RESUMEN
A total of 60 children (31 males and 29 females) between the ages of 3 and 12 years were randomly selected from Lanzhou City in Gansu Province, northwest China. Hand (soil/dust) SD samples from these children were collected using hand wipes. We determined the approximate amounts of hand SD and the concentrations of three tracer soil elements (Ce, Y, and V) in these samples. The approximate amounts of hand SD ranged from 42.28 to 173.76 mg, with a median value of 85.42 mg. In addition, the mean amounts of hand SD estimated using the concentrations of Ce, Y, and V in the samples were 4.63, 3.43, and 3.42 mg, respectively. The amount of hand SD varied greatly among the age groups: primary school children had more hand SD than kindergarten children, males had more hand SD than females, and children from rural areas had more hand SD than those from urban areas. The rates of daily ingestion of hand SD for kindergarten and primary school children were estimated to be 7.73 and 6.61 mg/day, respectively.
Asunto(s)
Cerio/análisis , Polvo , Ingestión de Alimentos , Mano , Boca , Suelo , Vanadio/análisis , Itrio/análisis , Niño , Preescolar , China , Polvo/análisis , Femenino , Humanos , Masculino , Espectrometría de Masas/métodos , Factores Sexuales , Suelo/químicaRESUMEN
Antimony ï¼Sbï¼ is a major pollutant that poses a serious threat to the environment in the mining and processing of nonferrous metals, coexisting with sulfide and oxide of arsenic ï¼Asï¼. Microorganisms play an important role in the migration, transformation, and repair of metals in soil. The ecological effects of bioavailable Sb and As on the microbial community in antimony mining areasï¼mining and smelting areasï¼are still poorly understood. The Wenzel method and high-throughput 16S rDNA amplicon were used to characterize soil pollution characteristics in different functional areas, and the relationship between the bacterial community and bioavailable concentrations have been investigated comprehensively. The results showed thatï¼ Chemical speciation of Sb and As were amorphous, and poorly crystalline hydrous oxides of Fe and Al ï¼F3ï¼ > well-crystallized hydrous oxides of Fe and Al ï¼F4ï¼ > residual phases ï¼F5ï¼ > specifically adsorbed ï¼F2ï¼ > non-specifically adsorbed ï¼F1ï¼. According to the estimation of the potential ecological risk index ï¼RIï¼ and geo-accumulation index ï¼Igeoï¼, the Sb pollution degree wasï¼ smelting area > mining area > contrast area, in which the smelting area showed serious pollution, and the mining area showed moderate to severe pollution. The As pollution degree wasï¼ mining area > smelting area > contrast area, in which the mining area and smelting area showed moderate to severe pollution. High-throughput 16S rDNA amplicon showed that Proteobacteria was the most abundant phylum in mining and smelting areasï¼ Kaistobacter, Pseudomonas, Sphingomonas, and Lysobacter were the most abundant microbial generaï¼ Geobacter and Luteolibacter had a high LDA score in mining areasï¼ and Thiobacillus had a high LDA score in antimony-contaminated areas. Spearman correlation analysis, variation partitioning analysis ï¼VPAï¼, and random forest ï¼RFï¼ analysis showed that Sb, As, bioavailable antimony [Sb ï¼Bioï¼], and bioavailable arsenic [As ï¼Bioï¼]were the main factors affecting the microbial community structure in different functional areas of antimony ore. Redundancy analysis ï¼RDAï¼ indicated that Sb and its bioavailable concentrations showed uniformly negative associations with the relative abundance of bacteria Nitrospirae and showed a significant positive correlation with Thiobacillus ï¼P<0.05ï¼. The in-depth research on the ecological effects of bioavailable Sb and As on the bacterial community provides references and new perspectives for environmental monitoring and management.
Asunto(s)
Antimonio , Arsénico , Monitoreo del Ambiente , Minería , Microbiología del Suelo , Contaminantes del Suelo , China , Contaminantes del Suelo/análisis , Bacterias/clasificación , Bacterias/genéticaRESUMEN
The concentrations of As, Cd, Cr, Cu, Pb, Ni, Zn, and Hg in 128 surface soil samples from Xiangfen County, Shanxi Province, China were measured. The concentrations of these eight heavy metals were lower than the critical values in the national soil quality standard. However, these concentrations were found to be slightly higher than their background values in soils in Shanxi Province, indicating enrichment of these metals in soils in Xiangfen County, especially for Hg and Cd. Principal component analysis coupled with cluster analysis was used to analyze the data and identify possible sources of these heavy metals; the results showed that the eight heavy metals in soils from Xiangfen County came from three different sources. Lead, Cd, Cu and Zn mainly arose from agricultural practices and vehicle emissions. Arsenic and Ni arose mainly from parent materials. Industrial practices were the main sources of Cr and Hg. The spatial distribution of the heavy metals varied greatly, and was closely correlated to local anthropogenic activities. This study will be helpful not only for improving local soil environmental quality but will also provide a basis for effectively targeting policies to protect soils from long-term heavy metal accumulation.
