X-ray (EDX) spectroscopy; these phases bestowed hardness as well as solid lubricating properties on the clad. The microhardness of the clad was found to be 2-3 times that of the substrate material. The wear behavior of the clad was studied in the load range of 5-15 N; the coefficient of friction (0.33 for clad and 0.5 for base), wear track depth profile, and wear mechanism revealed that the cladded sample has higher wear resistance as compared to the substrate material. The worn morphology showed that microcutting and microplowing are the major phenomena of wear occurrence. Further, X-ray photoelectron spectroscopy (XPS) analysis was performed to determine the binding energy of the compound formed at the clad zone, which can predict the most significant phase for the alteration of the mechanical behavior of the solid lubrication clad.

Green synthesis of flower shape ZnO-GO nanocomposite through optimized discharge parameter and its efficiency in energy storage device.

Numerous solution-based methods are used to prepare zinc oxide (ZnO) and graphene oxide (GO) nanocomposite (ZnO-GO NCs) such as sol-gel, hydrothermal, and precipitation. These methods require lots of reagents and involve many stages. In this study, a novel one-step solution-based discharge method is used to prepare ZnO-GO NCs through an electrochemical discharge process (ECDP) without the use of any catalyst or toxic chemical reagent. This study focused on analyzing the effects of input parameters on the production rate of ZnO-GO NCs. The experiment was performed by using Taguchi L9 orthogonal array. Materials removal rate (MRR) is considered as output response. The results reveal that voltage is the most significant factor, followed by temperature and duty cycle for obtaining higher MRR. The optimum parameters obtained from the Minitab software for higher MRR are 40 V, 30%, and 45 °C. Further, the morphology of the nanoparticles (NCs) produced at optimum parameters is analyzed which shows flower shape NCs with multilayer graphene oxide, confirmed by the FESEM and TEM images. The XRD peak at 11.27° and Raman spectroscopy peak of G and D bands reveal GO formation. The prepared ZnO-GO NCs tested as supercapacitor activity in the KOH solution. At the optimum parameter, the specific capacitance is observed to be 523.4 F/g at 2A/g current density. The NCs electrode shows good cyclic stability, with 86% retention of specific capacitance after 5000 cycles. This study shows a promising future of converting the e-waste product into valuable nanomaterials such as GO and ZnO from used dry cell batteries.

Harvesting marine plastic pollutants-derived renewable energy: A comprehensive review on applied energy and sustainable approach.

The inevitable use of plastics in the existing standard of life makes its way to ecosystems, predominantly into the marine ecosystem. Recent research on energy recycling from marine discarded plastics through biological, chemical, and thermal processes is summarized, which degrade plastic debris and transform it into energy-efficient products. In a system-oriented approach, different boundaries like carbon efficiency, global warming potential, cumulative energy demand, and cost of the product have been evaluated. Even these technologies may successfully reduce the yearly volume of marine plastics by up to 89% while reducing greenhouse gas emissions by 30%. Conversely, recycling a ton of marine discarded plastics may save 915 cubic feet of landfill space, 6500 kWh of energy, and barrels of oil. Energy may be recovered up to 79% from waste plastics using various techniques. Up to 84% liquid fuel had been generated, with a maximum calorific power of 45 MJ/kg. It has been shown that in Asian countries, the power generation capacity of throw-away facemask wastes regularly varies from 2256 kWh/day to 18.52 million kWh/day. Hence, the conversion of marine plastics into biofuel, syngas, biochar, hydrocarbons, electricity, and value-added functional materials by various biotechnological and chemical processes like biodegradation, pyrolysis, gasification, methanolysis, and hydrolysis should be improvised as a source of alternative energy in the immediate future. Our review signifies the potential benefits of energy harvesting technologies from marine plastics pollutants to overcome the growing challenge of energy demands and provide a long-term solution to underdeveloped and developing countries as a sustainable source of energy. Endorsing current strategies to harvest energy from marine plastic wastes that enhance power generation technologies will help in building a more sustainable and greener environment that imparts a healthy and circular economy while shielding natural resources.

