ABSTRACT
Nitrogen is an essential nutrient and a major limiting element for the ocean ecosystem. Since the preindustrial era, substantial amounts of nitrogen from terrestrial sources have entered the ocean via rivers, groundwater, and atmospheric deposition. China serves as a key hub in the global nitrogen cycle, but the pathways, sources, and potential mitigation strategies for land-ocean nitrogen transport are unclear. By combining the CHANS, WRF-Chem, and WNF models, we estimated that 8 million tonnes (Tg) of nitrogen was transferred into the ocean in 2017 in China, with atmospheric deposition contributing 1/3. About half variation of the offshore chlorophyll concentration was explained by atmospheric deposition. The Bohai Sea was the hot spot of nitrogen input, estimated at 214 kg N ha-1, while other areas were around 25-51 kg N ha-1. The largest contributors are agricultural systems (4 Tg, 55%), followed by domestic sewage (2 Tg, 21%). Abatement measures could reduce nitrogen export to the ocean by 43%, and mitigating ammonia and nitrogen oxide emissions accounts for 33% of this reduction, highlighting the importance of addressing air pollution in resolving ocean pollution. The cost-benefit analysis suggests the priority of nitrogen reduction in cropland and transport systems for the ocean environment.
Subject(s)
Air Pollution , Ecosystem , Nitrogen/analysis , Environment , Environmental Pollution/analysis , Air Pollution/analysis , China , Environmental MonitoringABSTRACT
The synergistic enhancement of pollution reduction and carbon mitigation (PRCM) is an inevitable requirement for China's ecological civilization construction. Existing studies primarily focus on macro-level research, and there is a relative lack of research specifically addressing the micro-level of industrial chains. Based on non-competitive IO tables, this study employed the structural path decomposition analysis method to analyze the synergistic disparities of the PRCM industry chain and its driving factors. The findings reveal: (1) The crucial emission industrial chains for CO2, SO2, and PM show a high overlap degree, accounting for 46.67 %, 46.67 %, 60.00 %, 50.00 %, and 56.67 % during 2002-2020. The PRCM industrial chains are operating at a low synergistic level, with proportions of only 13.33 %, 23.33 %, 20.00 %, and 16.67 %. PRCM exhibits a "similar origin with different paths" phenomenon. (2) China's carbon mitigation policies can reduce pollution, whereas pollution reduction policies have limited carbon mitigation effects. (3) The emission control effect is the primary disparate factor in PRCM synergy, while other factors exhibit consistent impact direction to three emissions. The study's conclusions and corresponding policy suggestions hold significant theoretical and practical implications for relevant authorities to systematically plan synergistic emission reduction pathways and establish targeted synergistic policies.
Subject(s)
Carbon , Environmental Pollution , Carbon/analysis , Environmental Pollution/analysis , Industry , Carbon Dioxide/analysis , China , Economic DevelopmentABSTRACT
Airborne Microplastics (MPs), an emerging environmental issue, have gained recent attention due to their newfound presence in indoor environments. Utilizing the Web of Science database for literature collection, the paper presents a comprehensive review of airborne MPs including emission sources, assessment methods, exposure risks, and mitigation strategies. This review delves into the diverse sources and mechanisms influencing indoor airborne MP pollution, underscoring the complex interplay between human activities, ventilation systems, and the characteristics of indoor environments. Major sources include the abrasion of synthetic textiles and the deterioration of flooring materials, with factors like carpeting, airflow, and ventilation significantly impacting MP levels. Human activities, such as increased movement in indoor spaces and the intensive use of plastic-based personal protective equipment (PPE) post-pandemic, notably elevate indoor MP concentrations. The potential health impacts of airborne MPs are increasingly concerning, with evidence suggesting their role in respiratory, immune, and nervous system diseases. Despite this, there is a scarcity of information on MPs in diverse indoor environments and the inhalation risks associated with the frequent use of PPE. This review also stresses the importance of developing effective strategies to reduce MP emissions, such as employing HEPA-filtered vacuums, minimizing the use of synthetic textiles, and enhancing indoor ventilation. Several future research directions were proposed, including detailed temporal analyses of indoor MP levels, interactions of MP with other atmospheric pollutants, the transport dynamics of inhalable MPs (≤10 µm), and comprehensive human exposure risk assessments.
