Hydrochemical, isotopic and microbiota characterization of telese mineral waters (Southern Italy).

The study deals with the analyses of springs and wells at the base of Montepugliano Hill that represents the SE edge of the wide carbonate Matese massif (Campania, southern Italy). At the base of the hill, from west to east and for almost one kilometre, cold springs HCO3-Ca type (Grassano springs, ~ 4.5 m3/s; TDS: about 0.45 g/L) pass to hypothermal, HCO3-Ca type, sulphurous and CO2-rich springs (~ 1 m3/s with TDS > 1 g/L). Some of the latter are widely used in Telese Spa and Centro Relax Spa. Chemical and isotopic analyses carried out for this study support the hypothesis that all these waters (mineral and non-mineral) have the same catchment area, which is located in the Matese massif. As regards the sulphurous springs, they receive both meteoric waters infiltration and uprising of deeper waters rich in endogenous CO2 and H2S gases through important faults systems. Far from these faults, the chemistry of groundwater is scarcely (or not at all) affected by these deep fluid enrichment processes. This scheme is very significant; in fact, when very important groundwater resources are present, it is possible to use both mineral waters in Spa and, in areas far from the faults, those not yet mineralized. Finally, at Montepugliano Hill, in the final stage of the flow path, groundwater is also affected by change in the microbiome: this could provide a basis for comparison between various mineral waters.

Changes in geochemical and isotopic contents in groundwater before seismic events in Ischia Island (Italy).

We analysed the hydrogeochemical and isotopic contents in groundwater for the period 2002-2020, in the Ischia Island, a volcanic island in Southern Italy, and compared them with seismic events that occurred in the same period. The study is based on a large hydrochemical database, which includes chemical (major and minor compounds, metals and trace elements) and isotopic analyses (δ18O and δ2H). For each of the 34 seismic events occurred in the studied period, we considered coordinates, date, time, depth and magnitude. To exclude the influence of meteorological variability on the hydrochemistry, we examined rainfall time series measured in four stations located in the island. Results show hydrogeochemical anomalies for some chemical elements observed months before the seismic events. Arsenic, electrical conductivity, chromium and vanadium have been identified as potentially affected by hydrogeochemical anomalies related to the earthquakes. The variations in stable isotopes (δ2H and δ18O) in groundwater also seem associated with the earthquakes. This study aims to contribute to the individuation of components in groundwater prone to register sudden changes related to seismic events and it highlights the need of a continuous and long-term hydrogeochemical monitoring in seismic areas. Indeed, the conclusions of this study must be further confirmed by a future continuous monitoring of major compounds, trace elements and isotopes in groundwater to evaluate the effective temporal coincidence/lag with the seismic events.