Flatband λ-Ti3O5 towards extraordinary solar steam generation.

Solar steam interfacial evaporation represents a promising strategy for seawater desalination and wastewater purification owing to its environmentally friendly character1-3. To improve the solar-to-steam generation, most previous efforts have focused on effectively harvesting solar energy over the full solar spectrum4-7. However, the importance of tuning joint densities of states in enhancing solar absorption of photothermal materials is less emphasized. Here we propose a route to greatly elevate joint densities of states by introducing a flat-band electronic structure. Our study reveals that metallic λ-Ti3O5 powders show a high solar absorptivity of 96.4% due to Ti-Ti dimer-induced flat bands around the Fermi level. By incorporating them into three-dimensional porous hydrogel-based evaporators with a conical cavity, an unprecedentedly high evaporation rate of roughly 6.09 kilograms per square metre per hour is achieved for 3.5 weight percent saline water under 1 sun of irradiation without salt precipitation. Fundamentally, the Ti-Ti dimers and U-shaped groove structure exposed on the λ-Ti3O5 surface facilitate the dissociation of adsorbed water molecules and benefit the interfacial water evaporation in the form of small clusters. The present work highlights the crucial roles of Ti-Ti dimer-induced flat bands in enchaining solar absorption and peculiar U-shaped grooves in promoting water dissociation, offering insights into access to cost-effective solar-to-steam generation.

A smart thermal-gated bilayer membrane for temperature-adaptive radiative cooling and solar heating.

Due to the huge energy consumption of traditional cooling- and heating-based electricity, passive radiative cooling and solar heating with a minimum carbon footprint using the outer space and Sun as natural thermodynamic resources have attracted much attention. However, most passive devices are static and monofunctional, and cannot meet the practical requirements of dynamic cooling and heating under various conditions. Here, we demonstrate a smart thermal-gated (STG) bilayer membrane that enables fully automatic and temperature-adaptive radiative cooling and solar heating. Specifically, this device can switch from reflective to absorptive (white to black) in the solar wavelength with the reduction in optical scattering upon ambient temperature, corresponding to a sunlight reflectivity change from 0.962 to 0.059 when the temperature drops below ∼30 °C, whereas its mid-infrared emissivity remains at ∼0.95. Consequently, this STG membrane achieves a temperature of ∼5 °C below ambient (a key signature of radiative cooling) under direct sunlight (peak solar irradiance >900 W m-2) in summer and a solar heating power of ∼550 W m-2 in winter. Theoretical analysis reveals the substantial advantage of this switchable cooling/heating device in potential energy saving compared with cooling-only and heating-only strategies when widely used in different climates. It is expected that this work will pave a new pathway for designing temperature-adaptive devices with zero energy consumption and provide an innovative way to achieve sustainable energy.

Nanocellulose-derived carbon/g-C3N4 heterojunction with a hybrid electron transfer pathway for highly photocatalytic hydrogen peroxide production.

Using oxygen reduction for the photocatalytic production of hydrogen peroxide (H2O2) has been considered a green and sustainable route. In the present study, to achieve high efficiency, graphitic carbon nitride (g-C3N4) was obtained using thermal polymerization from a bi-component precursor and was then assembled with cellulose nanofibers. It was found that a small quantity of cellulose nanofibers that generates carbon fibers upon pyrolysis greatly improves the photocatalytic activity compared with that of g-C3N4 alone. The well-defined carbon/g-C3N4 heterojunction-type material exhibits as high as 1.10 mmol L-1h-1 of photo-production of H2O2 under visible light, which is 4.2 times higher than that yielded by pristine g-C3N4 from a single precursor. A comprehensive characterization of the photocatalyst enables us to delineate the effect of the carbon nanofiber with respect to porosity, electron-hole separation, band gap regulation, and especially the electron transfer pathway. Our results demonstrate that nanocellulose-derived carbon, when precisely assembled with other functional material such as a photocatalyst, is a promising promoter of their activity.