ABSTRACT
Hydrogen gas (H2 ) is a viable energy carrier that has the potential to replace the traditional fossil fuels and contribute to achieving zero net emissions, making it an attractive option for a hydrogen-based society. However, current H2 purification technologies are often limited by high energy consumption, and as a result, there is a growing demand for alternative techniques that offer higher H2 purity and energy efficiency. Membrane separation has emerged as a promising approach for obtaining high-purity H2 gas with low energy consumption. Nevertheless, despite years of development, commercial polymeric membranes have limited performance, prompting researchers to explore alternative materials. In this context, carbon-based membranes, specifically graphene-based nanomaterials, have gained significant attention as potential membrane materials due to their unique properties. In this review, we provide a comprehensive overview of carbon-based membranes for H2 gas separation, fabrication of the membrane, and its characterization, including their advantages and limitations. We also explore the current technological challenges and suggest insights into future research directions, highlighting potential ways to improve graphene-based membranes performance for H2 separations.