RESUMEN
We observe multiple steplike jumps in a Dy-Fe-Ga-based ferrimagnetic alloy in its magnetic hysteresis curve at 2 K. The observed jumps are found to have a stochastic character with respect to their magnitude and the field position, and the jumps do not correlate with the duration of the field. The distribution of jump size follows a power law variation indicating the scale invariance nature of the jumps. We have invoked a simple two-dimensional random bond Ising-type spin system to model the dynamics. Our computational model can qualitatively reproduce the jumps and their scale-invariant character. It also elucidates that the flipping of antiferromagnetically coupled Dy and Fe clusters is responsible for the observed jumps in the hysteresis loop. These features are described in terms of the self-organized criticality.
RESUMEN
We report rich magnetic behavior for Co-Ir based double perovskites consisting of different rare earth cations Pr and Nd: Pr2CoIrO6(PCIO) and Nd2CoIrO6(NCIO). Both oxides show an antisite disorder of 10% and a ferrimagnetic transition,TFiMaround 96 K and 98 K respectively. The long range magnetic ordering is arising from the canted antiferromagnetic ordering between the Co2+and Ir4+ions. A prominent peak around 27 K in magnetization data of NCIO indicates that the total moment of Nd ion is antiferromagnetically coupled to the Co-Ir sublattice. The long range order of the Nd sublattice is corroborated by the evidence of an anomaly in specific heat at very low temperature. The compounds exhibit a maximum change of magnetic entropy of 0.57 (0.48) J kg.K-1atTFiMin a magnetic field of 5 T. The strong spin-orbit coupling in 5dstates of Ir and cation disorder lead to the Mott insulating phase as found from the analysis of temperature dependent resistivity. These unique behaviors suggest an interesting interplay between localized Pr/Nd-4f, itinerant Co-3dand Ir-5delectrons.
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We propose SnBi2Te4to be a novel topological quantum material exhibiting temperature (T) mediated transitions between rich electronic phases. Our combined theoretical and experimental results suggest that SnBi2Te4goes from a low-Tsemimetallic phase to a high-T(room temperature) insulating phase via an intermediate metallic phase. Single crystals of SnBi2Te4are characterized by various experimental probes including synchrotron based x-ray diffraction, magnetoresistance, Hall effect, Seebeck coefficient and magnetization. X-ray diffraction data confirms an anomalous thermal expansion of the unit cell volume below â¼100 K, which significantly affects the bulk band structure and hence the transport properties. Simulated surface states are found to be topologically robust with varyingT. This indirectly supports the experimentally observed paramagnetic singularity in the entireT-range. The proposed coexistence of such rich phases is a rare occurrence, yet it facilitates a fertile ground to tune them in a material driven by structural changes.
RESUMEN
The quaternary Heusler compound NiFeTiSn can be considered to be derived from the exotic pseudogap-compound Fe2TiSn by the replacement of one Fe atom by Ni. In contrast to Fe2TiSn, which shows a disorder induced ferromagnetic phase, the ground state of NiFeTiSn is antiferromagnetic with the signature of spin canting. Interestingly, NiFeTiSn shows a Griffiths-like phase characterized by isolated ferromagnetic clusters before attaining the antiferromagnetic state. The Griffiths-like phase is possibly associated with the antisite disorder between Fe and Ti sites as evident from our powder x-ray diffraction study. The compound also shows rather unusual temperature dependence of resistivity, which can be accounted by the prevailing structural disorder in the system. NiFeTiSn turned out to be a rare example where Griffiths-like phase is observed in a semiconducting 3dtransition metal based intermetallic compound with antiferromagnetic ground state.
RESUMEN
Heusler compounds are a large group of intermetallic compositions with versatile material properties. In recent times, they are found to be important for their practical applications in the fields of spintronics and shape memory effect. Interestingly, their physical properties can be easily tuned by varying the valence electron concentration through proper doping and substitution. Empirical laws concerning the valence electron concentration, such as Slater-Pauling or Hume-Rothery rules are found to be useful in predicting their electronic, magnetic and structural properties quite accurately. Electrical transport measurements are simple laboratory-based techniques to gather a handful of information on the electronic properties of metals and semiconductors. The present review aimed to provide a comprehensive view of the transport in 3dand 4dtransition metal-based bulk Heusler compositions. The main emphasis is given on resistivity, magnetoresistance, Hall effect, thermopower and spin-dependent transport in spintronics devices. The review primarily focuses on magnetic Heusler compounds and alloys, albeit it also addresses several non-magnetic materials showing superconductivity or large thermopower.
