Does livestock-Manure-Derived Biochar Suitable for the Stabilization of Cadmium and Zinc in Contaminated Soil?

Both livestock-manure and livestock-manure-derived biochar have been used to remediate heavy metal-contaminated soil. However, direct comparisons of the heavy metal stabilization efficiency of livestock-manure and EQC-manure-biochar (derived from an equal quantity of corresponding livestock-manure) are limited. In the present study, the effect of livestock-manures and EQC-manure-biochars on soil properties and heavy metal bioavailability and leachability were compared using two contrasting soils (Ferralsols and Fluvisols). The results showed that both the livestock-manures and EQC-manure-biochars significantly changed soil pH, available phosphorus, available potassium, alkaline nitrogen and organic matter content (p < 0.05), but the trends were variable. In Ferralsols, the DTPA-extractable Cd and Zn decreased by -0.38%~5.70% and - 3.79%~9.98% with livestock-manure application and by -7.99%~7.23% and - 5.67%~7.17% with EQC-manure-biochars application. In Fluvisols, the DTPA-extractable Cd and Zn decreased by 13.39%~17.41% and - 45.26%~14.24% with livestock-manure application and by 10.76%~16.90% and - 36.38%~16.37% with EQC-manure-biochar application. Furthermore, the change in TCLP-extractable Cd and Zn in both soils was similar to that of DTPA-extractable Cd and Zn. Notably, the Cd and Zn stabilization efficiency of the EQC-manure-biochars was no better than that of the corresponding livestock-manures. These results suggest that the use of livestock-manure-derived biochar is not cost-effective for the remediation of heavy metal-contaminated soil.

Soil pH restricts the ability of biochar to passivate cadmium: A meta-analysis.

Soil acidification is the main cause for aggravation of soil cadmium (Cd) pollution. Biochar treatment can increase the soil pH and decrease the Cd availability in soils. However, there is limited information in literature on the comprehensive assessment of the response of Cd fractions to biochar. Therefore, in the present meta-analysis study, we evaluate the response of Cd fractions to biochar application in soils with different pH and to further examine the effect of physicochemical properties of biochar on Cd. Results from the overall analysis indicated that biochar treatment increased the soil pH by 7.0%, thereby decreasing the amount of available Cd (37.3%). In acidic soil, biochar significantly reduced the acid-soluble fraction (Acid-Cd) of Cd by 36.8%, while Oxidizable fraction of Cd (Oxid-Cd, 20.9%) and Residual fraction of Cd (Resid-Cd, 22.2%) were significantly increased. In neutral soils, only Acid-Cd was significantly reduced (33.0%) in the presence of biochar. In alkaline soils, biochar caused significant reduction in Acid-Cd of 12.4% and an increase in Oxid-Cd and Resid-Cd of 26.6% and 47.8%, respectively. Further, our findings showed that biochar with cation exchange capacity >100 cmol+/kg effectively decreased Acid-Cd (32.4%), while biochar with the percentage of hydrogen <2% was more contributory in increasing Resid-Cd (64.3%). These results demonstrate the importance of soil pH in regulating the biological effectiveness of Cd in soil and the complexation between the functional groups of biochar and Cd, and provide key information for the remediation of Cd pollution in soils with different pH by biochar.

Enhanced removal of arsenic and cadmium from contaminated soils using a soluble humic substance coupled with chemical reductant.

Soil washing is an efficient, economical, and green remediation technology for removing several heavy metal (loid)s from contaminated industrial sites. The extraction of green and efficient washing agents from low-cost feedback is crucially important. In this study, a soluble humic substance (HS) extracted from leonardite was first tested to wash soils (red soil, fluvo-aquic soil, and black soil) heavily contaminated with arsenic (As) and cadmium (Cd). A D-optimal mixture design was investigated to optimize the washing parameters. The optimum removal efficiencies of As and Cd by single HS washing were found to be 52.58%-60.20% and 58.52%-86.69%, respectively. Furthermore, a two-step sequential washing with chemical reductant NH2OH•HCl coupled with HS (NH2OH•HCl + HS) was performed to improve the removal efficiency of As and Cd. The two-step sequential washing significantly enhanced the removal of As and Cd to 75.25%-81.53% and 64.53%-97.64%, which makes the residual As and Cd in soil below the risk control standards for construction land. The two-step sequential washing also effectively controlled the mobility and bioavailability of residual As and Cd. However, the activities of soil catalase and urease significantly decreased after the NH2OH•HCl + HS washing. Follow-up measures such as soil neutralization could be applied to relieve and restore the soil enzyme activity. In general, the two-step sequential soil washing with NH2OH•HCl + HS is a fast and efficient method for simultaneously removing high content of As and Cd from contaminated soils.

