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Luminescence ; 33(8): 1432-1437, 2018 Dec.
Article in English | MEDLINE | ID: mdl-30402900

ABSTRACT

BaGd2 O4 :Eu3+ scintillating phosphors by Pr3+ -codoping were synthesized at 1300°C in air using a solid-state reaction method. The as-synthesized phosphors were characterized by X-ray diffraction (XRD), photoluminescence (PL) including excitation and emission spectra, radioluminescence (RL) spectra excited by X-ray and thermoluminescence (TL) spectra. Both the PL and RL spectra are composed of the featured trivalent europium (Eu3+ ) without any praseodymium (Pr3+ ) ions, and the PL and RL intensities as well as the lifetimes of BaGd2 O4 :Eu3+ scintillating phosphors decrease dramatically with an increasing concentration of Pr3+ ions. Finally, the TL spectra reveal the trap concentration of the existing defects decrease with an increasing concentration of Pr3+ ions, while the relative TL intensity ratio of the high temperature band to the low temperature one increases with an increasing concentration of Pr3+ ions, which results in the afterglow suppression of BaGd2 O4 :Eu3+ scintillating phosphors.


Subject(s)
Barium/chemistry , Europium/chemistry , Gadolinium/chemistry , Luminescent Agents/chemistry , Oxides/chemistry , Praseodymium/chemistry , Luminescence , Luminescent Measurements
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