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1.
Phys Rev E ; 106(3-1): 034123, 2022 Sep.
Article in English | MEDLINE | ID: mdl-36266892

ABSTRACT

We have studied the critical properties of the three-dimensional random anisotropy Heisenberg model by means of numerical simulations using the Parallel Tempering method. We have simulated the model with two different disorder distributions, cubic and isotropic ones, with two different anisotropy strengths for each disorder class. For the case of the anisotropic disorder, we have found evidence of universality by finding critical exponents and universal dimensionless ratios independent of the strength of the disorder. In the case of isotropic disorder distribution the situation is very involved: we have found two phase transitions in the magnetization channel which are merging for larger lattices remaining a zero magnetization low-temperature phase. Studying this region using a spin-glass order parameter we have found evidence for a spin-glass phase transition. We have estimated effective critical exponents for the spin-glass phase transition for the different values of the strength of the isotropic disorder, discussing the crossover regime.

2.
J Phys Condens Matter ; 32(33): 335102, 2020 Apr 14.
Article in English | MEDLINE | ID: mdl-32289770

ABSTRACT

We propose the model of a random polymer network, formed on the base on Erdös-Rényi random graph. In the language of mathematical graphs, the chemical bonds between monomers can be treated as vertices, and their chemical functionalities as degrees of these vertices. We consider graphs with fixed number of vertices N = 5 and variable parameter c (connectedness), defining the total number of links L = cN(N - 1)/2 between vertices. Each link in such graphs is treated as a Gaussian polymer chain. The universal rotationally invariant size and shape characteristics, such as averaged asphericity and size ratio of such structures are obtained both numerically by application of Wei's method and analytically within the continuous chain model. In particular, our results quantitatively indicate an increase of asymmetry of polymer network structure when its connectedness c decreases.

3.
Phys Rev E Stat Nonlin Soft Matter Phys ; 79(3 Pt 1): 031109, 2009 Mar.
Article in English | MEDLINE | ID: mdl-19391904

ABSTRACT

We calculate the relaxational dynamical critical behavior of systems of O(n_{ parallel}) plus sign in circleO(n_{ perpendicular}) symmetry including conservation of magnetization by renormalization group theory within the minimal subtraction scheme in two-loop order. Within the stability region of the Heisenberg fixed point and the biconical fixed point, strong dynamical scaling holds, with the asymptotic dynamical critical exponent z=2varphinu-1 , where varphi is the crossover exponent and nu the exponent of the correlation length. The critical dynamics at n_{ parallel}=1 and n_{ perpendicular}=2 is governed by a small dynamical transient exponent leading to nonuniversal nonasymptotic dynamical behavior. This may be seen, e.g., in the temperature dependence of the magnetic transport coefficients.

4.
Phys Rev E Stat Nonlin Soft Matter Phys ; 80(1 Pt 1): 011108, 2009 Jul.
Article in English | MEDLINE | ID: mdl-19658654

ABSTRACT

The system of two scalar order parameters on a complex scale-free network is analyzed in the spirit of Landau theory. To add a microscopic background to the phenomenological approach, we also study a particular spin Hamiltonian that leads to coupled scalar order behavior using the mean-field approximation. Our results show that the system is characterized by either of two types of ordering: either one of the two order parameters is zero or both are nonzero but have the same value. While the critical exponents do not differ from those of a model with a single order parameter on a scale-free network, there are notable differences for the amplitude ratios and the susceptibilities. Another peculiarity of the model is that the transverse susceptibility is divergent at all T

5.
Phys Rev E Stat Nonlin Soft Matter Phys ; 78(4 Pt 1): 041124, 2008 Oct.
Article in English | MEDLINE | ID: mdl-18999396

