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1.
Environ Res ; 244: 117858, 2024 Mar 01.
Artículo en Inglés | MEDLINE | ID: mdl-38086500

RESUMEN

The solid waste management (SWM) system is in a transitional phase in developing economies, and local municipalities and waste management companies are stepping toward integrating a waste treatment approach in the scheme of waste handling. However, there is an urgent need to explore cost-effective techniques, models, and potential revenue streams to sustain the state-run waste sector self-sufficiently. The proposed SWM model aims to support the local waste sector in Islamabad, the capital city of Pakistan, with 100% service area coverage to attain environmental and economic sustainability by defining dedicated waste collection streams to ensure quality material recovery under a cost-effective approach and modality. The innovative approach is applied to allocate the tonnage to various streams as per the city's current land use plan. The estimated/cost of the cleanliness services will be USD13.1 million per annum with an estimated per ton cost of USD 23. The establishment of the proposed material recovery facility (MRF) will process about 500 t/d of waste to produce 45 t/d compost and recover 130 t/d of recyclables. The environmentally friendly model saves 2.4 million tons of CO2‒eq/month from composting and recycling. The average economic potential from MRF and debris-crushing plants, including environmental benefit value, is calculated as USD 3.97 million annually. Recovery of services fee (70%) for various collection streams based on city land use and socio-economic conditions will generate revenue of USD 7.33 million annually. The total revenue will be USD 11.31 million (86% of total annual expenditures) to track the sector's self-sufficiency. To successfully reach the Sustainable Development Goals (SDGs) and Nationally Determined Contributions (NDCs), engaging the private sector from environmentally advanced economies to collaborate in the waste sector to enhance local technical capabilities is recommended.


Asunto(s)
Eliminación de Residuos , Administración de Residuos , Residuos Sólidos , Eliminación de Residuos/métodos , Análisis Costo-Beneficio , Administración de Residuos/métodos , Reciclaje , Ciudades
2.
Neuroendocrinology ; 113(8): 822-833, 2023.
Artículo en Inglés | MEDLINE | ID: mdl-37040730

RESUMEN

INTRODUCTION: Asprosin is an adipokine released from white adipose tissue during fasting and acts through the olfactory receptor. It is known that adipokines play roles in reproductive physiology in mammals. However, there are very few studies conducted on role of asprosin in reproductive functions. There are no studies on its relationship with sexual motivation. It was shown in the literature that administration of asprosin to male mice improves olfaction. It is also known that there is a strong correlation between smell and sexual desire. In view of this, it was hypothesized that chronic administration of asprosin would improve olfactory performance and increase sexual incentive motivation in female rats for male partners. METHODS: This hypothesis was tested by applying the hidden cookie test, sexual incentive test, active research test, and sexual behavior test. The changes in serum hormone levels in female rats that chronically received asprosin were also measured and compared. RESULTS: Chronic asprosin exposure increased olfactory performance, male preference ratio, male investigation preference ratio, activity index, and anogenital investigation behavior. Also, serum oxytocin and estradiol levels increased following chronic administration of asprosin in female rats. CONCLUSION: These data suggest that chronic administration of asprosin can result in increased sexual incentive motivation for opposite sex in female rats over increased olfactory performance and changes in reproductive hormones.


Asunto(s)
Conducta Sexual Animal , Olfato , Ratas , Masculino , Ratones , Femenino , Animales , Olfato/fisiología , Conducta Sexual Animal/fisiología , Oxitocina , Motivación , Ayuno , Mamíferos
3.
Int J Phytoremediation ; 23(2): 139-150, 2021.
Artículo en Inglés | MEDLINE | ID: mdl-32757949

