RESUMEN
Bimetallic Pd1Nix alloys supported on nitrogen-doped carbon (Pd1Nix/N-C, x = 0.37, 1.3 and 3.6) exhibit higher activities than Pd/N-C towards dehydrogenation of formic acid (HCO2H, FA). Density functional theory (DFT) calculations provided electronic and atomic structures, energetics and reaction pathways on Pd(111) and Pd1Nix(111) surfaces of different Pd/Ni compositions. A density of states (DOS) analysis disclosed the electronic interactions between Pd and Ni revealing novel active sites for FA dehydrogenation. Theoretical analysis of FA dehydrogenation on Pd1Nix(111) (x = 0.33, 1 and 3) shows that the Pd1Ni1(111) surface provides optimum H2-release efficiency via a favorable 'HCOO pathway', in which a hydrogen atom and one of the two oxygen atoms of FA interact directly with surface Ni atoms producing adsorbed CO2 and H2. The enhanced efficiency is also attributed to the blocking of an unfavorable 'COOH pathway' through which a C-O bond is broken and side products of CO and H2O are generated.
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Syngas, a gaseous mixture of CO and H2, is a critical industrial feedstock for producing bulk chemicals and synthetic fuels, and its production via direct CO2 electroreduction in aqueous media constitutes an important step toward carbon-negative technologies. Herein, we report controlled syngas production with various H2/CO ratios via the electrochemical CO2 reduction reaction (CO2RR) on specifically formulated Au25 and PtAu24 nanoclusters (NCs) with core-atom-controlled selectivities. While CO was predominantly produced from the CO2RR on the Au NCs, H2 production was favored on the PtAu24 NCs. Density functional theory calculations of the free energy profiles for the CO2RR and hydrogen evolution reaction (HER) indicated that the reaction energy for the conversion of CO2 to CO was much lower than that for the HER on the Au25 NC. In contrast, the energy profiles calculated for the HER indicated that the PtAu24 NCs have nearly thermoneutral binding properties; thus, H2 production is favored over CO formation. Based on the distinctly different catalytic selectivities of Au25 and PtAu24 NCs, controlled syngas production with H2/CO ratios of 1 to 4 was demonstrated at a constant applied potential by simply mixing the Au25 and PtAu24 NCs based on their intrinsic catalytic activities for the production of CO and H2.
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Demand on the practical synthetic approach to the high performance electrocatalyst is rapidly increasing for fuel cell commercialization. Here we present a synthesis of highly durable and active intermetallic ordered face-centered tetragonal (fct)-PtFe nanoparticles (NPs) coated with a "dual purpose" N-doped carbon shell. Ordered fct-PtFe NPs with the size of only a few nanometers are obtained by thermal annealing of polydopamine-coated PtFe NPs, and the N-doped carbon shell that is in situ formed from dopamine coating could effectively prevent the coalescence of NPs. This carbon shell also protects the NPs from detachment and agglomeration as well as dissolution throughout the harsh fuel cell operating conditions. By controlling the thickness of the shell below 1 nm, we achieved excellent protection of the NPs as well as high catalytic activity, as the thin carbon shell is highly permeable for the reactant molecules. Our ordered fct-PtFe/C nanocatalyst coated with an N-doped carbon shell shows 11.4 times-higher mass activity and 10.5 times-higher specific activity than commercial Pt/C catalyst. Moreover, we accomplished the long-term stability in membrane electrode assembly (MEA) for 100 h without significant activity loss. From in situ XANES, EDS, and first-principles calculations, we confirmed that an ordered fct-PtFe structure is critical for the long-term stability of our nanocatalyst. This strategy utilizing an N-doped carbon shell for obtaining a small ordered-fct PtFe nanocatalyst as well as protecting the catalyst during fuel cell cycling is expected to open a new simple and effective route for the commercialization of fuel cells.
