Exploiting User Clustering and Fixed Power Allocation for Multi-Antenna UAV-Assisted IoT Systems.

Internet of Things (IoT) systems cooperative with unmanned aerial vehicles (UAVs) have been put into use for more than ten years, from transportation to military surveillance, and they have been shown to be worthy of inclusion in the next wireless protocols. Therefore, this paper studies user clustering and the fixed power allocation approach by placing multi-antenna UAV-mounted relays for extended coverage areas and achieving improved performance for IoT devices. In particular, the system enables UAV-mounted relays with multiple antennas together with non-orthogonal multiple access (NOMA) to provide a potential way to enhance transmission reliability. We presented two cases of multi-antenna UAVs such as maximum ratio transmission and the best selection to highlight the benefits of the antenna-selections approach with low-cost design. In addition, the base station managed its IoT devices in practical scenarios with and without direct links. For two cases, we derive closed-form expressions of outage probability (OP) and closed-form approximation ergodic capacity (EC) generated for both devices in the main scenario. The outage and ergodic capacity performances in some scenarios are compared to confirm the benefits of the considered system. The number of antennas was found to have a crucial impact on the performances. The simulation results show that the OP for both users strongly decreases when the signal-to-noise ratio (SNR), number of antennas, and fading severity factor of Nakagami-m fading increase. The proposed scheme outperforms the orthogonal multiple access (OMA) scheme in outage performance for two users. The analytical results match Monte Carlo simulations to confirm the exactness of the derived expressions.

Evaluation of Full-Duplex SWIPT Cooperative NOMA-Based IoT Relay Networks over Nakagami-m Fading Channels.

In this paper, we investigate the performance of non-orthogonal multiple access (NOMA)-based full-duplex Internet-of-Things (IoT) relay systems with simultaneous wireless information and power transfer (SWIPT) over Nakagami-m fading channels to improve the performance of a cell-edge user under perfect and imperfect successive interference cancellation (SIC). Two scenarios, i.e., direct and non-direct links, between the source node and cell-edge user are examined. The exact closed-form analytical and approximate expressions for the outage probability, system throughput, energy efficiency, and ergodic capacities are derived and validated via Monte Carlo simulations to characterize the proposed system performance. To further improve the system performance, we also provide a low-complexity algorithm to maximize the system throughput over-optimizing the time-switching factor. The results show that our proposed NOMA system can achieve superior performance compared to its orthogonal multiple access (OMA) counterpart under perfect SIC and with a low-to-medium signal-to-noise ratio under imperfect SIC, according to the level of residual self-interference and the quality of links.

Hybrid Approach for Indoor Localization Using Received Signal Strength of Dual-Band Wi-Fi.

In this paper, we propose a hybrid localization algorithm to boost the accuracy of range-based localization by improving the ranging accuracy under indoor non-line-of-sight (NLOS) conditions. We replaced the ranging part of the rule-based localization method with a deep regression model that uses data-driven learning with dual-band received signal strength (RSS). The ranging error caused by the NLOS conditions was effectively reduced by using the deep regression method. As a consequence, the positioning error could be reduced under NLOS conditions. The performance of the proposed method was verified through a ray-tracing-based simulation for indoor spaces. The proposed scheme showed a reduction in the positioning error of at least 22.3% in terms of the median root mean square error compared to the existing methods. In addition, we verified that the proposed method was robust to changes in the indoor structure.

One-Shot Learning for Partial Discharge Diagnosis Using Ultra-High-Frequency Sensor in Gas-Insulated Switchgear.

In recent years, deep learning has been successfully used in order to classify partial discharges (PDs) for assessing the condition of insulation systems in different electrical equipment. However, fault diagnosis using deep learning is still challenging, as it requires a large amount of training data, which is difficult and expensive to obtain in the real world. This paper proposes a novel one-shot learning method for fault diagnosis using a small dataset of phase-resolved PDs (PRPDs) in a gas-insulated switchgear (GIS). The proposed method is based on a Siamese network framework, which employs a distance metric function for predicting sample pairs from the same PRPD class or different PRPD classes. Experimental results over the small PRPD dataset that was obtained from an ultra-high-frequency sensor in the GIS show that the proposed method achieves outstanding performance for PRPD fault diagnosis as compared with the previous methods.

