Human exposure to endocrine-disrupting organochlorine and organophosphate pesticides in locally produced and imported honey in Nigeria.

The practice of exposing honeybees to pesticides by bee-keepers or via agricultural crops, is one of the ways in which honey becomes contaminated with pesticides. Though honey has many health advantages, however, human exposure to pesticides via consumption of honey has generated public health concerns due to their endocrine-disruptive abilities. Thus, this study evaluated human exposure to endocrine-disrupting pesticides in honey from Nigeria to establish the safety of honey consumed in Nigeria. Honey were analyzed for pesticides using a gas chromatograph combined with an electron capture detector. The concentrations of ∑20 OCPs and ∑14 OPPs in the honey ranged from 0.45-1045 ng/g and 1.13-632 ng/g respectively. The values of both individual and cumulative non-carcinogenic and carcinogenic risks for humans were <1 and 1 × 10-4 respectively suggesting that there are no potential health risks via the honey consumption. The source analysis showed that pesticides in these honey originated from historical and recent/fresh use.

Comparative study of zinc oxide nanocomposites with different noble metals synthesized by biological method for photocatalytic disinfection of Escherichia coli present in hospital wastewater.

Binary zinc oxide (ZnO) nanocomposites with different noble metals, silver (Ag) and ruthenium (Ru), were prepared from an aqueous leaf extract of Callistemon viminalis. The biosynthesized photocatalysts were characterized and examined for their photocatalytic disinfection against Escherichia coli isolated from hospital wastewater. The influence of the different noble metals showed a difference in physicochemical characteristics and photocatalytic efficiency between Ag-ZnO and Ru-ZnO. The photocatalytic degradation of methylene blue and photocatalytic disinfection were found to be in the order Ag-ZnO > Ru-ZnO > ZnO. The photocatalytic disinfection of Ag-ZnO reached a 75% reduction in 60 min, compared to 34 and 9% reductions of Ru-ZnO and ZnO, respectively. The kinetic reaction rate for the photocatalytic disinfection of Ag-ZnO was found to be 2.8 times higher than that of Ru-ZnO. The outstanding photocatalytic activity of Ag-ZnO over Ru-ZnO was attributed to higher crystallinity, greater UVA adsorption capacity, smaller particle size, and the additional antimicrobial effect of Ag itself. The C. viminalis-mediated Ag-ZnO nanocomposites can be a potential candidate for photocatalytic disinfection of drug-resistant E. coli in hospital wastewater.

Adaptive Robust Trajectory Tracking Control of Multiple Quad-Rotor UAVs with Parametric Uncertainties and Disturbances.

Recently, formation flying of multiple unmanned aerial vehicles (UAVs) found numerous applications in various areas such as surveillance, industrial automation and disaster management. The accuracy and reliability for performing group tasks by multiple UAVs is highly dependent on the applied control strategy. The formation and trajectories of multiple UAVs are governed by two separate controllers, namely formation and trajectory tracking controllers respectively. In presence of environmental effects, disturbances due to wind and parametric uncertainties, the controller design process is a challenging task. This article proposes a robust adaptive formation and trajectory tacking control of multiple quad-rotor UAVs using super twisting sliding mode control method. In the proposed design, Lyapunov function-based adaptive disturbance estimators are used to compensate for the effects of external disturbances and parametric uncertainties. The stability of the proposed controllers is guaranteed using Lyapunov theorems. Two variants of the control schemes, namely fixed gain super twisting SMC (STSMC) and adaptive super twisting SMC (ASTSMC) are tested using numerical simulations performed in MATLAB/Simulink. From the results presented, it is verified that in presence of disturbances, the proposed ASTSMC controller exhibits enhanced robustness as compared to the fixed gain STSMC.

Utilization of Cassava Wastewater for Low-Cost Production of Prodigiosin via Serratia marcescens TNU01 Fermentation and Its Novel Potent α-Glucosidase Inhibitory Effect.

