Suppressed-scattering spectral windows for radiative cooling applications.

The scattering of light by resonant nanoparticles is a key process for enhancing the solar reflectance in daylight radiative cooling. Here, we investigate the impact of material dispersion on the scattering performance of popular nanoparticles for radiative cooling applications. We show that, due to material dispersion, nanoparticles with a qualitatively similar response at visible frequencies exhibit fundamentally different scattering properties at infrared frequencies. It is found that dispersive nanoparticles exhibit suppressed-scattering windows, allowing for selective thermal emission within a highly reflective sample. The existence of suppressed-scattering windows solely depends on material dispersion, and they appear pinned to the same wavelength even in random composite materials and periodic metasurfaces. Finally, we investigate calcium-silicate-hydrate (CSH), the main phase of concrete, as an example of a dispersive host, illustrating that the co-design of nanoparticles and host allows for tuning of the suppressed-scattering windows. Our results indicate that controlled nanoporosities would enable concrete with daylight passive radiative cooling capabilities.

Effect of Epsilon-Near-Zero Modes on the Casimir Interaction between Ultrathin Films.

Vacuum fluctuation-induced interactions between macroscopic metallic objects result in an attractive force between them, a phenomenon known as the Casimir effect. This force is the result of both plasmonic and photonic modes. For very thin films, field penetration through the films will modify the allowed modes. Here, we theoretically investigate the Casimir interaction between ultrathin films from the perspective of force distribution over real frequencies for the first time. Pronounced repulsive contributions to the force are found due to the highly confined and nearly dispersion-free epsilon-near-zero (ENZ) modes that only exist in ultrathin films. These contributions persistently occur around the ENZ frequency of the film irrespective of the interfilm separation. We further associate the ENZ modes with a striking thickness dependence of a proposed figure of merit (FOM) for conductive thin films, suggesting that the motion of objects induced by Casimir interactions is boosted for deeply nanoscale sizes. Our results shed light on the correlation between special electromagnetic modes and the vacuum fluctuation-induced force as well as the resulting mechanical properties of ultrathin ENZ materials, which may create new opportunities for engineering the motion of ultrasmall objects in nanomechanical systems.

Near-zero-index media as electromagnetic ideal fluids.

Near-zero-index (NZI) supercoupling, the transmission of electromagnetic waves inside a waveguide irrespective of its shape, is a counterintuitive wave effect that finds applications in optical interconnects and engineering light-matter interactions. However, there is a limited knowledge on the local properties of the electromagnetic power flow associated with supercoupling phenomena. Here, we theoretically demonstrate that the power flow in two-dimensional (2D) NZI media is fully analogous to that of an ideal fluid. This result opens an interesting connection between NZI electrodynamics and fluid dynamics. This connection is used to explain the robustness of supercoupling against any geometrical deformation, to enable the analysis of the electromagnetic power flow around complex geometries, and to examine the power flow when the medium is doped with dielectric particles. Finally, electromagnetic ideal fluids where the turbulence is intrinsically inhibited might offer interesting technological possibilities, e.g., in the design of optical forces and for optical systems operating under extreme mechanical conditions.

Generalized approach to quantum interference in lossy N-port devices via a singular value decomposition.

Modeling quantum interference in the presence of dissipation is a critical aspect of quantum technologies. Including dissipation into the model of a linear device enables for assessing the detrimental impact of photon loss, as well as for studying dissipation-driven quantum state transformations. However, establishing the input-output relations characterizing quantum interference at a general lossy N-port network poses important theoretical challenges. Here, we propose a general procedure based on the singular value decomposition (SVD), which allows for the efficient calculation of the input-output relations for any arbitrary lossy linear device. In addition, we show how the SVD provides an intuitive description of the principle of operation of linear optical devices. We illustrate the applicability of our method by evaluating the input-output relations of popular reciprocal and nonreciprocal lossy linear devices, including devices with singular and nilpotent scattering matrices. Our method also enables the analysis of quantum interference in large lossy networks, as we exemplify with the study of an N-port epsilon-near-zero (ENZ) hub. We expect that our procedure will motivate future research on quantum interference in complex devices, as well as the realistic modelling of photon loss in linear lossy devices.

Manipulating thermal emission with spatially static fluctuating fields in arbitrarily shaped epsilon-near-zero bodies.