Endophytic bacteria promote biomass production and mercury-bioaccumulation of Bermuda grass and Indian goosegrass.

Plant growth-promoting endophytic bacteria can potentially improve the biomass production of Hg-accumulating grasses, resulting in improved Hg extraction from contaminated soils. This study aimed to analyze the effect of inoculation of Hg-resistant endophytic bacteria (i) Jeotgalicoccus huakuii (B1) and (ii) Bacillus amyloliquefaciens (B2), as single and consortium inoculant, on biomass production and Hg bioaccumulation of Bermuda grass (R1) and Indian goosegrass (R2) planted as monoculture and mixed cropping. The grass seeds were surface-sterilized before the inoculation. Both inoculated seeds with B1 and B2 (treatments) and uninoculated seeds were sown separately in sterilized sand. Grass seedlings of both treatments and control were replanted in the washed and sterilized sand medium, spiked with HgCl2 (100 mg kg-1). A subset of grass was harvested at 0, 4, 6, and 10 weeks after planting to measure biomass production and Hg bioaccumulation. The results showed that bacterial inoculation enhanced the grass biomass by 52.68% and Hg bioaccumulation by 47.76%. Mercury residue of Hg-spiked sand treated with the bacterial consortium was reduced by 80%. This suggests that endophytic bacteria can improve grass biomass production and enhance Hg bioaccumulation in grass biomass.

Biochar as a potential strategy for remediation of contaminated mining soils: Mechanisms, applications, and future perspectives.

Soil heavy metal contamination caused by mining activities is a global issue. These heavy metals can be enriched in plants and animals through the food chain, and eventually transferred to the human system and threatening public health. Biochar, as an environmentally friendly soil remediation agent, can effectively immobilize heavy metals in soil. However, most researchers concern more about the remediation effect and mechanism of biochar for industrial and agricultural contaminated soil, while related reviews focusing on mining soil remediation are limited. Furthermore, the remediation effect of soil in mining areas is affected by many factors, such as physicochemical properties of biochar, pyrolysis conditions, soil conditions, mining environment and application method, which can lead to great differences in the remediation effect of biochar in diverse mining areas. Therefore, it is necessary to systematically unravel the relevant knowledge of biochar remediation, which can also provide a guide for future studies on biochar remediation of contaminated soils in mining areas. The present paper first reviews the negative effects of mining activities on soil and the advantages of biochar relative to other remediation methods, followed by the mechanism and influencing factors of biochar on reducing heavy metal migration and bioavailability in mining soil were systematically summarized. Finally, the main research directions and development trends in the future are pointed out, and suggestions for future development are proposed.

Characteristics and applications of biochar for remediating Cr(VI)-contaminated soils and wastewater.

Chromium (Cr) is a common environmental contaminant due to industrial processes and anthropogenic activities such as mining of chrome ore, electroplating, timber treatment, leather tanning, fertilizer and pesticide, etc. Cr exists mainly in both hexavalent [Cr(VI)] and trivalent [Cr(III)] form, being Cr(VI) with non-degradability and potential to be hidden, thereby affecting surrounding environment and being toxic to human health. Therefore, researches on remediation of Cr pollution in the environment have received much attention. Biochar is a low-cost adsorbent, which has been identified as a suitable material for Cr(VI) immobilization and removal from soil and wastewater. This review incorporates existing literature to provide a detailed examination into the (1) Cr chemistry, the source and current status of Cr pollution, and Cr toxicity and health; (2) feedstock and characterization of biochar; (3) processes and mechanisms of immobilization and removal of Cr by biochar, including oxidation-reduction, electrostatic interactions, complexation, ion exchange, and precipitation; (4) applications of biochar for Cr(VI) remediation and the modification of biochar to improve its performance; (5) factors affecting removal efficiency of Cr(VI) with respect to its physico-chemical conditions, including pH, temperature, initial concentration, reaction time, biochar characteristics, and coexisting contaminants. Finally, we identify current issues, challenges, and put forward recommendations as well as proposed directions for future research. This review provides a thorough understanding of using biochar as an emerging biomaterial adsorbent in Cr(VI)-contaminated soils and wastewater.