RESUMEN

The study was carried out to identify the potential of phytoremediation within a flowing drain through Eichhornia crassipes in combination with two bacillus species to treat the inorganic and polycyclic aromatic hydrocarbons (PAHs) from industrial effluent at Kala Shah Kaku (KSK), Lahore, Pakistan. Results showed that the highest metals removal efficiency was found in Cr, Pb, Ni, and Cu as 72.4, 83.3, 82.35, and 63.63%, respectively. However, biochemical oxygen demand (BOD) and chemical oxygen demand (COD) removal efficiencies were also considerably higher (66.66 and 66.67%). The BOD, COD, sulfates, phosphate, and total dissolved solids (TDS) showed a higher reduction rate as 1442.7, 1967.3, 1148.2, 7225.4, and 911.5 g m-2 d-1, respectively. Chlorophyll a + b and carotenoid contents were decreased from 7.92 to 5.78 mg kg-1, 3.03 to 3.01 mg kg-1, respectively and total nitrogen was increased from 22 to 27 mg kg-1 in E. crassipes. Bio-concentration factor was higher for all metals and the maximum was found in Cr (<1). The reduction efficiency of Æ©PAHs was found up to 60% with different rings structure. The use of Bacillus safensis strain showed the higher percentage reduction for BOD, nitrates, sulfates, and phosphates. The Study provide practical reference for bacterial assisted phytoremediation of urban drain.


Asunto(s)
Eichhornia , Contaminantes Ambientales , Contaminantes Químicos del Agua , Bacillus , Bacterias , Biodegradación Ambiental , Clorofila A , Pakistán , Aguas del Alcantarillado , Aguas Residuales/análisis , Contaminantes Químicos del Agua/análisis
4.
Water Sci Technol ; 84(8): 1943-1953, 2021 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-34695022

RESUMEN

This study aims to investigate the decolourization efficiency of reactive black 5 (RB-5) dye by using CuMn2O4/gC3N4 coated zeolites (zeolite 4A) for the first time in a hybrid electro-flocculation-catalytic ozonation process. A comparison between various treatment options such as electro-flocculation, electro-flocculation in the presence of a catalyst, and catalytic ozonation in combination with electro-flocculation was explored. Moreover, the effect of different factors such as pH, time, catalyst dose, ozone dose, radical scavenger, and voltage has been studied in each treatment option mentioned earlier. The results indicated that the best treatment option was found to be catalytic ozonation in combination with electro-flocculation with removal efficiency (RE) of 90.31% at pH 10 after 30 min of the treatment process. The hydroxyl radical scavenger effect indicated that the synergistic catalytic process follows a radical mechanism. It is therefore concluded that CuMn2O4/gC3N4-zeolite catalysts in synergic electro-flocculation-catalytic ozonation process may be effectively used for the treatment of textile wastewaters.


Asunto(s)
Ozono , Contaminantes Químicos del Agua , Purificación del Agua , Zeolitas , Catálisis , Floculación , Naftalenosulfonatos , Contaminantes Químicos del Agua/análisis
5.
Int J Biometeorol ; 63(12): 1669-1682, 2019 Dec.
Artículo en Inglés | MEDLINE | ID: mdl-31446482

RESUMEN

In this study, the heat vulnerability index has been developed for a megacity Lahore. Although Pakistan stands at 12th rank among highly exposed countries to climate change, very little research has been dedicated in exploring the heat-related vulnerability of exposed populations. We have applied the principal component analysis with varimax rotation on well-established indicators of exposure, sensitivity, and adaptive capacity to determine the heat vulnerability. This study has resulted in two principal components sharing 70.4% variance. Principal component 1 comprises pre-existing illness, population density, housing density, education, and normalized difference vegetation index with following significant (> 0.4) loading values 0.91, 0.91, 0.91, 0.57, and - 0.773, respectively, and principal component 2 combines the nature of housing material (0.964) followed by the water availability (0.962) and minority status (0.539). The hot spot analysis and overlay analysis have also been applied on the extracted component, and the resultant co-occurrence of high variable class, high vulnerability, and hot spots of vulnerability helped to grip those areas which imperatively require the applications of heat-related health interventions. The heat vulnerability index developed in our study clarifies that the most vulnerable populations are confined in the central vicinities of Lahore and less vulnerable are those which inhibit towards the outskirts of the city.