Subject(s)
Air Pollution, Indoor , Water Pollutants, Chemical , Humans , Microplastics , Plastics/analysis , Environmental Monitoring/methods , Air Pollution, Indoor/analysis , Environmental Pollution/analysis , Water Pollutants, Chemical/analysisABSTRACT
Microplastics (MPs) pollution is an emerging environmental health concern, impacting soil, plants, animals, and humans through their entry into the food chain via bioaccumulation. Human activities such as improper solid waste dumping are significant sources that ultimately transport MPs into the water bodies of the coastal areas. Moreover, there is a complex interplay between the coastal climate dynamics, environmental factors, the burgeoning issue of MPs pollution and the complex web of coastal pollution. We embark on a comprehensive journey, synthesizing the latest research across multiple disciplines to provide a holistic understanding of how these inter-connected factors shape and reshape the coastal ecosystems. The comprehensive review also explores the impact of the current climatic patterns on coastal regions, the intricate pathways through which MPs can infiltrate marine environments, and the cascading effects of coastal pollution on ecosystems and human societies in terms of health and socio-economic impacts in coastal regions. The novelty of this review concludes the changes in climate patterns have crucial effects on coastal regions, proceeding MPs as more prevalent, deteriorating coastal ecosystems, and hastening the transfer of MPs. The continuous rising sea levels, ocean acidification, and strong storms result in habitat loss, decline in biodiversity, and economic repercussion. Feedback mechanisms intensify pollution effects, underlying the urgent demand for environmental conservation contribution. In addition, the complex interaction between human, industry, and biodiversity demanding cutting edge strategies, innovative approaches such as remote sensing with artificial intelligence for monitoring, biobased remediation techniques, global cooperation in governance, policies to lessen the negative socioeconomic and environmental effects of coastal pollution.
Subject(s)
Climate Change , Ecosystem , Microplastics , Microplastics/analysis , Water Pollutants, Chemical/analysis , Environmental Monitoring , Humans , Environmental Pollution/analysis , ClimateABSTRACT
The contribution of smelting of nonferrous metals to heavy metals in surface soil have become increasingly important over the past decade. In this study, the distribution of heavy metals around an abandoned mercury-bearing waste recovery enterprise were investigated. Soil (14) and plant (18) samples were collected in the surrounding area. The total concentration of heavy metals and methyl mercury content were measured by ICP-MS and HPLC-ICP-MS. The results show that the average contents of Cd, Cr, Pb, Hg and As in all soil samples are higher than the second-level values of Soil environmental quality-Risk control standard for soil contamination of development land (GB 36600-2018). Hg in the leaves ranged from 0.003 to 0.174 mg kg-1. Besides, the Pearson correlation analysis results indicate that Hg has a different environmental behavior compared to the other heavy metal under certain environmental or geographical conditions. But the mantel test statistical analysis results show that the Cr (P < 0.01), Cu, Pb, and Fe (P < 0.05) in the soil may have similar pollution sources with carbonate-bound mercury and iron-manganese oxide-bound mercury. The Hg concentrations show no correlation among plant leaves and soil, but significantly influenced by the distance and wind direction. These findings suggest that Hg in plant leaves may be derived from the deposition of atmospheric mercury from secondary mercury plant. The results will supplement those for relevant policy making for mercury-bearing waste recovery enterprises to improve urban environmental quality and human health.