The purpose of this study was to reuse cassava wastewater (CW) for scaled-up production, via the fermentation of prodigiosin (PG), and to conduct an evaluation of its bioactivities. PG was produced at the yield of high 6150 mg/L in a 14 L-bioreactor system, when the designed novel medium (7 L), containing CW and supplemented with 0.25% casein, 0.05% MgSO4, and 0.1% K2HPO4, was fermented with Serratia marcescens TNU01 at 28 °C in 8 h. The PG produced and purified in this study was assayed for some medical effects and showed moderate antioxidant, high anti-NO (anti-nitric oxide), and potential α-glucosidase inhibitory activities. Notably, PG was first reported as a novel effective α-glucosidase inhibitor with a low IC50 value of 0.0183 µg/mL. The commercial anti-diabetic drug acarbose was tested for comparison and had a lesser effect with a high IC50 value of 328.4 µg/mL, respectively. In a docking study, the cation form of PG (cation-PG) was found to bind to the enzyme α-glucosidase by interacting with two prominent amino acids, ASP568 and PHE601, at the binding site on the target enzyme, creating six linkages and showing a better binding energy score (-14.6 kcal/mol) than acarbose (-10.5 kcal/mol). The results of this work suggest that cassava wastewater can serve as a low-cost raw material for the effective production of PG, a potential antidiabetic drug candidate.

Forest Cover Change and Ecosystem Services: A Case Study of Community Forest in Mechinagar and Buddhashanti Landscape (MBL), Nepal.

The community-based forest management program has been successful in the conservation of forest cover in Nepal. We investigated forest cover change for the Mechinagar and Buddhashanti Landscape (MBL) area within the Jhapa district, Nepal, during 1990-2019 using Landsat images and GIS tools and valuated the major ecosystem services (ES) of Kalika Community-managed Forest (KCF) within the MBL landscape using the economic approach-market price method (revealed price). Land cover analysis of the MBL area indicated that over the study period, there were increases in urban/built-up areas, forest, and tea plantations, and declines in cultivated land, shrub, barren land, water body, and grassland areas. In particular, forest cover increased by 8.6% from 41.5 sq.km to 45.1 sq.km, due to the conversion of 3.9 sq.km cultivated land and 2.4 sq.km shrub into forest cover. KCF, the selected case study area for ES valuation, has been successful in providing noticeable economic benefits from provisioning and cultural services. Of the provisioning services, wood and timber make the largest contribution with an average revenue collection of Nepali Rupees (NRs) 3091.4 thousands followed by non-timber forest products (NRs 883.1 thousands) and firewood (NRs 524.3 thousands), respectively, while ecotourism-based income is also important (NRs 458.4 thousands) and is increasing in later years. As monitoring forest cover in a rapidly changing landscape and evaluating the ES of the community-managed forest cover are imperative for sustainable environmental planning and policy formulation, these research outputs are expected to be a significant benchmark for planners, policy makers, and future researchers.

Current trends and prospects of tidal energy technology.

Generation of energy across the world is today reliant majorly on fossil fuels. The burning of these fuels is growing in line with the increase in the demand for energy globally. Consequently, climate change, air contamination, and energy security issues are rising as well. An efficient alternative to this grave hazard is the speedy substitution of fossil fuel-based carbon energy sources with the shift to clean sources of renewable energy that cause zero emissions. This needs to happen in conjunction with the continuing increase in the overall consumption of energy worldwide. Many resources of renewable energy are available. These include thermal, solar photovoltaic, biomass and wind, tidal energy, hydropower, and geothermal. Notably, tidal energy exhibits great potential with regard to its dependability, superior energy density, certainty, and durability. The energy mined from the tides on the basis of steady and anticipated vertical movements of the water, causing tidal currents, could be converted into kinetic energy to produce electricity. Tidal barrages could channel mechanical energy, while tidewater river turbines can seize the energy from tidal currents. This study discusses the present trends, ecological effects, and the prospects for technology related to tidal energy.

Correction to: Assessment of natural radioactivity in coals and coal combustion residues from a coal-based thermoelectric plant in Bangladesh: implications for radiological health hazards.

The original version of this article unfortunately contained an error in eq. 1. The denominator Ɛ of Eq. (1) was missing.

Suitability of municipal solid waste in African cities for thermochemical waste-to-energy conversion: The case of Harare Metropolitan City, Zimbabwe.

The recovery of energy from municipal solid waste (MSW) has gained popularity in many industrialized countries, but its adoption in economically developing countries, especially in Africa, has been slow. While capital investments and technical requirements for waste-to-energy (WtE) systems are among the most important causes for this slow adoption, the unavailability of data on the thermochemical quality of MSW as a potential feedstock for energy recovery is also a limiting factor. In this paper, Harare, a typical African city, was selected as a case study. The evaluation was based on the analysis of the MSW's composition, moisture as-discarded, thermochemical properties and energy content. The results show that the quality of the MSW is comparable to that in regions outside Africa where WtE has been a success. The combustible fraction exceeded 75 wt% making it ideal for thermal treatment without requiring supplementary fuel. With an MSW throughput of 421,757 tonnes year-1 (11.1% of which is recycled), and a lower heating value of 10.1 MJ kg-1, the energetic potential was estimated at 3.8 × 106 GJ. MSW thermal treatment via conventional technologies can reduce the waste throughput to landfills by up to 40%, provide up to 112 GWh year-1 of electrical energy, and increase the annual share of electrical energy produced from bio-fuels and wastes from 1.3% to at least 2.2%. These benefits make thermal MSW treatment a suitable option for waste disposal in African cities.