RESUMEN
The rare-earth intermetallic compound Ho5Sn3demonstrates fascinating magnetic properties, which include temperature-driven multiple magnetic transitions and field-driven metamagnetism. We address the magnetic character of this exciting compound through a combined experimental and theoretical studies. Ho5Sn3orders antiferromagnetically below 28 K, and shows further spin reorientation transitions at 16 K and 12 K. We observe a sizable amount of low-temperature magnetocaloric effect (MEC) in Ho5Sn3with a maximum value of entropy change ΔS= -9.5 J Kg-1 K-1for an applied field ofH= 50 kOe at around 30 K. The field hysteresis is almost zero above 15 K where the MEC is important. Interestingly, ΔSis found to change its sign from positive to negative as the temperature is increased above about 8 K, which can be linked to the multiple spin reorientation transitions. The signature of the metamagnetism is visible in the ΔSversusHplot. The magnetic ground state, obtained from the density functional theory based calculation, is susceptible to the effective Coulomb interaction (Ueff) between electrons. Depending upon the value ofUeff, the ground state can be ferromagnetic or antiferromagnetic. The compound shows large relaxation (14% change in magnetisation in 60 min) in the field cooled state with a logarithmic time variation, which may be connected to the competing magnetic correlations observed in our theoretical calculations. The competing magnetic ground states are equally evident from the small value of the paramagnetic Curie-Weiss temperature.
RESUMEN
Iridium-based double perovskites having mixed 3d-5d-4fmagnetic sub-lattices are expected to exhibit exotic magnetic phenomenon. In this paper, we report a study of structural, magnetic and transport properties of the mixed 3d-5d-4fdouble perovskite Sm2CoIrO6(SMCO), which crystallizes in monoclinic structure with space groupP21/nand the crystal symmetry remains same throughout the measured temperature down to 15 K. High resolution synchrotron x-ray diffraction reveals an isostructural phase transition around 104 K. Magnetization measurements on polycrystalline samples indicate that SMCO orders ferrimagnetically atTFiM= 104 K; while, a second transition is observed below 10 K due to the rare-earth (Sm3+) ordering. The ferrimagnetic transition is well-understood by Néel's two-sublattice model, which is primarily ascribed to antiferromagnetic coupling between Co2+and Ir4+sub-lattices. Electronic transport measurement shows the insulting behaviour of SMCO, which follows Mott variable-range hopping conduction mechanism. However, dielectric measurements as a function of temperature rules out the presence of magneto dielectric coupling in this compound.
RESUMEN
Polycrystalline Nd2CoIrO6 double perovskite crystallizes in monoclinic crystal structure with P21/n space group. The average grain size of powder sample is 400-500 nm. The dielectric, impedance and ac conductivity of the sample were studied in the temperature range 5-300 K and in the frequency range 20 Hz-2 MHz. Dielectric constant reveals a step like increase from low temperature value of â¼5 to colossal value of â¼104 at high temperature. High value of dielectric constant is associated with Maxwell-Wagner polarization due to large grain boundary capacitance. Cations (Co2+ and Ir4+) disorder leads to variable range hopping conduction of electrons in grain and grain boundary regions. Distribution of grain size induces distribution of relaxation time as confirmed from depressed semicircles in Nyquist plots. Frequency dependent conductivity follows universal power law behavior.
