The effect of hydrate promoters on gas uptake.

Gas hydrate technology is considered as a promising technology in the fields of gas storage and transportation, gas separation and purification, seawater desalination, and phase-change thermal energy storage. However, to date, the technology is still not commercially used mainly due to the low gas hydrate formation rate and the low gas uptake. In this study, the effect of hydrate promoters on gas uptake was systematically studied and analyzed based on hydrate-based CH4 storage and CO2 capture from CO2/H2 gas mixture experiments. Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR) and gas chromatography (GC) were employed to analyze the microstructures and gas compositions. The results indicate that the effect of the hydrate promoter on the gas uptake depends on the physical and chemical properties of the promoter and gas. A strong polar ionic promoter is not helpful towards obtaining the ideal gas uptake because a dense hydrate layer is easily formed at the gas-liquid interface, which hinders gas diffusion from the gas phase to the bulk solution. For a weak polar or non-polar promoter, the gas uptake depends on the dissolution characteristics among the different substances in the system. The lower the mutual solubility among the substances co-existing in the system, the higher the independence among the substances in the system; this is so that each phase has an equal chance to occupy the hydrate cages without or with small interactions, finally leading to a relatively high gas uptake.

Molecular Dynamics Simulation of the Crystal Nucleation and Growth Behavior of Methane Hydrate in the Presence of the Surface and Nanopores of Porous Sediment.

The behavior of hydrate formation in porous sediment has been widely studied because of its importance in the investigation of reservoirs and in the drilling of natural gas hydrate. However, it is difficult to understand the hydrate nucleation and growth mechanism on the surface and in the nanopores of porous media by experimental and numerical simulation methods. In this work, molecular dynamics simulations of the nucleation and growth of CH4 hydrate in the presence of the surface and nanopores of clay are carried out. The molecular configurations and microstructure properties are analyzed for systems containing one H2O hydrate layer (System A), three H2O hydrate layers (System B), and six H2O hydrate layers (System C) in both clay and the bulk solution. It is found that hydrate formation is more complex in porous media than in the pure bulk solution and that there is cooperativity between hydrate growth and molecular diffusion in clay nanopores. The hydroxylated edge sites of the clay surface could serve as a source of CH4 molecules to facilitate hydrate nucleation. The diffusion velocity of molecules is influenced by the growth of the hydrate that forms a block in the throats of the clay nanopore. Comparing hydrate growth in different clay pore sizes reveals that the pore size plays an important role in hydrate growth and molecular diffusion in clay. This simulation study provides the microscopic mechanism of hydrate nucleation and growth in porous media, which can be favorable for the investigation of the formation of natural gas hydrate in sediments.

Study on the Application of Modified Sn-Based Solder in Cable Intermediate Joints.

With the increasing use of underground cables, the quantity and quality of intermediate joints demanded are also increasing. The quality of the traditional crimping intermediate joint is easily affected by the actual process of the operator, which may lead to the heating of the crimping part of the wire core, affecting the insulation performance of the cable, and finally causing the joint to break. However, aluminothermic reactive technology has some problems, such as a high welding temperature and an uncontrollable reaction. In order to solve these problems, according to the brazing principle and microalloying method, the optimal content of In in Sn-1.5Cu-based solder was explored, and then the connection of the middle joint of a 10 kV cable was completed using a connecting die and electrical connection process. The contact resistance and tensile strength of the joint were tested to verify the feasibility of this method. The results show that the maximum conductivity of the solder with 3.8% and 5% In content can reach 3.236 × 106 S/m, and the highest wettability is 93.6%. Finally, the minimum contact resistance of the intermediate joint is 7.05 µΩ, which is 43% lower than that of the aluminothermic welded joint, and the tensile strength is close to that of the welded joint, with a maximum of 7174 N.

Research progress on the effects of nanoparticles on gas hydrate formation.