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The effect of a subsurface hetero layer (thin gold) on the activity and stability of Pt skin surface in Pt3M system (M = 3d transition metals) is investigated using the spin-polarized density functional theory calculation. First, we find that the heterometallic interaction between the Pt skin surface and the gold subsurface in Pt/Au/Pt3M system can significantly modify the electronic structure of the Pt skin surface. In particular, the local density of states projected onto the d states of Pt skin surface near the Fermi level is drastically decreased compared to the Pt/Pt/Pt3M case, leading to the reduction of the oxygen binding strength of the Pt skin surface. This modification is related to the increase of surface charge polarization of outmost Pt skin atoms by the electron transfer from the gold subsurface atoms. Furthermore, a subsurface gold layer is found to cast the energetic barrier to the segregation loss of metal atoms from the bulk (inside) region, which can enhance the durability of Pt3M based catalytic system in oxygen reduction condition at fuel cell devices. This study highlights that a gold subsurface hetero layer can provide an additional mean to tune the surface activity toward oxygen species and in turn the oxygen reduction reaction, where the utilization of geometric strain already reaches its practical limit.
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The role of samarium (Sm) 4f states and Sm-perturbed O 2p states in determining the sulfur tolerance of Sm-doped CeO2 was elucidated by using the density functional theory (DFT) + U calculation. We find that the sulfur tolerance of Sm-doped CeO2 is closely related to the modification of O 2p states by the strong interaction between Sm 4f and O 2p states. In particular, the availability of unoccupied O 2p states near the Fermi level is responsible for enhancing the sulfur tolerance of Sm-doped CeO2 compared to the pure CeO2 by increasing the activity of the surface lattice oxygen toward sulfur adsorption, by weakening the interaction between Sm-O, and by increasing the migration tendency of the subsurface oxygen ion toward the surface.
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Density functional theory (DFT) studies of mercury oxidation on Au(111) are conducted to determine the potential Hg oxidation mechanisms taking place on catalytic gold surfaces by using the Perdew and Wang approximation (PW91) described by a generalized gradient approximation (GGA). The Hg oxidation was examined via a Langmuir-Hinshelwood mechanism where each Hg(0) and Cl2 (or HCl) species is separately adsorbed on the gold surface and the bimolecular reaction occurs through the formation of bound HgCl and HgCl2. For this, the Climbing Image-Nudged Elastic Band (CI-NEB) method has been employed to calculate the activation energies of HgCl and HgCl2 formation pathways. In the three-step Hg oxidation mechanism (Hg â HgCl â HgCl2), the second Cl attachment step is endothermic which is the reaction rate-limiting step, while the first Cl attachment step is exothermic. This observation implies that Hg oxidation prefers a pathway in which HgCl and HgCl2 are formed, rather than a pathway directly oxidizing Hg to HgCl2. In the presence of H atoms due to HCl dissociation on the Au surface, the H atoms lower the activation energy for Hg oxidation by consuming the electron charge of Au atoms, thereby weakening the strength of interaction between Cl and the Au surface and lowering an energy required to detach Cl from the Au surface. This mechanism is in the absence of site competition on the Au surface. In addition, details of the electronic properties of these systems are discussed.
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Oro/química , Mercurio/química , Oxidación-Reducción , Propiedades de SuperficieRESUMEN
Active B5-sites on Ru catalysts can be exploited for various catalytic applications; in particular, the epitaxial formation of Ru nanoparticles with hexagonal planar morphologies on hexagonal boron nitride sheets increases the number of active B5-sites along the nanoparticle edges. The energetics of adsorption of Ru nanoparticles on hexagonal boron nitride were investigated using density functional theory calculations. Then, to understand the fundamental reason for this morphology control, adsorption studies and charge density analysis were performed on fcc and hcp Ru nanoparticles heteroepitaxially formed on a hexagonal boron nitride support. Among the explored morphologies, hcp Ru(0001) nanoparticles exhibited the highest adsorption strength of -31.656 eV. To verify the hexagonal planar morphologies of the hcp-Ru nanoparticles, three different hcp-Ru(0001) nanoparticles-Ru60, Ru53, and Ru 41-were adsorbed onto the BN substrate. In agreement with the experimental studies, the hcp-Ru60 nanoparticles exhibited the highest adsorption energy owing to their long-range and perfect hexagonal match with the interacting hcp-BN(001) substrate.