ABSTRACT

We calculate the static critical behavior of systems of O(n_||)(plus sign in circle)O(n_perpendicular) symmetry by the renormalization group method within the minimal subtraction scheme in two-loop order. Summation methods lead to fixed points describing multicritical behavior. Their stability border lines in the space of the order parameter components n_|| and n_perpendicular and spatial dimension d are calculated. The essential features obtained already in two-loop order for the interesting case of an antiferromagnet in a magnetic field ( n_|| =1, n_perpendicular =2 ) are the stability of the biconical fixed point and the neighborhood of the stability border lines to the other fixed points, leading to very small transient exponents. We are also able to calculate the flow of static couplings, which allows us to consider the attraction region. Depending on the nonuniversal background parameters, the existence of different multicritical behavior (bicritical or tetracritical) is possible, including a triple point.

6.
Phys Rev E Stat Nonlin Soft Matter Phys ; 78(4 Pt 1): 041125, 2008 Oct.
Article in English | MEDLINE | ID: mdl-18999397

ABSTRACT

We calculate the relaxational dynamical critical behavior of systems of O(n_||)(plus sign in circle)O(n_perpendicular) symmetry by renormalization group method within the minimal subtraction scheme in two-loop order. The three different bicritical static universality classes previously found for such systems correspond to three different dynamical universality classes within the static borderlines. The Heisenberg and the biconical fixed point lead to strong dynamic scaling whereas in the region of stability of the decoupled fixed point weak dynamic scaling holds. Due to the neighborhood of the stability border between the strong and the weak scaling dynamic fixed point to the dynamical stable fixed point a very small dynamic transient exponent of omega(Beta)_(v) =0.0044 is present in the dynamics for the physically important case n_|| =1 and n_perpendicular =2 in d=3 .

7.
J Phys Condens Matter ; 30(21): 215101, 2018 May 31.
Article in English | MEDLINE | ID: mdl-29623906

ABSTRACT

In this paper we study the shape characteristics of star-like polymers in various solvent quality using a mesoscopic level of modeling. The dissipative particle dynamics simulations are performed for the homogeneous and four different heterogeneous star polymers with the same molecular weight. We analyse the gyration radius and asphericity at the poor, good and θ-solvent regimes. Detailed explanation based on interplay between enthalpic and entropic contributions to the free energy and analyses on of the asphericity of individual branches are provided to explain the increase of the apsphericity in θ-solvent regime.

8.
Phys Rev E Stat Nonlin Soft Matter Phys ; 74(3 Pt 1): 031801, 2006 Sep.
Article in English | MEDLINE | ID: mdl-17025657

ABSTRACT

We present a quantitative picture of the separation of star polymers in a solution where part of the volume is influenced by a porous medium. To this end, we study the impact of long-range-correlated quenched disorder on the entropy and scaling properties of f-arm star polymers in a good solvent. We assume that the disorder is correlated on the polymer length scale with a power-law decay of the pair correlation function g(r) approximately r-a. Applying the field-theoretical renormalization group approach we show in a double expansion in epsilon=4-d and delta=4-a that there is a range of correlation strengths delta for which the disorder changes the scaling behavior of star polymers. In a second approach we calculate for fixed space dimension d=3 and different values of the correlation parameter a the corresponding scaling exponents gammaf that govern entropic effects. We find that gammaf-1, the deviation of gammaf from its mean field value is amplified by the disorder once we increase delta beyond a threshold. The consequences for a solution of diluted chain and star polymers of equal molecular weight inside a porous medium are that star polymers exert a higher osmotic pressure than chain polymers and in general higher branched star polymers are expelled more strongly from the correlated porous medium. Surprisingly, polymer chains will prefer a stronger correlated medium to a less or uncorrelated medium of the same density while the opposite is the case for star polymers.