Subject(s)
Environmental Monitoring , Mercury , Metals, Heavy , Soil Pollutants , Soil Pollutants/analysis , China , Metals, Heavy/analysis , Mercury/analysis , Soil/chemistry , Plants/chemistry , Environmental Pollution/analysisABSTRACT
China is a typical agricultural country that heavily relies on pesticides. Some pesticides can remain in the soil after application and thus pose a significant threat to human health. In order to characterize the status and hazards of nationwide soil contamination, this study extracted concentration data from published literature and analyzed them by a scoring approach, standard comparison and health risk assessment. For the soil pollution score, northern regions got the highest values, such as Henan (0.63), Liaoning (0.55), Heilongjiang (0.54) and Jilin (0.53), which implies high soil pesticide residues in these provinces. In contrast, Qinghai (-0.77), Guizhou (-0.64) and Tibet (-0.63) had lower scores. China's soil pesticide standards cover only 16 pesticides, and these pesticide concentrations were all below the corresponding standards. Direct exposure to soil pesticides in this study generally posed a negligible risk to children. Furthermore, pesticide dissipation and usage intensity in each province were analyzed as they were possible influences on pollution. The result showed that soil in the northern regions could accumulate more pesticides than those in the southern regions, and this geographic pattern was basically consistent with the distribution of soil pollution. However, the relationship between agricultural activities and soil pollution was less well characterized. It is recommended to establish a long-term monitoring database for pesticides and include more pesticides in regulatory frameworks. Additionally, efforts to accelerate pesticide degradation and shift the planting structure to reduce pesticide usage can help alleviate the pressure on soil from pesticides. This study can serve as a critical reference for policymakers and stakeholders in the field of agriculture.
Subject(s)
Pesticides , Soil Pollutants , China , Soil Pollutants/analysis , Pesticides/analysis , Risk Assessment , Humans , Environmental Monitoring , Agriculture , Environmental Pollution/analysisABSTRACT
The Earth's history is documented in human civilizations, soil layers, river movement, and quiet sediments throughout millennia. This investigation explores the significant legacy of environmental toxins in these key planet components. Understanding how ancient activity shaped the terrain is crucial as mankind faces environmental issues. This interdisciplinary study uses environmental science, archaeology, and geology to uncover Earth's mysteries. It illuminates the dynamic processes that have built our globe by studying pollutants and soil, water, and sediments. This research follows human actions, both intentional and unintentional, from ancient civilizations through contemporary industrialization and their far-reaching effects. Environmental destiny examines how contaminants affect ecosystems and human health. This study of past contamination helps solve modern problems including pollution cleanup, sustainable land management, and water conservation. This review studies reminds us that our previous activities still affect the ecosystem in a society facing rapid urbanisation and industrialization. It emphasises the importance of environmental stewardship and provides a framework for making educated choices to reduce toxins in soil, water, and sediments. Discovery of Earth's secrets is not only a historical curiosity; it's a necessary step towards a sustainable and peaceful cohabitation with our home planet.
Subject(s)
Geologic Sediments , Geologic Sediments/chemistry , Geologic Sediments/analysis , Soil Pollutants/analysis , Humans , Earth, Planet , Soil/chemistry , Environmental Monitoring/history , Environmental Monitoring/methods , Water Pollutants, Chemical/analysis , Environmental Pollution/history , Environmental Pollution/analysisABSTRACT
Exploring whether informal environmental regulations (INER) can achieve carbon reduction in the context of pollution reduction and carbon reduction, as well as how to achieve carbon reduction, can help solve the dual failures of the market and government in environmental protection. Based on the polycentric governance theory and considering the characteristics of social subject environmental participation, the Stackelberg game is used to demonstrate the impact mechanism of INER on CO2. In addition, using the panel data of China's 30 provinces from 2003 to 2018, this paper validates the effectiveness of INER by Pooled Ordinary Least Square (POLS) and threshold panel model. Then, the mediating effect model is used to test the mechanism of INER's effect on carbon reduction. The results show that corruption is not conducive to CO2 reduction. The reduction effect of INER on CO2 exhibits heterogeneity with changes in other non-greenhouse gas pollutants. While INER effectively reduces local corruption, its more substantial indirect impact on CO2 reduction is prominent when levels of other pollutants are lower. Comparative analysis reveals that there are still biased governance behaviors to cope with INER's pressure in some regions nowadays. The findings show that for countries facing the dual task of pollution control and carbon reduction, the key to leveraging the supervisory role of INER should be focused on mitigating information asymmetry caused by the characteristics of CO2. Therefore, in the process of environmental protection, the public environmental participation system should be improved, and the process of disclosing polluters' carbon information should be accelerated.