Assessment of natural radioactivity in coals and coal combustion residues from a coal-based thermoelectric plant in Bangladesh: implications for radiological health hazards.

To study the level of radioactivity concentrations from a coal-based power plant (Barapukuria, Bangladesh) and to estimate the associated radiological hazards, coal and associated combustion residuals from the power plant were analyzed by gamma-ray spectrometry with high-purity germanium (HPGe) detector. The results reveal that the mean radioactivity (Bq kg-1) concentrations in feed coal samples are 66.5 ± 24.2, 41.7 ± 18.2, 62.5 ± 26.3, and 232.4 ± 227.2 for U-238, Ra-226, Th-232, and K-40, respectively, while in coal combustion residuals (CCRs), they are 206.3 ± 72.4, 140.5 ± 28.4, 201.7 ± 44.7, and 232.5 ± 43.8, respectively. With the exception of K-40, all the determined natural radionuclides are considerably higher in the investigated feed coal and associated combustion residues as compared with the world soil and world coal mean activities. On the average, CCRs contains 3.10-3.37 times more natural radionuclides than the feed coal, except for K-40. The radioactivity of fly ash and bottom ash is fractionated, and ratio ranges from 1.40 to 1.57. The mean values of the radiological hazard indices in the coal and their associated residuals are 153.1 and 446.8 Bq kg-1 for radium equivalent activity, 0.41 and 1.21 for the external hazard index, 70 and 200.1 nGy h-1 for the absorbed gamma dose rate, 0.09 and 0.25 mSv year-1 for the annual effective dose rate, and 3.0 × 10-4 and 8.6 × 10-4 Sv-1 for the excess lifetime cancer risk, respectively, most of which exceed the UNSCEAR-recommended respective threshold limits. The outcome of this study suggests a potential radiological threat to the environment as well as to the health of occupational workers and nearby inhabitants from the examined samples.

Blockchain Technology Application Challenges in Renewable Energy Supply Chain Management.

With the advent of new technologies and globalization of business, supply chains have turned into indispensable tools for gaining competitive advantage. The application of new technologies like blockchain can benefit sustainable energy supply chains by improving chain and logistics operations in the areas of trust, transparency and accountability, cooperation, information sharing, financial exchanges, and supply chain integration. However, the efforts to adopt such technologies in supply chains tend to face many challenges and challenges, which can seriously threaten their success. Therefore, it is crucial to carefully examine the challenges to blockchain technology application. This research focuses on identifying the criteria and challenges to the application of blockchain in renewable energy supply chains and also ranks the identified challenges in terms of their capacity to disrupt the process. The applicability of the suggested structure is examined in a case study of the renewable energy supply chain of Iran. In this study, the challenges are evaluated and ranked by the hybrid developed methods by the integration of the concept of gray numbers into the gray stepwise weight assessment ratio analysis (SWARA-Gray) and the gray evaluation based on distance from average solution (EDAS-Gray). Another group of hybrid methods including the gray weighted sum method (WSM-Gray), the gray complex proportional assessment (COPRAS-Gray), and the gray technique for order of preference by similarity to ideal solution (TOPSIS-Gray) is used to validate the results. The rankings obtained from all of these techniques show high degree of correlation. Among the identified challenges, "high investment cost" is found to be the most important challenge to the application of blockchain in sustainable energy supply chains.

Environmental and Human Microbiome for Health.

Microorganisms are an essential part of life on the earth and can exist in association with virtually any living thing. The environmental microbiome is much more diverse than the human microbiome. It is reported that most microbes existing in the environment are difficult to culture in the laboratory. Whereas both pathogenic and beneficial microbes may be prevailing in the environment, the human body can have three categories of microbes- beneficial, pathogenic, and opportunistic pathogenic. With at least 10-fold more cells than human cells, microbes as normal flora are critical for human survival. The microbes present in the human body play a crucial role in maintaining human health, and the environmental microbiome influences the human microbiome makeup. The interaction between the environmental and human microbiome highly influences human health, however it is poorly understood. In addition, as an established infection is associated with health-seeking behavior, a large number of studies have focused on the transmission and dynamics of infectious microorganisms than the noninfectious or beneficial ones. This review will summarize how the interaction between the environmental and human microbiome affects human health and identify approaches that might be beneficial for humans to improve health by being exposed to the natural environment.

