A python script for longitudinally measuring the duration of vacant land uses.

Populating and depopulating cities have some degree of underutilised land. The duration of vacancy, or length of time a property remains unused, more strongly influences urban decline than the amount of vacant land. Assessment of the duration of vacancy is seldom conducted, due to a lack of linking longitudinal data. This research creates and applies a Python script to track the duration of vacancy in Minneapolis, MN, U.S.A, to create a tool that can be utilised by cities with vacant land inventories. The tool can be used globally to prioritise treatment areas for urban regeneration plans.

Adjusting microwave sensing frequency through aspect ratio variation and bending repetitions in Permalloy ellipses.

The Ferromagnetic Resonance (FMR) phenomenon, marked by the selective absorption of microwave radiation by magnetic materials in the presence of a magnetic field, plays a pivotal role in the development of radar absorbing materials, high speed magnetic storage, and magnetic sensors. This process is integral for technologies requiring precise control over microwave absorption frequencies. We explored how variations in resonance fields can be effectively modulated by adjusting both the shape and stress anisotropies of magnetic materials on a flexible substrate. Utilizing polyethylene-naphthalate (PEN) as the substrate and Permalloy (Ni79Fe21, noted for its positive magnetostriction coefficient) as the magnetic component, we demonstrated that modifications in the aspect ratio and bending repetitions can significantly alter the resonance field. The results, consistent with Kittel's equation and the predictions of a uniaxial magnetic anisotropy model, underscore the potential for flexible substrates in enhancing the sensitivity and versatility of RF-based magnetic devices.

The self-annealing phenomenon of electrodeposited nano-twin copper with high defect density.

Electroplated copper was prepared under typical conditions and a high defect density to study the effect of the defects on its self-annealing phenomenon. Two conditions, grain growth and stress relaxation during self-annealing, were analyzed with electron backscattered diffraction and a high-resolution X-ray diffractometer. Abnormal grain growth was observed in both conditions; however, the grown crystal orientation differed. The direction and relative rate at which abnormal grain growth proceeds were specified through textured orientation, and the self-annealing mechanism was studied by observing the residual stress changes over time in the films using the sin2Ψ method.

Study of Cu Electrochemical Polishing Mechanism With Observation of Water Acceptor Diffusion.

The salt-film and water acceptor mechanisms were generally accepted mechanisms for Cu electrochemical polishing (ECP) theory. These mechanisms of Cu ECP are still controversial for a long time. Conventional and new electrochemical analysis methods were used to investigate the mechanisms and behaviors of Cu electrochemical polishing. Two cases of Cu dissolution, with and without polishing, were classified by results of linear scan voltammetry (LSV) and scanning electron microscopy (SEM). The electrochemical impedance spectroscopy (EIS) results showed the main difference in these two cases was in the low-frequency region. However, it was hard to distinguish between the salt-film and water acceptor mechanisms by conventional electrochemical analysis. A scanning electrochemical microscopy (SECM) system, a new electrochemical analysis method that measures the electrolysis currents of the water acceptors along with a set distance from the substrate, was used to investigate the Cu ECP mechanism. Accordingly, the diffusion of the water acceptors was successfully confirmed for the first time. Finally, the mechanisms of the Cu ECP are definitively described by using all analysis results.

Buy them out before they are built: evaluating the proactive acquisition of vacant land in flood-prone areas.

Rising flood damages have prompted local communities to implement buyout and property acquisition programmes to eliminate repetitive losses for at-risk properties. However, buyouts are often costly to implement and are reactionary solutions to flooding. This study quantifies the benefits of acquiring vacant private properties in flood-prone areas rather than acquiring such properties after they are built up. Using a geodesign framework that integrates concepts and analytical approaches derived from geographical, spatial and statistical-based disciplines, we analyse vacant properties with high development potential that intersect current and future floodplain areas in Houston (TX, USA). We use geospatial proximity analysis to select candidate properties, land-use prediction modelling to estimate future development and sea-level rise and benefit-cost analysis to assess the economic viability of buyouts. The results indicate that cumulative avoided flood losses exceed the cost of vacant land acquisition by a factor of nearly two to one, and up to a factor of ten to one in selected areas. This study emphasizes the benefits of proactive property buyouts that focus on acquiring parcels before they are built up, while also avoiding the social and institutional problems associated with traditional buyout programmes.