9.
J Phys Condens Matter ; 28(50): 505101, 2016 12 21.
Article in English | MEDLINE | ID: mdl-27792664

ABSTRACT

In this paper we study the shape characteristics of a polymer chain in a good solvent using a mesoscopic level of modelling. The dissipative particle dynamics simulations are performed in 3D space at a range of chain lengths N. The scaling laws for the end-to-end distance and gyration radius are examined first and found to hold for [Formula: see text] yielding a reasonably accurate value for the Flory exponent ν. Within the same interval of chain lengths, the asphericity, prolateness and some other shape characteristics of the chain are found to become independent of N. Their mean values are found to agree reasonably well with the respective theoretical results and lattice Monte Carlo (MC) simulations. We found the probability distribution for a wide range of shape characteristics. For the asphericity and prolateness they are quite broad, resembling in form the results of lattice MC simulations. By means of the analytic fitting of these distributions, the most probable values for the shape characteristics are found to supplement their mean values.

10.
Phys Rev E Stat Nonlin Soft Matter Phys ; 72(3 Pt 2): 036107, 2005 Sep.
Article in English | MEDLINE | ID: mdl-16241515

ABSTRACT

We consider the influence of quenched disorder on the relaxational critical dynamics of a system characterized by a nonconserved order parameter coupled to the diffusive dynamics of a conserved scalar density (model C). Disorder leads to model A critical dynamics in the asymptotics; however, it is the effective critical behavior that is often observed in experiments and in computer simulations, and this is described by the full set of dynamical equations of diluted model C. Indeed, different scenarios of effective critical behavior are predicted.

11.
Article in English | MEDLINE | ID: mdl-26565179

ABSTRACT

We analyze the critical properties of the three-dimensional Ising model with linear parallel extended defects. Such a form of disorder produces two distinct correlation lengths, a parallel correlation length ξ(∥) in the direction along defects and a perpendicular correlation length ξ(⊥) in the direction perpendicular to the lines. Both ξ(∥) and ξ(⊥) diverge algebraically in the vicinity of the critical point, but the corresponding critical exponents ν(∥) and ν(⊥) take different values. This property is specific for anisotropic scaling and the ratio ν(∥)/ν(⊥) defines the anisotropy exponent θ. Until now, estimates of quantitative characteristics of the critical behavior for such systems have been obtained only within the renormalization group approach. We report a study of the anisotropic scaling in this system via Monte Carlo simulation of the three-dimensional system with Ising spins and nonmagnetic impurities arranged into randomly distributed parallel lines. Several independent estimates for the anisotropy exponent θ of the system are obtained, as well as an estimate of the susceptibility exponent γ. Our results corroborate the renormalization group predictions obtained earlier.

12.
Phys Rev E Stat Nonlin Soft Matter Phys ; 65(4 Pt 1): 042801, 2002 Apr.
Article in English | MEDLINE | ID: mdl-12005898

ABSTRACT

We analyze the scaling laws for a set of two different species of long flexible polymer chains joined together at one of their extremities (copolymer stars) in space dimension D=2. We use a formerly constructed field-theoretic description and compare our perturbative results for the scaling exponents with recent conjectures for exact conformal scaling dimensions derived by a conformal invariance technique in the context of D=2 quantum gravity. A simple Monte Carlo simulation brings about reasonable agreement with both approaches. We analyze the remarkable multifractal properties of the spectrum of scaling exponents.

13.
Phys Rev E Stat Nonlin Soft Matter Phys ; 70(3 Pt 2): 035104, 2004 Sep.
Article in English | MEDLINE | ID: mdl-15524568

ABSTRACT

The scaling properties of self-avoiding walks on a d -dimensional diluted lattice at the percolation threshold are analyzed by a field-theoretical renormalization group approach. To this end we reconsider the model of Phys. Rev. Lett. 63, 2819 (1989)] and argue that via renormalization its multifractal properties are directly accessible. While the former first order perturbation did not agree with the results of other methods our analytic result gives an accurate description of the available MC and exact enumeration data in a wide range of dimensions 2

14.
Phys Rev E Stat Nonlin Soft Matter Phys ; 85(2 Pt 1): 021143, 2012 Feb.
Article in English | MEDLINE | ID: mdl-22463188

