ABSTRACT
The presented study was focused on the simple, eco-friendly synthesis of composite hydrogels of crosslinked carboxymethyl cellulose (CMC)/alginate (SA) with encapsulated g-C3N4 nanoparticles. The structural, textural, morphological, optical, and mechanical properties were determined using different methods. The encapsulation of g-C3N4 into CMC/SA copolymer resulted in the formation of composite hydrogels with a coherent structure, enhanced porosity, excellent photostability, and good adhesion. The ability of composite hydrogels to eliminate structurally different dyes with the same or opposite charge properties (cationic Methylene Blue and anionic Orange G and Remazol Brilliant Blue R) in both single- and binary-dye systems was examined through adsorption and photocatalytic reactions. The interactions between the dyes and g-C3N4 and the negatively charged CMC/SA copolymers had a notable influence on both the adsorption capacity and photodegradation efficiency of the prepared composites. Scavenger studies and leaching tests were conducted to gain insights into the primary reactive species and to assess the stability and long-term performance of the g-C3N4/CMC/SA beads. The commendable photocatalytic activity and excellent recyclability, coupled with the elimination of costly catalyst separation requirements, render the g-C3N4/CMC/SA composite hydrogels cost-effective and environmentally friendly materials, and strongly support their selection for tackling environmental pollution issues.
Subject(s)
Alginates , Carboxymethylcellulose Sodium , Coloring Agents , Hydrogels , Water Pollutants, Chemical , Carboxymethylcellulose Sodium/chemistry , Hydrogels/chemistry , Alginates/chemistry , Coloring Agents/chemistry , Catalysis , Water Pollutants, Chemical/chemistry , Methylene Blue/chemistry , Azo Compounds/chemistry , Nitriles/chemistry , Nitrogen Compounds/chemistry , Photolysis , Adsorption , Green Chemistry Technology/methods , Anthraquinones , GraphiteABSTRACT
Waste and recycled materials have recently been used in the construction industry to comply with the principles of circular economy and sustainable development. The aim of this paper is to examine the potentials of solidified wastewater treatment sludge (SWWTS) as a supplementary cementitious material (SCM) in the production of lightweight pervious concrete pavers (LWPCP) suitable for pedestrian trails and rooftops (green) that comply with EU standards. Detailed characterization of SWWTS was performed, in order to understand its properties related to application as SCM, which led to the conclusion that it may be applied only as a filler, having 89.5% of Ca(OH)2. After thorough characterization, LWPCP samples were prepared and testing of physical and mechanical properties was conducted. The research showed that partial replacement of cement with SWWTS led to the decrease of all mechanical properties, ranging between 3.91 and 5.81 MPa for compressive strength and 0.97 to 1.23 MPa for flexural strength. However, all of the investigated mixtures showed a value higher than 3.5 MPa, which was defined as the lowest compressive strength in the range of pervious concrete properties. The addition of SWWTS led to a slight decrease in bulk density of the mixtures and an increase in water absorption. This could be explained by the reduction in hydration products that would fill in the micropores of the matrix, since SWWTS showed no pozzolanic reactivity. Pore sizes that prevail in the tested binder matrices are in accordance with the results measured on ordinary pervious concrete (the largest fraction of pores had a diameter between 0.02 and 0.2 µm). Low thermal conductivity nominates produced pavers as potential rooftop elements.