Impact of coconut-fiber biochar on lead translocation, accumulation, and detoxification mechanisms in a soil-rice system under elevated lead stress.

Biochar, an environmentally friendly material, was found to passivate lead (Pb) in contaminated soil effectively. This study utilized spectroscopic investigations and partial least squares path modeling (PLS-PM) analysis to examine the impact of coconut-fiber biochar (CFB) on the translocation, accumulation, and detoxification mechanisms of Pb in soil-rice systems. The results demonstrated a significant decrease (p < 0.05) in bioavailable Pb concentration in paddy soils with CFB amendment, as well as reduced Pb concentrations in rice roots, shoots, and brown rice. Synchrotron-based micro X-ray fluorescence analyses revealed that CFB application inhibited the migration of Pb to the rhizospheric soil region, leading to reduced Pb uptake by rice roots. Additionally, the CFB treatment decreased Pb concentrations in the cellular protoplasm of both roots and shoots, and enhanced the activity of antioxidant enzymes in rice plants, improving their Pb stress tolerance. PLS-PM analyses quantified the effects of CFB on the accumulation and detoxification pathways of Pb in the soil-rice system. Understanding how biochar influences the immobilization and detoxification of Pb in soil-rice systems could provide valuable insights for strategically using biochar to address hazardous elements in complex agricultural settings.

Effect of biochar-derived DOM on contrasting redistribution of chromate during Schwertmannite dissolution and recrystallization.

Biochar-derived dissolved organic matter (BDOM), is extensively involved in the recrystallization of minerals and the speciation alteration of associated toxic metals. This study investigates how BDOM extracted from tobacco petiole (TP) or tobacco stalk (TS) biochar influences the speciation repartitioning of Cr(VI) in environments impacted by acid mine drainage (AMD), focusing on interactions with secondary minerals during Schwertmannite (Sch) dissolution and recrystallization. TP-BDOM, rich in lignin-like substances, slowed down the Cr-Sch dissolution and Cr release under acidic conditions compared to TS-BDOM. TP-BDOM's higher O/C component exerts a delayed impact on Cr-Sch stability and Cr(VI) reduction. In-situ ATR-FTIR and 2D-COS analysis showed that carboxylic and aromatic N-OH groups in BDOM could interact with Cr-Sch surfaces, affecting sulfate and Cr(VI) release. It was also observed that slight recrystallization occurred from Cr-Sch to goethite, along with increased Cr incorporation into secondary minerals within TS-BDOM. This enhances our understanding of BDOM's role in Cr(VI) speciation changes in AMD-contaminated sites.

Pristine and Fe-functionalized biochar for the simultaneous immobilization of arsenic and antimony in a contaminated mining soil.

This study examined the effectiveness of pristine biochar (BC) and Fe-functionalized biochar (FBC) in remediating As-Sb co-contaminated soil, and revealed the resulting impact on soil enzymatic activities and bacterial communities. Results from incubation experiments showed that the 1.5% FBC treatment reduced the bioavailable As and Sb concentration by 13.5% and 27.1%, respectively, in compared to the control, and reduced the proportion of specifically adsorbed and amorphous Fe-Mn oxide-bound metal(loid) fractions in the treated soil. Among the BC treatments, only the 1.5% BC treatment resulted in a reduction of bioavailable As by 11.7% and Sb by 21.4%. The 0.5% BC treatment showed no significant difference. The FBC achieved high As/Sb immobilization efficiency through Fe-induced electrostatic attraction, π-π electron donor-acceptor coordination, and complexation (Fe-O(H)-As/Sb) mechanisms. Additionally, the 1.5% FBC treatment led to a 108.2% and 367.4% increase in the activities of N-acetyl-ß-glucosaminidase and urease in soils, respectively, compared to the control. Furthermore, it significantly increased the abundance of Proteobacteria (15.2%), Actinobacteriota (37.0%), Chloroflexi (21.4%), and Gemmatimonadota (43.6%) at the phylum level. Co-occurrence network analysis showed that FBC was better than BC in increasing the complexity of bacterial communities. Partial least squares path modeling further indicated that the addition of biochar treatments can affect soil enzyme activities by altering soil bacterial composition. This study suggests that FBC application offers advantages in simultaneous As and Sb immobilization and restructuring the bacterial community composition in metal(loid)-contaminated soil.