NLOS Identification in WLANs Using Deep LSTM with CNN Features.

Identifying channel states as line-of-sight or non-line-of-sight helps to optimize location-based services in wireless communications. The received signal strength identification and channel state information are used to estimate channel conditions for orthogonal frequency division multiplexing systems in indoor wireless local area networks. This paper proposes a joint convolutional neural network and recurrent neural network architecture to classify channel conditions. Convolutional neural networks extract the feature from frequency-domain characteristics of channel state information data and recurrent neural networks extract the feature from time-varying characteristics of received signal strength identification and channel state information between packet transmissions. The performance of the proposed methods is verified under indoor propagation environments. Experimental results show that the proposed method has a 2% improvement in classification performance over the conventional recurrent neural network model.

Simultaneous Wireless Power Transfer and Secure Multicasting in Cooperative Decode-and-Forward Relay Networks.

In this paper, we investigate simultaneous wireless power transfer and secure multicasting via cooperative decode-and-forward (DF) relays in the presence of multiple energy receivers and eavesdroppers. Two scenarios are considered under a total power budget: maximizing the minimum harvested energy among the energy receivers under a multicast secrecy rate constraint; and maximizing the multicast secrecy rate under a minimum harvested energy constraint. For both scenarios, we solve the transmit power allocation and relay beamformer design problems by using semidefinite relaxation and bisection technique. We present numerical results to analyze the energy harvesting and secure multicasting performances in cooperative DF relay networks.

Transmit Power Allocation for Physical Layer Security in Cooperative Multi-Hop Full-Duplex Relay Networks.

In this paper, we consider a transmit power allocation problem for secure transmission in multi-hop decode-and-forward (DF) full-duplex relay (FDR) networks, where multiple FDRs are located at each hop and perform cooperative beamforming to null out the signal at multiple eavesdroppers. For a perfect self-interference cancellation (PSIC) case, where the self-interference signal at each FDR is completely canceled, we derive an optimal power allocation (OPA) strategy using the Karush-Kuhn-Tucker (KKT) conditions to maximize the achievable secrecy rate under an overall transmit power constraint. In the case where residual self-interferences exist owing to imperfect self-interference cancellation (ISIC), we also propose a transmit power allocation scheme using the geometric programming (GP) method. Numerical results are presented to verify the secrecy rate performance of the proposed power allocation schemes.

Mitigating polyethylene-mediated periprosthetic tissue inflammation through MEDSAH-grafting.

Periprosthetic tissue inflammation is a challenging complication arising in joint replacement surgeries, which is often caused by wear debris from polyethylene (PE) components. In this study, we examined the potential biological effects of grafting a [2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl)ammonium hydroxide (MEDSAH) polymer onto the surface of PE through a solvent-evaporation technique. J774A.1 macrophage-like cells and primary cultured mouse osteoblasts were treated with PE powder with or without the MEDSAH coating. MEDSAH grafting on PE substantially reduced the expression of pro-inflammatory cytokines and other mediators in primary cultured mouse osteoblasts, but did not significantly impact macrophage-mediated inflammation. Our findings suggest that a MEDSAH coating on PE-based materials has potential utility in mitigating periprosthetic tissue inflammation and osteolysis and preventing aseptic loosening in total joint replacements. Further research, including large-scale clinical trials and biomechanical analyses, is needed to assess the long-term performance and clinical implications of MEDSAH-coated PE-based materials in total joint arthroplasty.

Non-thermal atmospheric pressure plasma treatment increases hydrophilicity and promotes cell growth on titanium alloys in vitro.

