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Chem Commun (Camb) ; 50(68): 9650-2, 2014 Sep 04.
Article in English | MEDLINE | ID: mdl-25007289

ABSTRACT

Dihydrolevoglucosenone (Cyrene) is a bio-based molecule, derived in two simple steps from cellulose, which demonstrates significant promise as a dipolar aprotic solvent. The dipolarity of dihydrolevoglucosenone is similar to NMP, DMF and sulpholane. Dihydrolevoglucosenone demonstrates similar performance to NMP in a fluorination reaction and the Menschutkin reaction.


Subject(s)
Bridged Bicyclo Compounds, Heterocyclic/chemistry , Cellulose/analogs & derivatives , Halogenation , Models, Molecular , Solvents/chemistry
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