Iron-modified biochar effectively mitigates arsenic-cadmium pollution in paddy fields: A meta-analysis.

The escalating problem of compound arsenic (As) and cadmium (Cd) contamination in agricultural soils necessitates the urgency for effective remediation strategies. This is compounded by the opposing geochemical behaviors of As and Cd in soil, and the efficacy of biochar treatment remains unclear. This pioneering study integrated 3780 observation pairs referred from 92 peer-reviewed articles to investigate the impact of iron-modified biochar on As and Cd responses across diverse soil environments. Regarding the treatments, 1) biochar significantly decreased the exchangeable and acid-soluble fraction of As (AsF1, 20.9%) and Cd (CdF1, 24.0%) in paddy fields; 2) iron-modified biochar significantly decreased AsF1 (32.0%) and CdF1 (27.4%); 3) iron-modified biochar in paddy fields contributed to the morphological changes in As and Cd, mainly characterized by a decrease in AsF1 (36.5%) and CdF1 (36.3%) and an increase in the reducible fraction of As (19.7%) and Cd (39.2%); and 4) iron-modified biochar in paddy fields increased As (43.1%) and Cd (53.7%) concentrations in the iron plaque on root surfaces. We conclude that iron-modified biochar treatment of paddy fields is promising in remediating As and Cd contamination by promoting the formation of iron plaque.

Effects of biochar in combination with varied N inputs on grain yield, N uptake, NH3 volatilization, and N2O emission in paddy soil.

Biochar application can improve crop yield, reduce ammonia (NH3) volatilization and nitrous oxide (N2O) emission from farmland. We here conducted a pot experiment to compare the effects of biochar application on rice yield, nitrogen (N) uptake, NH3 and N2O losses in paddy soil with low, medium, and high N inputs at 160 kg/ha, 200 kg/ha and 240 kg/ha, respectively. The results showed that: (1) Biochar significantly increased the rice grain yield at medium (200 kg/ha) and high (240 kg/ha) N inputs by 56.4 and 70.5%, respectively. The way to increase yield was to increase the rice N uptake, rice panicle number per pot and 1,000 grain weight by 78.5-96.5%, 6-16% and 4.4-6.1%, respectively; (2) Under low (160 kg/ha) N input, adding biochar effectively reduced the NH3 volatilization by 31.6% in rice season. The decreases of pH value and NH4+-N content in surface water, and the increases of the abundance of NH4+-N oxidizing archaea and bacteria (AOA and AOB) communities contributed to the reduction of NH3 volatilization following the biochar application; (3) Under same N input levels, the total N2O emission in rice season decreased by 43.3-73.9% after biochar addition. The decreases of nirK and nirS gene abundances but the increases of nosZ gene abundance are the main mechanisms for biochar application to reduce N2O emissions. Based on the results of the current study, adding biochar at medium (200 kg/ha) N level (N200 + BC) is the best treatment to synchronically reduce NH3 and N2O losses, improve grain yield, and reduce fertilizer application in rice production system.

Crawfish shell- and Chinese banyan branch-derived biochars reduced phytoavailability of As and Pb and altered community composition of bacteria in a contaminated arable soil.

Globally, soil contamination with arsenic (As) and lead (Pb) has become a severe environmental issue. Herein, a pot experiment was conducted using pak choi (Brassica chinensis L.) to investigate the effects of biochars derived from crawfish (Procambarus clarkia) shells (CSB) and Chinese banyan (Ficus microcarpa) branches (CBB) on the phytoavailability of As and Pb, and bacterial community composition in soils. Our results showed that the application of CSB and CBB decreased the concentrations of DTPA-extractable Pb in soils ranging from 26.8 % to 28.8 %, whereas CSB increased the concentration of NH4H2PO4-extractable As in soils, compared to the control. Application of both biochars reduced the uptake of As and Pb in the edible part of pak choi. In addition, application of CBB significantly (P < 0.05) increased the activities of α-glucosidase, ß-glucosidase, cellobiohydrolase, and acid phosphomonoesterase by 55.0 %, 54.4 %, 195.1 %, and 76.7 %, respectively, compared to the control. High-throughput sequencing analysis revealed that the predominant bacteria at the phyla level in both biochar-treated soils were Firmicutes, Proteobacteria, and Actinobacteriota. Redundancy and correlation analyses showed that the changes in bacterial community composition could be related to soil organic carbon content, As availability, and nutrient availability in soils. Overall, the Chinese banyan branch biochar was more suitable than the crawfish shell biochar as a potential amendment for the remediation of soils co-contaminated with As and Pb.