Asunto(s)
Cambio Climático , Calor , Ciudades , Humanos , Pakistán , Poblaciones Vulnerables
6.
Int J Phytoremediation ; 21(10): 939-943, 2019.
Artículo en Inglés | MEDLINE | ID: mdl-31016996

RESUMEN

Phytoremediation by aquatic macrophytes is a promising technology with higher efficiency and no energy consumption. For this purpose, two macrophytes (Pistia stratiotes, Eichhornia crassipes), and an alga (Oedogonium sp.) were used to treat textile effluents rich in COD, BOD, dyes, and heavy metals (Pb, Fe, Cd, Cu). The aim of the study was to focus on comparative phytoremediation potential of these species by their metal removal capability. During 7 days experiment (day 0-day 6), the results showed that Oedogonium sp. was the best for COD removal and decolorization. Eichhornia crassipes was the best for BOD and heavy metal removal and proves more efficient than Pistia stratiotes and Oedogonium sp. However, Pistia stratiotes was found to accumulate more concentrations of Pb and Fe than Eichhornia stratiotes.


Asunto(s)
Araceae , Eichhornia , Contaminantes Químicos del Agua/análisis , Biodegradación Ambiental , Textiles
7.
Water Environ Res ; 90(2): 129-135, 2018 Feb 01.
Artículo en Inglés | MEDLINE | ID: mdl-28646571

RESUMEN

In the present study two designs, vertical and horizontal systems, were used and two different plant species, Water Lettuce (Pistia stratiotes) and Reed plant (Phragmites karka), compared for their removal efficiency. The vertical system appeared to be more stable and efficient for almost all the parameters. The vertical system, planted with Water Lettuce, showed percentage removal efficiency for BOD, phosphate and chloride as 82, 95.4, and 51, respectively, whereas turbidity and total suspended solids removal efficiencies were almost the same. However, fecal coliform removal by the Water Lettuce was 98.8% for both designs (vertical and horizontal), showing the ability of the plant to uptake nutrients and release toxins for pathogen disinfection. It appears that the vertical system could be the better option, planted with Water Lettuce, or with both plants in a co-culture environment.


Asunto(s)
Biodegradación Ambiental , Eliminación de Residuos Líquidos/métodos , Humedales , Araceae , Aguas Residuales/química , Contaminantes Químicos del Agua/análisis , Purificación del Agua
8.
Int J Phytoremediation ; 19(10): 894-898, 2017 Oct 03.
Artículo en Inglés | MEDLINE | ID: mdl-28448165

RESUMEN

Extensive use of Pesticides in agriculture and its surface runoff in river water is a major environmental concern. The present study evaluated the phytoremediation potential of Eichornia crassipes, Pistia strateotes and algae (Chaetomorpha sutoria, Sirogonium sticticum and Zygnema sp.) for organochlorine and pyrethroid pesticides. Water and plant samples were extracted by liquid phase and solid phase extraction respectively and analyzed by high-performance liquid chromatography. Eleven treatments (T1-T11) with and without plants were used for phytoremediation of organochlorine and pyrethroid pesticides. During the experiment, P. strateotes, E. crassipes and algae (C. sutoria, S. sticticum and Zygnema sp.) showed the highest removal efficiency with 62 (71% root, 29% shoot), 60 (67% root, 33% shoot), and 58% respectively for organochlorine and 76 (76% root, 24% shoot), 68 (69% root, 31% shoot), and 70% respectively for pyrethroids for the respective aquatic plants. Dissipation rate constant of treatments with plants (T2, T3, T5, T6, T8, and T9) was significantly higher (p < 0.05) as compared to that of treatments without plants (T10 and T11, control) for both organochlorine and pyrethroid. The bioconcentration factor of pyrethroid treatments (T3, T6, and T9) was significantly higher (p < 0.05) as compared to that of organochlorine treatments (T2, T5 and T8). The removal efficiency of E. crassipes, P. strateotes and algae (C. sutoria, S. sticticum and Zygnema sp.) for pyrethroids was significantly higher (p < 0.01) as compared to that of organochlorine.


