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1.
Bioorg Med Chem Lett ; 24(23): 5446-9, 2014 Dec 01.
Artículo en Inglés | MEDLINE | ID: mdl-25454269

RESUMEN

The natural compounds carvacrol and thymol completely prevented seizures in the 6 Hz, 32 mA partial seizure model. Carvacrol and thymol, both exhibited an ED50 = 35.8 mg/kg, ip and yielded protective indices of 5.3 and 3.4, respectively. At 44 mA current intensity, carvacrol and thymol exhibited ED50s of 88.82 mg/kg (PI = 2.15) and 73.0 mg/kg (PI = 1.65), respectively. Thymol, but not carvacrol showed partial inhibitory activity in the maximal electroshock (MES), sc Metrazol (scMET) and Corneal-kindled models. These results suggest that carvacrol and thymol are more efficacious anticonvulsants than suggested by their lower efficacies in the conventional MES and scMET tests.


Asunto(s)
Monoterpenos/uso terapéutico , Fenoles/uso terapéutico , Convulsiones/prevención & control , Timol/uso terapéutico , Animales , Anticonvulsivantes/farmacología , Cimenos , Modelos Animales de Enfermedad , Desempeño Psicomotor/efectos de los fármacos
2.
Polymers (Basel) ; 16(20)2024 Oct 10.
Artículo en Inglés | MEDLINE | ID: mdl-39458690

RESUMEN

This paper presents research aimed at laboratory experiments on static and cyclic fatigue testing of low-density polyethylene (LDPE) recovered from post-consumer waste in order to develop a recycled product exhibiting satisfactory mechanical and thermo-mechanical properties. The results of the cyclic fatigue tests set up to 80% of the maximum load in static tensile testing demonstrated satisfactory functionality of the recycled material developed by using the injection molding process. There was no significant change in the tensile strength under static and cyclic fatigue tests. Under cyclic loading, there was a quasi-static effect manifested by plastic deformation, and the displacement increased significantly. The static and cyclic tensile tests indicated improvement in the mechanical performance of the recycled LDPE as compared to the virgin material, owing to the high quality of the regranulates. Fourier Transform Infrared Spectroscopy (FTIR) was conducted to analyze the functional groups in virgin and recycled LDPE samples. The analysis showed no significant change in the transmittance spectra. The thermal degradation performance was also analyzed by Differential Scanning Calorimetry (DSC) and Dynamic Mechanical Analysis (DMA). The results were quite similar for both virgin and recycled LDPE.

3.
Polymers (Basel) ; 16(11)2024 Jun 03.
Artículo en Inglés | MEDLINE | ID: mdl-38891534

RESUMEN

This article is focused on the experimental study of flexural properties in different multi-layer carbon fiber-reinforced polymer (CFRP) composites and correlations with the results of finite element method (FEM) simulations of mechanical properties. The comparison of the results shows the possibility of reducing the number of experimental specimens for testing. The experimental study of flexural properties for four types of carbon fiber-reinforced polymer matrix composites with twill weaves (2 × 2) was carried out. As input materials, pre-impregnated carbon laminate GG 204 T and GG 630 T (prepreg) and two types of carbon fiber fabrics (GG 285 T and GG 300 T (fabric)) were used. Multi-layer samples were manufactured from two types of prepregs and two types of fabrics, which were hand-impregnated during sample preparation. The layers were stacked using same orientation. All specimens for flexural test were cut with the longer side in the weft direction. Pre-impregnated carbon laminates were further impregnated with resin DT 121H. Carbon fabrics were hand-impregnated with epoxy matrix LG 120 and hardener HG 700. To fulfill the aim of this research, finite element method (FEM)-based simulations of mechanical properties were performed. The FEM simulations and analysis were conducted in Hexagon's MSC Marc Mentat 2022.3 and Digimat 2022.4 software. This paper presents the results of actual experimental bending tests and the results of simulations of bending tests for different composite materials (mentioned previously). We created material models for simulations based on two methods-MF (Mean Field) and FE (Finite Element), and the comparative results show better agreement with the MF model. The composites (GG 285 T and GG 300 T) showed better flexural results than composites made from pre-impregnated carbon laminates (GG 204 T and GG 630 T). The difference in results for the hand-impregnated laminates was about 15% higher than for prepregs, but this is still within an acceptable tolerance as per the reported literature. The highest percentage difference of 14.25% between the simulation and the real experiment was found for the software tool Digimat FE 2022.4-GG 630 T composite. The lowest difference of 0.5% was found for the software tool Digimat MF 2022.4-GG 204 T composite. By comparing the results of the software tools with the results of the experimental measurements, it was found that the Digimat MF 2022.4 tool is closer to the results of the experimental measurements than the Digimat FE 2022.4 tool.