Transgenic chickpea (Cicer arietinum L.) harbouring AtDREB1a are physiologically better adapted to water deficit.

BACKGROUND: Chickpea (Cicer arietinum L.) is the second most widely grown pulse and drought (limiting water) is one of the major constraints leading to about 40-50% yield losses annually. Dehydration responsive element binding proteins (DREBs) are important plant transcription factors that regulate the expression of many stress-inducible genes and play a critical role in improving the abiotic stress tolerance. Transgenic chickpea lines harbouring transcription factor, Dehydration Responsive Element-Binding protein 1A from Arabidopsis thaliana (AtDREB1a gene) driven by stress inducible promoter rd29a were developed, with the intent of enhancing drought tolerance in chickpea. Performance of the progenies of one transgenic event and control were assessed based on key physiological traits imparting drought tolerance such as plant water relation characteristics, chlorophyll retention, photosynthesis, membrane stability and water use efficiency under water stressed conditions. RESULTS: Four transgenic chickpea lines harbouring stress inducible AtDREB1a were generated with transformation efficiency of 0.1%. The integration, transmission and regulated expression were confirmed by Polymerase Chain Reaction (PCR), Southern Blot hybridization and Reverse Transcriptase polymerase chain reaction (RT-PCR), respectively. Transgenic chickpea lines exhibited higher relative water content, longer chlorophyll retention capacity and higher osmotic adjustment under severe drought stress (stress level 4), as compared to control. The enhanced drought tolerance in transgenic chickpea lines were also manifested by undeterred photosynthesis involving enhanced quantum yield of PSII, electron transport rate at saturated irradiance levels and maintaining higher relative water content in leaves under relatively severe soil water deficit. Further, lower values of carbon isotope discrimination in some transgenic chickpea lines indicated higher water use efficiency. Transgenic chickpea lines exhibiting better OA resulted in higher seed yield, with progressive increase in water stress, as compared to control. CONCLUSIONS: Based on precise phenotyping, involving non-invasive chlorophyll fluorescence imaging, carbon isotope discrimination, osmotic adjustment, higher chlorophyll retention and membrane stability index, it can be concluded that AtDREB1a transgenic chickpea lines were better adapted to water deficit by modifying important physiological traits. The selected transgenic chickpea event would be a valuable resource that can be used in pre-breeding or directly in varietal development programs for enhanced drought tolerance under parched conditions.

ELEPHANT ENDOTHELIOTROPIC HERPESVIRUS HEMORRHAGIC DISEASE OUTBREAK IN AN INDIAN ZOO.

Elephant endotheliotropic herpesvirus hemorrhagic disease (EEHV HD) is an acute viral infection of growing Asian elephants (Elephas maximus). Four apparently healthy subadult Asian elephants aged between 6 and 10 yr at Nandankanan Zoological Park (NKZP), India, died of EEHV HD during August-September 2019. All four elephants were rescued from different reserved forests of Odisha state at less than 1 yr of age and hand reared in the NKZP. Elephants exhibited the clinical signs of lethargy, head swelling, fever, loss of appetite, abdominal distension, scant urination and defecation, signs of colic, lameness, trunk discharge, cyanosis/ulceration of tongue, erratic behavior, and recumbence before death. Period of illness varied between 28 and 42 h. Thrombocytopenia was the common significant hematological observation. No significant biochemical alterations were recorded except for higher creatinine concentrations. Analysis of blood samples in RT-PCR assay using two different sets of primers and probes that targeted terminase gene and major DNA-binding protein gene followed by cPCR and sequencing was positive for EEHV-1A in all four animals. Postmortem examination of all four carcasses showed hemorrhages in internal organs, including the hard palate, heart, lungs, stomach, mesenteric lymph nodes, mesentery, colon serosa, spleen, liver, kidney, and meninges. Histopathology showed congestion and/or hemorrhages in heart, lung, brain, kidney, and liver. There was presence of intranuclear inclusion bodies in the sinusoidal epithelial cells. The outbreak of EEHV HD that resulted in the acute death of four juvenile captive Asian elephants within <30 d, the first of its kind documented in India, is increasing the fear of similar outbreaks in the future.