Asunto(s)
Agricultura , Monitoreo del Ambiente/métodos , Metales Pesados/análisis , Contaminantes del Suelo/análisis , Suelo/química , China , Análisis por Conglomerados , Análisis de Componente Principal , Suelo/normas , Análisis EspacialRESUMEN
We collected and analyzed 128 surface soil samples from Xiangfen County for dichlorodiphenyltrichloroethane (DDT), dichlorodiphenyldichloroethane (DDD), and dichlorodiphenyldichloroethylene (DDE). Total DDT concentrations (DDTs; sum of p,p'-DDD, p,p'-DDE, and p,p'-DDT) ranged from ND to 427.81 ng g(-1) (dry weight, dw), with a mean of 40.26 ng g(-1) (dw). Among the three compounds, p,p'-DDD was the most dominant. The DDTs in Xiangfen County soils mainly originated from historical DDT use, but there were also new inputs likely related to dicofol use. The DDTs in Xiangfen County soils were mainly degraded under anaerobic conditions, and direct degradation to DDD was the main degradation route. Regions with relatively high concentrations of DDTs were mainly located in North and South Xiangfen County. In these regions, many soil samples contained p,p'-DDT as the predominant pollutant, suggestive of extensive new inputs of DDT. A health risk assessment revealed that there are no serious long-term health impacts of exposure to DDTs in soil, for adults or children.
Asunto(s)
DDT/análisis , Diclorodifenil Dicloroetileno/análisis , Diclorodifenildicloroetano/análisis , Neoplasias/inducido químicamente , Contaminantes del Suelo/análisis , Adulto , Niño , China , DDT/efectos adversos , Diclorodifenil Dicloroetileno/efectos adversos , Diclorodifenildicloroetano/efectos adversos , Monitoreo del Ambiente , Humanos , Insecticidas/efectos adversos , Insecticidas/análisis , Medición de Riesgo , Factores de Riesgo , Suelo/química , Contaminantes del Suelo/efectos adversosRESUMEN
The emission inventory of air pollutants from the thermal power plants in the year of 2010 was set up. Based on the inventory, the air quality of the prediction scenarios by implementation of both 2003-version emission standard and the new emission standard were simulated using Models-3/CMAQ. The concentrations of NO2, SO2, and PM2.5, and the deposition of nitrogen and sulfur in the year of 2015 and 2020 were predicted to investigate the regional air quality improvement by the new emission standard. The results showed that the new emission standard could effectively improve the air quality in China. Compared with the implementation results of the 2003-version emission standard, by 2015 and 2020, the area with NO2 concentration higher than the emission standard would be reduced by 53.9% and 55.2%, the area with SO2 concentration higher than the emission standard would be reduced by 40.0%, the area with nitrogen deposition higher than 1.0 t x km(-2) would be reduced by 75.4% and 77.9%, and the area with sulfur deposition higher than 1.6 t x km(-2) would be reduced by 37.1% and 34.3%, respectively.
Asunto(s)
Contaminantes Atmosféricos/normas , Modelos Teóricos , Centrales Eléctricas/normas , Contaminación del Aire/análisis , China , Óxido Nítrico/análisis , Material Particulado/análisis , Dióxido de Azufre/análisisRESUMEN
Ozone concentrations obtained from 35 automatic air monitoring stations in Beijing were analyzed to investigate their temporal and spatial distribution characteristics. A process with high ozone concentration in summer was analyzed. The results showed that ozone maintained relatively high concentration from May to August while in other months, the ozone concentration was at a low level. Overall, the average concentrations of ozone in different stations in a descending order were comparison and regional station, suburban environment evaluation station, urban environmental assessment station and traffic pollution monitoring station. Ozone diurnal variation showed a single peak distribution, the peak of which appeared at 15:00 or 16:00. Ozone concentration showed obvious weekend effect, which meant ozone concentration in daytime of weekend was higher than that in weekday. Ozone concentration was lower in urban Beijing, higher in surrounding counties and the highest in northeast area with more vegetation. A high ozone concentration process occurred in Beijing on June 3, 2013. Under the effect of southwest wind in the afternoon, the concentration peaks of ozone in Yufa, Fengtaihuayuan, Olympic center and Huairou station occurred in order from south to north. Concentration peak of ozone in Huairou station occurred at 20:00 in the night. It could be concluded that significant ozone transmission characteristic was reflected in this process.