Most medical implants are made of titanium. When titanium is exposed to air for a long time, hydrocarbons are deposited and the surface becomes hydrophobic. Cell attachment is important for bone ingrowth to occur on the implant surface, and hydrophilicity can enhance this. We examined whether non-thermal atmospheric pressure plasma treatment could increase the hydrophilicity of the titanium surface. Samples coated with four widely used coating types [grit blasting, micro arc oxidation (MAO), titanium plasma spray (TPS), and direct metal fabrication (DMF)] were treated with plasma. Each of the four surface-treated samples was divided into groups with and without plasma treatment. We analysed wettability by surface analysis and evaluation of contact angles, cell proliferation, and adhesion using scanning electron microscopy (SEM), confocal laser scanning microscopy, absorbance tests, and alkaline phosphatase (ALP) activity assay; four different Ti6Al4V surface types were compared. After plasma treatment, the contact angle was reduced on all surfaces, and the carbon content was reduced on all surfaces based on X-ray photoelectron spectroscopy (XPS) surface analysis. Under confocal laser scanning, the cell layer was thicker on the plasma-treated samples, especially in groups TPS and DMF. Cell proliferation was 41.8%, 17.7%, 54.9%, and 83.8% greater for the plasma- than non-plasma-treated grit blasting, MAO, TPS, and DMF samples, respectively. Hydrophilicity increased significantly under plasma treatment, and biological responsivity was also improved.

Bioavailability of xenobiotics in the soil environment.

It is often presumed that all chemicals in soil are available to microorganisms, plant roots, and soil fauna via dermal exposure. Subsequent bioaccumulation through the food chain may then result in exposure to higher organisms. Using the presumption of total availability, national governments reduce environmental threshold levels of regulated chemicals by increasing guideline safety margins. However, evidence shows that chemical residues in the soil environment are not always bioavailable. Hence, actual chemical exposure levels of biota are much less than concentrations present in soil would suggest. Because "bioavailability" conveys meaning that combines implications of chemical sol persistency, efficacy, and toxicity, insights on the magnitude of a chemicals soil bioavailability is valuable. however, soil bioavailability of chemicals is a complex topic, and is affected by chemical properties, soil properties, species exposed, climate, and interaction processes. In this review, the state-of-art scientific basis for bioavailability is addressed. Key points covered include: definition, factors affecting bioavailability, equations governing key transport and distributive kinetics, and primary methods for estimating bioavailability. Primary transport mechanisms in living organisms, critical to an understanding of bioavailability, also presage the review. Transport of lipophilic chemicals occurs mainly by passive diffusion for all microorganisms, plants, and soil fauna. Therefore, the distribution of a chemical between organisms and soil (bioavailable proportion) follows partition equilibrium theory. However, a chemical's bioavailability does not always follow partition equilibrium theory because of other interactions with soil, such as soil sorption, hysteretic desorption, effects of surfactants in pore water, formation of "bound residue", etc. Bioassays for estimating chemical bioavailability have been introduced with several targeted endpoints: microbial degradation, uptake by higher plants and soil fauna, and toxicity to organisms. However, there bioassays are often time consuming and laborious. Thus, mild extraction methods have been employed to estimate bioavailability of chemicals. Mild methods include sequential extraction using alcohols, hexane/water, supercritical fluids (carbon dioxide), aqueous hydroxypropyl-beta-cyclodextrin extraction, polymeric TENAX beads extraction, and poly(dimethylsiloxane)-coated solid-phase microextraction. It should be noted that mild extraction methods may predict bioavailability at the moment when measurements are carried out, but not the changes in bioavailability that may occur over time. Simulation models are needed to estimate better bioavailability as a function of exposure time. In the past, models have progressed significantly by addressing each group of organisms separately: microbial degradation, plant uptake via evapotranspiration processes, and uptake of soil fauna in their habitat. This approach has been used primarily because of wide differences in the physiology and behaviors of such disparate organisms. However, improvement of models is badly needed, Particularly to describe uptake processes by plant and animals that impinge on bioavailability. Although models are required to describe all important factors that may affect chemical bioavailability to individual organisms over time (e.g., sorption/desorption to soil/sediment, volatilization, dissolution, aging, "bound residue" formation, biodegradation, etc.), these models should be simplified, when possible, to limit the number of parameters to the practical minimum. Although significant scientific progress has been made in understanding the complexities in specific methodologies dedicated to determining bioavailability, no method has yet emerged to characterized bioavailability across a wide range of chemicals, organisms, and soils/sediments. The primary aim in studying bioavailability is to define options for addressing bioremediation or environmental toxicity (risk assessment), and that is unlikely to change. Because of its importance in estimating research is needed to more comprehensively address the key environmental issue of "bioavailability of chemicals in soil/sediment."