Mode insensitive switch for on-chip interconnect mode division multiplexing systems.

A mode insensitive switch is proposed and experimentally demonstrated on a silicon-on-insulator platform using a balanced Mach-Zehnder interferometer structure with a mode insensitive phase shifter for on-chip mode division multiplexing interconnects. Switching the first three quasi-transverse electric (TE) modes, consuming less than 40 mW power is demonstrated. The whole system exhibits approximately $ - {2},\;{ - 3.7}$-2,-3.7, and $ - {5.2}\;{\rm dB}$-5.2dB insertion loss for the TE0, TE1, and TE2 modes at 1550 nm, respectively. The corresponding crosstalk is less than $ - {8.6}\;({\rm - 9}), {- 8} ({ - 10.3})$-8.6(-9),-8(-10.3), and $ - {10}\;{\rm dB}$-10dB ($ - {10.3}\;{\rm dB}$-10.3dB) within the wavelength range of 40 nm (1535-1575 nm) for the cross (bar) states, respectively. The extinction ratios (ERs) for the cross (bar) states are 20.1 (19.5), 22.8 (33.7), and 15.4 dB (18.1 dB) for the TE0, TE1, and TE2 modes at 1550 nm, respectively. The payload transmission is also conducted using non-return-to-zero pseudorandom binary sequence (PRBS)-31 data signals at 10 Gb/s for single-mode transmission and simultaneous three-mode transmissions. For all the scenarios, open eyes are observed.

Oscillating Transcriptome during Rice-Magnaporthe Interaction.

Rice blast disease caused by the fungus, Magnaporthe oryzae, is one of the most devastating diseases of rice. Deciphering molecular mechanism of host-pathogen interactions is of great importance in devising disease management strategies. Transcription being the first step for gene regulation in eukaryotes, basic understanding of the transcriptome is sine qua non for devising effective management strategy. The availability of genome sequences of rice and M. oryzae has facilitated the process to a large extent. The current review summarizes recent understanding of rice-blast pathosystem, application of transcriptomics approaches to understand the interactions employing different platforms, major determinants in the interaction and possibility of using certain candidate for conditioning enhanced disease resistance (Effector Triggered Immunity and PAMP Triggered Immunity) and downstream signalling in rice. A better understanding of the interaction elements and effective strategies hold potential to reduce yield losses in rice caused by M. oryzae.

Molecular identification of indigenous manganese solubilising bacterial biodiversity from manganese mining deposits.

Manganese (Mn) ranks twelfth among the most exuberant metal present in the earth's crust and finds its imperative application in the manufacturing steel, chemical, tannery, glass, and battery industries. Solubilisation of Mn can be performed by several bacterial strains which are useful in developing environmental friendly solutions for mining activities. The present investigation aims to isolate and characterize Mn solubilising bacteria from low grade ores from Sanindipur Manganese mine of Sundargh district in Odisha state of India. Four morphologically distinct bacterial strains showing visible growth on Mn supplemented plates were isolated. Mn solubilising ability of the bacterial strains was assessed by visualizing the lightening of the medium appearing around the growing colonies. Three isolates were gram negative and rod shaped while the remaining one was gram positive, coccobacilli. Molecular identification of the isolates was carried out by 16S rRNA sequencing and the bacterial isolates were taxonomically classified as Bacillus anthrasis MSB 2, Acinetobacter sp. MSB 5, Lysinibacillus sp. MSB 11, and Bacillus sp. MMR-1 using BLAST algorithm. The sequences were deposited in NCBI GenBank with the accession number KP635223, KP635224, KP635225 and JQ936966, respectively. Manganese solubilisation efficiency of 40, 96, 97.5 and 48.5% were achieved by MMR-1, MSB 2, MSB 5 and MSB 11 respectively. The efficiency of Mn solubilisation is suggested with the help of a pH variation study. The results are discussed in relation to the possible mechanisms involved in Manganese solubilisation efficiency of bacterial isolates.