Advancing Scenario Planning through Integrating Urban Growth Prediction with Future Flood Risk Models.

High uncertainty about future urbanization and flood risk conditions limits the ability to increase resiliency in traditional scenario-based urban planning. While scenario planning integrating urban growth prediction modeling is becoming more common, these models have not been effectively linked with future flood plain changes due to sea level rise. This study advances scenario planning by integrating urban growth prediction models with flood risk scenarios. The Land Transformation Model, a land change prediction model using a GIS based artificial neural network, is used to predict future urban growth scenarios for Tampa, Florida, USA, and future flood risks are then delineated based on the current 100-year floodplain using NOAA level rise scenarios. A multi-level evaluation using three urban prediction scenarios (business as usual, growth as planned, and resilient growth) and three sea level rise scenarios (low, high, and extreme) is conducted to determine how prepared Tampa's current land use plan is in handling increasing resilient development in lieu of sea level rise. Results show that the current land use plan (growth as planned) decreases flood risk at the city scale but not always at the neighborhood scale, when compared to no growth regulations (business as usual). However, flood risk when growing according to the current plan is significantly higher when compared to all future growth residing outside of the 100-year floodplain (resilient growth). Understanding the potential effects of sea level rise depends on understanding the probabilities of future development options and extreme climate conditions.

A Review of Driving Factors, Scenarios, and Topics in Urban Land Change Models.

Due to the increase in future uncertainty caused by rapid environmental, societal, and technological change, exploring multiple scenarios has become increasingly important in urban planning. Land Change Modeling (LCM) enables planners to have the ability to mold uncertain future land changes into more determined conditions via scenarios. This paper reviews the literature on urban LCM and identifies driving factors, scenario themes/types, and topics. The results show that: (1) in total, 113 driving factors have been used in previous LCM studies including natural, built environment, and socio-economic factors, and this number ranges from three to twenty-one variables per model; (2) typical scenario themes include "environmental protection" and "compact development"; and (3) LCM topics are primarily growth prediction and prediction tools, and the rest are growth-related impact studies. The nature and number of driving factors vary across models and sites, and drivers are heavily determined by both urban context and theoretical framework.

Integrating Prediction and Performance Models into Scenario-based Resilient Community Design.

Urban expansion can worsen climate change conditions and enlarge hazard zones. Sea level rise due to climate change makes coastal populations more susceptible to flood risks. The use of land change prediction modelling to inform scenario-based planning has been shown to help increase capabilities when dealing with uncertainties in urbanization such as urban growth and flood risk, when compared to singular comprehensive plans. This research uses the Land Transformation model to predict three different urban growth scenarios for Tampa, FL to determine how effective the current comprehensive plan is in adapting urban growth to decreasing flood risk and pollutant load. To achieve this, the research develops master plans according to each scenario then assesses their probable impact using the Long-Term Hydrologic Impact Analysis Low Impact Development Spreadsheet as a performance model. Findings show that the current future land use plan for Tampa, while it appears to be better than current patterns of development, has higher flood exposure, stormwater runoff, and pollutant discharge that current conditions but more than a purely resilient approach to future growth.

Effect of Pulse Current and Pre-annealing on Thermal Extrusion of Cu in Through-Silicon via (TSV).

Thermal stress induced by annealing the Cu filling of through-silicon vias (TSVs) requires further investigation as it can inhibit the performance of semiconductor devices. This study reports the filling behavior of TSVs prepared using direct current and pulse current Cu electrodeposition with and without pre-annealing. The thermal extrusion of Cu inside the TSVs was studied by observing the extrusion behavior after annealing and the changes in grain orientation using scanning electron microscopy and electron backscatter diffraction. The bottom-up filling ratio achieved by the direct current approach decreased because the current was used both to fill the TSV and to grow bump defects on the top surface of the wafer. In contrast, pulse current electrodeposition yielded an improved TSV bottom-up filling ratio and no bump defects, which is attributable to strong suppression and thin diffusion layer. Moreover, Cu deposited with a pulse current exhibited lesser thermal extrusion, which was attributed to the formation of nanotwins and a change in the grain orientation from random to (101). Based on the results, thermal extrusion of the total area of the TSVs could be obtained by pulse current electrodeposition with pre-annealing.