Subject(s)
Air Pollution , Carbon Dioxide , Environmental Policy , China , Carbon Dioxide/analysis , Environmental Policy/legislation & jurisprudence , Air Pollution/prevention & control , Air Pollution/legislation & jurisprudence , Air Pollution/analysis , Environmental Pollution/prevention & control , Environmental Pollution/legislation & jurisprudence , Environmental Pollution/analysis , Air Pollutants/analysisABSTRACT
Field rapid determination of soil accessible Cr(â ¥) is of great significance for on-site assessment and decision-making about the health risks of contaminated sites. When the thickness of solutions with various concentrations of Cr(â ¥) is constant, there would be a quantitative relationship between the chromogenic difference of Cr(â ¥) solutions and the concentration of Cr(â ¥). The chromogenic difference could be described by Red (R), Green (G), Blue (B) values. Based on the chromogenic reaction between 1,5-diphenylcarbazide and Cr(â ¥), this study first established the calibration curve between the chromogenic difference and the concentration of Cr(â ¥) in standard solution with or without 0.01â¯M CaCl2, using an RGB color sensor. This is the subsequent determination basis of the method for rapidly assessing accessible Cr(â ¥) in the field (M-RGB). Then, the concentration of accessible Cr(â ¥) of contaminated soil with "hand-shaking + standing" field extraction method was compared with "end-over-end shaking" laboratory extraction method. Finally, the accessible Cr(â ¥) of contaminated soil extractants was determined via M-RGB integrating the field extraction method. Results indicated there was a highly significant linear relationship between colorimetric difference value (∆E) and Cr(â ¥) concentration in the range of 0.1-3â¯mg/L (R2 > 0.99, P < 0.01), based on the Euclidean formula for calculating ∆E. The "hand-shaking + standing" field extraction method was effective in obtaining accessible Cr(â ¥) extractants with or without 0.01â¯M CaCl2, with the high extraction efficiency within 100±1%. The concentrations of accessible Cr(â ¥) in various polluted soils determined by M-RGB were consistent with that determined by the ultraviolet-visible spectrophotometry, with the relative error within ±5%, and the relative standard deviation ≤ 20%. The spiked recovery experiments showed that the recovery of M-RGB was between 95% and 105%, which means M-RGB could realize the trace analysis for accessible Cr(â ¥) in the field.
Subject(s)
Chromium , Soil , Calcium Chloride , Chromium/analysis , Environmental Pollution/analysisABSTRACT
Deposition of potentially toxic elements (PTEs) in soils due to different types of mining activities has been an increasingly important concern worldwide. Quantitative differences of soil PTEs contamination and related health risk among typical mines remain unclear. Herein, data from 110 coal mines and 168 metal mines across China were analyzed based on 265 published literatures to evaluate pollution characteristics, spatial distribution, and probabilistic health risks of soil PTEs. The results showed that PTE levels in soil from both mine types significantly exceeded background values. The geoaccumulation index (Igeo) revealed metal-mine soil pollution levels exceeded those of coal mines, with average Igeo values for Cd, Hg, As, Pb, Cu, and Zn being 3.02-15.60â¯times higher. Spearman correlation and redundancy analysis identified natural and anthropogenic factors affecting soil PTE contamination in both mine types. Mining activities posed a significant carcinogenic risk, with metal-mine soils showing a total carcinogenic risk an order of magnitude higher than in coal-mine soils. This study provides policymakers a quantitative foundation for developing differentiated strategies for sustainable remediation and risk-based management of PTEs in typical mining soils.