Copper induces nitrification by ammonia-oxidizing bacteria and archaea in pastoral soils.

Copper (Cu) is the main co-factor in the functioning of the ammonia monooxygenase (AMO) enzyme, which is responsible for the first step of ammonia oxidation. We report a greenhouse-based pot experiment that examines the response of ammonia-oxidizing bacteria and archaea (AOB and AOA) to different bioavailable Cu concentrations in three pastoral soils (Recent, Pallic, and Pumice soils) planted with ryegrass (Lolium perenne L.). Five treatments were used: control (no urine and Cu), urine only at 300 mg N kg-1 soil (Cu0), urine + 1 mg Cu kg-1 soil (Cu1), urine + 10 mg Cu kg-1 soil (Cu10), and urine + 100 mg Cu kg-1 soil (Cu100). Pots were destructively sampled at Day 0, 1, 7, 15, and 25 after urine application. The AOB/AOA amoA gene abundance was analyzed by real-time quantitative polymerase chain reaction at Days 1 and 15. The AOB amoA gene abundance increased 10.0- and 22.6-fold in the Recent soil and 2.1- and 2.5-fold in the Pallic soil for the Cu10 compared with Cu0 on Days 1 and 15, respectively. In contrast, the Cu100 was associated with a reduction in AOB amoA gene abundance in the Recent and Pallic soils but not in the Pumice soil. This may be due to the influence of soil cation exchange capacity differences on the bioavailable Cu. Bioavailable Cu in the Recent and Pallic soils influenced nitrification and AOB amoA gene abundance, as evidenced by the strong positive correlation between bioavailable Cu, nitrification, and AOB amoA. However, bioavailable Cu did not influence the nitrification and AOA amoA gene abundance increase.

Nitrification rate in dairy cattle urine patches can be inhibited by changing soil bioavailable Cu concentration.

Ammonia oxidation to hydroxylamine is catalyzed by the ammonia monooxygenase enzyme and copper (Cu) is a key element for this process. We investigated the effect of soil bioavailable Cu changes induced through the application of Cu-complexing compounds on nitrification rate, ammonia-oxidizing bacteria (AOB) and archaea (AOA) amoA gene abundance, and mineral nitrogen (N) leaching in urine patches using the Manawatu Recent soil. Further, evaluated the combination of organic compound calcium lignosulphonate (LS) with a growth stimulant Gibberellic acid (GA). Treatments were applied in May 2021 as late-autumn treatments: control (no urine), urine-only at 600 kg N ha-1, urine + dicyandiamide (DCD), urine + co-poly-acrylic-maleic acid (PA-MA), urine + LS, urine + split-application of LS (2LS), and urine + combination of GA plus LS (GA + LS). In addition, another four treatments were applied in July 2021 as mid-winter treatments: control, urine-only at 600 kg N ha-1, urine + GA, and urine + GA + LS. Soil bioavailable Cu and mineral N leaching were examined during the experimental period. The AOB/AOA amoA genes were quantified using quantitative polymerase chain reaction. Changes in soil bioavailable Cu across treatments correlated with nitrification rate and AOB amoA abundance in late-autumn while the AOA amoA abundance did not change. The reduction in soil bioavailable Cu induced by the PA-MA and 2LS was linked to significant (P < 0.05) reduction in mineral N leaching of 16 and 30%, respectively, relative to the urine-only. The LS did not induce a significant effect on either bioavailable Cu or mineral N leaching relative to urine-only. The GA + LS reduced mineral N leaching by 10% relative to LS in late-autumn, however, there was no significant effect in mid-winter. This study demonstrated that reducing soil bioavailable Cu can be a potential strategy to reduce N leaching from urine patches.

Iron-rich sand promoted nitrate reduction in a study for testing of lignite based new slow-release fertilisers.