Asunto(s)
Biodegradación Ambiental , Plaguicidas , Piretrinas , Agua Dulce , Microalgas , Contaminantes Químicos del Agua
9.
Environ Monit Assess ; 189(4): 189, 2017 Apr.
Artículo en Inglés | MEDLINE | ID: mdl-28353206

RESUMEN

Th aim of this study is to investigate spatio-temporal trends of dengue vector breeding and epidemic (disease incidence) influenced by climatic factors. The spatio-temporal (low-, medium-, and high-intensity periods) evaluation of entomological and epidemiological investigations along with climatic factors like rainfall (RF), temperature (Tmax), relative humidity (RH), and larval indexing was conducted to develop correlations in the area of Lahore, Pakistan. The vector abundance and disease transmission trend was geo-tagged for spatial insight. The sufficient rainfall events and optimum temperature and relative humidity supported dengue vector breeding with high larval indices for water-related containers (27-37%). Among temporal analysis, the high-intensity period exponentially projected disease incidence followed by post-rainfall impacts. The high larval incidence that was observed in early high-intensity periods effected the dengue incidence. The disease incidence had a strong association with RF (r = 0.940, α = 0.01). The vector larva occurrence (r = 0.017, α = 0.05) influenced the disease incidence. Similarly, RH (r = 0.674, α = 0.05) and average Tmax (r = 0.307, α = 0.05) also induced impact on the disease incidence. In this study, the vulnerability to dengue fever highly correlates with meteorological factors during high-intensity period. It provides area-specific understanding of vector behavior, key containers, and seasonal patterns of dengue vector breeding and disease transmission which is essential for preparing an effective prevention plan against the vector.


Asunto(s)
Aedes , Dengue/epidemiología , Dengue/transmisión , Insectos Vectores , Animales , Monitoreo del Ambiente , Humanos , Humedad , Incidencia , Larva , Pakistán , Lluvia , Reproducción , Temperatura
10.
Heliyon ; 10(11): e31235, 2024 Jun 15.
Artículo en Inglés | MEDLINE | ID: mdl-38845869

RESUMEN

Municipal solid waste management is a major concern in developing economies, requiring collective international efforts to achieve carbon neutrality by diverting waste from disposal facilities. This study aims to highlight the importance of the waste sector as it has the potential to significantly contribute to climate change and its toxicity impact on the local ecosystem. Out of the total municipal solid waste generated, only 78 % is collected, either open dumped or thrown in sanitary landfills. The waste sector's ecological impact value is calculated for the Earth's regions, and it is very high at >50 % in Africa, Asia, Latin America and the Caribbean. This sectoral impact value is mainly responsible for greenhouse gas emissions and degradation of the local ecosystem health. Current business‒as‒usual practices attribute 3.42 % of global emissions to the waste sector. Various scenarios are developed based on waste diversion and related emissions modelling, and it is found that scenarios 3 and 4 will support the policymakers of the regions in attaining zero carbon footprints in the waste sector. Our findings conclude that cost-effective nature-based solutions will help low‒income countries reduce emissions from disposal sites and significantly improve the local ecosystem's health. Developed economies have established robust waste‒handling policies and implementation frameworks, and there is a need for collaboration and knowledge sharing with developing economies at the regional level to sustain the sector globally.

11.
Arch Physiol Biochem ; : 1-9, 2024 Aug 02.
Artículo en Inglés | MEDLINE | ID: mdl-39092983

RESUMEN

OBJECTIVE: To investigate the comprehensive effects of daily chronic asprosin administration on various pubertal and reproductive parameters in female rats. This study aims to elucidate the role of asprosin in regulating the onset of puberty and its influence on hormonal profiles and ovarian histology. METHODS: Asprosin was administered intraperitoneally (i.p.) at a dose of 500 ng/kg daily for eight weeks. Hormonal assays and histological analyses were performed to evaluate the effects of asprosin on the onset of puberty and reproductive function. RESULTS: Daily chronic administration of asprosin accelerated the onset of the first oestrus. Hormonal assays revealed significant elevations in serum levels of Follicle-Stimulating Hormone (FSH) and Oestradiol (E2), while Inhibin B levels decreased. Histological evaluations demonstrated an increased number of primary and secondary follicles in ovarian tissue, without affecting primordial follicle counts or reproductive organ weights. CONCLUSIONS: Role of adipokines in regulating puberty and reproductive function has increasingly gained recognition. This study aimed to provide the first comprehensive examination of the effects of daily chronic asprosin administration on pubertal and reproductive parameters in female rats. Utilising hormonal assays and histological analyses, asprosin was administered intraperitoneally (i.p.) at a dose of 500 ng/kg, daily, for eight weeks. Our findings revealed that daily chronic administration of asprosin accelerated the onset of the first oestrus. Hormonal assays showed significant elevations in serum levels of Follicle-Stimulating Hormone (FSH) and Oestradiol (E2), while Inhibin B levels decreased. Histological evaluations demonstrated an increased number of primary and secondary follicles in ovarian tissue, without affecting primordial follicle counts or reproductive organ weights. These results provide new insights into asprosin's role in advancing the age of first oestrus and modulating hormonal profiles, thereby offering potential benefits to the female reproductive system.