Subject(s)
Environmental Monitoring , Mining , Soil Pollutants , Soil Pollutants/analysis , Risk Assessment , China , Environmental Monitoring/methods , Humans , Coal Mining , Metals, Heavy/analysis , Metals/analysis , Soil/chemistry , Coal , Environmental Pollution/analysis , Environmental Pollution/statistics & numerical dataABSTRACT
Foreign direct investment benefits developing countries. However, concerns have arisen that the influx of FDI potentially exacerbates environmental pollution. While this debate continues, growing attention has recently emerged on the role of institutions in mitigating FDI's potential damages, although the empirical findings remain inconclusive. This paper examines how institutional quality shapes the relationship between FDI and CO2, both at the aggregate level and across different income groupings, using a reduced-form CO2 emissions model, panel data from 2000 to 2018 and the IVGMM techniques. Three key conclusions emerge. First, the findings show that FDI reduces CO2 emissions, but its magnitude depends on the measure used. Second, institutional quality is directly associated with higher emissions across income groups, suggesting current regulations inadequately ameliorate environmental pollution. Third, we find a positive interaction effect between CO2 emissions and institutional quality. We argue that, for FDI to consistently curb CO2 emissions, the quality of institutions must improve to better regulate foreign investors' activities, especially in low and high-income nations. Enhancing the quality of institutions will help translate FDI into improved environmental outcomes across income groups.
Subject(s)
Carbon Dioxide , Economic Development , Carbon Dioxide/analysis , Environmental Pollution/analysis , Internationality , InvestmentsABSTRACT
Despite the prevalence of discussions on the "resource curse", the impact of natural resources on environmental quality for better or for worse has not been clearly answered, this study aims to answer the question by introducing the role of Information and Communication Technologies (ICT). To that end, by using the Instrumental Variable Generalized Method of Moments (IV GMM) estimator and a sample of 102 developing and emerging economies from 2006 to 2016, this paper studies the impact of ICT on the relationship between natural resources and environmental quality. Specially, the Environmental Performance Index (EPI) captures the environmental quality. The results show that natural resources have a significant negative effect on EPI, specially, EPI decreases by one unit with a 1% increase in natural resource rents. ICT significantly mitigates this adverse effect, and marginal effects analysis further confirms its positive moderate effects. The results proved to be robust by Lewbel 2SLS and Driscoll-Kraay techniques or other robust tests. It is noteworthy that the adverse effect of natural resources on EPI is greater and the mitigating effect of ICT is more pronounced in low-income countries and lower-middle income countries. Overall, these results remind resource-based countries to vigorously develop ICT, and apply intelligent exploration, digital monitoring, or other digital technologies to realize the high-efficiency use of natural resources, reducing environmental pollution and ecological damage.
Subject(s)
Communication , Economic Development , Natural Resources , Environmental Pollution/analysis , Cost-Benefit Analysis , Carbon Dioxide/analysisABSTRACT
Organic contaminated sites have gained significant attention as a prominent contributor to shallow groundwater contamination. However, limited knowledge exists regarding the impact of hydrodynamic effects on microbially mediated contaminant degradation at such sites. In this study, we investigated the distribution characteristics and community structure of prokaryotic microorganisms at the selected site during both wet and dry seasons, with a particular focus on their environmental adaptations. The results revealed significant seasonal variations (P < 0.05) in the α-diversity of prokaryotes within groundwater. The dry season showed more exclusive OTUs than the wet season. The response of prokaryotic metabolism to organic pollution pressure in different seasons was explored by PICRUSt2, and enzymes associated with the degradation of organic pollutants were identified based on the predicted functions. The results showed that hormesis was considered as an adaptive response of microbial communities under pollution stress. In addition, structural equation models demonstrated that groundwater level fluctuations can, directly and indirectly, affect the abundance and diversity of prokaryotes through other factors such as oxidation reduction potential (ORP), dissolved oxygen (DO), and naphthalene (Nap). Overall, our findings imply that the taxonomic composition and functional properties of prokaryotes in groundwater in organic contaminated sites is influenced by the interaction between seasonal variations and characteristics of organic pollution. The results provide new insights into microbiological processes in groundwater systems in organic contaminated sites.