ABSTRACT

This article concludes a series of papers [Folk, Holovatch, and Moser, Phys. Rev. E 78, 041124 (2008); 78, 041125 (2008); 79, 031109 (2009)] where the tools of the field theoretical renormalization group were employed to explain and quantitatively describe different types of static and dynamic behavior in the vicinity of multicritical points. Here we give the complete two-loop calculation and analysis of the dynamic renormalization-group flow equations at the multicritical point in anisotropic antiferromagnets in an external magnetic field. We find that the time scales of the order parameters characterizing the parallel and perpendicular ordering with respect to the external field scale in the same way. This holds independent whether the Heisenberg fixed point or the biconical fixed point in statics is the stable one. The nonasymptotic analysis of the dynamic flow equations shows that due to cancellation effects the critical behavior is described, in distances from the critical point accessible to experiments, by the critical behavior qualitatively found in one-loop order. Although one may conclude from the effective dynamic exponents (taking almost their one-loop values) that weak scaling for the order parameter components is valid, the flow of the time-scale ratios is quite different, and they do not reach their asymptotic values.


Subject(s)
Magnetic Fields , Magnets , Models, Theoretical , Rheology/methods , Computer Simulation
15.
Phys Rev E Stat Nonlin Soft Matter Phys ; 83(1 Pt 1): 011803, 2011 Jan.
Article in English | MEDLINE | ID: mdl-21405706

ABSTRACT

We consider star polymers, consisting of two different polymer species, in a solvent subject to quenched correlated structural obstacles. We assume that the disorder is correlated with a power-law decay of the pair-correlation function g(x)~x(-a). Applying the field-theoretical renormalization group approach in d dimensions, we analyze different scenarios of scaling behavior working to first order of a double ɛ=4-d, δ=4-a expansion. We discuss the influence of the correlated disorder on the resulting scaling laws and possible manifestations such as diffusion-controlled reactions in the vicinity of absorbing traps placed on polymers as well as the effective short-distance interaction between star copolymers.

16.
Phys Rev E Stat Nonlin Soft Matter Phys ; 83(6 Pt 1): 061114, 2011 Jun.
Article in English | MEDLINE | ID: mdl-21797309

ABSTRACT

We analyze the entropic equation of state for a many-particle interacting system in a scale-free network. The analysis is performed in terms of scaling functions, which are of fundamental interest in the theory of critical phenomena and have previously been theoretically and experimentally explored in the context of various magnetic, fluid, and superconducting systems in two and three dimensions. Here, we obtain general scaling functions for the entropy, the constant-field heat capacity, and the isothermal magnetocaloric coefficient near the critical point in uncorrelated scale-free networks, where the node-degree distribution exponent λ appears to be a global variable and plays a crucial role, similar to the dimensionality d for systems on lattices. This extends the principle of universality to systems on scale-free networks and allows quantification of the impact of fluctuations in the network structure on critical behavior.

17.
Phys Rev E Stat Nonlin Soft Matter Phys ; 82(1 Pt 1): 011145, 2010 Jul.
Article in English | MEDLINE | ID: mdl-20866603

ABSTRACT

In this paper, we address the logarithmic corrections to the leading power laws that govern thermodynamic quantities as a second-order phase transition point is approached. For phase transitions of spin systems on d-dimensional lattices, such corrections appear at some marginal values of the order parameter or space dimension. We present scaling relations for these exponents. We also consider a spin system on a scale-free network which exhibits logarithmic corrections due to the specific network properties. To this end, we analyze the phase behavior of a model with coupled order parameters on a scale-free network and extract leading and logarithmic correction-to-scaling exponents that determine its field and temperature behavior. Although both nontrivial sets of exponents emerge from the network structure rather than from the spin fluctuations they fulfill the respective thermodynamic scaling relations. For the scale-free networks the logarithmic corrections appear at marginal values of the node degree distribution exponent. In addition we calculate scaling functions, which also exhibit nontrivial dependence on intrinsic network properties.

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