Elastic Textile Threads for Fog Harvesting.

The potential applications of textile materials in fog harvesting have long been demonstrated. This work designed novel fog harvesters according to the distinct features of elastic textile threads (ETTs) to enhance droplet capture, large-droplet growth, and droplet pouring and improve fog harvesting efficiency. We prepared m@ETTs (modified ETTs) using three novel chemical and physical methods. First, we prepared spandex elastic threads with a non-uniform rough surface containing silica nanoparticles and titanium particles through the sol-gel triethoxymethylsilane method. Second, we prepared a rubber/polyester thread with a rough surface by breaking the thread shell with toluene solution, creating knots on the surface of the rubber core. Third, we prepared a polyurethane thread with a bumpy superhydrophobic surface by spraying a tetrafluoroethylene adhesive and silica nanoparticles on the thread. Furthermore, we connected ETTs to an automatic stretching-recovery system to obtain auto-ETTs as another group of harvesters. We obtained auto-i@ETTs by introducing elastic bumps/knots onto the auto-ETT surface. The fog harvesting efficiencies of m@ETTs were approximately 60-120% greater than those of the ETTs. The water harvesting rate of the auto-i@ETT was 2.5 times that of the ETT, with the highest water harvesting rate of auto-i@ETT reaching 3.35 g/h/cm2. Moreover, several novel principles of droplet behavior and thread elasticity were revealed. The elastic elongation level of the ETTs was proportional to their water harvesting efficiency. The stretching-recovery state of the elastic thread did not influence the water contact angle but affected the droplet state on the thread surface. The temporary slack/stick state of adjacent elastic threads on auto-ETTs contributed to droplet convergence and pouring. Overall, this novel approach demonstrates the significant potential of elastic threads in fog harvesting applications.

Bionic e-skin with precise multi-directional droplet sliding sensing for enhanced robotic perception.

Electronic skins with deep and comprehensive liquid information detection are desired to endow intelligent robotic devices with augmented perception and autonomous regulation in common droplet environments. At present, one technical limitation of electronic skins is the inability to perceive the liquid sliding information as realistically as humans and give feedback in time. To this critical challenge, in this work, a self-powered bionic droplet electronic skin is proposed by constructing an ingenious co-layer interlaced electrode network and using an overpass connection method. The bionic skin is used for droplet environment reconnaissance and converts various dynamic droplet sliding behaviors into electrical signals based on triboelectricity. More importantly, the two-dimensional sliding behavior of liquid droplets is comprehensively perceived by the e-skin and visually fed back in real-time on an indicator. Furthermore, the flow direction warning and intelligent closed-loop control of water leakage are also achieved by this e-skin, achieving the effect of human neuromodulation. This strategy compensates for the limitations of e-skin sensing droplets and greatly narrows the gap between artificial e-skins and human skins in perceiving functions.

Stretchable and Self-Powered Mechanoluminescent Triboelectric Nanogenerator Fibers toward Wearable Amphibious Electro-Optical Sensor Textiles.

Flexible electro-optical dual-mode sensor fibers with capability of the perceiving and converting mechanical stimuli into digital-visual signals show good prospects in smart human-machine interaction interfaces. However, heavy mass, low stretchability, and lack of non-contact sensing function seriously impede their practical application in wearable electronics. To address these challenges, a stretchable and self-powered mechanoluminescent triboelectric nanogenerator fiber (MLTENGF) based on lightweight carbon nanotube fiber is successfully constructed. Taking advantage of their mechanoluminescent-triboelectric synergistic effect, the well-designed MLTENGF delivers an excellent enhancement electrical signal of 200% and an evident optical signal whether on land or underwater. More encouragingly, the MLTENGF device possesses outstanding stability with almost unchanged sensitivity after stretching for 200%. Furthermore, an extraordinary non-contact sensing capability with a detection distance of up to 35 cm is achieved for the MLTENGF. As application demonstrations, MLTENGFs can be used for home security monitoring, intelligent zither, traffic vehicle collision avoidance, and underwater communication. Thus, this work accelerates the development of wearable electro-optical textile electronics for smart human-machine interaction interfaces.