Subject(s)
Groundwater , Microbiota , Groundwater/chemistry , Environmental Pollution/analysisABSTRACT
The use of recycled aggregate (RA) in pervious concrete (PC) is a green approach that can effectively mitigate urban waterlogging, excessive RA, and runoff pollution, thereby enhancing the urban ecological environment. This article focuses on the long-term purification efficiency of runoff pollutants by PC at different porosities and RA dosages. Moreover, the purification mechanism of pollutants by recycled aggregate pervious concrete (RAPC) was revealed utilizing particle size analysis, microstructure, and elemental analysis. Finally, the recovery effects of different maintenance approaches on the purification capacity of RAPC were explored. The results indicate that an increase in the RA dosage reduced the effective porosity of PC, thereby decreasing the permeability of RAPC. In addition, PC with a lower porosity demonstrated a slightly greater purification effectiveness for pollutants. However, the utilization of RA significantly enhanced the purification capacity of PC for various pollutants, primarily by leveraging advantages in terms of pore structure, micromorphology, and surface chemical composition. Additionally, RAPC exhibited nearly 100 % retention effectiveness for particles larger than 68.95 µm but relatively lower purification efficiency for particles ranging from 1.541 to 17.11 µm. In particular, it displayed the poorest purification performance for particles with a diameter of 6.396 µm. The surface of RAPC's pore channels exhibited a loose state with high porosity and appeared rough and uneven with numerous pits and grooves. RAPC had a larger surface area and contained more components, such as SiO2, CaCO3, and Al2O3, than regular PC. Therefore, RAPC possessed a higher purification capacity. High-pressure flushing (HPF) and sodium citrate flushing (SCF) under different maintenance frequencies significantly contributed to the recovery of the purification efficiency of RAPC. However, overall, a lower maintenance frequency led to a less favorable recovery effect. Furthermore, SCF had a better recovery effect than HPF.
Subject(s)
Environmental Pollutants , Water Pollutants, Chemical , Environmental Pollutants/analysis , Silicon Dioxide , Water Pollutants, Chemical/analysis , Environmental Pollution/analysis , Water MovementsABSTRACT
The increased use of antibiotics by humans for various purposes has left the environment polluted. Antibiotic pollution remediation is challenging because antibiotics exist in trace amounts and only highly sensitive detection techniques could be used to quantify them. Nevertheless, their trace quantity is not a hindrance to their transfer along the food chain, causing sensitization and the development of antibiotic resistance. Despite an increase in the literature on antibiotic pollution and the development and transfer of antibiotic-resistant genes (ARGs), little attention has been given to the behavior of antibiotics at the soil-solution interface and how this affects antibiotic adsorption-desorption interactions and subsequent uptake and transformation by plants. Thus, this review critically examines the interactions and possible degradation mechanisms of antibiotics in soil and the link between antibiotic soil-solution chemistry and uptake by plants. Also, different factors influencing antibiotic mobility in soil and the transfer of ARGs from one organism to another were considered. The mechanistic and critical analyses revealed that: (a) the charge characteristics of antibiotics at the soil-root interface determine whether they are adsorbed to soil or taken up by plants; (b) antibiotics that avoid soil colloids and reach soil pore water can be absorbed by plant roots, but their translocation to the stem and leaves depends on the ionic state of the molecule; (c) few studies have explored how plants adapt to antibiotic pollution and the transformation of antibiotics in plants; and (d) the persistence of antibiotics in cropland soils can be influenced by the content of soil organic matter, coexisting ions, and fertilization practices. Future research should focus on the soil/solution-antibiotic-plant interactions to reveal detailed mechanisms of antibiotic transformation by plants and whether plant-transformed antibiotics could be of environmental risk.