Activity of double wash-coat monolith catalyst with noble metals and zeolites in selective catalytic reduction of NO(x) with C3H6.

The selective catalytic reduction (SCR) of NO(x) with C3H6 was studied in the presence of oxygen. The double wash-coat monolith catalysts for SCR comprised a lower layer of Au (or Pt)/Al2O3 and a upper layer of zeolites. The catalytic performance of the double wash-coated catalyst was remarkably improved to broaden the temperature window. The Au and Pt particles were dispersed uniformly on the monolith with particle sizes range of 3 approximately 5 nm and 5 approximately 10 nm, respectively. The catalyst binders used were colloidal silica, potassium silicate and tetraethyl orthosilicate, and the best catalyst activity was achieved with using colloidal silica as a binder. The zeolites used for the catalyst upper layer were MCM-41, FER, Y5.3-Zeolite and ZSM5, among which the NH4-ZSM5-coated catalyst showed the highest activity. The experimental results confirmed the promising potential of the double wash-coat, monolith catalyst for SCR of NO(x) with C3H6 due to the effective combination of noble metal monolith catalyst with zeolite for the removal of NO(x) by SCR with hydrocarbons.

Risk assessment of human antibiotics in Korean aquatic environment.

In Korea, antibiotic usage has received a lot of attention from the public due to the increasing number of bacteria resistant to the currently used antibiotics. In this study based on FDA regulation and EU draft guideline, the most concerned antibiotics regarding their environmental risk in Korea were assessed and the refined predicted environmental concentration in surface water (PEC(surface water)) was obtained by applying a GIS-based KORea ECOlogical Risk assessment (KOREOCORisk) model. Thirteen antibiotics, which expected introductory concentration (EIC) greater than the trigger value (1.0µg/L), were chosen to assess ecological risk and the PEC/PNEC ratio exceeded 1.0 for amoxicillin, erythromycin and roxithromycin. The results in this study using conservative assumptions did not represent that there is a risk for acute toxic effects in the environment based on today's use of pharmaceuticals in Korea. However, the results do not exclude the potential for chronic environmental effects.

Soil metabolism of a new herbicide, [14C]Pyribenzoxim, under flooded conditions.

To elucidate the fate of a new pyrimidinyloxybenzoic herbicide, pyribenzoxim, a soil metabolism study was carried out with [14C]pyribenzoxim applied to a sandy loam soil under flooded conditions. The material balance of applied radioactivity ranged from 96.4 to 104.4% and from 96.1 to 101.9% for nonsterile and sterile soils, respectively. The half-life of [14C]pyribenzoxim was calculated to be approximately 1.3 and 9.4 days for nonsterile and sterile soils, respectively. The metabolites identified during the study were 2,6-bis(4,6-dimethoxypyrimidin-2-yloxy)benzoic acid (M1) and 2-hydroxy-6-(4,6-dimethoxypyrimidin-2-yloxy)benzoic acid (M2), resulting from the cleavage of the ester bond and subsequent hydrolysis. The nonextractable radioactivity levels increased to 37.8% for nonsterile conditions at 50 days after treatment and to 38.2% for sterile conditions at 60 days after treatment. Fractionation of the nonextractable soil residues indicated that bound radioactivity was associated mainly with humin fraction. No significant volatile products or [14C]carbon dioxide was observed during the study. On the basis of these results, pyribenzoxim is considered to undergo rapid degradation in soil by microbial and chemical reactions, mainly hydrolysis, which limits its transfer to and accumulation in lower soil layers and groundwater. Therefore, the possibility of environmental contamination from the use of pyribenzoxim is expected to be very low.