The control and manipulation of thermal fields is a key scientific and technological challenge, usually addressed with nanophotonic structures with a carefully designed geometry. Here, we theoretically investigate a different strategy based on epsilon-near-zero (ENZ) media. We demonstrate that thermal emission from ENZ bodies is characterized by the excitation of spatially static fluctuating fields, which can be resonantly enhanced with the addition of dielectric particles. The "spatially static" character of these temporally dynamic fields leads to enhanced spatial coherence on the surface of the body, resulting in directive thermal emission. By contrast with other approaches, this property is intrinsic to ENZ media and it is not tied to its geometry. This point is illustrated with effects such as geometry-invariant resonant emission, beamforming by boundary deformation, and independence with respect to the position of internal particles. We numerically investigate a practical implementation based on a silicon carbide body containing a germanium rod.

Silicon carbide as a material-based high-impedance surface for enhanced absorption within ultra-thin metallic films.

The absorption of infrared radiation within ultra-thin metallic films is technologically relevant for different thermal engineering applications and optoelectronic devices, as well as for fundamental research on sub-nanometer and atomically-thin materials. However, the maximal attainable absorption within an ultra-thin metallic film is intrinsically limited by both its geometry and material properties. Here, we demonstrate that material-based high-impedance surfaces enhance the absorptivity of the films, potentially leading to perfect absorption for optimal resistive layers, and a fourfold enhancement for films at deep nanometer scales. Moreover, material-based high-impedance surfaces do not suffer from spatial dispersion and the geometrical restrictions of their metamaterial counterparts. We provide a proof-of-concept experimental demonstration by using titanium nanofilms on top of a silicon carbide substrate.

Soft surfaces and enhanced nonlinearity enabled via epsilon-near-zero media doped with zero-area perfect electric conductor inclusions.

Introducing a dielectric inclusion inside an epsilon-near-zero (ENZ) host has been shown to dramatically affect the effective permeability of the host for a TM-polarized incident wave, a concept coined as photonic doping [Science355, 1058 (2017)SCIEAS0036-807510.1126/science.aal2672]. Here, we theoretically study the prospect of doping the ENZ host with infinitesimally thin perfect electric conductor (PEC) inclusions, which we call "zero-area" PEC dopants. First, we theoretically demonstrate that zero-area PEC dopants enable the design of soft surfaces with an arbitrary cross-sectional geometry. Second, we illustrate the possibility of engineering the PEC dopants with the goal of transforming the electric field distribution inside the ENZ while maintaining a spatially invariant magnetic field. We exploit this property to enhance the effective nonlinearity of the ENZ host.

Zero-index structures as an alternative platform for quantum optics.

Vacuum fluctuations are one of the most distinctive aspects of quantum optics, being the trigger of multiple nonclassical phenomena. Thus, platforms like resonant cavities and photonic crystals that enable the inhibition and manipulation of vacuum fluctuations have been key to our ability to control light-matter interactions (e.g., the decay of quantum emitters). Here, we theoretically demonstrate that vacuum fluctuations may be naturally inhibited within bodies immersed in epsilon-and-mu-near-zero (EMNZ) media, while they can also be selectively excited via bound eigenmodes. Therefore, zero-index structures are proposed as an alternative platform to manipulate the decay of quantum emitters, possibly leading to the exploration of qualitatively different dynamics. For example, a direct modulation of the vacuum Rabi frequency is obtained by deforming the EMNZ region without detuning a bound eigenmode. Ideas for the possible implementation of these concepts using synthetic implementations based on structural dispersion are also proposed.

Isotropic single-photon sources.

Classical antenna theory establishes that there are no coherent isotropic radiators. Thermal radiators can be isotropic, but they lack temporal coherence. Here, we demonstrate that quantum interference processes enable the design of isotropic and unpolarized single-photon sources that preserve temporal coherence properties. We illustrate how this effect can be realized with relatively simple multilevel emitters with degenerate ground states, and we discuss potential implementations based on atomic and solid-state single-photon sources.

Superbackscattering nanoparticle dimers.

The theory and design of superbackscattering nanoparticle dimers are presented. We analytically derive the optimal configurations and the upper bound of their backscattering cross-sections. In particular, it is demonstrated that electrically small nanoparticle dimers can enhance the backscattering by a factor of 6.25 with respect to single dipolar particles. We demonstrate that optimal designs approaching this theoretical limit can be found by using a simple circuit model. The study of practical implementations based on plasmonic and high-permittivity particles has been also addressed. Moreover, the numerical examples reveal that the dimers can attain close to a fourfold enhancement of the single nanoparticle response even in the presence of high losses.

Magnetic dipole super-resonances and their impact on mechanical forces at optical frequencies.