The N losses and agronomic performances of newly developed slow-releasing fertilisers (SRFs; Epox5 and Poly5) were tested against conventional N fertilisers, urea and diammonium phosphate (DAP), in a climate-controlled lysimeter system. The dry matter (DM) yield and N losses of SRFs were not significantly different from urea and DAP. However, nitrate leaching and nitrous oxide (N2O) losses were unexpectedly low and therefore, it was inferred that nitrate underwent a chemical transformation. It was observed that a thick fibreglass wick interrupted drainage and created an anaerobic condition in the soil. The subsoil was found to have a high extractable total iron and it was postulated that iron played a role in the observed low level of N losses. An investigation was carried out with a factorial design using sand types and rates of N application as the main factors. Two types of sand; with high and low iron concentration and four levels of N applications; 0 (control), 50, 100 and 200 kg N ha-1 were employed in a leaching column and nitrate and N2O losses were measured. The nitrate leaching was significantly (P < 0.05) affected by sand types wherein a lower nitrate level was recorded for high­iron concentration sand than for low-iron concentration sand at all N application levels. The N2O emission was significantly (P < 0.05) lower for high-iron sand than for low-iron sand for the 200 N treatment, but not significantly different between sand types for other treatments. These observations provide evidence for the involvement of iron in nitrate transformation under anaerobic conditions and it was hypothesised path was dissimilar nitrate reduction (DNR). Further studies are recommended, to identify the underlying mechanism responsible for nitrate reduction with iron-rich sand.

Hydrothermal carbonization aqueous phase promotes nutrient retention and humic substance formation during aerobic composting of chicken manure.

The aqueous phase (AP) of hydrothermal carbonization is rich in humic substances (HSs), which could influence the poultry manure composting process and the product quality. Here, raw AP and its modified product (MAP) with different nitrogen (N) contents were added into chicken manure composting at low (5%) or high (10%) rate. Results showed that all APs addition decreased the temperature and pH but AP-10% increased total N, HSs, and humic acid (HA) of compost by 12%, 18% and 27%, respectively. MAP applications increased the total phosphorus by 8-9% and MAP-10% enhanced the total potussium content by 20%. Additionally, both AP and MAP additions increased the contents of three major components of dissolved organic matter by 20-64%. In conclusion, both AP and MAP can generally improve the chicken manure compost quality, which provides a new idea for the recycling of APs derived from agro-forestry wastes during hydrothermal carbonization.

Remediation technologies for neonicotinoids in contaminated environments: Current state and future prospects.

Neonicotinoids (NEOs) are synthetic insecticides with broad-spectrum insecticidal activity and outstanding efficacy. However, their extensive use and persistence in the environment have resulted in the accumulation and biomagnification of NEOs, posing significant risks to non-target organisms and humans. This review provides a summary of research history, advancements, and highlighted topics in NEOs remediation technologies and mechanisms. Various remediation approaches have been developed, including physiochemical, microbial, and phytoremediation, with microbial and physicochemical remediation being the most extensively studied. Recent advances in physiochemical remediation have led to the development of innovative adsorbents, photocatalysts, and optimized treatment processes. High-efficiency degrading strains with well-characterized metabolic pathways have been successfully isolated and cultured for microbial remediation, while many plant species have shown great potential for phytoremediation. However, significant challenges and gaps remain in this field. Future research should prioritize isolating, domesticating or engineering high efficiency, broad-spectrum microbial strains for NEO degradation, as well as developing synergistic remediation techniques to enhance removal efficiency on multiple NEOs with varying concentrations in different environmental media. Furthermore, a shift from pipe-end treatment to pollution prevention strategies is needed, including the development of green and economically efficient alternatives such as biological insecticides. Integrated remediation technologies and case-specific strategies that can be applied to practical remediation projects need to be developed, along with clarifying NEO degradation mechanisms to improve remediation efficiency. The successful implementation of these strategies will help reduce the negative impact of NEOs on the environment and human health.

Biochar Derived from Urban Green Waste Can Enhance the Removal of Cd from Water and Reduce Soil Cd Bioavailability.