Integrating a Resilience Scorecard and Landscape Performance into a Geodesign Process.

Uncertainty about the impacts of sea level rise make the ability to forecast future spatial conditions a necessary planning/design tool. Geodesign integrates multiple fields of science with change/impact models and planning/design strategies. Proactive planning analyses such as newly developed scorecards allow for plan evaluation; design strategies can now be quantitatively assessed using landscape performance calculators. Neither have been explored as Geodesign tools. A Geodesign process was developed using the resilience scorecard to assess flood vulnerability using projections for the 100 year floodplain with sea level rise by 2100. Projections were used as a guide to develop a resilient master plan for League City, TX, USA. Future impacts of the plan are projected using landscape performance measures.

GROWTH AND SHRINKAGE PRE AND POST TSUNAMI IN FUKUSHIMA PREFECTURE, JAPAN.

Depopulation is a severe problem in many urban areas globally. Massive population migrations can occur due to relocation after natural disasters and significantly change the demographic composition of regions and cities. The 2011 Great Tsunami in Japan resulted in a combined total of deaths and missing persons of more than 24,500. Post-tsunami recovery efforts resulted in widespread population relocation of high-risk communities into lower-risk areas. Using the Fukushima Prefecture in Japan as the study area, a region characterized by several depopulating cities both pre and post-tsunami, this research examines how the population relocation efforts have either exacerbated or assisted in lessening the effects of urban shrinkage and decline after the earthquake and tsunami of 2011. The results show that 30 municipalities have seen population and economic growth since 2011, and 12 municipalities are underdoing trends toward decline within Fukushima. Negatively affected cities tend to have larger populations than positively affected cities. Most of the small towns and villages closer to the inundation area are fall into the category of negatively affected areas. Moreover, the population increases in many post-disaster cities are primarily due to significant increases in elderly populations with minimal young persons that will inevitably decline in the next decade. By determining the effects of their relocation efforts, the government can better develop targeted strategies that good for the prosperity and development of the Fukushima Prefecture.

Climate Change Preparedness: Comparing Future Urban Growth and Flood Risk in Amsterdam and Houston.

Rising sea levels and coastal population growth will increase flood risk of more people and assets if land use changes are not planned adequately. This research examines the efficacy of flood protection systems and land use planning by comparing Amsterdam in the Netherlands (renown for resilience planning methods), with the city of Houston, Texas in the US (seeking ways of increasing resilience due to extreme recent flooding). It assesses flood risk of future urban growth in lieu of sea level rise using the Land Transformation Model, a Geographic Information Systems (GIS)-based Artificial Neural Network (ANN) land use prediction tool. Findings show that Houston has currently developed much more urban area within high-risk flood-prone zones compared to Amsterdam. When comparing predicted urban areas under risk, flood-prone future urban areas in Amsterdam are also relatively smaller than Houston. Finally, the increased floodplain when accounting for sea level rise will impact existing and future urban areas in Houston, but do not increase risk significantly in Amsterdam. The results suggest that the protective infrastructure used in the Netherlands has protected its future urban growth from sea level rise more adequately than has Houston.

Interface polarization model for a 2-dimensional electron gas at the BaSnO3/LaInO3 interface.

In order to explain the experimental sheet carrier density n2D at the interface of BaSnO3/LaInO3, we consider a model that is based on the presence of interface polarization in LaInO3 which extends over 2 pseudocubic unit cells from the interface and eventually disappears in the next 2 unit cells. Considering such interface polarization in calculations based on 1D Poisson-Schrödinger equations, we consistently explain the dependence of the sheet carrier density of BaSnO3/LaInO3 heterinterfaces on the thickness of the LaInO3 layer and the La doping of the BaSnO3 layer. Our model is supported by a quantitative analysis of atomic position obtained from high resolution transmission electron microscopy which evidences suppression of the octahedral tilt and a vertical lattice expansion in LaInO3 over 2-3 pseudocubic unit cells at the coherently strained interface.

Molecular analysis of endogenous avian leukosis/sarcoma virus genomes in Korean chicken embryos.