RESUMEN
La2CuIrO6 is a spin-orbit coupled Mott insulator, and shows a transition to noncollinear antiferromagnetic state from paramagnetic state below 74 K, and further into a weak ferromagnetic state below 54 K. Despite having two different magnetic phases, the La2CuIrO6 compound does not exhibit exchange bias phenomenon. In this present work, we report an experimental investigation on the structural and magnetic properties of the double perovskite compound La2Cu0.9Cr0.1IrO6 through high-resolution synchrotron x-ray diffraction, x-ray absorption near edge structure (XANES), and temperature and field-dependent magnetization measurements. Powder x-ray diffraction analysis reveals that the sample crystallizes in triclinic structure (space group P [Formula: see text]) alike parent La2CuIrO6 compound, while XANES measurements rule out the possibility of valence state alteration between constituting elements in this sample. Interestingly, La2Cu0.9Cr0.1IrO6 compound is found to exhibit ferromagnetic cluster glass behavior, where field-cooled magnetization undergoes two ferromagnetic transitions. A significant enhancement of ferromagnetic component is also evident from hysteresis loop study, which is likely associated with the electron hopping between J eff = 1/2 pseudospin state of Ir4+ ions and empty eg-orbital of Cr3+ ions. Exclusively, this Cr-doped compound exhibits exchange bias effect, which is related to the complex interfacial exchange coupling between the ferromagnetic clusters and the host antiferromagnetic matrix.
RESUMEN
Rare earth based cobalt-ruthenium double perovskites A2CoRuO6 (A = La, Pr, Nd and Sm) were synthesized and investigated for their structural and magnetic properties. All the compounds crystallize in the monoclinic P21/n structure with the indication of antisite disorder between Co and Ru sites. While La compound is already reported to have an antiferromagnetic state below 27 K, the Pr, Nd and Sm systems are found to be ferrimagnetic below [Formula: see text], 55 and 78 K respectively. Field-dependent magnetization data indicate prominent hysteresis loop below [Formula: see text] in the samples containing magnetic rare-earth ions, however, magnetization does not saturate even at the highest applied fields. Our structural analysis indicates strong distortion in the Co-O-Ru bond angle, as La3+ is replaced by smaller rare-earth ions such as Pr3+ , Nd3+ , and Sm3+ . The observed ferrimagnetism is possibly associated with the enhanced antiferromagnetic superexchange interaction in the Co-O-Ru pathway due to bond bending. The Pr, Nd and Sm samples also show the small magnetocaloric effect with the Nd sample showing the highest value of magnitude â¼3 J kg-1K-1 at 50 kOe. The change in entropy below 20 K is found to be positive in the Sm sample as compared to the negative value in the Nd counterpart.
RESUMEN
Sc2Cu2O5 is a non centro-symmetric oxide comprising of zig-zag chains made up of Cu2+ ions in a distorted square planer coordination. We present here a combined experimental and theoretical investigation on this compound, which is based on magnetization, electron spin resonance (ESR), heat capacity as well as density functional theory (DFT) based calculations. Short range magnetic correlation prior to the long range order at [Formula: see text] K is evidenced by a broad hump like feature ([Formula: see text]43 K) found in the magnetic contribution of the heat capacity as well as by deviations from a regular Curie-Weiss behavior observed in the bulk magnetization and the Cu2+ ESR intensity. The DFT results indicate the existence of ferro-orbital ordering at the Cu-sites, which gives rise to chain like arrangements of Cu ions along the crystallographic b axis. It also signifies complex nature of the spin structure with nonuniform magnetic interactions along the zig-zag chains. The ground state energy is found to be minimum for ferromagnetically coupled spin-dimers along the chains, whereas the adjacent chains are themselves antiferromagnetically coupled. The experimentally observed short range magnetic correlations possibly arise due to this chain like structure.
RESUMEN
Application of hydrostatic pressure under adiabatic conditions causes a change in temperature in any substance. This effect is known as the barocaloric effect and the vast majority of materials heat up when adiabatically squeezed, and they cool down when pressure is released (conventional barocaloric effect). There are, however, materials exhibiting an inverse barocaloric effect: they cool when pressure is applied, and they warm when it is released. Materials exhibiting the inverse barocaloric effect are rather uncommon. Here we report an inverse barocaloric effect in the intermetallic compound La-Fe-Co-Si, which is one of the most promising candidates for magnetic refrigeration through its giant magnetocaloric effect. We have found that application of a pressure of only 1 kbar causes a temperature change of about 1.5 K. This value is larger than the magnetocaloric effect in this compound for magnetic fields that are available with permanent magnets.