4.
Materials (Basel) ; 17(2)2024 Jan 15.
Artículo en Inglés | MEDLINE | ID: mdl-38255598

RESUMEN

Green methanol, ethanol, and diesel-based hydrotreated vegetable oils are some of the renewable liquid fuels that show satisfactory performance in diesel engines. A notable advantage of these fuels is that they are renewable and do not require significant modifications in the existing engines for successful operation. Suitable fuel systems, especially their material compatibility, remain unresolved, and therefore, it is a weak link in their large-scale adaptation. Elastomer-based sealing O-rings lose their mechanical properties after a short exposure time to these fuels, adversely impacting their functionality. This research study evaluated the long-term material compatibility of different elastomer-based sealing materials by immersing the O-rings in these test fuels (hydrotreated vegetable oil, methanol, ethanol, and diesel) for different time intervals (i.e., up to 15 months). The material compatibility was assessed mainly by investigating these changes in various mechanical properties of these O-rings, namely tensile strength (ΔTs), elongation at break (ΔEb), Shore A hardness (ΔH), and mass (ΔM). The degradation of mechanical properties was studied and analyzed during the immersion interval from 0.9 to 15.2 months and compared with O-rings kept in a normal atmosphere. It was noted that individual fuels affect various mechanical properties significantly. In a short interval of 0.9 months (28 days), significant changes in the mechanical properties of the sealing O-rings were observed.

5.
Polymers (Basel) ; 16(5)2024 Mar 01.
Artículo en Inglés | MEDLINE | ID: mdl-38475355

RESUMEN

This article focuses on the computational analysis of sandwich composite materials based on polypropylene, polyester, glass, and cotton fibers. In the automotive components prepared from these fiber materials, the various components are used in different proportions. Through the manufacturing process, isotropic materials become somewhat anisotropic. Part of this article is aimed at obtaining input values of material characteristics for calculations using finite element analysis (FEM) and the comparison of experimental results with FEM-based material models created using the Digimat 2023.1 software. This article analyzes the modeling of two-phase as well as multiphase composite materials. This work focuses on calculations using FEM according to the test defined in the PR375 standard for loading the finished product in the luggage compartment of a car. The defined methodology enables the application of the FEM-based calculation directly to the product design in the initial phase of research. The construction and production of expensive prototypes and the subsequent production of automotive parts is replaced by computer-based simulation. This procedure makes it possible to simulate several optimization cycles over a relatively shorter time. From the results of computational simulations, it is clear that materials based on PP/PET/glass fibers show a much higher modulus of elasticity than materials created using cotton, i.e., materials of the PP/PET/cotton type. In order to achieve a high strength and stiffness, it is, therefore, appropriate to use glass fibers in the composite materials used for such applications.

6.
Materials (Basel) ; 17(2)2024 Jan 14.
Artículo en Inglés | MEDLINE | ID: mdl-38255580

RESUMEN

Limited efficiency, lower durability, moisture absorbance, and pest/fungal/bacterial interaction/growth are the major issues relating to porous nonwovens used for acoustic and thermal insulation in buildings. This research investigated porous nonwoven textiles composed of recycled cotton waste (CW) fibers, with a specific emphasis on the above-mentioned problems using the treatment of silicon coating and formation of nanofibers via facile-solution processing. The findings revealed that the use of an economic and eco-friendly superhydrophobic (contact angle higher than 150°) modification of porous nonwovens with silicon nanofibers significantly enhanced their intrinsic characteristics. Notable improvements in their compactness/density and a substantial change in micro porosity were observed after a nanofiber network was formed on the nonwoven material. This optimized sample exhibited a superior performance in terms of stiffness, surpassing the untreated samples by 25-60%. Additionally, an significant enhancement in tear strength was observed, surpassing the untreated samples with an impressive margin of 70-90%. Moreover, the nanofibrous network of silicon fibers on cotton waste (CW) showed significant augmentation in heat resistance ranging from 7% to 24% and remarkable sound absorption capabilities. In terms of sound absorption, the samples exhibited a performance comparable to the commercial standard material and outperformed the untreated samples by 20% to 35%. Enhancing the micro-roughness of fabric via silicon nanofibers induced an efficient resistance to water absorption and led to the development of inherent self-cleaning characteristics. The antibacterial capabilities observed in the optimized sample were due to its superhydrophobic nature. These characteristics suggest that the proposed nano fiber-treated nonwoven fabric is ideal for multifunctional applications, having features like enhanced moisture resistance, pest resistance, thermal insulation, and sound absorption which are essential for wall covers in housing.