Food waste to resource recovery: a way of green advocacy.

Due to the massive growth in population and urbanization, there has been a huge increase in the volume of food waste globally. The Food and Agriculture Organization (FAO) has estimated that around one-third of all food produced each year is wasted. Food waste leads to the emission of greenhouse gas and depletion of the soil fertility. Nevertheless, it has immense potential for the recovery of high-value energy, fuel, and other resources. This review summarizes the latest advances in resource recovery from food waste by using technologies that include food waste-mediated microbial fuel cell (MFC) for bioenergy production. In addition to this, utilization of food waste for the production of bioplastic, biogas, bioethanol, and fertilizer has been also discussed in detail. Competitive benefits and accompanying difficulties of these technologies have also been highlighted. Furthermore, future approaches for more efficient use of food waste for the recovery of valuable resources have been also offered from an interdisciplinary perspective.

A Critical Review on the Recovery of Base and Critical Elements from Electronic Waste-Contaminated Streams Using Microbial Biotechnology.

Pollution by end-of-life electronics is a rapid ever-increasing threat and is a universal concern with production of million metric tons of these wastes per annum. Electronic wastes (E-waste) are rejected electric or electronic equipment which have no other applications. The aggrandized unproper land filling of E-waste may generate hazardous effects on living organisms and ecosystem. At present, millions of tons of E-waste await the advancement of more efficient and worthwhile recycling techniques. Recovery of base and critical elements from electronic scraps will not only reduce the mining of these elements from natural resources but also reduces the contamination caused by the hazardous chemicals (mostly organic micropollutants) released from these wastes when unproperly disposed of. Bioleaching is reported to be the most eco-friendly process for metal recycling from spent electronic goods. A detailed investigation of microbial biodiversity and a molecular understanding of the metabolic pathways of bioleaching microorganisms will play a vital function in extraction of valuable minerals from the end-of-life scraps. Bioleaching technique as an economic and green technology costs around 7 USD per kg for effective reusing of E-waste as compared to other physical and chemical techniques. This review provides a summary of worldwide scenario of electronic pollutants; generation, composition and hazardous components of electronic waste; recycling of valuable elements through bioleaching; mechanism of bioleaching; microorganisms involved in base and critical element recovery from E-waste; commercial bioleaching operations; and upcoming aspects of this eco-friendly technique.

Effect of Current Waveforms during Directed Energy Deposition of 4043 Aluminum Alloy on Microstructure, Hardness, and Wear of Alloy.

Wire arc additive manufacturing (WAAM) was employed to fabricate 4043 aluminum alloy walls. To investigate the effects of sinusoidal, triangular, and rectangular waveforms of alternating current (AC) and their transients on the wall geometry, microstructure evolution, hardness, and wear properties were evaluated. The root mean square (RMS) current value was maximum for the rectangular and minimum for the triangular waveform. The section produced by the triangular waveform had the highest height-to-width ratio, indicating that this waveform can be a favorable choice for creating components using WAAM. The optical micrographs of the transverse cross-section of the printed sections revealed the grain structure produced with this waveform to be heterogeneous, having a columnar dendritic structure at the bottom and equiaxed at the top portion. The waveforms also had an impact on the hardness and wear characteristics of all the walls, which were attributed to their cooling rate.

Assessment of inter and intra-observer variation of Leonetti and Tigani CT bases classification of tibial pilon fractures.

