RESUMEN
A new procedure for the synthesis of MoS(2) nanotubes is reported, and additionally demonstrated for MoSe(2), WS(2), and WSe(2). Highly concentrated sunlight creates continuous high temperatures, strong temperature gradients, and extended hot annealing regions, which, together with a metallic (Pb) catalyst, are conducive to the formation of different inorganic nanotubes. Structural characterization (including atomic resolution images) reveals a three-step reaction mechanism. In the first step, MoS(2) platelets react with water-air residues, decompose by intense solar irradiation, and are converted to molybdenum oxide. Subsequently, the hot annealing environment leads to the growth of Pb-stabilized MoO(3-x) nanowhiskers. Shortly afterward, the surface of the MoO(3-x) starts to react with the sulfur vapor supplied by the decomposition of nearby MoS(2) platelets and becomes enveloped by MoS(2) layers. Finally, the molybdenum oxide core is gradually transformed into MoS(2) nanotubes. These findings augur well for similar syntheses of as yet unattained nanotubes from other metal chalcogenides.
RESUMEN
We report the synthesis and supporting density-functional-theory computations for a closed-cage, misfit layered-compound superstructure from PbS-SnS2, generated by highly concentrated sunlight from a precursor mixture of Pb, SnS2, and graphite. The unique reactor conditions created in our solar furnace are found to be particularly conducive to the formation of these nanomaterials. Detailed structural and chemical characterization revealed a spontaneous inside-out formation mechanism, with a broad range of nonhollow fullerene-like structures starting at a diameter of â¼20 nm and a wall thickness of â¼5 layers. The computations also reveal a counterintuitive charge transfer pathway from the SnS2 layers to the PbS layers, which indicates that, in contrast to binary-layered compounds where it is principally van der Waals forces that hold the layers together, polar forces appear to be as important in stabilizing superstructures of misfit layered compounds.