Subject(s)
Anti-Bacterial Agents , Soil Pollutants , Humans , Anti-Bacterial Agents/metabolism , Soil , Soil Pollutants/chemistry , Plants/metabolism , Environmental Pollution/analysisABSTRACT
This paper examines the impact of air pollution control policies targeting key polluting enterprises, highlighting a strategic shift towards precision pollution control that concentrates on high-emission, high-risk businesses. The paper explores the efficacy of these policies and their potential spatial spillover effects, utilizing panel data from 259 Chinese cities from 2013 to 2021. Employing the difference-in-differences (DID) model and spatial Durbin model, the study analyzes both the direct local effects and the broader spatial consequences of these regulatory measures on air quality. The findings indicate a significant reduction in air pollutant concentrations in urban areas, attributing this improvement to factors such as industrial restructuring, increased investment in science and technology, and economic growth. Spatial econometric analysis further reveals a substantial positive correlation in air quality among Chinese cities. However, estimates of the spillover effect indicate that while such policies successfully reduce pollution locally, they could unintentionally degrade air quality in adjacent areas. The study highlights the need for nuanced policy strategies to mitigate unintended spatial spillovers and enhance overall effectiveness. It recommends tailored policies that integrate environmental and socioeconomic objectives, national and regional coordination for consistent enforcement, technology-driven compliance strategies, and incentives for sustainable enterprise practices.
Subject(s)
Air Pollutants , Air Pollution , Environmental Pollution/prevention & control , Environmental Pollution/analysis , Air Pollution/prevention & control , Air Pollution/analysis , Air Pollutants/analysis , Cities , Policy , Economic Development , ChinaABSTRACT
The impact of fluorine on plants remains poorly understood. We examined duckweed growth in extracts of soil contaminated with fluorine leached from chicken manure. Additionally, fluorine levels were analyzed in fresh manure, outdoor-stored manure, and soil samples at varying distances from the manure pile. Fresh manure contained 37-48 mg F- × kg-1, while soil extracts contained 2.1 to 4.9 mg F- × kg-1. We evaluated the physiological effects of fluorine on duckweed cultured on soil extracts or in 50% Murashige-Skoog (MS) medium supplemented with fluorine concentrations matching those in soil samples (2.1 to 4.9 mg F- × L-1), as well as at 0, 4, and 210 mg × L-1. Duckweed exposed to fluorine displayed similar toxicity symptoms whether in soil extracts or supplemented medium. Fluoride at concentrations of 2.1 to 4.9 mg F- × L-1 reduced the intact chlorophyll content, binding the porphyrin ring at position 32 without affecting Mg2+. This reaction resulted in chlorophyll a absorption peak shifted towards shorter wavelengths and formation of a new band of the F--chlorophyll a complex at λ = 421 nm. Moreover, plants exposed to low concentrations of fluorine exhibited increased activities of aminolevulinic acid dehydratase and chlorophyllase, whereas the activities of both enzymes sharply declined when the fluoride concentration exceeded 4.9 mg × L-1. Consequently, fluorine damages chlorophyll a, disrupts the activity of chlorophyll-metabolizing enzymes, and diminishes the plant growth rate, even when the effects of these disruptions are too subtle to be discerned by the naked human eye.
Subject(s)
Araceae , Chlorophyll , Fluorides , Araceae/metabolism , Araceae/drug effects , Araceae/growth & development , Chlorophyll/metabolism , Fluorides/analysis , Soil Pollutants/analysis , Soil Pollutants/toxicity , Soil/chemistry , Manure/analysis , Environmental Pollution/analysisABSTRACT
The dam failure of the Córrego do Feijão Mine (CFM) located in Minas Gerais State, Brazil, killed at least 278 people. In addition, large extensions of aquatic and terrestrial ecosystems were destroyed, directly compromising the environmental and socioeconomic quality of the region. This study assessed the pollution and human health risks of soils impacted by the tailing spill of the CFM dam, along a sample perimeter of approximately 200 km. Based on potential ecological risk and pollution load indices, the enrichments of Cd, As, Hg, Cu, Pb and Ni in soils indicated that the Brumadinho, Mário Campos, Betim and São Joaquim de Bicas municipalities were the most affected areas by the broken dam. Restorative and reparative actions must be urgently carried out in these areas. For all contaminated areas, the children's group indicated an exacerbated propensity to the development of carcinogenic and non-carcinogenic diseases, mainly through the ingestion pathway. Toxicological risk assessments, including acute, chronic and genotoxic effects, on people living and working in mining areas should be a priority for public management and mining companies to ensure effective environmental measures that do not harm human health and well-being over time.
