RESUMO
In the title compound, C(14)H(15)N(3)S, the imidazo[2,1-b][1,3,4]thia-diazole fused-ring system is close to planar, with a maximum deviation of 0.042â (1)â Å, and the dihedral angle between it and the phenyl ring is 24.21â (6)°. The isobutyl group is disordered over two sets of sites in a 0.899â (9):0.101â (9) ratio. In the crystal, weak aromatic π-π stacking inter-actions involving the imidazole and thia-diazole rings with a centroid-centroid distance of 3.8067â (7)â Å occur.
RESUMO
In the title compound, C(15)H(17)N(3)OS, the dihedral angle between the statistically planar imidazo[2,1-b][1,3,4]thia-dia-zole fused-ring system (r.m.s. deviation = 0.002â Å) and the methyoxbenzene ring is 4.52â (6)°. In the crystal, mol-ecules are arranged into columns and stacked down the a axis. The crystal structure is stabilized by weak C-Hâ¯π and π-π inter-actions [centroid-centroid separations = 3.6053â (8) and 3.7088â (7)â Å].
RESUMO
In the title compound, C(14)H(14)ClN(3)S, the imidazo[2,1-b][1,3,4]thia-diazole system is essentially planar, with a maximum deviation of 0.006â (2)â Å. The dihedral angle between the imidazo[2,1-b][1,3,4]thia-diazole and chloro-phenyl rings is 5.07â (8)°. In the crystal, there are no classical hydrogen bonds but stabilization is provided by weak π-π [centroid-centroid distance = 3.5697â (11)â Å] and C-Hâ¯π inter-actions.