7.
Heliyon ; 10(4): e26704, 2024 Feb 29.
Artículo en Inglés | MEDLINE | ID: mdl-38434044

RESUMEN

This work investigates the effect of varying the knitting structure and stitch length (SL) on various thermo-physiological and ergonomic comfort properties of the occupational graduated compression socks. Thermo-physiological comfort, ergonomic comfort and dimensional stability of theses stockings were analysed in a comparative manner. Obtained results were evaluated statistically using the technique of analysis of variance (ANOVA). A Fisher's multiple comparison test was commissioned to analyze the relationship between the alteration of stitch length (SL) on various utility functions and properties desired in the occupational compression socks. In order to examine whether the difference of stitch length is significant, p values were determined. Further the influence of knitting structures e.g., plain, 2 × 2 Rib and 1 × 3 Rib was analysed on the selected properties. The interactive effect of both stitch length (SL) and knitting structure was studied using statistical techniques. It was concluded that knitting structure has a stronger impact on thermo-physiological and ergonomic comfort properties. Results showed a significant variation in thermo-physiological and ergonomic comfort by altering stitch length by means of the statistical analysis. An innovative approach for the manufacturers has been developed for optimizing performance in compression stockings. The construction of the compression socks can thus be optimized in terms of constructional parameters to provide optimum comfort to the users.

8.
Polymers (Basel) ; 15(4)2023 Feb 06.
Artículo en Inglés | MEDLINE | ID: mdl-36850092

RESUMEN

Textile-reinforced structural composites are a major discipline of modern-day research and development [...].

9.
Materials (Basel) ; 16(21)2023 Oct 27.
Artículo en Inglés | MEDLINE | ID: mdl-37959502

RESUMEN

This paper presents an experimental study on the influence of alkaline environments on natural fibers of plant and mineral origin in concretes. The durability of concrete-based composite materials is influenced by the properties of the reinforcing fiber, and the serviceability of concrete is dependent on its durability. The aim of the present study is to investigate the strength, weight loss %, and surface degradation of jute, sugarcane, coconut, sisal, as well as basalt fibers through an accelerated aging method when used as reinforcements in concrete. The samples were immersed in an alkaline environment of sodium and calcium hydroxide at two different levels of pH for one week. Further, the fibers were immersed in NaOH and Ca(OH)2 solutions of 1 M, 2 M, 4 M, and 6 M concentrations for 48 h in order to investigate the gradual effect of an alkaline environment on the mechanical properties of the fiber. It was concluded that the weight loss % was greatest for jute fibers when used in concrete composite, while there was no significant effect on the basalt fiber samples. The strength of jute fiber in the concrete sample was also most severely affected by the aging process, compared to other fibers. The strength of basalt fibers in a concrete composite was least affected by the aging process. In some cases, the sisal fiber sample showed an increase in fiber tenacity after the aging process due to fibrillation, which might have increased the interfacial area. The fiber microstructure before and after the aging was evaluated through the use of scanning electron microscopy (SEM). SEM analyses of different fibers were carried out to investigate surface degradation. The fiber pull-out strength was found to be the greatest for basalt fiber, followed by jute and sisal. This is indicative of the excellent adhesion of such fibers with cement in a concrete composite. In these cases, the use of sisal fiber results in defibrillation and increased specific surface area. Sugarcane and coconut fibers ruptured due to their inherent weakness and provided only a small increment in the mechanical performance of the concrete. Basalt fiber-reinforced concrete offered the greatest compressive strength, followed by jute and sisal. These observations provide crucial information regarding the durability and aging of natural fiber-reinforced concrete.