Subject(s)
Metals, Heavy , Soil Pollutants , Child , Humans , Soil , Metals, Heavy/toxicity , Metals, Heavy/analysis , Ecosystem , Brazil , Environmental Monitoring , Environmental Pollution/analysis , Soil Pollutants/toxicity , Soil Pollutants/analysis , Risk AssessmentABSTRACT
Coal is an essential component in achieving the goal of fulfilling the energy demands of the world. Nevertheless, the extensive practice of coal mining has resulted in environmental contamination through the release of both organic and inorganic pollutants, including polycyclic aromatic compounds and potentially toxic elements, into various mediums, notably soil. The escalating coal-mining activities across Europe have amplified the concentration of specific elements in the soil. Therefore, a thorough and meticulous assessment of these environmental impacts is imperative to furnish policymakers, industries, and communities with valuable insights, facilitating the formulation and adoption of effective mitigation strategies. Considering the results of studies from 2018 to 2023, this review thoroughly evaluates the current state of soil pollution in the coal mining areas of Europe, focusing on polycyclic aromatic hydrocarbons and potentially toxic elements. By analyzing the acquired data, this study aims to evaluate the levels of contamination by these pollutants in soils. The findings reveal that low molecular weight polycyclic aromatic hydrocarbons dominate the polycyclic aromatic compounds present, while potentially toxic elements including Zn, Pb, Mn, and Cr emerge as major contributors to soil contamination in coal mining areas from Europe.
Subject(s)
Coal Mining , Environmental Monitoring , Polycyclic Aromatic Hydrocarbons , Soil Pollutants , Soil Pollutants/analysis , Europe , Polycyclic Aromatic Hydrocarbons/analysis , Environmental Pollution/analysis , Soil/chemistry , Metals, Heavy/analysisABSTRACT
The aim of this study was to investigate the status of trace metals (As, Cr, Cu, Ni, Pb, Fe, and Zn) and health and carcinogenic risk associated then in the Ebolowa Municipal Lake (EML) basin. To this end, 21 water samples were collected from the EML and its two tributaries, Mfoumou and Bengo'o, and analyzed by Quantofix method (nanocolors and visiocolor ECO) by using the MACHEREY-NAGEL photometer. The data were processed using multivariate statistics. The results showed that all the physicochemical parameters (pH, EC, and TDS), with the exception of TDS, comply with were within WHO limits. The distribution of trace metals at the three sites investigated was as follows: Zn (80-400 ± 1.58 µg/L) > Cu (50-150 ± 9.38 µg/L) > Fe (10-40 ± 0.71 µg/L) > Pb (1-20 ± 3.02 µg/L) > As (1-9 ± 0.44 µg/L) > Ni (1-9 ± 1.48 µg/L). However, the highest values were observed in the EML and the Mfoumou River, where Pb pollution was noted. Statistical analysis showed that anthropogenic inputs increase the presence of Cr, Cu, Pb, and Zn. Trace Metal Pollution Index values were below 15 at all sites, illustrating low levels of pollution. The trace metal evaluation index values for the Bengo'o stream are pure (mean = 0.6), slightly affected in the Mfoumou stream (mean = 2.0), and moderately affected in the EML (mean = 2.2). The toxicity load index values illustrate that the waters studied are toxic. The non-carcinogenic (HI) and carcinogenic (CR) health risk index values suggest a risk linked to oral ingestion in the LME and Mfoumou watercourses. The latter appears to be the main source of allochthonous pollutant input to the EML.