RESUMEN
The anionic components have a significant role in regulating the electrochemical properties of mixed transition-metal (MTM)-based materials. However, the relationship between the anionic components and their inherent electrochemical properties in MTM-based materials is still unclear. Herein, we report the anion-dependent supercapacitive and oxygen evolution reaction (OER) properties of in situ grown binary Ni-Co-selenide (Se)/sulfide (S)/phosphide (P) nanosheet arrays (NAs) over nickel foam starting from MOF-derived Ni-Co layered double hydroxide precursors. Among them, the Ni-Co-Se NAs exhibited the best specific capacity (289.6 mA h g-1 at 4 mA cm-2). Furthermore, a hybrid device constructed with Ni-Co-Se NAs delivered an excellent energy density (74 W h kg-1 at 525 W kg-1) and an ultra-high power density (10â¯832 W kg-1 at 46 W h kg-1) with outstanding durability (â¼94%) for 10â¯000 cycles. Meanwhile, the Ni-Co-Se NAs showed superior electrocatalytic OER outputs with the lowest overpotential (235 mV at 10 mA cm-2) and Tafel slope. In addition, Ni-Co-Se NAs outperformed IrO2 as an anode in an anion exchange membrane water electrolyzer at a high current density (>1.0 A cm-2) and exhibited a stable performance up to 48 h with a 99% Faraday efficiency. Theoretical analyses validate that the Se promotes OH adsorption and improves the electrochemical activity of the Ni-Co-Se through a strong electronic redistribution/hybridization with an active metal center due to its valence 4p and inner 3d orbital participations. This study will provide in-depth knowledge of bifunctional activities in MTM-based materials with different anionic substitutions.
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Ruthenium is one of the most active catalysts for ammonia dehydrogenation and is essential for the use of ammonia as a hydrogen storage material. The B5 -type site on the surface of ruthenium is expected to exhibit the highest catalytic activity for ammonia dehydrogenation, but the number of these sites is typically low. Here, a B5 -site-rich ruthenium catalyst is synthesized by exploiting the crystal symmetry of a hexagonal boron nitride support. In the prepared ruthenium catalyst, ruthenium nanoparticles are formed epitaxially on hexagonal boron nitride sheets with hexagonal planar morphologies, in which the B5 sites predominate along the nanoparticle edges. By activating the catalyst under the reaction condition, the population of B5 sites further increases as the facets of the ruthenium nanoparticles develop. The electron density of the Ru nanoparticles also increases during catalyst activation. The synthesized catalyst shows superior catalytic activity for ammonia dehydrogenation compared to previously reported catalysts. This work demonstrates that morphology control of a catalyst via support-driven heteroepitaxy can be exploited for synthesizing highly active heterogeneous catalysts with tailored atomic structures.
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The structural and electronic properties of Hg, SO(2), HgS, and HgO adsorption on Au(111) surfaces have been determined using density functional theory with the generalized gradient approximation. The adsorption strength of Hg on Au(111) increases by a factor of 1.3 (from -9.7 to -12.6 kcal/mol) when the number of surface vacancies increases from 0 to 3; however, the adsorption energy decreases with more than three vacancies. In the case of SO(2) adsorption on Au(111), the Au surface atoms are better able to stabilize the SO(2) molecule when they are highly undercoordinated. The SO(2) adsorption stability is enhanced from -0.8 to -9.3 kcal/mol by increasing the number of vacancies from 0 to 14, with the lowest adsorption energy of -10.2 kcal/mol at 8 Au vacancies. Atomic sulfur and oxygen precovered-Au(111) surfaces lower the Hg stability when Hg adsorbs on the top of S and O atoms. However, a cooperative effect between adjacent Hg atoms is observed as the number of S and Hg atoms increases on the perfect Au(111) surface, resulting in an increase in the magnitude of Hg adsorption. Details of the electronic structure properties of the Hg-Au systems are also discussed.
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Contaminantes Ambientales/aislamiento & purificación , Oro/química , Compuestos de Mercurio/aislamiento & purificación , Mercurio/aislamiento & purificación , Adsorción , Modelos Moleculares , Teoría Cuántica , Dióxido de Azufre/aislamiento & purificación , Propiedades de Superficie , TermodinámicaRESUMEN
Herein, we report the significant effects of natural organic matter contained in natural zeolite (Z-NOM) on the physicochemical characteristics of a Ni/Fe@natural zeolite (NF@NZ) catalyst and its decontamination performance toward the dechlorination of trichloroethylene (TCE). Z-NOM predominantly consists of humic-like substances and has demonstrable utility in the synthesis of bimetallic catalysts. Compared to NF@NZ600C (devoid of Z-NOM), NF@NZ had increased dispersibility and mobility and showed significant enhancement in the catalytic dechlorination of TCE owing to the encapsulation of Ni0/Fe0 nanoparticles by Z-NOM. The results of corrosion experiments, spectroscopic analyses, and H2 production experiments confirmed that Ni0 acted as an efficient cocatalyst with Fe0 to enhance the dechlorination of TCE to ethane, and Z-NOM-capped Ni0 showed improved adsorption of TCE and atomic hydrogen on their reactive sites and oxidation resistance. The density functional theory (DFT) studies have substantiated the improved adsorption of TCE due to the presence of NOM (especially by COOH structure) and the enhanced charge density at the Ni site in the Ni/Fe bimetal alloy for the stronger adsorption of hydrogen atoms that ultimately enhanced the TCE reduction reaction. These findings illustrate the efficiency of NOM containing natural minerals toward the synthesis of bimetallic catalysts for practical applications.
