Assessment of ground and surface water quality along the river Varuna, Varanasi, India.

Multivariate statistical techniques were employed for monitoring of ground-surface water interactions in rivers. The river Varuna is situated in the Indo-Gangetic plain and is a small tributary of river Ganga. The study area was monitored at seven sampling sites for 3 years (2010-12), and eight physio-chemical parameters were taken into account for this study. The data obtained were analysed by multivariate statistical techniques so as to reveal the underlying implicit information regarding proposed interactions for the relevant area. The principal component analysis (PCA) and cluster analysis (CA), and the results of correlations were also studied for all parameters monitored at every site. Methods used in this study are essentially multivariate statistical in nature and facilitate the interpretation of data so as to extract meaningful information from the datasets. The PCA technique was able to compress the data from eight to three parameters and captured about 78.5% of the total variance by performing varimax rotation over the principal components. The varifactors, as yielded from PCA, were treated by CA which grouped them convincingly into three groups having similar characteristics and source of contamination. Moreover, the loading of variables on significant PCs showed correlations between various ground water and surface water (GW-SW) parameters. The correlation coefficients calculated for various physiochemical parameters for ground and surface water established the correlations between them. Thus, this study presents the utility of multivariate statistical techniques for evaluation of the proposed interactions and effective future monitoring of potential sites.

Solar Light Responsive Graphitic Carbon Nitride Coupled Porphyrin Photocatalyst that Uses for Solar Fine Chemical Production.

Photocatalysis is a defendable manner for production of several organic chemicals, energy and its storage from solar energy. For the evolution of metal free, cost-effective catalyst a 2D composite has been appear as a photocatalyst. Here, we had reported the synthesis of a light harvesting composite as a photocatalyst which was assembled by a poly-condensation mechanism between graphitic carbon nitride and tetrakis(4-nitrophenyl) porphyrin and the resulting composite manifest the excellent light harvesting properties, suitable energy band and low charge recombination. The photocatalyst [(NO2 )4 TPP@g-C3 N4 ] enables the efficient photocatalytic production of nicotinamide adenine dinucleotide (NADH) from consumed NAD+ also the production of organic chemicals like 4-methoxybenzylimines from 4-methoxybenzylamines. The photocatalytic efficiency of the photocatalyst was estimated by the percentage of NADH regeneration and the percentage yield of organic transformations. It shows the tetrakis(4-nitrophenyl) porphyrin could enhance the charge transfer capacity of graphitic carbon nitride which shows excellent photocatalysis activities and organic transformations.

Dye Degradation and Sulfur Oxidation of Methyl Orange and Thiophenol via Newly Designed Nanocomposite GQDs/NiSe-NiO Photocatalyst Under Homemade LED Light.

Photocatalytic processes triggered by graphene-based photocatalysts under solar light have sparked interest as a new sort of instrument for solar chemical synthesis. Herein we investigated self-assembled graphene quantum dots (GQDs)/NiSe-NiO composite photocatalyst for organic transformation as well as dye degradation. The synthesized GQDs/NiSe-NiO composite photocatalyst has an excellent suitable band gap, high molar extinction coefficient, low toxicity and chemical/thermal stability. The GQDs/NiSe-NiO composite photocatalyst emerges as a new standard for sulfur oxidation and dye degradation reactions under homemade LED light with high yield.

Sun Light Responsive 2D Covalent-Organic Frameworks Platform as a Catalysts Boost C-H Bond Arylation and Dopamine Regeneration.

Photocatalysis is one of the most promising methods for producing organic compounds with a renewable source of energy. Two-dimensional covalent organic frameworks (2D COFs) are a type of polymer that has developed as a potential light-harvesting catalyst for artificial photosynthesis with a design-controllable platform that might be developed into a new type of cost-effective and metal-free photocatalyst. Here, we present a two-dimensional covalent organic framework synthesis technique as a low-cost and highly efficient visible light active flexible photocatalyst for C-H bond activation and dopamine regeneration. 2D COF were synthesized from tetramino-benzoquinone (TABQ) and terapthaloyl chloride monomer through condensation polymerization reaction and the resultant photocatalyst have remarkable performance due to its visible light-harvesting capacity, appropriate band gap, and highly organized π-electron channels. The synthesized photocatalyst is capable to convert dopamine into leucodopaminechrome with a higher yield (77.08%) and also capable to activate the C-H bond between 4-nitrobenzenediazonium tetrafluoroborate and pyrrole.