12.
Environ Sci Pollut Res Int ; 30(14): 40340-40355, 2023 Mar.
Artículo en Inglés | MEDLINE | ID: mdl-36609971

RESUMEN

The aim of the present study was to determine the occurrence, spatio-temporal variations, source apportioning, and ecological risk assessment of selected PCBs and OCPs in surface water and sediments collected riverine environment of Punjab province, Pakistan. The concentration of ΣOCPs (water: 64-455 ng/L; sediments: 117-616 ng/g) and ΣPCBs (water: 2-132 ng/L; sediments: 3.27-200 ng/g) was found comparatively higher than the levels reported from other parts of the world. The higher concentrations of DDTs and HCHs were detected in both studied matrices, whereas among PCBs, CB-28, 49 and CB-37, 82 were dominant in water and sediments, respectively. The isomeric ratios including α-HCH/γ-HCH, (DDE + DDD) / DDTs, and α /ß-endosulfan reflected the recent use of lindane, technical DDT, and endosulfan in the study area. The WHO-TEQ values of DL-PCBs ranged from 3.6 × 10-6 to 0.115 ng/L and 8.7 × 10-6 to 0.157 ng/g in surface water and sediments in both seasons, respectively. The spatial variation analysis revealed that the sites in the industrial and agricultural zones were highly contaminated. The OCPs and PCBs fluxes to downstream areas were estimated to be 12.4 tons/year and 1.9 tons/year, respectively. The significant ecological risks were estimated to be posed by OCPs and PCBs, as their levels in 67% and 62% of surface water and sediment samples were exceeding the threshold limits, highlighting effects to ecological integrities.


Asunto(s)
Hidrocarburos Clorados , Plaguicidas , Bifenilos Policlorados , Contaminantes Químicos del Agua , Estaciones del Año , Bifenilos Policlorados/análisis , Plaguicidas/análisis , DDT/análisis , Pakistán , Ecosistema , Contaminantes Químicos del Agua/análisis , Monitoreo del Ambiente , Hidrocarburos Clorados/análisis , Endosulfano/análisis , Medición de Riesgo , Agua/análisis , Sedimentos Geológicos
13.
Environ Sci Pollut Res Int ; 30(43): 98377-98388, 2023 Sep.
Artículo en Inglés | MEDLINE | ID: mdl-37608167

RESUMEN

This study was designed to assess the distribution of organochlorines (OCs) in fish species, their spatio-temporal variations, bioaccumulation potential, and associated human health risks via dietary intake. The levels of twenty-three organochlorine pesticides (OCPs) and thirty-five polychlorinated biphenyls (PCBs) were analyzed in six fish species collected from the riverine ecosystem of Punjab Province, Pakistan. The results indicated that the mean levels of Σ23OCPs were 74.1 ng/g ww and 184 ng/g ww, and for Σ35PCBs the levels were 38.8 ng/g ww and 74.8 ng/g ww in herbivorous and carnivorous fish species, respectively. The most abundant contaminants in all fish species were DDTs (65%) and HCHs (14%) among OCPs and heavier PCB congeners (62%) among PCBs. As for dioxin-like PCBs, the WHO toxic equivalency values (ng TEQ/g ww) were in the range of 0.21 (Cyprinus Carpio) to 2.38 (Rita Rita), exceeding the maximum allowable limit of 0.004 ng TEQ/g, ww by the European Commission. Spatio-temporal analysis indicated relatively higher OC levels in winter season with elevated concentrations in fish samples from industrial zone. The bioconcentration factor (L/kg) values ranged from 723 to 2773 for PCBs and 315 to 923 for OCPs in all fish species, with higher levels were reported in carnivorous species. The human health risk assessment at both 50th and 95th percentiles revealed the absence of any significant non-carcinogenic risk as calculated HR was less than 1. However, the critical carcinogenic risk was found to be associated for most of the contaminants, signifying the dietary exposure to OCPs and PCBs might pose the public health concern.


