RESUMEN
We have constructed a new nanomanipulator (NM) in a field emission scanning electron microscope (FE-SEM) to fabricate carbon nanotube (CNT) tip to precisely adjust the length and attachment angle of CNT onto the mother atomic force microscope (AFM) tip. The new NM is composed of 2 modules, each of which has the degree of freedom of three-dimensional rectilinear motionx,yandzand one-dimensional rotational motionθ. The NM is mounted on the stage of a FE-SEM. With the system of 14 axes in total which includes 5 axes of FE-SEM and 9 axes of nano-actuators, it was possible to see CNT tip from both rear and side view about the mother tip. With the help of new NM, the attachment angle error could be reduced down to 0° as seen from both the side and the rear view, as well as, the length of the CNT could be adjusted with the precision using electron beam induced etching. For the proper attachment of CNT on the mother tip surface, the side of the mother tip was milled with focused ion beam. In addition, electron beam induced deposition was used to strengthen the adhesion between CNT and the mother tip. In order to check the structural integrity of fabricated CNT, transmission electron microscope image was taken which showed the fine cutting of CNT and the clean surface as well. Finally, the performance of the fabricated CNT tip was demonstrated by imaging 1-D grating and DNA samples with atomic force microscope in tapping mode.
RESUMEN
A series of Ce3+ doped La1-xCexAlO3/MgO (x = 0, 0.7, 0.9, 1.0 and 2.0 mol%) nano-composites have successfully been synthesized employing the Pechini sol-gel method. XRD profiles assisted with Rietveld refinement results manifested the rhombohedral/face-centered structures of the two phases of the generated composite. Thermogravimetric results corroborate the crystallization temperature of the compound to be 900 °C, that further remains stable up to 1200 °C. Materials have been found to be wide band gap semi-conductors having Eg in the range of 5.5-5.8 eV. Photoluminescence studies reveal their green emission under UV excitation of 272 nm. Application of Dexter's theory and Burshtein model to PL and TRPL profiles, respectively reveals the q-q multipole interlinkages to be the viable cause of concentration quenching beyond optimum concentration of 0.9 mol%. Shifting of the energy transfer route from cross-relaxation to migration assisted mechanism with Ce3+ concentration has also been investigated. Other luminescence based parameters such as energy transfer probabilities, efficiencies, CIE and CCT have also been found to be in an admirable range. From the aforesaid results, it was observed that the optimized nano-composite (i.e. La1-xCexAlO3/MgO (x = 0.9 mol%)) can also be utilized for latent finger-printing (LFP) application that evinces its versatility for photonic as well as imaging applications.