Valorization of rubberwood sawdust and sewage sludge by pyrolysis and co-pyrolysis using agitated bed reactor for producing biofuel or value-added products.

This study investigated experimentally pyrolysis of rubberwood sawdust (RWS), sewage sludge (SS), and their blends (25:75, 50:50, and 75:25 by weight) in an agitated bed pyrolysis reactor. The yields and characteristics of liquid product and biochar were determined for pyrolysis at 450, 500, and 550 °C and were affected both by temperature and feedstock type. The liquid and biochar yields were in the ranges 27.30-52.42 and 21.43-49.66 (wt%). Pyrolysis of RWS at 550 °C provided the highest liquid yield, while SS gave a high biochar yield. Co-pyrolysis of SS with RWS improved yield and quality of liquid and biochar products. The liquid product had 57.54-70.70 wt% of water and a low hydrocarbon content. The higher heating value (HHV) of water-free liquid product was 14.73-22.45 MJ/kg. The major compounds of liquid product included acetic acid, 2-propanone, 1-hydroxy, and phenols according to GC-MS. The biochar from RWS had a high carbon content (83.37 wt%) and a high HHV (33.57 MJ/kg), while SS biochar was mainly ash (67.62 wt%) with low carbon content. The SS biochar also had high contents of Si, Ca, Fe, K, and Mg as determined by XRF. Co-pyrolysis of SS with RWS improved the biochar by increasing its carbon content and reducing ash and inorganic elements. The surface of RWS biochar was more porous, while SS biochar had the larger specific surface according to SEM and BET. Based on these results, co-pyrolysis of 75:25 feedstock mix is recommended for further studies on applications of liquid product and biochar.

Phthalate Esters in Tap Water, Southern Thailand: Daily Exposure and Cumulative Health Risk in Infants, Lactating Mothers, Pregnant and Nonpregnant Women.

Human exposure to phthalate esters (PAEs) via drinking water has generated public health concerns due to their endocrine disruptive abilities. This study reports on the occurrence and fate of six PAEs in raw and tap water samples collected from provincial waterworks located in Songkhla Province, Southern Thailand. In addition, the daily exposure and cumulative health risk of susceptible populations due to drinking tap water were evaluated by using four different reference dose (RfDs) sources. The maximum concentrations of PAEs in raw water were between 1.68 and 4.84 and 0.52 and 1.24 µg/L in tap water. Moreover, the levels of PAEs in the tap water samples indicated the poor PAEs removal efficiency of the conventional treatment process (59.9-69.1%). The contribution of water to the daily intake of PAEs did not exceed 0.37% in all the groups. Furthermore, both the individual and cumulative risk assessment showed negligible noncarcinogenic and antiandrogenic risk for all the groups. Nevertheless, the cumulative risk showed an increasing trend in the order of infants > lactating mothers > pregnant women > nonpregnant women, suggesting that infants are more vulnerable. In additional, the newly proposed RfDAA yielded higher hazard quotient and hazard index estimates, which indicates it is a more sensitive tool than other RfDs for the assessment of the individual and mixture risk of pollutants. The carcinogenic risk of DEHP was acceptable in every group. However, we recommend a future cumulative risk assessment of vulnerable groups considering their simultaneous exposure to all chemicals that have antiandrogenic effects via tap water.

Environmental geochemistry of higher radioactivity in a transboundary Himalayan river sediment (Brahmaputra, Bangladesh): potential radiation exposure and health risks.

This study of a downstream segment (Brahmaputra, Bangladesh) of one of the longest transboundary (China-India-Bangladesh) Himalayan rivers reveals elevated radioactivity compared to other freshwater basins across the world. Naturally occurring radioactive nuclides (226Ra, 232Th, and 40K) and metal contents (transition metals, Fe, Ti, Sc, and V; rare earth elements, La, Ce, Eu, Sm, Dy, Yb, and Lu; high field strength elements, Ta and Hf; and actinides, Th and U) in thirty sediment samples were measured by HPGe γ-spectrophotometry and research reactor-based neutron activation analysis, respectively. We systematically investigated the mechanism of the deposition of higher radioactivity concentrations and rare earth elements (REEs) associated with heavy minerals (HMs) and photomicrograph-based mineralogical analysis. The results show that total REEs (∑REE) and Ta, Hf, U, and Th are generally 1.5- to 3.0-fold elevated compared to crustal values associated with -δEu and -δCe anomalies, suggesting a felsic source provenance. The enrichment of light REEs (×1.5 upper continental crust (UCC)) and Th (×1.9 UCC), besides Th/U (=7.74 ± 2.35) and 232Th/40K ratios, along with the micrographic and statistical approaches, revealed the elevated presence of HMs. Fluvial suspended sedimentary transportation (from upstream) followed by mineralogical recycling and sorting enriched the HM depositions in this basin. Bivariate plots, including La/Th-Hf, La/Th-Th/Yb, and La/V-Th/Yb, revealed significant contributions of felsic source rock compared to mafic sources. The assessment of radiological hazards demonstrates ionizing-radiation-associated health risks to the local residents and people inhabiting houses made from Brahmaputra River sediments (as construction material).