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Tricloroetileno , Zeolitas , Catálisis , Sustancias Húmicas , Hidrógeno , Hierro/química , Tricloroetileno/químicaRESUMEN
This study evaluates the ability of Beijerinckia indica (B. indica) as a biomaterial for aerobic biofilm barriers. B. indica's ability to remove phenanthrene was measured using a two-phase partitioning bioreactor. Approximately 500 mg/L of phenanthrene was gradually removed over a two week period under aerobic conditions of the bioreactor. B. indica's ability to reduce hydraulic conductivity was evaluated using rigid wall soil columns inoculated with the bacteria. B. indica formed a large quantity of strongly adhesive biofilm among soil particles, reducing the hydraulic conductivity in the soil columns by 2 or 3 orders of magnitude. To assess recovery of the biofilm, the formed biofilm was purposely destroyed by introducing landfill leachate into the soil columns. The biofilm recovery test showed that the hydraulic conductivity increased after leachate introduction. However, re-permeation of nutrient solution restored the permeability to its original lower value, which suggests a full recovery of the damaged biofilm. This study suggests that B. indica may be used as a possible biomaterial for aerobic biofilm barriers for the removal of phenanthrene from groundwater, provided that sufficient substrate and electron acceptor are provided to the treatment system.
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Beijerinckiaceae/metabolismo , Fenantrenos/metabolismo , Contaminantes Químicos del Agua/metabolismo , Biodegradación Ambiental , Biopelículas , Factores de Tiempo , Contaminantes Químicos del Agua/químicaRESUMEN
The mobility of heavy metalloids including As, Sb, Mo, W, and Cr in soil was investigated under both reducing and oxidizing conditions. The effects of soil mineralogy and the presence of competitive anions were studied as important factors affecting the mobility of these contaminants. Batch experiments conducted with the addition of oxidized and fresh FeS exhibited enhanced sorption rates for As and W under oxidizing conditions, and for Mo under reducing conditions. The inhibitory effect of phosphate on the sorption rates was most apparent for As and Mo under both oxidizing and reducing conditions, while only a small phosphate effect was observed for Sb and W. For Sb and W mobility, pH was determined to be the most important controlling factor. The results of long-term batch experiments revealed that differences in the mobility of metalloids, particularly As, were also influenced by microbial activity in the oxidizing and reducing conditions.
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Contaminación Ambiental/análisis , Compuestos de Hierro/análisis , Metaloides/análisis , Fosfatos/análisis , Contaminantes del Suelo/análisis , Suelo/química , Arsénico/análisis , Cromo/análisis , Hierro/análisis , Molibdeno/análisis , Oxidación-Reducción , Sulfuros/análisis , Tungsteno/análisisRESUMEN
The effect of alloying with transition metals (Ni, Co, Fe) on the adsorption strength of phosphoric acid on Pt alloy surfaces was investigated using electrochemical analysis and first-principles calculations. Cyclic voltammograms of carbon-supported Pt3M/C (M = Ni, Co, and Fe) electrocatalysts in 0.1 M HClO4 with and without 0.01 M H3PO4 revealed that the phosphoric acid adsorption charge density near the onset potential on the nanoparticle surfaces was decreased by alloying with transition metals in the order Co, Fe, Ni. First-principles calculations based on density functional theory confirmed that the adsorption strength of phosphoric acid was weakened by alloying with transition metals, in the same order as that observed in the electrochemical analysis. The simulation suggested that the weaker phosphoric acid adsorption can be attributed to a lowered density of states near the Fermi level due to alloying with transition metals.
