Sn0.1-Li4Ti5O12/C as a promising cathode material with a large capacity and high rate performance for Mg-Li hybrid batteries.

The development prospects of conventional Li-ion batteries are limited by the paucity of Li resources. Mg-Li hybrid batteries (MLIBs) combine the advantages of Li-ion batteries and magnesium batteries. Li+ can migrate rapidly in the cathode materials, and the Mg anode has the advantage of being dendrite-free. In this study, a type of Li4Ti5O12 composite material doped with Sn4+ and a conductive carbon skeleton (Li4Ti4.9Sn0.1O12/C, Sn0.1-LTO/C) was prepared by a simple one-pot sol-gel method. The doped Sn4+ replaces part of Ti4+ in the crystal lattice, which makes Ti3+ require charge compensation, thus improving the ionic conductivity. The intervention of the conductive carbon skeleton further improves the conductivity of the Sn0.1-LTO/C composite material. The performance of Sn0.1-LTO/C as the cathode of MLIBs is explored. The initial discharge capacity was 159.1 mA h g-1 at 0.5 C, and it was maintained at 105 mA h g-1 even after 500 cycles. The excellent electrochemical performance is attributed to a small amount of Sn doping and the involvement of the conductive carbon skeleton, which indicated that the Sn0.1-LTO/C composite material provides great potential application in MLIBs.

Chemical synthesis of germanium nanoparticles with uniform size as anode materials for lithium ion batteries.

A simple Mg-thermal reduction reaction is reported to synthesize germanium (Ge) nanoparticles with a uniform size at a low temperature of 400 °C in an autoclave. The as-prepared Ge nanoparticles exhibit promising anode applications in lithium ion batteries with high capacity and excellent cycling stability.