Degradations of endocrine-disrupting chemicals and pharmaceutical compounds in wastewater with carbon-based nanomaterials: a critical review.

Although water occupies 75% of the earth's surface, only 0.0067% of the total water is available for human activities. These statistics further decline with the population growth and consequent multiplication in the amount of annual waste produced. The demand for clean and safe drinking water has always been a prime concern in the global scenario. Among various types of waste materials, endocrine-disrupting chemicals (EDCs) and pharmaceutical effluents have become a constant threat to the aquatic ecosystem and possess challenges worldwide. Endocrine-disrupting chemicals (EDCs) are a mixed group of emerging concern chemicals with the ability to mimic the mechanisms of biosynthesis, transport, and metabolism of hormones. These chemicals pose various health threats such as early puberty, infertility, obesity, diabetes, reproductive disorders, cancerous tumors, and related disorders (immune cells, hormones' activity, and various organs). On the other hand, pharmaceutical compounds such as antibiotics also harm the natural environment, human health, and soil microbiology. Their low concentration, ranging from a few ng/L to µg/L, gives rise to a micro-pollution phenomenon, which makes it difficult to detect, analyze, and degrade in wastewater treatment plants. Activated carbons (ACs) and other adsorbents, including naturally occurring materials (wood, keratin) are considered as nanomaterials (NMs) reference for the separation of organic pollutants. It is generally acknowledged that mass-transfer phenomena control sorption kinetics at the liquid/solid interface, with retention controlled by the sorbent/sorbate properties. Therefore, the type of interaction (strong or weak van der Waals forces) and the hydrophilic/hydrophobic properties of the adsorbent are two crucial factors. Besides, EDCs and pharmaceutical compound sorption on such kinds of nanoporous solids depend on both the molecule size and charge density. The applications of nanomaterials on non-conservative methods, like advanced oxidation processes or AOPs (e.g., photocatalysis and Fenton reaction), are contemplated as more apt in comparison to conservative technology like reverse osmosis nanofiltration, and adsorption, etc. One of the reasons is that AOPs generate free radicals (hydroxyls), which are strong oxidants for the demineralization of organic compounds and the extreme case that hydroxyl radicals can attack any kinds of pollutants with the generation of only water and carbon dioxide as final products. AOPs may imply the use of NMs as either catalysts or photocatalysts, which improve the selective removal of the target pollutant. Therefore, various literature reviews have revealed that there is a timely need to upgrade the efficiency of the remediation approaches to protect the environment against EDCs and pharmaceuticals adequately. There is currently a lack of definitive risk assessment tools due to their complicated detection and associated insufficiency in the health risk database. Hence, our present review focuses on applying carbon-based nanomaterials to remove EDCs and pharmaceuticals from aqueous systems. The paper covers the effect of these pollutants and photocatalytic methods for treating these compounds in wastewater, along with their limitations and challenges, plausible solutions, and prospects of such techniques.

Exploring temple floral refuse for biochar production as a closed loop perspective for environmental management.

Religious faith and ritual activities lead to significant floral offerings production and its disposal as waste to the nearby open lands and water bodies. These activities result into various social and environmental nuisances because of their high organic content. Alternatively, it can be used as valuable resources for various biochemical and thermo-chemical processes. Floral refuse has been utilized in natural dye extraction, however, the residual solid refuse is of significant environmental concern due to its nutrient rich nature. This study explores the potential utilization of solid residue of temple floral refuse after natural dye extraction by thermo-chemical decomposition of it. The slow pyrolysis of solid residue was performed at 350 °C and 500 °C, and the biochar yield of 42 and 36% was obtained, respectively. TGA-DTG analysis was performed to observe the thermo-chemical behaviour of floral refuse. The biochar products were further characterized by FTIR, SEM, EDX, BET, XRD, and RAMAN spectroscopy to observe the impact of pyrolysis temperature (PT) on the resulting material, i.e. biochar and its possible application measures. EDX results revealed the presence of various macro-nutrients such as C, N, P, K Ca and Mg in different proportions which showed its soil amelioration potential. Moreover, based on the SEM and BET results, biochar prepared at 500 °C was further explored for adsorption of methylene blue dye at various dose and pH conditions. Based on Langmuir (R2 = 0.98) and Freundlich (R2 = 0.97) isotherms, it is found as a potential adsorbent material for removal of methylene blue dye. The results revealed that biochar conversion of colour extracted floral refuse can be a vital option for quick and efficient management of it in a closed loop approach.