Since the status of endogenous avian leucosis/sarcoma virus (ALSV) infections in Korean broiler chickens is unclear, this study examined embryonated eggs obtained from broiler farms and Korean native chicken breeds in Korea using PCR with the primer sets specific for endogenous ALSVs. The PCR assays detected the genomes of EAV, ev, ev/J and ART-CH belonging to the endogenous ALSV from all embryos tested. Phylogenetically, the Korean EAV genomes were more closely related to the prototype EAV-0 than to the other prototype, E51. The Korean ART-CH elements clustered together but were distinct from the prototype ART-CH clones, 5 and 14. Although there was comparatively little divergence in the nucleotide and amino acid sequences of the Korean ev and ev/J genomes compared with the other known ev and ev/J genomes, the Korean genomes had phylogenetically distinct branches. From these results, endogenous genomes are quite prevalent in Korean broiler chickens. In addition, the endogenous genomes circulating in Korean broiler chickens are genetically different from the other known endogenous genomes. These results are expected to provide useful information for the control and establishment of a surveillance system for endogenous ALSVs in Korea.

Relationship between DNA ploidy and proliferative cell nuclear antigen index in canine hemangiopericytoma.

The mitotic index is reported to be correlated with recurrence, mean patient survival, and metastasis of canine hemangiopericytoma (CHP). However, to the authors' knowledge, studies investigating the parameters that can predict recurrence or metastasis of CHP with low mitotic index have not been done. To evaluate growth kinetics of CHP with low mitotic index, a retrospective analysis of the proliferative activity by antiproliferative cell nuclear antigen monoclonal antibody and DNA contents by flow cytometry (FCM) was performed with 21 formalin-fixed and paraffin-embedded CHP samples. Of the 21 tumors evaluated by FCM, 6 (26.6%) were aneuploid tumors, and 15 (71.4%) were diploid tumors. There was significant correlation between the PCNA index and ploidy pattern. The diploid group had 39.1 +/- 9.2 PCNA index, whereas the aneuploid group's proliferative cell nuclear antigen (PCNA) index was 63.1 +/- 8.2. The diploid group had mean mitotic index value of 1.140 +/- 0.855, and the aneuploid group had a mean value of 1.067 +/- 0.767. From these results, the CHP samples with low mitotic index were classified into either the aneuploid group with higher PCNA index or the diploid group with lower PCNA index, suggesting that DNA ploidy and proliferative activity may give an indication about malignancy of CHPs with a low mitotic index.

Molecular analysis of S gene of spike glycoprotein of winter dysentery bovine coronavirus circulated in Korea during 2002-2003.

Since the molecular analysis of spike (S) glycoprotein gene of bovine coronavirus (BCoV) has been conducted and compared mainly among American and Canadian isolates and/or strains, it is unclear whether BCoV circulated in the other countries are distinctive in genetic characteristics. In the present study, we analyzed the S glycoprotein gene to characterize 10 winter dysentery (WD) coronavirus strains circulated in Korea during 2002-2003 and compared the nucleotide (nt) and deduced amino acid (aa) sequences with the other known BCoV. The phylogenetic analysis of the entire S glycoprotein gene revealed that the aa sequences of all Korean WD strains were more homologous to each other and were very closely related to respiratory bovine coronavirus (RBCV) strain OK and enteric bovine coronavirus (EBCV) strain LY-138, but were distinct from the other known BCoVs. Based on the phylogenetic analysis of the hypervariable region of the S1 subunit, all Korean WD strains clustered with the respiratory strain OK, BCQ3994 and the enteric strain LY-138, while the Canadian BCQ calf diarrhea and WD strains, and the American RBCV LSU, French EBCV F15 and avirulent VACC, L9, and Mebus strains clustered on a separate major branch. These data suggest that the WD strains circulated in Korea had a genetic property of both RBCV and EBCV and were significantly distinct from the ancestral enteric strain.

Segmental aplasia of uterine body in an adult mixed breed dog.

