ABSTRACT
CuNi-ZrO2 nanocomposites were prepared by a simple coprecipitation technique of copper, nickel and zirconium ions with potassium carbonate. The structures of the nanocomposites were characterized by N2 physical adsorption, XRD, H2-TPR and STEM-EDS. The Cu0.05Ni0.45-ZrO2 nanocomposite showed outstanding catalytic performance in hydrogenation of levulinic acid (LA) to γ-valerolactone (GVL), especially NaOH solution (0.5 mol L-1) as a solvent. 100% LA conversion and > 99.9% GVL selectivity are achieved over Cu0.05Ni0.45-ZrO2 catalyst at 200 °C, 3 MPa for 1.5 h. Characterization results suggest that the excellent reactivity of the Cu0.05Ni0.45-ZrO2 may be due to a better reducibility of nickel oxide in the CuONiO-ZrO2, dispersion of Ni in the Cu0.05Ni0.45-ZrO2 compared to nickel oxide in the NiO-ZrO2 and Ni in the Ni0.5-ZrO2 and promotion of OH-. The results demonstrate that the Cu0.05Ni0.45-ZrO2 nanocomposite has potential to realize high efficiency and low-cost synthesis of liquid fuels from biomass.