Artificial magnetism enables various transformative optical phenomena, including negative refraction, Fano resonances, and unconventional nanoantennas, beamshapers, polarization transformers and perfect absorbers, and enriches the collection of electromagnetic field control mechanisms at optical frequencies. We demonstrate that it is possible to excite a magnetic dipole super-resonance at optical frequencies by coating a silicon nanoparticle with a shell impregnated with active material. The resulting response is several orders of magnitude stronger than that generated by bare silicon nanoparticles and is comparable to electric dipole super-resonances excited in spaser-based nanolasers. Furthermore, this configuration enables an exceptional control over the optical forces exerted on the nanoparticle. It expedites huge pushing or pulling actions, as well as a total suppression of the force in both far-field and near-field scenarios. These effects empower advanced paradigms in electromagnetic manipulation and microscopy.

Review on the Scientific and Technological Breakthroughs in Thermal Emission Engineering.

The emission of thermal radiation is a physical process of fundamental and technological interest. From different approaches, thermal radiation can be regarded as one of the basic mechanisms of heat transfer, as a fundamental quantum phenomenon of photon production, or as the propagation of electromagnetic waves. However, unlike light emanating from conventional photonic sources, such as lasers or antennas, thermal radiation is characterized for being broadband, omnidirectional, and unpolarized. Due to these features, ultimately tied to its inherently incoherent nature, taming thermal radiation constitutes a challenging issue. Latest advances in the field of nanophotonics have led to a whole set of artificial platforms, ranging from spatially structured materials and, much more recently, to time-modulated media, offering promising avenues for enhancing the control and manipulation of electromagnetic waves, from far- to near-field regimes. Given the ongoing parallelism between the fields of nanophotonics and thermal emission, these recent developments have been harnessed to deal with radiative thermal processes, thereby forming the current basis of thermal emission engineering. In this review, we survey some of the main breakthroughs carried out in this burgeoning research field, from fundamental aspects to theoretical limits, the emergence of effects and phenomena, practical applications, challenges, and future prospects.

Radiative Cooling Properties of Portlandite and Tobermorite: Two Cementitious Minerals of Great Relevance in Concrete Science and Technology.

Although concrete and cement-based materials are the most engineered materials employed by mankind, their potential for use in daytime radiative cooling applications has yet to be fully explored. Due to its complex structure, which is composed of multiple phases and textural details, fine-tuning of concrete is impossible without first analyzing its most important ingredients. Here, the radiative cooling properties of Portlandite (Ca(OH)2) and Tobermorite (Ca5Si6O16(OH)2·4H2O) are studied due to their crucial relevance in cement and concrete science and technology. Our findings demonstrate that, in contrast to concrete (which is a strong infrared emitter but a poor sun reflector), both Portlandite and Tobermorite exhibit good radiative cooling capabilities. These results provide solid evidence that, with the correct optimization of composition and porosity, concrete can be transformed into a material suitable for daytime radiative cooling.

Incandescent temporal metamaterials.

Regarded as a promising alternative to spatially shaping matter, time-varying media can be seized to control and manipulate wave phenomena, including thermal radiation. Here, based upon the framework of macroscopic quantum electrodynamics, we elaborate a comprehensive quantum theoretical formulation that lies the basis for investigating thermal emission effects in time-modulated media. Our theory unveils unique physical features brought about by time-varying media: nontrivial correlations between fluctuating electromagnetic currents at different frequencies and positions, thermal radiation overcoming the black-body spectrum, and quantum vacuum amplification effects at finite temperature. We illustrate how these features lead to striking phenomena and innovative thermal emitters, specifically, showing that the time-modulation releases strong field fluctuations confined within epsilon-near-zero (ENZ) bodies, and that, in turn, it enables a narrowband (partially coherent) emission spanning the whole range of wavevectors, from near to far-field regimes.

Spectrally stable thermal emitters enabled by material-based high-impedance surfaces.

Radiative thermal engineering with subwavelength metallic bodies is a key element for heat and energy management applications, communication and sensing. Here, we numerically and experimentally demonstrate metallic thermal emitters with narrowband but extremely stable emission spectra, whose resonant frequency does not shift with changes on the nanofilm thickness, the angle of observation and/or polarization. Our devices are based on epsilon-near-zero (ENZ) substrates acting as material-based high-impedance substrates. They do not require from complex nanofabrication processes, thus being compatible with large-area and low-cost applications.

Noise Cancellation Effects in Integrated Photonics with Wilkinson Power Dividers.