Catalytic performance of nanosized Pt-Au alloy catalyst in oxidation of methanol and toluene.

The alloy formed between a group-VII metal such as platinum and a group-IB metal such as gold changes the catalytic behavior compared to the monometallic phase, increasing the selectivity toward certain products and also decreasing the deactivation rate. Pt-Au alloy nanoparticles coated on alumina support were found to be catalytically very active for complete oxidation of methanol and toluene. Furthermore, the nanosized Pt-Au particles were added to ZnO/Al2O3 on monolith catalyst. Also, effect of various parameters such as concentration of methanol and toluene and feed flow rate was investigated. Au particles were sized in 20 approximately 30 nm and Pt particles were well dispersed. In case of alumina supported powder catalyst, complete oxidation of methanol occurred at a temperature lower than that of toluene. From oxidation activity of monolithic honeycomb with Pt and Au particles, the conversion of methanol was increased with increasing the concentration of methanol, but conversion of toluene showed a decreasing tendency as the concentration of toluene increased. Also, conversion of methanol over honeycomb catalyst was not largely affected by feed flow rate, while conversion in toluene oxidation was decreased rapidly as feed flow rate was increased. As a result, the Pt-Au/ZnO/Al2O3/M catalyst used is likely to efficiently treat a large volume of exhaust gas containing VOCs.

Preparation of nanosized Pt-Au alloy catalyst and its activity in methanol oxidation.

The alloy catalyst has been widely used because it will be able to improve the activity and selectivity of the single metal catalyst in a given chemical reaction. In this study, the preparation and characteristics of nanosized Pt and Au particles on alumina and their catalytic activity were described. Nanosized Pt-Au catalysts were prepared by impregnation (IMP) method and deposition (DP) method using alumina or ZnO/Al2O3 as support. The size of Pt and Au particles were observed by transmission electron microscopy (TEM), energy dispersive spectroscope (EDS), and X-ray diffraction (XRD). Catalytic activity for oxidation of methanol was measured using a flow reactor. It could be seen that the Pt particle size and dispersion in the alloy catalysts was rarely influenced by preparation methods and Au particles coated by deposition method were well dispersed. TEM images showed that Au particles were well dispersed in the Pt/Au/ZnO/Al2O3 catalyst of which Au particles was supported by deposition method. The catalytic activity for methanol are given in the order of Pt-Au[IMP]/ZnO/Al2O3 > Pt[IMP]/Au[DP]/ZnO/Al2O3 > Au[DP]/Pt[IMP]/ZnO/Al2O3 > Pt-Au[DP]/ZnO/Al2O3. Therefore, Au particle size was doing not play an important role in increasing the oxidation activity, but the Au particles may promote the methanol oxidation.

Relationship between Exposure to Household Humidifier Disinfectants and Risk of Lung Injury: A Family-Based Study.

BACKGROUND: In South Korea, a cluster of acute lung disease patients included lung injury disease suspected of being caused by the use of humidifier disinfectants. We examined the relationship between humidifier disinfectant exposure and clinically diagnosed humidifier disinfectant-associated lung injury (HDLI) in a family-based study. METHODS: This case-control study included 169 clinically confirmed HDLI cases and 303 family controls who lived with the HDLI patients. A range of information on exposure to humidifier disinfectants was obtained using a structured questionnaire and field investigations. Odds ratios (ORs) and confidence intervals (CIs) were estimated using unconditional logistic regression models that were adjusted for age, sex, presence of a factory within 1 km of residence, and the number of household chemical products used. RESULTS: HDLI risk increased approximately two-fold or more among the highest quartile compared with the lowest quartile in terms of the hours sleeping in a room with an operating humidifier treated with disinfectant (adjusted OR = 2.0, 95 % CI = 1.1-3.7), average hours of disinfectant-treated humidifier use per day (adjusted OR = 2.1, 95 % CI = 1.0-4.5), airborne disinfectant intensity (adjusted OR = 2.6, 95% CI = 1.2-5.3), and cumulative disinfectant inhalation level (adjusted OR = 2.0, 95% CI = 1.0-4.1). HDLI risk increased as the distance of the bed from humidifier gets shorter; compared with longer distance (> 1 m), the odds ratio was 2.7 for 0.5 to 1 m (95 % CI = 1.5-5.1) and 13.2 for <0.5 m (95 % CI = 2.4-73.0). CONCLUSIONS: The use of household humidifier disinfectants was associated with HDLI risk in a dose-response manner.

