Recent Progress in Wearable Near-Sensor and In-Sensor Intelligent Perception Systems.

As the Internet of Things (IoT) becomes more widespread, wearable smart systems will begin to be used in a variety of applications in people's daily lives, not only requiring the devices to have excellent flexibility and biocompatibility, but also taking into account redundant data and communication delays due to the use of a large number of sensors. Fortunately, the emerging paradigms of near-sensor and in-sensor computing, together with the proposal of flexible neuromorphic devices, provides a viable solution for the application of intelligent low-power wearable devices. Therefore, wearable smart systems based on new computing paradigms are of great research value. This review discusses the research status of a flexible five-sense sensing system based on near-sensor and in-sensor architectures, considering material design, structural design and circuit design. Furthermore, we summarize challenging problems that need to be solved and provide an outlook on the potential applications of intelligent wearable devices.

Highly Sensitive Pressure Sensor Based on Elastic Conductive Microspheres.

Elastic pressure sensors play a crucial role in the digital economy, such as in health care systems and human-machine interfacing. However, the low sensitivity of these sensors restricts their further development and wider application prospects. This issue can be resolved by introducing microstructures in flexible pressure-sensitive materials as a common method to improve their sensitivity. However, complex processes limit such strategies. Herein, a cost-effective and simple process was developed for manufacturing surface microstructures of flexible pressure-sensitive films. The strategy involved the combination of MXene-single-walled carbon nanotubes (SWCNT) with mass-produced Polydimethylsiloxane (PDMS) microspheres to form advanced microstructures. Next, the conductive silica gel films with pitted microstructures were obtained through a 3D-printed mold as flexible electrodes, and assembled into flexible resistive pressure sensors. The sensor exhibited a sensitivity reaching 2.6 kPa-1 with a short response time of 56 ms and a detection limit of 5.1 Pa. The sensor also displayed good cyclic stability and time stability, offering promising features for human health monitoring applications.

Self-Assembly of CoPt Magnetic Nanoparticle Arrays and its Underlying Forces.

Nanoparticles covered with surfactants are often used to study particle motion patterns and self-assembly processes in solutions. Surfactants have influence on the interparticle interactions and therefore on the particle motion tracks and final patterns. In this study, CoPt nanoparticles are synthesized in aqueous solution without any surfactant. In situ transmission electron microscopy observation is performed to monitor the self-assemble process. Two types of magnetic nanoparticle superlattice arrays are formed: hexagonal equal distance superlattice arrays when particle size is 3 nm, and tight unequal distance superlattice arrays when particle size is 4.5 nm. It is interesting to observe that two small arrays merge into a large one through rotational and translational movements. A Monte Carlo simulation is carried out which successfully restores the whole process. It is identified that the underlying forces are van der Waals and magnetic dipolar interactions. The latter is responsible for orientation of each particle during the whole process. This investigation leads to a better understanding of the formation mechanism of magnetic nanoparticle superlattice arrays.

Dynamic Observation of Anisotropic Chainlike Structures during Nonclassical Two-Step Nucleation in Solid-State Iron Oxide Crystallization.

The demonstration of the self-crystallization nucleation process from an amorphous precursor in a solid is crucial for understanding of interactions between atoms. We report a study of dynamic crystallization process of iron oxides by virtue of in situ measurement of transmission electron microscopy. At first, semiordered chainlike structures are observed with the increase of concentration, and when sufficient chains form, the crystalline lattice begins to grow. The two-step nucleation pathway has also been confirmed by performing a molecular dynamics simulation, where Lennard-Jones and magnetic dipole-dipole interaction potentials are both taken into account and take effect individually predominantly in different ranges of distance between atoms. Furthermore, the total free energy profile in the crystallization nucleation process is calculated to evidence the stabilization of intermediate state. This work advances our understanding of nonclassical nucleation theory.

High-Performance Anisotropic Nanocomposites with a Novel Core/shell Microstructure.

Anisotropic nanostructures of magnetically hard and soft materials are fascinating for exploring next-generation ultrastrong permanent magnets with less expensive rare-earth elements. It is a big challenge fabricating high-performance nanocomposites due to the difficulty in controlling the grain size of the soft phase. Here, surfactant-assisted low-temperature chemical coating (LTCC) is adopted to fabricate SmCo5@FeCo nanocomposites. A uniform coating layer of the soft phase ranging from 5 to 15 nm FeCo particles is obtained. Both high coercivity Hc of 17.2 kOe and high energy product (BH)max of 29.4 MGOe in the optimal anisotropic SmCo5@FeCo nanocomposites with 15 wt % soft phase coating had been successfully fabricated, which has an enhancement of 31% compared with that of the uncoated single SmCo5 phase. The excellent performance is ascribed to nanosized grains of both soft and hard phases and a high remanence ratio Mr/Ms of 0.976. These results made a big step toward synthesizing a stronger bulk nanocomposite system.

Growth mechanism and magnetic properties of monodisperse L1(0)-Co(Fe)Pt@C core-shell nanoparticles by one-step solid-phase synthesis.

In this report, we present a novel one-step solid-phase reaction method for the synthesis of L10-CoPt@C core-shell nanoparticles (NPs) using organic metal precursors without surfactants. The obtained CoPt@C NPs have a good face-centered tetragonal single crystal structure and regular shape. The mean size of CoPt is 14 nm with a uniform carbon shell. The evolution of the core-shell structure during the synthesizing process is investigated in detail. Firstly organic metal precursors are decomposed, followed by the formation of grains/clusters in a metal-carbon intermediate state. Then the metal-carbon small grains/clusters agglomerate and recrystallize into single crystal metal alloy NPs covered with a carbon layer. The carbon shell is effective in preventing the coalescence of L10-CoPt NPs during high temperature sintering. The prepared L10-FePt nanoparticles have a high coercivity of up to 12.2 kOe at room temperature. This one-step solid-state synthesizing method could also be employed for the preparation of other types of nanostructures with high crystallinity, monodispersity and chemically ordered phase.

Growth mechanisms and size control of FePt nanoparticles synthesized using Fe(CO)x (x < 5)-oleylamine and platinum(ii) acetylacetonate.

By using Fe(CO)x-OAm (oleylamine, x < 5) as the Fe precursor to slow down the formation rate of FePt nanoparticles (NPs), a time dependence of the NPs' nucleation and growth process was observed by transmission electron microscopy (TEM). The complexing temperature of OAm and Fe(CO)5 at which Fe(CO)x-OAm was formed has a strong influence on the nucleation rate and growth process of the NPs. TEM analyses indicated that the NPs with isotropic shape were single crystalline throughout the synthesis and were formed by a diffusion-controlled Ostwald-ripening (OR) growth mechanism. The nanorod particles were first formed via joining of arbitrarily oriented single crystals and the two crystals formed a uniform particle afterwards, as described by the oriented-attachment (OA) mechanism. The ratio of OAm to Fe(CO)5 used in the preparation of Fe(CO)x-OAm has a significant influence on the growth process, and subsequently the shape, size and size distribution of the FePt NPs. By adjusting the ratio and its complexing temperature, single-crystal FePt NPs with controllable size and isotropic shape were obtained. The insight into the exploration of the specific roles of the reaction conditions and the formation mechanisms provided important information for controlling the morphology of the nanoparticles.