Asunto(s)
Carpas , Hidrocarburos Clorados , Plaguicidas , Bifenilos Policlorados , Animales , Humanos , Bioacumulación , Pakistán , Ecosistema , Carcinógenos , Carcinogénesis , Medición de Riesgo
14.
Environ Sci Pollut Res Int ; 30(1): 1825-1840, 2023 Jan.
Artículo en Inglés | MEDLINE | ID: mdl-35921015

RESUMEN

This study aims to evaluate municipal landfill sites' operational and financial viability, waste amount and characterization, primary and secondary collection systems, revenue generation from MSW, vehicle routing, and age of landfill sites located in Akhtarabad, Sahiwal Division. Three operational and financial models were developed to calculate cost/ton value based on obtained data. The obtained results indicate that the cost/ton values for models are the following: 20.01 USD for Model-1, 8.96 USD Model-2, and Model-3 is about 10.23 USD. The waste characterization represented waste consisting of compostable (57%), recyclable (10%), Refuse Derived Fuel (RDF) (12%), earth fill (20%), and disposable material (1%). Revenue/ton of municipal solid waste was about 19.47 USD, and according to cost-benefit analysis, the cost of Model-1 was higher than the benefit. In contrast, the costs of Model-2 and Model-3 were found to be lower than the revenue/ton. However, the waste collection efficiency of Model-1 was greater than both remaining models. The study concluded that utilizing all generated waste, only 21% of waste is dumped at the landfill site. It will reduce the area required for landfill sites from 431437 to 90602 m2 for the next 10 years and increase the age of landfill sites by over 20 years. It is recommended that the reuse of municipal solid waste and implementation of the no waste to landfill model would surely save money, land, and fuel, and it will also increase the age of landfill sites.


Asunto(s)
Eliminación de Residuos , Administración de Residuos , Eliminación de Residuos/métodos , Residuos Sólidos/análisis , Ciudades , Pakistán , Instalaciones de Eliminación de Residuos , Administración de Residuos/métodos
15.
Biol Futur ; 73(4): 483-493, 2022 Dec.
Artículo en Inglés | MEDLINE | ID: mdl-36495402

RESUMEN

The purpose of this study was to investigate the effects of treadmill exercise training on obesity-induced behavioral changes in high-fat diet (HFD)-induced male rats. In this study, 40 male Sprague-Dawley rats were divided into 4 groups after they were weaned: Control (C), Exercise (E), Obese (O) and Obese + Exercise (O + E). For the obesity model % 60 high-fat diet were applied. After obesity was induced, rats were either moderate aerobic exercise (treadmill running) trained or left untrained. Different tasks to assess spatial learning and memory (Morris water maze test (MWMT)), depressive-like behavior (forced swimming test(FST), tail suspension test (TST) and anxiety-like behavior (light-dark test (LDT) and open field test (OFT)) were conducted. Exercise caused a significant reduction in duration of immobility in the O group in FST and the decrease in immobility in the O + E rats in TST. The O + E rats demonstrated a significant increase in the time spent in the light box as compared to the O group in the LDT. The O + E rats did not show any behavioral alterations as compared to all the other groups in the OFT. In the O + E group, there was a significant increase in the time spent in the target quadrant compared to the O group in the MWMT. Our results support that treadmill exercise could improve cognitive, depressive-like, anxiety-like behavioral changes in the HFD-induced obese rats.


Asunto(s)
Ansiedad , Dieta Alta en Grasa , Ratas , Animales , Masculino , Dieta Alta en Grasa/efectos adversos , Ratas Sprague-Dawley , Ansiedad/etiología , Ansiedad/terapia , Ansiedad/psicología , Obesidad/terapia , Obesidad/psicología , Ejercicio Físico
16.
Environ Sci Pollut Res Int ; 29(24): 36721-36739, 2022 May.
Artículo en Inglés | MEDLINE | ID: mdl-35064515