Nationwide Study of Humidifier Disinfectant Lung Injury in South Korea, 1994-2011. Incidence and Dose-Response Relationships.

RATIONALE: Humidifier disinfectant lung injury is an acute lung disease attributed to recurrent inhalation of certain disinfectant aerosols emitted from room humidifiers. An outbreak of this toxic lung injury occurred in South Korea from 1995 until all humidifier disinfectant products were recalled from the consumer market by the government in 2011. OBJECTIVES: A nationwide study was conducted to ascertain and classify all potential cases of humidifier disinfectant lung injury in Korea and to assess dose-response relationships. METHODS: By several mechanisms, clinicians and the general public were invited to report all suspected cases of humidifier disinfectant lung injury to public health officials in South Korea. A committee was convened to define diagnostic criteria based on pathologic, radiologic, and clinical findings for index cases, combined with assessment of environmental exposure to humidifier disinfectants. Clinical review and environmental assessments were performed and later combined to determine overall likelihood of disease for each study participant, classified as definite, probable, possible, or unlikely. Survival time from exposure to onset of symptoms was analyzed to assess dose-response relationships. Three broad categories of risk factors were examined: (1) biological susceptibility, (2) temporal cycle of exposure and recovery, and (3) spatial conditions and density of disinfectant. MEASUREMENTS AND MAIN RESULTS: Of 374 possible cases identified and reviewed, 329 were unanimously classified by the diagnostic committee, as follows: 117 definite, 34 probable, 38 possible and 140 unlikely cases. A total of 62 individuals with definite or probable disease died. Risk factors examined for polyhexamethyleneguanidine phosphate exposure that were found to be significant in shortening survival included age 4 years or younger at onset, use of disinfectant for 7 days per week, airborne density of 800 µg/m(3) or more of disinfectant, and daily exposure 11 or more hours in duration. CONCLUSIONS: Dose-response analysis indicated that development of humidifier disinfectant lung injury and death were associated strongly with recurrent, intense, acute exposure without sufficient recovery time between exposures, more so than long-term cumulative exposure. These findings may explain some reversible or clinically unapparent cases among coexposed family members.

Combined isobutoxycarbonylation and tert-butyldimethylsilylation for the GC/MS-SIM detection of alkylphenols, chlorophenols and bisphenol A in mackerel samples.

The alkylphenols, chlorophenols, and bisphenol A were determined by gas chromatography/mass spectrometry-selected ion monitoring (GC/MS-SIM) followed by two work-up methods for comparison: isobutoxycarbonyl (isoBOC) derivatization and tert-butyldimethylsilyl (TBDMS) derivatization. Eleven endocrine disrupting chemicals (EDCs) of phenols in biological samples were extracted with acetonitrile and then the acetonitrile layer underwent freezing filtration 60 degrees C for 2 hours. Solid-phase extraction (SPE) was used with XAD-4 and subsequent conversion to isoBOC or TBDMS derivatives for sensitivity analysis with the GC/MS-SIM mode. For isoBOC derivatization and TBDMS derivatization the recoveries were 92.3 approximately 150.6% and 93.8-108.3%, the method detection limits (MDLs) of bisphenol A for SIM were 0.062 microg/kg and 0.010 microg/kg, and the SIM responses were linear with the correlation coefficient varying by 0.9755-0.9981 and 0.9908-0.9996, respectively. When these methods were applied to mackerel samples, the concentrations of the 11 phenol EDCs were below the MDL.