INTRODUCTION: tibial pilon fracture constitutes 5-7% of all tibial fractures. The treatment of choice is an open reduction with anatomical articular reconstruction and stable fixation. A relievable fracture classification is needed for the preoperative planning the surgical management of these fractures. Hence, we assessed the inter- and intra-observer variation of Leonetti and Tigani CT bases classification of tibial pilon fractures. MATERIALS AND METHODS: In this prospective study, 37 patients aged between 18-65 years with an ankle fracture were included. All these patients underwent a CT scan for the ankle fracture, and the CT scan was further evaluated by 5 independent observers (Orthopaedic surgeon). A kappa value was determined for inter and intra-observer variation. RESULTS: Leonetti and Tigani's CT-based classification of the kappa values was 0.657 to 0.751, with a mean value of 0.700. The range of values for the intra-observer variation using Leonetti and Tigani CT-based classification on the kappa values was 0.658 to 0.875 with a mean value of 0.755. The P-value < 0.001 states that there was a significant agreement between the inter-observer and intra-observer classification. CONCLUSION: Leonetti and Tigani Classification have shown substantial inter- and intra-observer agreement, and the "4B" subclass of Leonetti and Tigani CT-based classification showed a predominance in the present study.

A novel blast resistance gene, Pi54rh cloned from wild species of rice, Oryza rhizomatis confers broad spectrum resistance to Magnaporthe oryzae.

The dominant rice blast resistance gene, Pi54 confers resistance to Magnaporthe oryzae in different parts of India. In our effort to identify more effective forms of this gene, we isolated an orthologue of Pi54 named as Pi54rh from the blast-resistant wild species of rice, Oryza rhizomatis, using allele mining approach and validated by complementation. The Pi54rh belongs to CC-NBS-LRR family of disease resistance genes with a unique Zinc finger (C(3)H type) domain. The 1,447 bp Pi54rh transcript comprises of 101 bp 5'-UTR, 1,083 bp coding region and 263 bp 3'-UTR, driven by pathogen inducible promoter. We showed the extracellular localization of Pi54rh protein and the presence of glycosylation, myristoylation and phosphorylation sites which implicates its role in signal transduction process. This is in contrast to other blast resistance genes that are predicted to be intracellular NBS-LRR-type resistance proteins. The Pi54rh was found to express constitutively at basal level in the leaves, but upregulates 3.8-fold at 96 h post-inoculation with the pathogen. Functional validation of cloned Pi54rh gene using complementation test showed high degree of resistance to seven isolates of M. oryzae collected from different geographical locations of India. In this study, for the first time, we demonstrated that a rice blast resistance gene Pi54rh cloned from wild species of rice provides broad spectrum resistance to M. oryzae hence can be used in rice improvement breeding programme.

Comparison of Maraging Steel Surface Integrity in Hybrid and Conventional Micro-ECDM Processes.

Maraging steel is one of the exotic materials showing the potential for application in the field of the aerospace industry. However, machining these materials with high surface quality and material removal rate is problematic. The micro-electro chemical discharge (MECDM) process is capable of resolving this problem to some extent, however, due to the spark action, it fails to attain a high surface finish. In the current investigation, micro-hole drilling is performed on maraging steel with powder-mixed alumina (1% wt. of Al2O3) using the micro-electro chemical discharge machining (PMECDM) process. The effect of different input process factors, for example, voltage (V), duty cycle (D), the electrolyte concentration (C), are considered for investigating the machining performance, i.e., rate of material removal (MRR) and roughness of surface (SR) of the machined substrate. Further, a comparative analysis is established between micro-ECDM (MECDM) and mixed powder ECDM (PMECDM). The Box-Behnken design is used to conduct all the experiments and analysis of variance (ANOVA) is used to optimize the results. The outcomes reveal that MRR in PMECDM is enhanced by 34%, and the average surface roughness is reduced by 21% over the MECDM process. The maximum MRR was observed to be 2.44 mg/min and the hole machined by the PMECDM results in a cleaner hole wall surface than the MECDM process due to the grinding action by the powder particles. The residual stress measurement indicates that the PMECDM (-128.3 ± 3.85 MPa) has the lowest equivalent stress as compared to the parent material (-341.04 ± 10.24 MPa) and MECDM (-200.7 ± 6.02 MPa) surfaces. The applied voltage is the most significant parameter, followed by the duty factor and electrolyte concentration for enhancing the MRR and surface finish. The addition of powder improves the surface integrity of the machined surface as compared to the surfaces produced by the MECDM processes.