10.
Materials (Basel) ; 16(14)2023 Jul 08.
Artículo en Inglés | MEDLINE | ID: mdl-37512173

RESUMEN

The current work is focused on numerical and experimental studies of woven fabric composites modified by hybridisation with biological (cellulosic) filler materials. The mechanical performance of the composites is characterized under tensile, bending and impact loads and the effect of hybridisation is observed with respect to pure and nonhybrid composites. Numerical models are developed using computational tools to predict mechanical performance under tensile loading. The computational prediction results are compared and validated with relevant experimental results. This research is aimed at understanding the mechanical performance of basalt-epoxy composites partially reinforced with micro-/nano-sized bio-fillers from cellulose and intended for various application areas. Different weave structures, e.g., plain, twill, matt, etc., were investigated with respect to the mechanical properties of the hybrid composites. The effects of hybridizing with cellulose particles and different weave patterns of the basalt fabric are studied. In general, the use of high-strength fibres such as basalt along with cellulosic fillers representing up to 3% of the total weight improves the mechanical performance of the hybrid structures. The thermomechanical performance of the hybrid composites improved significantly by using basalt fabric as well as by addition of 3% weight of cellulosic fillers. Results reveal the advantages of hybridisation and the inclusion of natural cellulosic fillers in the hybrid composite structures. The material developed is suitable for high-end applications in components for construction that demand advanced mechanical and thermomechanical performance. Furthermore, the inclusion of biodegradable fillers fulfills the objectives of sustainable and ecological construction materials.

11.
Polymers (Basel) ; 15(4)2023 Feb 16.
Artículo en Inglés | MEDLINE | ID: mdl-36850277

RESUMEN

This paper presents a study conducted on prepregs manufactured by a novel method for the impregnation of a thermoplastic matrix. Different composite prepregs based on polypropylene and reinforced with natural fibers (e.g., basalt and jute fibers) were developed. The mechanical and dynamic mechanical properties were investigated. DMA tests were conducted at 1 Hz frequency and properties such as storage modulus and damping (tan δ) were evaluated. The overall mechanical properties of the basalt fiber composites were found to be superior to that of the jute fiber-based samples. Thermo-gravimetric analysis (TG/DTG) of the composite samples showed that the thermal degradation temperatures of the basalt-based composites shifted to higher temperature regions compared to the PP or jute fiber composites. The addition of basalt fiber considerably improved the thermal stability of the composite samples. Microscopic images of the tensile fractured composite samples illustrated better fiber-matrix interfacial interaction due to the novel technology of prepregs. Single-ply and 2-ply prepregs showed significantly superior mechanical, thermal, and thermo-dynamical performance compared to the control sample (pure PP). 2-Ply composites demonstrated higher modulus, tensile strength, and storage modulus due to the higher fiber volume fraction. Basalt-based samples showed a minimum weight loss of about 57% up to 700 °C in contrast to 96.05% weight loss in the jute-based samples and 98.4% in the case of pure PP. The heat resistance index (THRI) is more than twice for basalt compared to jute and PP. Furthermore, the superior thermal stability of basalt is reflected in its DSC curves, showing the highest endothermic peak. The technique of using the resin in the form of thermoplastic yarns offers cost effective and efficient alternatives for composite manufacturing.

12.
Materials (Basel) ; 16(14)2023 Jul 12.
Artículo en Inglés | MEDLINE | ID: mdl-37512230

RESUMEN

The paper deals with research focused on the use of fillers in the field of polymeric materials produced by additive technology SLA (stereolithography). The aim of the research is to evaluate 3D printing parameters, the mechanical properties (tensile strength, hardness), and the interaction of individual phases (polymer matrix and filler) in composite materials using SEM analysis. The tested fillers were cotton flakes and ground carbon fibres in different proportions. For the photosensitive resins, the use of cotton flakes as filler was found to have a positive effect on the mechanical properties not only under static but also under cyclic loading, which is a common cause of material failure in practice. The cyclic stress reference value was set at an amplitude of 5-50% of the maximum force required to break the pure resin in a static tensile test. A positive effect of fillers on the cyclic stress life of materials was demonstrated. The service life of pure resin was only 168 ± 29 cycles. The service life of materials with fillers increased to approximately 400 to 540 cycles for carbon fibre-based fillers and nearly 1000 cycles for cotton flake-based fillers, respectively. In this paper, new composite materials suitable for the use of SLA additive manufacturing techniques are presented. Research demonstrated the possibilities of adding cotton-based fillers in low-cost, commercially available resins. Furthermore, the importance of material research under cyclic loading was demonstrated.