Biodegradation of C.I. Acid Red 1 by indigenous bacteria Stenotrophomonas sp. BHUSSp X2 isolated from dye contaminated soil.

A significant proportion of xenobiotic recalcitrant azo dyes are being released in environment during carpet dyeing. The bacterial strain Stenotrophomonas sp. BHUSSp X2 was isolated from dye contaminated soil of carpet industry, Bhadohi, India. The isolated bacterial strain was identified morphologically, biochemically, and on the basis of 16S rRNA gene sequence. The isolate decolorized 97 % of C.I. Acid Red 1 (Acid RED G) at the concentration of 200 mg/l within 6 h under optimum static conditions (temperature -35 °C, pH 8, and initial cell concentration 7 × 10(7) cell/ml). Drastic reduction in dye degradation rate was observed beyond initial dye concentration from 500 mg/l (90 %), and it reaches to 25 % at 1000 mg/l under same set of conditions. The analysis related to decolorization and degradation was done using UV-Vis spectrophotometer, HPLC, and FTIR, whereas the GC-MS technique was utilized for the identification of degradation products. Phytotoxicity analysis revealed that degradation products are less toxic as compared to the original dye.

Emerging trends in photodegradation of petrochemical wastes: a review.

Various human activities like mining and extraction of mineral oils have been used for the modernization of society and well-beings. However, the by-products such as petrochemical wastes generated from such industries are carcinogenic and toxic, which had increased environmental pollution and risks to human health several folds. Various methods such as physical, chemical and biological methods have been used to degrade these pollutants from wastewater. Advance oxidation processes (AOPs) are evolving techniques for efficient sequestration of chemically stable and less biodegradable organic pollutants. In the present review, photocatalytic degradation of petrochemical wastes containing monoaromatic and poly-aromatic hydrocarbons has been studied using various heterogeneous photocatalysts (such as TiO2, ZnO and CdS. The present article seeks to offer a scientific and technical overview of the current trend in the use of the photocatalyst for remediation and degradation of petrochemical waste depending upon the recent advances in photodegradation of petrochemical research using bibliometric analysis. We further outlined the effect of various heterogeneous catalysts and their ecotoxicity, various degradation pathways of petrochemical wastes, the key regulatory parameters and the reactors used. A critical analysis of the available literature revealed that TiO2 is widely reported in the degradation processes along with other semiconductors/nanomaterials in visible and UV light irradiation. Further, various degradation studies have been carried out at laboratory scale in the presence of UV light. However, further elaborative research is needed for successful application of the laboratory scale techniques to pilot-scale operation and to develop environmental friendly catalysts which support the sustainable treatment technology with the "zero concept" of industrial wastewater. Nevertheless, there is a need to develop more effective methods which consume less energy and are more efficient in pilot scale for the demineralization of pollutant.

Biodegradation of Navy N5RL1 carpet dye by Staphylococcus saprophyticus strain BHUSS X3.

Biodegradation of Navy N5RL1, a widely used acidic azo dye in carpet industry, was studied by bacterial strain isolated from the dye-contaminated soil collected from a carpet industry premises located in Bhadohi, Sant Ravidas Nagar and Uttar Pradesh, India. The isolated strain was identified as Staphylococcus saprophyticus BHUSS X3 on the basis of morphological, biochemical and 16S rRNA gene sequencing analysis. The strain BHUSS X3 decolorized 95.7 % of dye (100 mg/l) within 6 h at optimum pH 8, temperature 35 °C, inoculum 4.0 % under static condition during 24 h incubation. The isolated bacterial strain BHUSS X3 can toralate dye concentration upto 1,000 mg/l. The dye degradation metabolites were confirmed by analysis of degraded products using UV-Vis spectrophotometric, HPLC and FTIR technique. The phytotoxicity analysis was also conducted on Phaseolus aureus and enhanced seed germination was recorded.