Lapatinib Suppresses HER2-Overexpressed Cholangiocarcinoma and Overcomes ABCB1- Mediated Gemcitabine Chemoresistance.

Background: Recent breakthroughs in cholangiocarcinoma (CCA) genomics have led to the discovery of many unique identifying mutations, of which HER2 has been found to be overexpressed specifically in cases of extrahepatic CCA. However, whether or not lapatinib (an oral tyrosine kinase inhibitor selective for inhibition of HER2), or a combination of lapatinib and gemcitabine, exerts inhibitory effects on HER2-overexpressed CCA is still unclear. Methods: The effect of lapatinib and a lapatinib-gemcitabine combination treatment on CCA was determined using organoid and cell line models. Cell cycle arrest, apoptosis and proteins involving HER2-dependent downstream signaling pathways were analyzed to assess the effect of lapatinib on HER2+ CCA. The synergistic effect of lapatinib and gemcitabine was interpreted by docking analysis, ABCB1-associated ATPase assay, rhodamine transport assay and LC-MS/MS analyses. Results: dFdCTP, the active metabolite of gemcitabine, is proved to be the substrate of ABCB1 by docking analysis and ATPase assay. The upregulation of ABCB1 after gemcitabine treatment accounts for the resistance of gemcitabine. Lapatinib exerts a dual effect on HER2-overexpressed CCA, suppressing the growth of CCA cells by inhibiting HER2 and HER2-dependent downstream signaling pathways while inhibiting ABCB1 transporter function, allowing for the accumulation of active gemcitabine metabolites within cells. Conclusions: Our data demonstrates that lapatinib can not only inhibit growth of CCA overexpressing HER2, but can also circumvent ABCB1-mediated chemoresistance after gemcitabine treatment. As such, this provides a preclinical rationale basis for further clinical investigation into the effectiveness of a combination treatment of lapatinib with gemcitabine in HER2-overexpressed CCA.

Novel Ramie Fabric-Based Draping Evaporator for Tunable Water Supply and Highly Efficient Solar Desalination.

Interfacial solar-driven evaporation is a promising path to address the scarcity of freshwater. Lots of efforts have been made to develop highly efficient photothermal materials and optimize operational efficiency. However, the designed solar evaporator tends to directly contact with seawater, leading to inevitable parasitic heat loss and the total suppression of evaporation of the backside. Here, we show a novel draping fabric system by separating the evaporation interface from bulk water. The evaporation area was exposed to air with enhanced natural convection and double-side evaporation. The draping fabric was prepared by coating the mixture of carbon black (CB) and cross-linked sodium alginate (SA) on ramie fabric (CSRF). The draping CSRF realized an evaporation rate of 1.81 kg m-2 h-1 and efficiency of 96.6% under 1 sun illumination (1 kW m-2). In addition, by changing the yarn fineness of the fabric, a tunable water supply can be realized to optimize the energy distribution. This work provides a new strategy to design and optimize the solar evaporation system, exhibiting great potential in real-world applications.

Three-Dimensional Multilayer Vertical Filament Meshes for Enhancing Efficiency in Fog Water Harvesting.

Novel types of vertical filament mesh (VFM) fog harvesters, 3D VFM fog harvesters, and multilayer 3D VFM fog harvesters were developed by mimicking the water-harvesting nature of desert beetles and the spider silks from fog. Four different types of polymer filaments with different hydrophilic-hydrophobic properties were used. The polymer filaments were modified with the polyurethane-sodium alginate (PU-SA) mixture solution, and a simple spraying method was used to form alternating 3D PU-SA microbumps. Polymer VFMs exhibited a higher fog-harvesting efficiency than the vertical metal meshes. Moreover, the hydrophobic VFM was more efficient in fog harvesting than the hydrophilic VFM. Notably, the fog-harvesting efficiency of all VFMs increased by 30-80% after spraying with the mixed PU-SA solution to form a 3D geometric surface structure (3D PU-SA microbumps), which mimicked the desert beetle back surface. This modification caused the fog-harvesting efficiency of PTFE 3D VFM to be thrice higher than that of Fe VFM. This increase was attributed to the improved synergistic effects of fog capturing, droplet growing, and droplet shedding. The multilayer VFMs were more efficient in fog harvesting than the single-layer VFMs because of a larger droplet capture area. The fog-harvesting efficiency of two-layer and four-layer polymer VFMs was approximately 35% and about 45% higher than that of the single-layer polymer VFMs, respectively. The four-layer PTFE 3D VFM with the type B PU-SA bump surface (bump/PU-SA) had the highest efficiency of 287.6 mL/m2/h. Besides the high fog-harvesting efficiency, the proposed polymer VFMs are highly stable, cost-effective, rust-free, and easy to install in practical applications. These advantages are ascribed to the elasticity of the polymer filaments. This work provides new ideas and methods for developing high-performance fog harvesters such as the 3D VFM.