13.
Materials (Basel) ; 16(23)2023 Nov 25.
Artículo en Inglés | MEDLINE | ID: mdl-38068090

RESUMEN

This paper investigates the development of fabric materials using several blends of inherently fire-resistant (FR) fibers and various knitted structures. The samples are evaluated with respect to their performance and comfort-related properties. Inherently fire-resistant fibers, e.g., Nomex, Protex, carbon and FR viscose, were used to develop different structures of knitted fabrics. Cross-miss, cross-relief, and vertical tubular structures were knitted by using optimum fiber blend proportions and combinations of stitches. Several important aspects of the fabric samples were investigated, e.g., their physical, mechanical and serviceability performance. Thermo-physiological and tactile/touch-related comfort properties were evaluated in addition to flame resistance performance. An analysis of mechanical performance indicated that the knitted structure has a significant influence on the tensile strength, bursting strength and pilling resistance. The cross-relief structure proved to be the strongest followed by the cross-miss and vertical tubular structures. The FR station suits made from 70:30 Protex/Nomex exhibited the best combination of tensile and bursting strength; therefore, this material is recommended for making a stable and durable station suit. Interestingly, it was also concluded from the experimental study that knitted samples with a cross-relief structure exhibit the best fire-resistance performance. Fiber blends of 70:30 Protex/Nomex and 70:30 Nomex/carbon were found to be optimum in terms of overall performance. The best flame resistance was achieved with Nomex:carbon fiber blends. These results were confirmed with vertical flammability tests, TGA, DTGA and cone calorimetry analysis. The optimization of blend composition as well as knitting structure/architecture is a crucial finding toward designing the best FR station suit in terms of mechanical, dimensional, thermal, thermo-physiological and flame resistance performance.

14.
Polymers (Basel) ; 15(7)2023 Mar 31.
Artículo en Inglés | MEDLINE | ID: mdl-37050358

RESUMEN

Current research deals with thermoplastic polyamide (PA6)-based composites reinforced with basalt and Kevlar fabrics. Hybrid composites were developed by altering the stacking sequence of basalt and two kinds of Kevlar fabrics. Pure-basalt- and pure-Kevlar-based samples were also developed for comparison purposes. The developed samples were evaluated with respect to mechanical and thermomechanical properties. Mechanical tests, e.g., tensile, flexural, and impact strength, were conducted along with thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) to ascertain the load-bearing and high-temperature stability of the hybrid composite samples vis-à-vis pure-basalt- and Kevlar-based samples. Scanning electron microscopy (SEM) was carried out to study the nature of fracture and failure of the composite samples. The pure-basalt-based PA6 thermoplastic composites exhibited the best mechanical performance. Hybridization with basalt proved to be beneficial for improving the mechanical performance of the composites using Kevlar fabrics. However, a proper stacking sequence and density of Kevlar fabric has to be selected. The thermogravimetric analysis showed minimal weight loss for basalt-based composites. Furthermore, the thermal stability of the composites using Kevlar fabric was improved by hybridization with basalt fabric. The thermomechanical characteristics of hybrid composites may be altered by changing the stacking order of the reinforcements. Differential scanning calorimetry further established that the hybrid composites with alternate layers of basalt and Kevlar can improve the heat flow rate and enable survivability at extreme temperatures. Such novel hybrid composites can be used for high-load-bearing and high-temperature applications, e.g., defense, aerospace, automotives, and energy applications.

