RESUMEN
Addressing the demand for integrating strength and durability reinforcement in shape memory polyurethane (SMPU) for diverse applications remains a significant challenge. Here a series of SMPUs with ultra-high strength, self-healing and recyclability, and excellent shape memory properties through introducing dynamic boron-urethane bonds are synthesized. The introducing of boric acid (BA) to polyurethane leading to the formation of dynamic covalent bonds (DCB) boron-urethane, that confer a robust cross-linking structure on the SMPUs led to the formation of ordered stable hydrogen-bonding network within the SMPUs. The flexible crosslinking with DCB represents a novel strategy for balancing the trade-off between strength and durability, with their strengths reaching up to 82.2 MPa while also addressing the issue of durability in prolonged usage through the provision of self-healing and recyclability. The self-healing and recyclability of SMPU are demonstrated through rapid dynamic exchange reaction of boron-urethane bonds, systematically investigated by dynamic mechanical analysis (DMA). This study sheds light on the essential role of such PU with self-healing and recyclability, contributing to the extension of the PU's service life. The findings of this work provide a general strategy for overcoming traditional trade-offs in preparing SMPUs with both high strength and good durability.
Asunto(s)
Boro , Poliuretanos , Poliuretanos/química , Poliuretanos/síntesis química , Boro/química , Uretano/química , Enlace de Hidrógeno , Estructura Molecular , Ácidos Bóricos/químicaAsunto(s)
Antígenos CD19/inmunología , Inmunoterapia Adoptiva/métodos , Linfoma de Células B/terapia , Células Madre Pluripotentes/citología , Animales , Subunidad alfa 2 del Factor de Unión al Sitio Principal/metabolismo , Células Madre Hematopoyéticas/citología , Células Madre Hematopoyéticas/metabolismo , Proteínas de Homeodominio/metabolismo , Linfoma de Células B/inmunología , Linfoma de Células B/metabolismo , Ratones , Ratones Endogámicos C57BLRESUMEN
The polymer-grafted magnetic composite particles have been synthesized and developed to harvest oil by use of their speical wettability. Different from gravity-driven oil-water separation, the prepared polymer brushes-grafted magnetic composite particles can act as solid-stabilizers that diffuse to the oil-water interfical region and effectively minimize the direct oil-water interfical area by volume exclusion, whereas the magnetic Fe3O4 core allows easy separation of Pickering emulsions from oil-water mixture under an external magnetic field. When the emulsions were heated from room temperature to 50 °C, the coil-to-globule transition of poly(N-isopropylacrylamide) (PNIPAM) acts as the driving force for the destabilization of the emulsion, thereby achieving the release of oil. The novel materials can be used in aspects of oil-water separation, inducing oil droplet transport and release of lipophilic substrates.