Wilkinson power dividers (WPDs) are a popular element in RF and microwave technologies known for providing isolation capabilities. However, the benefits that WPDs could offer to integrated photonic systems are far less studied. Here, we investigate the thermal emission from and the noise performance of silicon-on-insulator (SOI) WPDs. We find that WPDs exhibit a noiseless port, with important implications for receiving systems and absorption-based quantum state transformations. At the same time, the thermal signals exiting noisy ports exhibit nontrivial correlations, opening the possibility for noise cancellation. We analyze passive and active networks containing WPDs showing how such nontrivial correlations can prevent the amplification of the thermal noise introduced by WPDs while benefiting from their isolation capabilities. Using this insight, we propose a modified ring-resonator amplifier that improves by N times the SNR in comparison with conventional traveling wave and ring-resonator amplifiers, with N being the number of inputs/outputs of the WPD. We believe that our results represent an important step forward in the implementation of SOI-WPDs and their integration in complex photonic networks, particularly for mid-IR and quantum photonics applications.

Addressing the Impact of Surface Roughness on Epsilon-Near-Zero Silicon Carbide Substrates.

Epsilon-near-zero (ENZ) media have been very actively investigated due to their unconventional wave phenomena and strengthened nonlinear response. However, the technological impact of ENZ media will be determined by the quality of realistic ENZ materials, including material loss and surface roughness. Here, we provide a comprehensive experimental study of the impact of surface roughness on ENZ substrates. Using silicon carbide (SiC) substrates with artificially induced roughness, we analyze samples whose roughness ranges from a few to hundreds of nanometer size scales. It is concluded that ENZ substrates with roughness in the few nanometer scale are negatively affected by coupling to longitudinal phonons and strong ENZ fields normal to the surface. On the other hand, when the roughness is in the hundreds of nanometers scale, the ENZ band is found to be more robust than dielectric and surface phonon polariton (SPhP) bands.

New Horizons in Near-Zero Refractive Index Photonics and Hyperbolic Metamaterials.

The engineering of the spatial and temporal properties of both the electric permittivity and the refractive index of materials is at the core of photonics. When vanishing to zero, those two variables provide efficient knobs to control light-matter interactions. This Perspective aims at providing an overview of the state of the art and the challenges in emerging research areas where the use of near-zero refractive index and hyperbolic metamaterials is pivotal, in particular, light and thermal emission, nonlinear optics, sensing applications, and time-varying photonics.

Momentum considerations inside near-zero index materials.

Near-zero index (NZI) materials, i.e., materials having a phase refractive index close to zero, are known to enhance or inhibit light-matter interactions. Most theoretical derivations of fundamental radiative processes rely on energetic considerations and detailed balance equations, but not on momentum considerations. Because momentum exchange should also be incorporated into theoretical models, we investigate momentum inside the three categories of NZI materials, i.e., inside epsilon-and-mu-near-zero (EMNZ), epsilon-near-zero (ENZ) and mu-near-zero (MNZ) materials. In the context of Abraham-Minkowski debate in dispersive materials, we show that Minkowski-canonical momentum of light is zero inside all categories of NZI materials while Abraham-kinetic momentum of light is zero in ENZ and MNZ materials but nonzero inside EMNZ materials. We theoretically demonstrate that momentum recoil, transfer momentum from the field to the atom and Doppler shift are inhibited in NZI materials. Fundamental radiative processes inhibition is also explained due to those momentum considerations inside three-dimensional NZI materials. Absence of diffraction pattern in slits experiments is seen as a consequence of zero Minkowski momentum. Lastly, consequence on Heisenberg inequality, microscopy applications and on the canonical momentum as generator of translations are discussed. Those findings are appealing for a better understanding of fundamental light-matter interactions at the nanoscale as well as for lasing applications.

Geometry-independent antenna based on Epsilon-near-zero medium.

It is well known that electromagnetic radiation from radiating elements (e.g., antennas, apertures, etc.) shows dependence on the element's geometry shape in terms of operating frequencies. This basic principle is ubiquitous in the design of radiators in multiple applications spanning from microwave, to optics and plasmonics. The emergence of epsilon-near-zero media exceptionally allows for an infinite wavelength of electromagnetic waves, manifesting exotic spatially-static wave dynamics which is not dependent on geometry. In this work, we analyze theoretically and verify experimentally such geometry-independent features for radiation, thus presenting a novel class of radiating resonators, i.e., antennas, with an operating frequency irrelevant to the geometry shape while only determined by the host material's dispersions. Despite being translated into different shapes and topologies, the designed epsilon-near-zero antenna resonates at a same frequency, while exhibiting very different far-field radiation patterns, with beams varying from wide to narrow, or even from single to multiple. Additionally, the photonic doping technique is employed to facilitate the high-efficiency radiation. The material-determined geometry-independent radiation may lead to numerous applications in flexible design and manufacturing for wireless communications, sensing, and wavefront engineering.