15.
Microbiol Spectr ; 10(5): e0336822, 2022 10 26.
Artículo en Inglés | MEDLINE | ID: mdl-36190429

RESUMEN

The trace metal manganese in excess affects iron-sulfur cluster and heme-protein biogenesis, eliciting cellular toxicity. The manganese efflux protein MntP is crucial to evading manganese toxicity in bacteria. Recently, two Mn-sensing riboswitches upstream of mntP and alx in Escherichia coli have been reported to mediate the upregulation of their expression under manganese shock. As the alx riboswitch is also responsive to alkaline shock administered externally, it is intriguing whether the mntP riboswitch is also responsive to alkaline stress. Furthermore, how both manganese and alkaline pH simultaneously regulate these two riboswitches under physiological conditions is a puzzle. Using multiple approaches, we show that manganese shock activated glutamine synthetase (GlnA) and glutaminases (GlsA and GlsB) to spike ammonia production in E. coli. The elevated ammonia intrinsically alkalizes the cytoplasm. We establish that this alkalization under manganese stress is crucial for attaining the highest degree of riboswitch activation. Additional studies showed that alkaline pH promotes a 17- to 22-fold tighter interaction between manganese and the mntP riboswitch element. Our study uncovers a physiological linkage between manganese efflux and pH homeostasis that mediates enhanced manganese tolerance. IMPORTANCE Riboswitch RNAs are cis-acting elements that can adopt alternative conformations in the presence or absence of a specific ligand(s) to modulate transcription termination or translation initiation processes. In the present work, we show that manganese and alkaline pH are both necessary for maximal mntP riboswitch activation to mitigate the manganese toxicity. This study bridges the gap between earlier studies that separately emphasize the importance of alkaline pH and manganese in activating the riboswitches belonging to the yybP-ykoY family. This study also ascribes a physiological relevance as to how manganese can rewire cellular physiology to render cytoplasmic pH alkaline for its homeostasis.


Asunto(s)
Proteínas de Escherichia coli , Riboswitch , Escherichia coli/genética , Escherichia coli/metabolismo , Manganeso/toxicidad , Manganeso/química , Manganeso/metabolismo , Regulación Bacteriana de la Expresión Génica , Ligandos , Glutamato-Amoníaco Ligasa/metabolismo , Amoníaco/metabolismo , Hierro/metabolismo , Hemo/metabolismo , Azufre/metabolismo , Proteínas de Transporte de Membrana/genética , Proteínas de Escherichia coli/metabolismo
16.
Polymers (Basel) ; 14(6)2022 Mar 11.
Artículo en Inglés | MEDLINE | ID: mdl-35335464

RESUMEN

This work presents the manufacture of polymer composites using 3D woven structures (orthogonal, angle interlock and warp interlock) with glass multifilament tows and epoxy as the resin. The mechanical properties were analyzed by varying the processing parameters, namely, add-on percentage, amount of hardener, curing time, curing temperature and molding pressure, at four different levels during the composite fabrication for three different 3D woven structures. The mechanical properties of composites are affected by resin infusion or resin impregnation. Resin infusion depends on many processing conditions (temperature, pressure, viscosity and molding time), the structure of the reinforcement and the compatibility of the resin with the reinforcement. The samples were tested for tensile strength, tensile modulus, impact resistance and flexural strength. Optimal process parameters were identified for different 3D-woven-structure-based composites for obtaining optimal results for tensile strength, tensile modulus, impact resistance and flexural strength. The tensile strength, elongation at break and tensile modulus were found to be at a maximum for the angle interlock structure among the various 3D woven composites. A composition of 55% matrix (including 12% of hardener added) and 45% fiber were found to be optimal for the tensile and impact performance of 3D woven glass-epoxy composites. A curing temperature of about 140 °C seemed to be optimal for glass-epoxy composites. Increasing the molding pressure up to 12 bar helped with better penetration of the resin, resulting in higher tensile strength, modulus and impact performance. The optimal conditions for the best flexural performance in 3D woven glass-epoxy composites were 12% hardener, 140 °C curing temperature, 900 s curing time and 12 bar molding pressure.

17.
Polymers (Basel) ; 14(22)2022 Nov 15.
Artículo en Inglés | MEDLINE | ID: mdl-36433057

RESUMEN

In this paper, the fatigue behavior of polylactic acid (PLA) material with bamboo filler printed by 3D additive printing using fused deposition modelling (FDM) technology at different infill densities and print nozzle diameters is investigated. The mechanical test results are supported by the findings from SEM image analysis. The fatigue behavior was tested at four consecutive 250 cycles at loads ranging from 5 to 20, 30, 40, and 50% based on the limits found in the static tensile test. The results of the static tensile and low-cycle fatigue tests confirmed significant effects of infill density of 60%, 80%, and 100% on the tensile strength of the tested specimens. In particular, the research results show a significant effect of infill density on the fatigue properties of the tested materials. The influence of cyclic tests resulted in the strengthening of the tested material, and at the same time, its viscoelastic behavior was manifested. SEM analysis of the fracture surface confirmed a good interaction between the PLA matrix and the bamboo-based filler using nozzle diameters of 0.4 and 0.6 mm and infill densities of 60%, 80%, and 100%. Low-cycle testing showed no reductions in the mechanical properties and fatigue lives of the 3D printed samples.

