1.
Angew Chem Int Ed Engl
; 48(8): 1447-51, 2009.
Artigo
em Inglês
| MEDLINE
| ID: mdl-19145614
RESUMO
Shall we dance? Within the proposed mechanism for the palladium-catalyzed title reaction, the strained alkene norbornene (or norbornadiene) enters and exits the catalytic cycle in a catalytic "square dance", acting as both a promoter and a coupling partner in the formation of four carbon-carbon bonds, two of them by challenging C--H activation processes.