An Eco-friendly Porous Nanocomposite Fabric-Based Triboelectric Nanogenerator for Efficient Energy Harvesting and Motion Sensing.

A wearable and effective tribopositive material, especially an economical and eco-friendly triboelectric fabric developed from biomaterials, is highly crucial for the development of green wearable triboelectric nanogenerators. In this work, we design a porous nanocomposite fabric (PNF) with strong charge accumulation capacity through a facile dry-casting method and use it as a tribopositive material to construct attractive wearable triboelectric nanogenerators (abbreviated as TENGs). Specifically, the porous nanocomposite is developed by the incorporation of nano-Al2O3 fillers into cellulose acetate networks. By adjusting the concentration of casting solution and the content of nano-Al2O3 fillers, we systematically engineer the physical properties of the PNF for obtaining a large triboelectric charge yield. When a 10 wt % solution concentration and 10 wt % nanofiller content are adopted for the PNF, the corresponding PNF-TENG can deliver an electrical performance of ∼2.5 mW/cm2 on a 0.8 MΩ external resistor. This remarkable output can be ascribed to the synergistic effect between the appropriate porous network and improved dielectric properties of the nanocomposite. Moreover, the PNF-TENG also exhibits good reliable electrical outputs under multiple stain-washing measurements or after experiencing cyclical contact-separation 13,500 times. Also, the device is capable of charging various capacitors, lighting LED arrays, and driving commercial wrist watches and is proven to be an efficient and reliable green wearable power source. Furthermore, a PNF-TENG-based elbow supporter and a grip ball, as self-powered sensors, are proposed to realize real-time detection for human actions during sports exercise. This work proposes an eco-friendly nanocomposite fabric as an effective tribopositive material, verifies the feasibility of developing environmentally friendly wearable power sources and sensors, and provides new insights into the design of green wearable triboelectric nanogenerators.

Oxygen-Rich Polymers as Highly Effective Positive Tribomaterials for Mechanical Energy Harvesting.

Triboelectric nanogenerators (TENGs) are a potential solution to the depleted state of fossil fuels, on the condition that the energy conversion efficiency can be further improved. Tribomaterials are important not only for improving the output performance of TENGs but also for extending their applications. In this work, a poly-ε-caprolactone (PCL) electrospun membrane is proposed as a highly effective positive tribomaterial, paired with an expanded polytetrafluoroethylene (ePTFE) membrane, to fabricate TENGs (PCL/ePTFE TENGs). Compared with a widely used polyamide-6 (PA6)/ePTFE TENG, the output performance of the PCL/ePTFE TENG is enhanced by about 28%, indicating that PCL possesses a stronger electron-donating ability owing to the existence of oxygen-containing functional groups as electron donors. Furthermore, the PCL membrane is modified using poly(ethylene glycol) methyl ether (mPEG), which possesses more O atoms, by electrospinning (ES) and dip coating (DC). The results reveal that mPEG is very effective at improving the positive electron polarity of PCL. With the increase of mPEG content, the output performance increases by more than 40%, yielding a maximum power density of 115.83 W·m-2. More polymers have been compared to confirm that many oxygen-rich polymers show excellent electron-donating abilities and act as highly efficient positive tribomaterials. This work also provides additional options for more effective positive tribomaterials.