Detection of Environmental Microfiber Pollutants through Vibrational Spectroscopic Techniques: Recent Advances of Environmental Monitoring and Future Prospects.

A robust environmental monitoring system is highly essential for the instant detection of environmental microfiber pollutants for the sustainable management of the environment and human health. The extent of microfiber pollution is growing exponentially across the globe in both terrestrial and marine environments. An immediate and accurate environmental monitoring system is crucial to investigate the composition and distribution of these micropollutants. Fourier Transform Infrared Spectroscopy and Raman Spectroscopy are vibrational spectroscopic techniques that have the novel ability to detect microfibers within a minute concentration from diverse environmental samples. The major micropollutants which have been analyzed are polyethylene, polypropylene, nylon 6, polystyrene, and polyethylene terephthalate. After a detailed and critical study of the various aspects of spectroscopic analysis, the review is concluded with a comprehensive discussion of the significance of these robust methods and their application in future aspects for further preventing microfiber pollution in the marine environment. This study highlights the utilities and significance of vibrational spectroscopic detection techniques for the immediate and accurate identification of synthetic microfibers. This review also evaluated the implementation of spectroscopic methods as a precise tool for the characterization and monitoring of microfiber pollutants in the environment.

Recent Advances in Sensor-Based Detection of Toxic Dyes for Bioremediation Application: a Review.

Extensive use of these harmful dyes has resulted in the surplus presence of these emerging pollutants in the environment, thus demanding an instant and sensitive detection method. Various synthetic dyes are illegitimately mixed into food and other consuming items for displaying bright colours that attracts consumers. The synthetic dyes cause a number of environmental health hazards and promote toxicity, mutagenicity and carcinogenicity in humans. Despite these serious health glitches, synthetic dyes are widely used due to their much lower cost. As a result, a faster, more selective and extremely sensitive technology for detecting and quantifying hazardous dyes in trace amount is urgently needed. This topic is currently in its initial phases of development and needs continuous refinements, such as explaining various sensing methods and potential future uses linked with dye detection technologies. The present review encompasses a comprehensive literature survey on detection of dyes and latest progress in developing sensors for dye detection and summarizes different detection mechanisms, including biosensor-, optical- and electrochemical-based sensors. Detection methodologies are examined with a focus on biosensor-based recent advancements in dye detection and the growing demand for more appropriate systems in terms of accuracy and efficiency.

Detection, characterization and possible biofragmentation of synthetic microfibers released from domestic laundering wastewater as an emerging source of marine pollution.

Synthetic microfibers are universally recognized as an emerging pollutant in all ecosystems. The present investigation focuses on the evaluation and quantification of synthetic microfiber released from domestic laundering wastewater from different regions of Bhubaneswar city of Odisha state of India. The estimated number of microfibers collected from 500 ml of sample varied from 200 to 500 in numbers with an average amount of biomass in the range of 0.4-4 g. The surface morphology of the samples was assessed by Scanning Electron Microscopic analysis which revealed that the fibers were having a length of approximately 10-30 mm and diameter of 10-20 µm. Carbonyl (CO) stretching band at 1711 cm-1 and Aldehyde (CH) Weak bond at 2917.38 cm-1 absorption were recorded from Fourier transform infrared spectroscopic analysis. As microfibers released from synthetic apparels are major source of environmental microplastic pollution their precise detection could help in controlling this problem.