RESUMEN

The electronic waste generation rate is increasing drastically at a rate of 3 to 5% per year in developing countries. The aim of this study is to analyze the environmental sustainability and economic benefits of such e-waste management in the developing economies like Pakistan. The life cycle assessment (LCA) method has been employed for streamlined impact analysis of the end-of-life processing of e-waste focusing mainly on laptop computers and liquid crystal display (LCD) desktop computers in Pakistan. The method of cumulative exergy extraction from the natural environment (CEENE) has also been deployed for the relative assessment of resources' consumption of e-waste recycling versus landfilling scenario. The determined impact scores are 1.79E + 03 kg CO2 eq., 7.19E-07 kg CFC-11 eq., 1.02E + 03 kg 1,4-DCB, 7.13E + 01 kg 1,4-DCB, and 3.41E-03 kg Cu eq. in climate change potential, stratospheric ozone depletion, ecotoxicity potential, human noncarcinogenic potential, and mineral resource depletion impact categories, respectively. The results of CEENE analysis reveal that approximately 80% of the impact on natural resources is reduced by the efficient recycling of e-waste. The comparative assessment of respective scores for current and target material weight recovery (MWR) indicators represented that by increasing the MWR indicator by 33.8% for laptop computers and by 27.2% for LCD computers, the country will achieve an annual economic benefit of US $191.56 million. This is greatly significant for a transitional shift towards e-waste revalorization while realizing the objectives of sustainable resource consumption. Innovative improvement measures ensuring economically feasible, energy-efficient, and environment friendly waste collection, treatment, and recycling practices present an invaluable opportunity for developing countries.


Asunto(s)
Residuos Electrónicos , Eliminación de Residuos , Administración de Residuos , Países en Desarrollo , Humanos , Pakistán , Reciclaje/métodos , Administración de Residuos/métodos
17.
Environ Sci Pollut Res Int ; 28(19): 24807-24815, 2021 May.
Artículo en Inglés | MEDLINE | ID: mdl-33394427

RESUMEN

A multi-elemental analysis, including heavy metals and trace elements in ambient air samples, was conducted for computers, wires, lead batteries, and iron extraction facilities in Lahore by proton-induced X-ray emission (PIXE) spectroscopy. The data obtained from PIXE analysis revealed the presence of Mg, Al, Zn, S, Pb, K, Ti, Fe, Si, K, and Cr elements at e-waste recycling facilities. The computer dismantling site revealed a higher concentration of Fe (634.7 µg/m3), Al (176.8 µg/m3), Pb (135.4 µg/m3) and Zn (122.5 µg/m3) in the air samples. The decreasing order of heavy metals and trace elements contribution at the computer dismantling site was as Si > Fe > Al > Pb > Zn > Mg > Ca > Cr > K > S > Ti. Similarly, at wires/cables burning site, a higher concentration of Fe, Al, and Pb (829.8 µg/m3, 184.5 µg/m3 and 115.6 µg/m3, respectively) were observed, and the elements revealed a descending trend as Si > Fe > Al > Zn > Pb > Mg > Ca > Cr > Ti > K > S. The lead batteries dismantling site showed the highest Pb concentration (141.2 µg/m3) due to the disassembling of lead acid batteries. Al, Zn, Fe, and Cr also revealed higher concentration in air samples and exhibited a declining trend as Si > Fe > Al > Pb > Zn > Cr > Ca > Mg > Ti > K > S. However, the highest concentration of Fe (865.7 µg/m3) was detected in air samples of iron extraction sites besides Al and Zn. The descending order of trace elements contribution was Si > Fe > Al > Zn > Mg > K > Ca > Ti > S. Furthermore, the correlation between workers' awareness and their possible health impacts were also examined in the study. Most of the workers were less aware of the hazardous impacts. Majority of workers and residents were suffering from a respiratory illness (27.5% and 32.5%), kidney failure (15% and 22.5%), and neurological disorders (15% and 7.5%), respectively, due to exposure of airborne particulate matter which could be correlated with the higher concentration of heavy metals such as Pb, Cr, Zn, and Fe in the ambient air at the e-waste recycling sites.


