An Integrated Approach to Using Sheep Wool as a Fibrous Material for Enhancing Strength and Transport Properties of Concrete Composites.

An important goal to achieve sustainable development is to use raw materials that are easily recyclable and renewable, locally available, and eco-friendly. Sheep wool, composed of 60% animal protein fibers, 10% fat, 15% moisture, 10% sheep sweat, and 5% contaminants on average, is an easily recyclable, easily renewable, and environmentally friendly source of raw material. In this study, slump testing, compressive and flexural strengths, ultrasonic pulse velocity, sorptivity, and chloride penetration tests were investigated to assess the influence of wool fibers on the strength and transport properties of concrete composites. Ordinary Portland cement was used to make five concrete mixes incorporating conventional wool fibers (WFs) ranging from 0.5 to 2.5% and a length of 70 mm. The wool fibers were modified (MWFs) via a pre-treatment technique, resulting in five different concrete compositions with the same fiber content. The addition of WF and MWF to fresh concrete mixes resulted in a decrease in slump values. The compressive strength of concrete was reduced when wool fibers were added to the mix. The MWF mixes, however, achieved compressive strength values of more than 30 MPa after a 90-day curing period. Furthermore, by including both WF and MWF, the flexural strength was higher than that of plain concrete. In addition, adding fibers with volume fractions of up to 2% reduced the concrete composite's sorptivity rate and chloride penetration depths for both WF and MWF content mixes. Consequently, biomass waste like sheep wool could be recycled and returned to the field following the circular economy and waste valorization principles.

Effects of Sulfate and Sulfuric Acid on Efficiency of Geopolymers as Concrete Repair Materials.

Various geopolymer mortars (GPMs) as concrete repairing materials have become effective owing to their eco-friendly properties. Geopolymer binders designed from agricultural and industrial wastes display interesting and useful mechanical performance. Based on this fact, this research (experimental) focuses on the feasibility of achieving a new GPM with improved mechanical properties and enhanced durability performance against the aggressive sulfuric acid and sulfate attacks. This new ternary blend of GPMs can be achieved by combining waste ceramic tiles (WCT), fly ash (FA) and ground blast furnace slag (GBFS) with appropriate proportions. These GPMs were designed from a high volume of WCT, FA, and GBFS to repair the damaged concretes existing in the construction sectors. Flexural strength, slant shear bond strength, and compatibility of the obtained GPMs were compared with the base or normal concrete (NC) before and after exposure to the aggressive environments. Tests including flexural four-point loading and thermal expansion coefficient were performed. These GPMs were prepared using a low concentration of alkaline activator solution with increasing levels of GBFS and FA replaced by WCT. The results showed that substitution of GBFS and FA by WCT in the GPMs could enhance their bond strength, mechanical characteristics, and durability performance when exposed to aggressive environments. In addition, with the increase in WCT contents from 50 to 70%, the bond strength performance of the GPMs was considerably enhanced under sulfuric acid and sulfate attack. The achieved GPMs were shown to be highly compatible with the concrete substrate and excellent binders for various civil engineering construction applications. It is affirmed that the proposed GPMs can efficiently be used as high-performance materials to repair damaged concrete surfaces.

Enhanced Acoustic Properties of a Novel Prepacked Aggregates Concrete Reinforced with Waste Polypropylene Fibers.

This research aimed to investigate the performance of prepacked aggregates fiber-reinforced concrete (PAFRC) with adequate acoustic characteristics for various applications. PAFRC is a newly developed concrete made by arranging and packing aggregates and short fibers in predetermined formworks, then inserting a grout mixture into the voids amongst the aggregate particles using a pump or gravity mechanism. After a one-year curing period, the effects of utilizing waste polypropylene (PP) fibers on the strength and acoustic characteristics of PAFRC mixes were examined. Compressive and tensile strengths, ultrasonic pulse velocity (UPV), sound absorption, and transmission loss were investigated on plain concrete and PAFRC mixtures comprising 0-1% PP fibers. The results revealed that the use of PP fibers slightly decreased the compressive strength and UPV of PAFRC mixes. The inclusion of waste PP fibers also significantly increased the tensile strength and sound insulation coefficient of PAFRC mixes, especially at higher fiber dosages. In the medium-to-high frequency ranges, more than 60% acoustic absorption coefficient was observed, indicating that PAFRC specimens have good sound insulation properties.

Improving the Self-Healing of Cementitious Materials with a Hydrogel System.

Despite cement's superior performance and inexpensive cost compared to other industrial materials, crack development remains a persistent problem in concrete. Given the comparatively low tensile strength, when cracks emerge, a pathway is created for gas and water to enter the cementitious matrix, resulting in steel reinforcement corrosion which compromises the durability of concrete. Superabsorbent hydrogels have been developed as a novel material for enhancing the characteristics of cementitious materials in which they have been demonstrated to decrease autogenous shrinkage and encourage self-healing. This study will detail the design and application of polyelectrolyte hydrogel particles as internal curing agents in concrete and provide new findings on relevant hydrogel-ion interactions. When hydrogel particles are mixed into concrete, they generate their stored water to fuel the curing reaction that results in less cracking and shrinkage, thereby prolonging the service life of the concrete. The interaction of hydrogels with cementitious materials is addressed in this study; the effect of hydrogels on the characteristics and self-healing of cementitious materials was also studied. Incorporating hydrogel particles into cement decreased mixture shrinkage while increasing the production of particular inorganic phases within the vacuum region formerly supplied by the swollen particle. In addition, considering the control paste, cement pastes containing hydrogels exhibited less autogenous shrinkage. The influence of hydrogels on autogenous shrinkage was found to be chemically dependent; the hydrogel with a delayed desorption rate displayed significantly low shrinkage in cement paste.

The Numerical Analysis of Replenishment of Hydrogel Void Space Concrete Using Hydrogels Containing Nano-Silica Particles through ELM-ANFIS.

Currently, Nano-materials are gaining popularity in the building industry due to their high performance in terms of sustainability and smart functionality. In order to reduce cement production and CO2 emissions, nano-silica (NS) has been frequently utilized as a cement alternative and concrete addition. The influence of Nano-silica-containing hydrogels on the mechanical strength, electrical resistivity, and autogenous shrinkage of cement pastes was investigated. The goal of this study was to identify the main structure-property relationships of water-swollen polymer hydrogel particles used as internal curing agents in cementitious admixtures, as well as to report a unique synthesis process to combine pozzolanic materials with hydrogel particles and determine the replenishment of hydrogel void space. Experiments were designed to measure the absorption capacity and kinetics of hydrogel particles immersed in pure water and cementitious pore solution, as well as to precisely analyze the data derived from the tests using hybridized soft computing models such as Extreme learning machine (ELM) and Adaptive neuro-fuzzy inference system (ANFIS). The models were developed, and the findings were measured using regression indices (RMSE and R2). The findings indicated that combining nano-silica with polymeric hydrogel particles creates a favorable environment for the pozzolanic reaction to occur, and that nano-silica assists in the refilling of hydrogel void space with hydrated cement phases.