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Here we report the preparation of hollow microspheres with a thin shell composed of mixed cobalt nitride (Co-N) and cobalt oxide (Co-O) nanofragments encapsulated in thin layers of nitrogen-doped carbon (N-C) nanostructure (Co-N/Co-O@N-C) arrays with enhanced bifunctional oxygen electrochemical performance. The hybrid structures are synthesized via heat treatment of N-doped hollow carbon microspheres with cobalt nitrate, and both the specific ratio of these precursors and the selected annealing temperature are found to be the key factors for the formation of the unique hybrid structure. The as-obtained product (Co-N/Co-O@N-C) presents a large specific surface area (493 m2 g-1), high-level heteroatom doping (Co-N, Co-O, and N-C), and hierarchical porous nanoarchitecture containing macroporous frameworks and mesoporous walls. Electronic interaction between the thin N-C layers and the encapsulated Co-N and Co-O nanofragments efficiently optimizes oxygen adsorption properties on the Co-N/Co-O@N-C and thereby triggers bifunctional oxygen electrochemical activity at the surface. The Co-N/Co-O@N-C nanohybrid exhibited a high onset potential of 0.93 V, and a limiting current density of 5.6 mA cm-2 indicating 4-electron oxygen reduction reaction (ORR), afforded high catalytic activity for the oxygen evolution reaction (OER) and even exceeded the catalytic stability of the commercial precious electrocatalysts; furthermore, when integrated into the oxygen electrode of a regenerative fuel cell device, it exhibited high-performance oxygen electrodes for both the ORR and the OER.
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Structure effects of NiS and Ni3S2 nanoparticles were investigated for their electrocatalytic activity in the hydrogen evolution reaction in both acid and alkaline media. Owing to the different atomic configurations and crystalline structures, there is a hydrogen adsorption energy difference, which induces a difference in the activity. From density functional theory calculations and experimental observations, the importance of designing an electrocatalyst with an appropriate atomic configuration is evident.
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To date, carbon-based materials including various carbon nanostructured materials have been extensively used as an electrocatalyst support for proton exchange membrane fuel cell (PEMFC) applications due to their practical nature. However, carbon dissolution or corrosion caused by high electrode potential in the presence of O2 and/or water has been identified as one of the main failure modes for the device operation. Here, we report the first TiN nanofiber (TNF)-based nonwoven structured materials to be constructed via electrospinning and subsequent two-step thermal treatment processes as a support for the PEMFC catalyst. Pt catalyst nanoparticles (NPs) deposited on the TNFs (Pt/TNFs) were electrochemically characterized with respect to oxygen reduction reaction (ORR) activity and durability in an acidic medium. From the electrochemical tests, the TNF-supported Pt catalyst was better and more stable in terms of its catalytic performance compared to a commercially available carbon-supported Pt catalyst. For example, the initial oxygen reduction performance was comparable for both cases, while the Pt/TNF showed much higher durability from an accelerated degradation test (ADT) configuration. It is understood that the improved catalytic roles of TNFs on the supported Pt NPs for ORR are due to the high electrical conductivity arising from the extended connectivity, high inertness to the electrochemical environment and strong catalyst-support interactions.
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Described herein is the development of a novel Co-based oxygen electrode catalyst coupled with unique carbon structures. The present carbon shell coated Co nanoparticles of which the surface composites are modified by phosphorus incorporation, exhibit efficient oxygen reduction activities as well as oxygen evolving properties.
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Density functional theory studies demonstrate that defective graphene-supported Cu nanoparticles can modify the structural and electronic properties of copper for enhancing electrochemical reduction of carbon dioxide (CO2) into hydrocarbon fuels (CH4, CO, and HCOOH). We not only provide improved understanding of CO2 conversion mechanisms on both Cu and the Cu nanoparticle system, but also explain a key factor for enhanced CO2 conversion. A promising catalytic material for CO2 conversion into hydrocarbon fuels may allow for geometry flexibility upon interaction with a key intermediate of CHO*.
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Edge-exposed MoS2 nano-assembled structures are designed for high hydrogen evolution reaction activity and long term stability. The number of sulfur edge sites of nano-assembled spheres and sheets is confirmed by Raman spectroscopy and EXAFS analysis. By controlling the MoS2 morphology with the formation of nano-assembled spheres with the assembly of small-size fragments of MoS2, the resulting assembled spheres have high electrocatalytic HER activity and high thermodynamic stability.