RESUMEN
Promising composite coatings based on hematite (α-Fe2O3) mesocrystals of size 110 nm and chitosan (CHT) molecules for different biotechnological applications have been successfully obtained by electrophoretic deposition (EPD). Homogeneous and reproducible coatings have been obtained by studying and controlling the chemical interactions between both phases (α-Fe2O3 and CHT). A voltage of 25 V and a deposition time of 5 min were chosen as best deposition conditions, which resulted in highly homogeneous coatings with well-distributed α-Fe2O3 particles. According to TGA measurements, the content of α-Fe2O3 and chitosan in the final composite coating were found to be 74 and 26 wt%, respectively. The presence of both phases in the composite coating was determined by XRD analysis and the coatings microstructure was observed by SEM.
Asunto(s)
Quitosano/química , Materiales Biocompatibles Revestidos/química , Compuestos Férricos/química , Nanocompuestos/química , ElectroforesisRESUMEN
Two organic/inorganic composite coatings based on alginate, as organic matrix, and zinc oxide nanoparticles (n-ZnO) with and without bioactive glass (BG), as inorganic components, intended for biomedical applications, were developed by electrophoretic deposition (EPD). Different n-ZnO (1-10 g/L) and BG (1-1.5 g/L) contents were studied for a fixed alginate concentration (2 g/L). The presence of n-ZnO was confirmed to impart antibacterial properties to the coatings against gram-negative bacteria Escherichia coli, while the BG induced the formation of hydroxyapatite on coating surfaces thereby imparting bioactivity, making the coating suitable for bone replacement applications. Coating composition was analyzed by thermogravimetric analysis (TG), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDS) analyses. Scanning electron microscopy (SEM) was employed to study both the surface and the cross section morphology of the coatings. Polarization curves of the coated substrates made in cell culture media at 37 °C confirmed the corrosion protection function of the novel organic/inorganic composite coatings.
Asunto(s)
Alginatos/química , Antibacterianos/química , Materiales Biocompatibles Revestidos/química , Vidrio/química , Óxido de Zinc/química , Antibacterianos/farmacología , Corrosión , Durapatita/química , Electroforesis/métodos , Escherichia coli/efectos de los fármacos , Ácido Glucurónico/química , Ácidos Hexurónicos/química , Microscopía Electrónica de Rastreo/métodos , Nanopartículas/química , Espectrometría por Rayos X/métodos , Espectroscopía Infrarroja por Transformada de Fourier/métodos , Difracción de Rayos X/métodosRESUMEN
Modern electrochemical devices require the morphological control of the active material. In this paper the synthesis of nickel hydroxide, as common active compound of such devices, is presented. The influence of ultrasound in the synthesis of nickel hydroxide from aqueous ammonia complexes is studied showing that ultrasound allows the fabrication of flower-like particles with sizes ranging in between 0.7 and 1.0µm in contrast with the 6-8µm particles obtained in the absence of ultrasound. The influence of gas flow, temperature of the process and surfactants in the ultrasonically prepared powders is discussed in term of shape, size and agglomeration of the particles. Adjusting the experimental condition, spherical or platelet-like particles are obtained with sizes ranging from 1.3µm to 200nm.