Asunto(s)
Contaminantes Atmosféricos , Metales Pesados , Oligoelementos , Contaminantes Atmosféricos/análisis , Cromo , Monitoreo del Ambiente , Humanos , Metales Pesados/análisis , Material Particulado/análisis , Reciclaje , Oligoelementos/análisis
18.
Environ Technol ; 41(12): 1514-1519, 2020 May.
Artículo en Inglés | MEDLINE | ID: mdl-30355050

RESUMEN

Phytoremediation is a cost-effective and eco-friendly process to remove heavy metals from water. A small-scale experiment was conducted to determine the phytoremediation efficiency of two macrophytes, i.e. Pistia stratiotes and Eichhornia crassipes for the removal of chromium and copper from the prepared metal solutions of different concentrations (2, 4, 6, 8 mg/L) for a period of one month. Both aquatic macrophytes showed different efficiency for the removal and accumulation of Chromium (Cr) and Copper (Cu). The dry biomass of both macrophytes increased over the period of time. The average accumulation of chromium in roots and leaves of P. stratiotes was 85 mg, 56 mg and copper was 96 mg and 70 mg, respectively whereas the average accumulation of chromium in roots and leaves of E. crassipes was 90 mg, 53 mg and copper was 86 mg, 50 mg, respectively. Higher absorbance of metals was observed in roots as compared to the leaves of both macrophytes. The concentration of metals in the solution significantly decreased from day 1 to day 30. The results of one-way ANOVA showed that removal of Cr was significantly (p < .05) greater in E. crassipes and removal of Cu was significantly (p < .05) greater in P. stratiotes.


Asunto(s)
Araceae , Eichhornia , Contaminantes Químicos del Agua , Biodegradación Ambiental , Cromo , Cobre
19.
Sci Total Environ ; 742: 140561, 2020 Nov 10.
Artículo en Inglés | MEDLINE | ID: mdl-32623176

RESUMEN

Till date no medication or vaccine is available to cope with the COVID-19 infection and infection rate is increasing drastically across the globe. Only preventive measures and healthy life style with efficient immune system have been suggested by WHO to fight and stay safe from COVID-19. WHO recommended alcohol based hand sanitizers for frequent hand hygiene, which are mainly made up from ethanol, isopropyl alcohols, hydrogen peroxides in different combinations. These preparations may become toxic to human health and environment when misused. These chemicals have known toxic and hazardous impact on environment when released by evaporation. In early five months of 2020, American Association of Poison Control Center reported 9504 alcoholic hand sanitizer exposure cases in children under the age of 12 years and recognized that even a small amount of alcohol can cause alcohol poisoning in children that is responsible for confusion, vomiting and drowsiness, and in severe cases, respiratory arrest and death. Furthermore, frequent usage of said hand sanitizers has reported increased chance of antimicrobial resistance and chance of other viral diseases. Current review is designed with main objective to highlight the toxic and serious health risks to human health and environment by frequent using hand hygiene products with alcohols based formulations.


Asunto(s)
Infecciones por Coronavirus , Desinfectantes para las Manos , Pandemias , Neumonía Viral , Betacoronavirus , COVID-19 , Niño , Desinfección de las Manos , Humanos , SARS-CoV-2 , Estados Unidos
20.
Environ Sci Pollut Res Int ; 27(18): 23081-23093, 2020 Jun.
Artículo en Inglés | MEDLINE | ID: mdl-32333350

RESUMEN

In this study, the multi-attribute utility theory model, one of the most widely utilized multi-criteria decision-making methods, is employed to analyze the relative sustainability and cleaner development mechanism (CDM) potential of a novel bioenergy project in Pakistan and four registered CDM bioenergy installations in China, India, Sri Lanka, and Thailand. Four major sustainability evaluation criteria selected for the study are technology, economy, environment, and social aspects, whereas "simple multi-attribute rating technique" (SMART) and "additive synthesis method" were utilized for the calculation of weighting factors. The most significant indicator was emission reduction, and least significant indicator was job creation with 24% and 15% respective weightages, in the sustainability scoring. Moreover, for three considered evaluation scenarios, (I) base case, (II) per kilowatt, and (III) per kilowatt hour, the bioenergy project in Pakistan has the highest comparative sustainability values of 0.735, 0.592, and 0.492 respectively. This analysis will provide an insight assistance to developing countries for establishing sustainable energy installations under CDM.


Asunto(s)
Conservación de los Recursos Naturales , China , India , Pakistán , Sri Lanka , Tailandia
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