Numerical Simulation of the Performance of Sb2Se3 Solar Cell via Optimizing the Optoelectronic Properties Based SCAPS-1D.

Antimony trisulfide (Sb2Se3), a non-toxic and accessible substance, has possibilities as a material for use in solar cells. The current study numerically analyses Sb2Se3 solar cells through the program Solar Cell Capacitance Simulator (SCAPS). A detailed simulation and analysis of the influence of the Sb2Se3 layer's thickness, defect density, band gap, energy level, and carrier concentration on the devices' performance are carried out. The results indicate that a good device performance is guaranteed with the following values in the Sb2Se3 layer: an 800 optimal thickness for the Sb2Se3 absorber; less than 1015 cm-3 for the absorber defect density; a 1.2 eV optimum band gap; a 0.1 eV energy level (above the valence band); and a 1014 cm-3 carrier concentration. The highest efficiency of 30% can be attained following optimization of diverse parameters. The simulation outcomes offer beneficial insights and directions for designing and engineering Sb2Se3 solar cells.

Recovery of FTO coated glass substrate via environment-friendly facile recycling perovskite solar cells.

Organic-inorganic perovskite solar cells (PSCs) have recently emerged as a potential candidate for large-scale and low-cost photovoltaic devices. However, the technology is still susceptible to degradation issues and toxicity concerns due to the presence of lead (Pb). Therefore, investigation on ideal methods to deal with PSC wastes once the device attains its end-of-life is crucial and to recycle the components within the cell is the most cost effective and energy effective method by far. This paper reported on a layer-by-layer extraction approach to recycle the fluorine-doped tin oxide (FTO) coated glass substrate which is the most expensive component in the device architecture of mesoporous planar PSC. By adapting the sequential removal of each layer, chemical properties of individual components, including spiro-OMeTAD and gold can be preserved, enabling the material to be easily reused. It also ensured that the toxic Pb component could be isolated without contaminating other materials. The removal of all individual layers allows the retrieval of FTO conductive glass which can be used in various applications that are not only restricted to photovoltaics. Comparison of electrical, morphological and physical properties of recycled FTO glasses to commercial ones revealed minimal variations. This confirmed that the recycling approach was useful in retrieving the substrate without affecting its physicochemical properties.

Simultaneous appraisals of pathway and probable health risk associated with trace metals contamination in groundwater from Barapukuria coal basin, Bangladesh.

In this study, we analyzed 33 groundwater samples from the Barapukuria coal basin (BCB), Bangladesh for 10 trace metals (TMs) using Atomic Absorption Spectroscopy. Pathways and associated probable health risk were appraised by employing multivariate statistical approaches, health risk model and Monte-Carlo simulation. Except for the Cu, Cr and Zn concentrations, the mean concentrations of all TMs in the basin were above the permissible water quality limits set by Bangladesh and international standards. Correlation coefficient and principal component analysis, supported by cluster analysis indicated that anthropogenic inputs were more contributed to the elevated concentrations of TMs compared to geogenic sources as the major reasons of groundwater pollution in the basin. The results of non-carcinogenic risk appraisal depicted that hazard index (HI) values for both adults and children were exceeded the safe limits (>1.0) except for few locations, indicating serious health risks on the human via oral and dermal absorption pathways. However, the carcinogenic risk values of Cd and Cr exceeded the US EPA range of 1 × 10-6 to 1 × 10-4, with higher risk for children than adults, with oral intake as the key exposure pathway. A sensitivity study identified the concentration of Cr, exposure frequency and ingestion rate for carcinogenic effect as the most sensitive parameters influencing the probable health risk. Overall, the results suggest that Cr in drinking water could cause detrimental effects to exposed local residents; thus, strict health regulation and groundwater management should concentrate on Cr contamination in groundwater from the coal basin.