Gas hydrate has great application potential in gas separation, energy storage, seawater desalination, etc. However, the intensity of mass and heat transfer is not enough to meet the needs of efficient hydrate synthesis. Nanoparticles, different from other liquid chemical additives, are considered as effective additives to promote hydrate formation due to their rich specific surface area and excellent thermal conductivity. This work summarizes the effect of the nanoparticles on the thermodynamics and kinetics of hydrate formation. And also, this work probes into the mechanism of the effect of the nanoparticles on the formation of hydrate as well as provides some suggestions for future research. It is found that it's difficult for nanoparticles to effectively promote the formation of the gas hydrate without the use of surfactants, because the adhesion characteristics of the nanoparticles make them easily agglomerate or even agglomerate in solution. In addition, at present, the research on the influence of nanoparticles on the formation and decomposition of natural gas hydrate is still very fragmented, and the micro mechanism of the influence is not clear, which requires more systematic and specific research in the future. At the same time, the development of nanoparticles that can promote the formation of natural gas hydrate should also become the focus of future research.

Microscopic Insights into the Effect of the Initial Gas-Liquid Interface on Hydrate Formation by In-Situ Raman in the System of Coalbed Methane and Tetrahydrofuran.

The serious issues of energy shortage and greenhouse gas emission have led to the development of coalbed methane (CBM) with new commercial ramifications. A hydrate-based gas separation technology is introduced to recover methane from CBM. However, the mechanism of hydrate nucleation needs to be clear for enhancing the hydrate formation rate and gas recovery efficiency. In this work, we studied, by means of in-situ Raman spectroscopy, the microscopic characterizations of hydrates forming in/around the initial gas-liquid interface in the case of CBM and tetrahydrofuran (THF). It is found that the hydrates accumulate as a film with horizontal crevices in the initial gas-liquid interface. These crevices prevent the hydrate film from hindering gas-liquid contact and limiting hydrate formation. Raman spectroscopy results illustrate that the initial gas-liquid interface shows a positive impact on water aggregation, and that the holding gas molecules stay stably with the water molecules. Nitrogen molecules encage into the cavities of THF hydrates along with methane molecules. For the interface and hydrate layer, water aggregation is evaluated by the Raman intensity ratio of hydrogen-bonded water (BW) and free water (FW) without any hydrogen bonds, abbreviated as I BW/I FW. A value of I BW/I FW higher than 0.85 can symbolize the occurrence of hydrate nucleation in the interface and help assess the hydrate formation.

Sulfonated poly (fluorenyl ether ketone nitrile) membranes used for high temperature PEM fuel cell.

A series of sulfonated poly (fluorenyl ether ketone nitrile)s with different equivalent weights (EW) ranging from 681 to 369 g mequiv.-1 were used to assemble a series of single proton exchange membrane fuel cells (PEMFC) in their turns. The mechanical strength and morphology of the copolymer were studied systematically. This paper mainly evaluated and compared their cell performance. The polarization curves showed that the prepared films have good performance at low temperature and high relative humidity. Due to the increase of temperature, dehydration seriously deteriorated the performance of the cell, especially for the membrane with high electron flow and low proton conductivity. However, at 100 °C, the cell performance of the membrane containing 441 g mequiv.- 1 was even better than that of Nafion@117 membrane. It could even be used at 125 °C. In the short life test, the output power density was stable at about 0.24 W•cm-2 within 24 h. These results show that our membranes were suitable for the applications of PEM fuel cell at high temperature.

Molecular dynamics simulation of the intercalation behaviors of methane hydrate in montmorillonite.

The formation and mechanism of CH4 hydrate intercalated in montmorillonite are investigated by molecular dynamics (MD) simulation. The formation process of CH4 hydrate in montmorillonite with 1 ~ 8 H2O layers is observed. In the montmorillonite, the "surface H2O" constructs the network by hydrogen bonds with the surface Si-O ring of clay, forming the surface cage. The "interlayer H2O" constructs the network by hydrogen bonds, forming the interlayer cage. CH4 molecules and their surrounding H2O molecules form clathrate hydrates. The cation of montmorillonite has a steric effect on constructing the network and destroying the balance of hydrogen bonds between the H2O molecules, distorting the cage of hydrate in clay. Therefore, the cages are irregular, which is unlike the ideal CH4 clathrate hydrates cage. The pore size of montmorillonite is another impact factor to the hydrate formation. It is quite easier to form CH4 hydrate nucleation in montmorillonite with large pore size than in montmorillonite with small pore. The MD work provides the constructive information to the investigation of the reservoir formation for natural gas hydrate (NGH) in sediments.