Electroless Ni-P-MoS2-Al2O3 Composite Coating with Hard and Self-Lubricating Properties.

The work aimed to produce Ni-P-MoS2-Al2O3 on Al-7075 alloys with multiple attributes through an electroless (EL) plating route. The effects of additives (MoS2 and Al2O3) in the EL bath on the surface morphology, topography, hardness, composition (phase and elemental), roughness, wettability, and coating thickness were evaluated. Results indicate a substantial enhancement in microhardness of the EL-coated surfaces by 70% (maximum hardness = ~316 HV) using powders, and 30% (244 HV) without powders. The maximum coating thickness and water contact angle obtained with powders were 6.16 µm and 100.46°, respectively. The coefficient of friction for the samples prepared using powders was 0.12, and for the base material it was 0.18. The compositional analysis through EDS and XRD suggested the incorporation of a hard and lubricious layer on the EL-coated surface owing to the presence of different phases of Al, Mo, P, Zn, O, and S. Therefore, the resulting coating surfaces impart hardness, self-lubrication, hydrophobicity, and wear resistance simultaneously.

A Review on Heavy Metal Ion Adsorption on Synthetic Microfiber Surface in Aquatic Environments.

Synthetic microfibers (SMFs), tiny particles which gets fragmented from large fragments of large synthetic fibers having less than 10 µm in diameter, have gathered ubiquitously in each and every corner of the earth. After their release into the aquatic environment, they remain there without natural degradation. Furthermore, it can be anticipated that floating units are transported along the food chain leading to bioaccumulation. It has been estimated that approximately 10-20 Mt of large fabric products as garbage enter into aquatic system per annum. Recently, these synthetic fragments have been investigated as transporters of heavy metal ions (HMs) showing different types of interactions. Yet, the underlying mechanism of these types of interaction is not known, especially the factors stimulating this process and how badly they affect biotic communities. Through this article, a detailed survey was carried out on the sources of microfibers and HMs into the aquatic environment, adsorption of different types of HMs on the SMF surface, mechanics favors these HM-MF interactions, particularly highlighting the significant roles of interaction on microbial biofilm formation. Their collaborative effects which possess harmful effects on aquatic as well as terrestrial organisms was also discussed. Lastly, the future investigations should focus on rigorous research in this field. This article to the best of our knowledge briefly describes the current research developments and emphasizes the vital function of the microorganisms on MFs-HMs interactions with the encouragement for rigorous research in this field to reveal accurate mechanisms and decrease the hazards related with MF presence.

Fiber Laser Welded Cobalt Super Alloy L605: Optimization of Weldability Characteristics.

The present study describes the laser welding of Co-based superalloy L605 (52Co-20Cr-10Ni-15W) equivalent to Haynes-25 or Stellite-25. The influence of laser welding process input parameters such as laser beam power and welding speed on mechanical and metallurgical properties of weld joints were investigated. Epitaxial grain growth and dendritic structures were visible in the weld zone. The phase analysis results indicate the formation of hard phases like CrFeNi, CoC, FeNi, and CFe in the weld zone. These hard phases are responsible for the increase in microhardness up to 321 HV0.1 in the weld zone, which is very close to the microhardness of the parent material. From the tensile strength tests, the ductile failure of welded specimens was confirmed due to the presence of dimples, inter-granular cleavage, and micro voids in the fracture zone. The maximum tensile residual stress along the weld line is 450 MPa, whereas the maximum compressive residual stress across the weld line is 500 MPa. On successful application of Response Surface methodology (RSM), laser power of 1448.5 W and welding speed of 600 mm/min i.e., line energy or heat input equal to 144 J/mm, were found to be optimum values for getting sound weld joint properties. The EBSD analysis reveals the elongated grain growth in the weld pool and very narrow grain growth in the heat-affected zone.