The beneficial utilization of potentially increasing urban green waste (UGW) is critical for sustainable urban development in China. In this study, UGW was pyrolyzed at different temperatures, and the resulting biochar was used to amend Cd-contaminated soils to grow cabbage. Our results showed that the Cd adsorption capacity of UGW-biochar was positively correlated with the surface area, O/C, and (O+N)/C value of biochar. Furthermore, UGW-biochar was incorporated into three Cd-contaminated soils, including one acidic soil and two neutral soils, to assess its impact on the availability of Cd. The most substantial reduction in the concentration of available Cd was observed in the acidic soil, of the three tested soils. In the neutral soils, a more substantial reduction was found in the heavily Cd-contaminated soil compared to the lightly Cd-contaminated soil. UGW-biochar amendments to the three Cd-contaminated soils resulted in an increase in the cabbage biomass in acidic soil, whereas in neutral soils, it increased in lightly contaminated soils but decreased in heavily contaminated soils. Additionally, the Cd bioaccumulation factor (BCF), translocation factor (TF), and removal efficiency (RE), as impacted by the biochar application, were calculated in the lightly Cd-contaminated soil-cabbage system. The BCF decreased from 5.84 to 3.80 as the dosage of the UGW-biochar increased from 0% to 3%, indicating that the UGW-biochar immobilized Cd and reduced its bioaccumulation in cabbage roots. Based on our investigations, UGW-biochar effectively immobilizes Cd by reducing its mobility and bioavailability in a lightly contaminated environment matrix.

Nitrate Leaching Mitigation Options in Two Dairy Pastoral Soils and Climatic Conditions in New Zealand.

This lysimeter study investigated the effect of late-autumn application of dicyandiamide (DCD), co-poly acrylic-maleic acid (PA-MA), calcium lignosulphonate (LS), a split-application of calcium lignosulphonate (2LS), and a combination of gibberellic acid (GA) and LS (GA + LS) to reduce N leaching losses during May 2020 to December 2020 in lysimeter field sites in Manawatu (Orthic Pumice soil) and Canterbury (Pallic Orthic Brown soil), New Zealand. In a second application, urine-only, GA only and GA + LS treatments were applied during July 2020 in mid-winter on both sites. Results showed that late-autumn application of DCD, 2LS and GA + LS reduced mineral N leaching by 8%, 16%, and 35% in the Manawatu site and by 34%, 11%, and 35% in the Canterbury site, respectively when compared to urine-only. There was no significant increase in cumulative herbage N uptake and yield between urine-treated lysimeters in both sites. Mid-winter application of GA and GA + LS reduced mineral N leaching by 23% and 20%, respectively in the Manawatu site relative to urine-only treated lysimeters, but no significant reduction was observed in the Canterbury site. Our results demonstrated the potential application of these treatments in different soils under different climate and management conditions.

Being applied at rice or wheat season impacts biochar's effect on gaseous nitrogen pollutants from the wheat growth cycle.

Biochar (BC) application to agricultural soil can impact two nitrogen (N) gases pollutants, i.e., the ammonia (NH3) and nitrous oxide (N2O) losses to atmospheric environment. Under rice-wheat rotation, applied at which growth cycle may influence the aforementioned effects of BC. We conducted a soil column (35 cm in inner diameter and 70 cm in height) experiment to evaluate the responses of wheat N use efficiency (NUE), NH3 volatilization, and N2O emission from wheat season to biochar applied at rice (R) or wheat (W) growth cycle, meanwhile regarding the effect of inorganic fertilizer N input rate, i.e., 72, 90, and 108 kg ha-1 (named N72, N90, and N108, respectively). The results showed that BC application influenced the wheat growth and grain yield. In particular, BC applied at rice season increased the wheat grain yield when receiving 90 and 108 kg N ha-1. The improved wheat grain yield was attributed to that N90 + BC(R) and N108 + BC(R) enhanced the wheat NUE by 53.8% and 52.8% over N90 and N108, respectively. More N input led to higher NH3 volatilization and its emission factor. Interestingly, 19.7%-34.0% lower NH3 vitalizations were recorded under treatments with BC applied in rice season, compared with the treatments only with fertilizer N. BC applied at rice season exerted higher efficiency on mitigating N2O emission than that applied at wheat season under three N input rates, i.e., 60.5%-77.6% vs 29.8%-34.8%. Overall, considering the crop yield and global warming potential resulting from NH3 volatilization and N2O emission of wheat season, N90 + BC(R) is recommended. In conclusion, farmers should consider the application time and reduce inorganic fertilizer N rate when using BC.