18.
Polymers (Basel) ; 14(19)2022 Sep 30.
Artículo en Inglés | MEDLINE | ID: mdl-36236056

RESUMEN

This investigation deals with the prediction of mechanical behavior in basalt-fiber-reinforced concrete using the finite element method (FEM). The use of fibers as reinforcement in concrete is a relatively new concept which results in several advantages over steel-reinforced concrete with respect to mechanical performance. Glass and polypropylene (PP) fibers have been extensively used for reinforcing concrete for decades, but basalt fibers have gained popularity in recent years due to their superior mechanical properties and compatibility with concrete. In this study, the mechanical properties of basalt-fiber-reinforced concrete are predicted using FEM analysis, and the model results are validated by conducting experiments. The effect of fiber-volume fraction on the selected mechanical performance of concrete is evaluated in detail. Significant improvement is observed when the loading is increased. There are superior mechanical properties, e.g., load bearing and strain energy in basalt-fiber-reinforced concrete as compared to conventional concrete slabs reinforced with gravel or stones. The results of the simulations are correlated with experimental samples and show a very high similarity. Basalt-fiber-reinforced concrete (BFRC) offers a lightweight construction material as compared to steel-fiber-reinforced concrete (SFRC). Further, the problem of corrosion is overcome by using this novel fiber material in concrete composites.

19.
Polymers (Basel) ; 14(10)2022 May 17.
Artículo en Inglés | MEDLINE | ID: mdl-35631928

RESUMEN

This paper focuses on the comfort properties of graduated and preventive compression stockings for people who work long hours in standing postures and for athletes for proper blood circulation. The present study was conducted in order to investigate the effects of the yarn insertion density and inlaid stitches on the performance of the compression stockings. The effects of these parameters on the thermo-physiological comfort properties were tested with standard and developed methods of testing. All compression stockings were maintained with class 1 pressure as per German standards. The structural parameters of the knitted fabric structures were investigated. The stretching and recovery properties were also investigated to determine the performance properties. The theoretical pressure was predicated using the Laplace's law by testing the stockings' tensile properties. The compression interface pressures of all stockings were also investigated using a medical stocking tester (MST) from Salzmann AG, St. Gallen, Switzerland. Correlation between the theoretical pressures and pressures measured using the MST system were also assessed. The current research used a multi-response optimization technique, i.e., principal component analysis (PCA), to identify the best structure based on the optimalization of the above-mentioned properties. The results also revealed that samples with higher insertion density levels exhibit better comfort properties. The results showed that sample R1 was the best sample, followed by R2 and P. In addition, all developed stocking samples exhibited better comfort properties than the control sample from the market.

20.
Polymers (Basel) ; 14(7)2022 Mar 23.
Artículo en Inglés | MEDLINE | ID: mdl-35406175

RESUMEN

Additive production is currently perceived as an advanced technology, where intensive research is carried out in two basic directions-modifications of existing printing materials and the evaluation of mechanical properties depending on individual production parameters and the technology used. The current research is focused on the evaluation of the fatigue behavior of 3D-printed test specimens made of pure PLA and PLA reinforced with filler based on pinewood, bamboo, and cork using FDM (fused deposition modeling) technology. This research was carried out in response to the growing demand for filaments from biodegradable materials. This article describes the results of tensile fatigue tests and image analysis of the fracture surface determined by the SEM method. Biodegradable PLA-based materials have their limitations that influence their applicability in practice. One of these limitations is fatigue life, which is the cyclic load interval exceeding 50% of the tensile strength determined in a static test. Comparison of the cyclic fatigue test results for pure PLA and PLA reinforced with natural reinforcement, e.g., pinewood, bamboo, and cork, showed that, under the same loading conditions, the fatigue life of the 3D-printed specimens was similar, i.e., the filler did not reduce the material's ability to respond to low-cycle fatigue. Cyclic testing did not have a significant effect on the change in tensile strength and associated durability during this loading interval for PLA-based materials reinforced with biological filler. Under cyclic loading, the visco-elastic behavior of the tested materials was found to increase with increasing values of cyclic loading of 30%, 50% and 70%, and the permanent deformation of the tested materials, i.e., viscoelastic behavior (creep), also increased. SEM analysis showed the presence of porosity, interlayer disturbances, and at the same time good interfacial compatibility of PLA with the biological filler.

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