Ethnicity, Race, and Gender in Engineering Education: The Nuanced Experiences of Male and Female Latinx Engineering Undergraduates Targeted by Microaggressions.

Compared to other groups, relatively less research has specifically addressed the retention of Latinx students in STEM disciplines. These students face many negative stereotypes about their group, especially related to their academic success, yet there is limited research regarding how microaggressions, subtle or ambiguous discriminatory behaviors, targeting Latinx students in engineering education settings impact their experience in those programs. Guided by Sue's definitions and taxonomy of microaggressions, Critical Race Theory and Latino Critical Theory, the purpose of the current study was to answer the following research questions: 1) What microaggressions do Latinx engineering undergraduates experience in an engineering education environment? and 2) How do these microaggressions impact Latinx engineering undergraduates' academic well-being, as defined by their academic self-efficacy and academic performance?

Microplastics in landfill leachate: Sources, detection, occurrence, and removal.

Due to the accumulation of an enormous amount of plastic waste from municipal and industrial sources in landfills, landfill leachate is becoming a significant reservoir of microplastics. The release of microplastics from landfill leachate into the environment can have undesirable effects on humans and biota. This study provides the state of the science regarding the source, detection, occurrence, and remediation of microplastics in landfill leachate based on a comprehensive review of the scientific literature, mostly in the recent decade. Solid waste and wastewater treatment residue are the primary sources of microplastics in landfill leachate. Microplastic concentration in raw and treated landfill leachate varied between 0-382 and 0-2.7 items L-1. Microplastics in raw landfill leachate are largely attributable to local plastic waste production and solid waste management practices. Polyethylene, polystyrene, and polypropylene are the most prevalent microplastic polymers in landfill leachate. Even though the colors of microplastics are primarily determined by their parent plastic waste, the predominance of light-colored microplastics in landfill leachate indicates long-term degradation. The identified morphologies of microplastics in leachate from all published sources contain fiber and fragments the most. Depending on the treatment method, leachate treatment processes can achieve microplastic removal rates between 3% and 100%. The review also provides unique perspectives on microplastics in landfill leachate in terms of remediation, final disposal, fate and transport among engineering systems, and source reduction, etc. The landfill-wastewater treatment plant loop and bioreactor landfills present unique difficulties and opportunities for managing microplastics induced by landfill leachate.

Release efficiencies of potassium permanganate controlled-release biodegradable polymer (CRBP) pellets embedded in polyvinyl acetate (CRBP-PVAc) and polyethylene oxide (CRBP- PEO) for groundwater treatment.

In-situ chemical oxidation (ISCO) is a commonly used method for the remediation of environmental contaminants in groundwater systems. However, traditional ISCO methods are associated with several limitations, including safety and handling concerns, rebound of groundwater contaminants, and difficulty in reaching all areas of contamination. To overcome these limitations, novel Controlled-Release Biodegradable Polymer (CRBP) pellets containing the oxidant KMnO4 were designed and tested. The CRBP pellets were encapsulated in Polyvinyl Acetate (CRBP-PVAc) and Polyethylene Oxide (CRBP-PEO) at different weight percentages, baking temperatures, and time. Their release efficiency was tested in water, soil, and water and soil mixture media. Results showed that CRBP-PVAc pellets with 60 % KMnO4 and baked at 120 °C for 2 min had the highest release percentage and rate across different conditions tested. Natural organic matter was also found to be an important factor to consider for in-field applications due to its potential reducing effect with MnO4-. Overall, the use of CRBP pellets offers an innovative and sustainable solution to remediate contaminated groundwater systems, with the potential to overcome traditional ISCO limitations. These findings suggest that CRBP pellets could provide sustained and controlled release of the oxidant, reducing the need for multiple injections and minimizing safety and handling concerns. This study represents an important step towards developing a new and effective approach for ISCO remediation.

Effect of byproducts from the ozonation of pyrene: biphenyl-2,2',6,6'-tetracarbaldehyde and biphenyl-2,2',6,6'-tetracarboxylic acid on gap junction intercellular communication and neutrophil function.

In this study, biphenyl-2,2',6,6'-tetracarbaldehyde, an initial byproduct formed from the ozonation of pyrene, and biphenyl-2,2',6,6'-tetracarboxylic acid, a subsequent pyrene ozonation byproduct, were evaluated using two toxicology assays to compare the toxicity of ozonation byproducts with that of the parent compound. The first assay measured the potential for the compounds to block gap junctional intercellular communication (GJIC) using the scrape loading/dye transfer technique in normal WB-344 rat liver epithelial cells. The second assay evaluated the ability of the compounds to affect neutrophil function by measuring the production of superoxide in a human cell line (HL-60). Pyrene significantly blocked intercellular communication (f = 0.2-0.5) at 40 microM and complete inhibition of communication (f < 0.2) occurred at 50 microM. Gap junctional intercellular communication in cells exposed to biphenyl-2,2',6,6'-tetracarbaldehyde reached f < 0.5 at a concentration of 15 microM. At concentrations greater than 20 microM, biphenyl-2,2',6,6'-tetracarbaldehyde was cytotoxic and the inhibition of GJIC was caused by cell death. Biphenyl-2,2',6,6'-tetracarboxylic acid was neither cytotoxic nor inhibitory to GJIC at the concentrations tested (10-500 microM). Exposure to biphenyl-2,2',6,6'-tetracarbaldehyde resulted in a concentration-dependent decrease in phorbol 12-myristate 13-acetate-stimulated O2- production. Neither exposure to pyrene nor biphenyl-2,2',6,6'-tetracarboxylic acid caused a significant toxic effect on neutrophil function.