Segmental aplasia of the uterine body was diagnosed in a 5-year-old, mixed breed bitch. Abdominal radiography and transabdominal ultrasonography revealed marked dilation of fluid-filled uterine horns with no evidence of a uterine body. Sex hormone assays did not detect the presence of estradiol-17 beta; however, progesterone (2 ng/ml) was found in the serum, indicating anestrus. On gross examination of the reproductive tract, the uterine body was absent, apparently never formed. In its place, a cord-like piece of tissue was identified as an aplastic/dysplastic remnant, connecting the cervix and right uterine horn. The tip of the cord-like piece branched into 5 string-like pieces of tissue, 1 of which was connected to the region dividing the left and right uterine horns. Both the uterine horns were dilated markedly revealing hydrometra. Histologically, uterine body remnant tissues from the endometrium, myometrium, and perimetrium were detected in proximal and distal parts of the uterine body. The string-like piece of tissue connecting the uterine body remnant and the uterine horn consisted of a round cluster of smooth muscle cells surrounding a central core of adipose tissue with blood vessels. It was concluded that the hydrometra observed in both uterine horns was induced by an obstruction resulting from segmental aplasia in the uterine body. This is the first known report of segmental aplasia in the uterine body of a bitch.

Detection and isolation of winter dysentery bovine coronavirus circulated in Korea during 2002-2004.

Although winter dysentery (WD) has been suspected to occur frequently in Korea, to date the exact epidemiology of WD has remained unknown. Therefore, we investigated the causative agents of WD by using electron microscopy, ELISA, RT-PCR, and nested PCR from 97 fecal samples of 32 WD-affected herds collected from 8 provinces during 2002-2004. The bovine coronavirus (BoCV) was consistently detected in all herds with WD. Of other pathogens, only coccidian oocyts were inconsistently but concurrently detected with BoCV. Ten isolates were identified as BoCV by immune electron microscope, immunofluorescent test and ELISA with antiserum to BoCV, and RT-PCR. From these results, it is concluded that WD caused by BoCV occurred in relatively high frequency and was widespread in Korea. The results provide important epidemiological data for the control and establishment of a surveillance system for WD in Korea.

Antimelanogenic and antioxidant properties of gallic acid.

To find novel skin-whitening agents, the melanogenesis inhibitory action of gallic acid (GA) was investigated. In this current study, the effects of GA on mushroom tyrosinase, tyrosinase inhibitory activity, and melanin content were assessed in B16 melanoma cells (B16 cells). Results indicated that GA has a strong antityrosinase activity (IC50=3.59x10(-6) M). Furthermore, data on murine tyrosinase activity and melanin biosynthesis revealed that GA effectively suppressed murine tyrosinase action and the amount of melanin. To investigate the relation between GA's inhibition of melanogenesis and antioxidant activity, the effect of GA on reactive species (RS) generation and the reduced glutathione (GSH)/oxidized glutathione (GSSG) ratio in were determined in B16 cells. Results indicated that GA effectively down-regulated the RS generation and enhanced the GSH/GSSG ratio. Based on these results, I propose that GA exerts antimelanogenic activity coupled with antioxidant properties by suppressing RS generation and maintaining a higher GSH/GSSG ratio.

Molecular characterization of novel G5 bovine rotavirus strains.

Group A rotaviruses are a major cause of acute gastroenteritis in young children as well as many domestic animals. The rotavirus genome is composed of 11 segments of double-stranded RNA and can undergo genetic reassortment during mixed infections, leading to progeny viruses with novel or atypical phenotypes. The aim of this study was to determine if the bovine group A rotavirus strains KJ44 and KJ75, isolated from clinically infected calves, share genetic features with viruses obtained from heterologous species. All 11 genes sequences of the KJ44 and KJ75 strains were sequenced and analyzed. The KJ44 VP4 had 91.7% to 96.3% deduced amino acid identity to the bovine related P[1] strain, whereas the KJ75 strain was most closely related to the bovine related P[5] strain (91.9% to 96.9% amino acid identity). Both KJ44 and KJ75 strains also contained the bovine related VP3 gene. The remaining 9 segments were closely related to porcine group A rotaviruses. The KJ44 and KJ75 strains showed high amino acid identity to the G5 rotaviruses, sharing 90.4% to 99.0% identity. In addition, these strains belonged to the NSP4 genotype B, which is typical of porcine rotaviruses and subgroup I, with the closest relationship to the porcine JL-94 strain. These results strongly suggest that bovine rotavirus strains with the G5 genotype occur in nature as a novel G genotype in cattle as a result of a natural reassortment between bovine and porcine strains.