RESUMO
Fluorescence decay of the 2s2p(6)np (1)P(o) excited states of neon has been observed directly for the first time. This process has also been observed indirectly by threshold photoelectron spectroscopy and in electron/photon coincidences. The measurements have allowed this weak decay channel to be characterized and branching ratios derived. The fluorescence excitation spectrum is well described by a simple Rydberg model that highlights the interplay and competition between the decay channels of autoionization and fluorescence.
RESUMO
The combined effects of post-collision interaction in the final state and interference due to the indistinguishability of the two electrons have been studied in a selected case of resonant double photoionization of neon. In our coincidence experiments, the photo- and Auger-electron pair was measured when the two electrons have nearly equal energy and are ejected at small mutual angle. The obtained energy distributions exhibit a strong interplay of post-collision interaction and interference effects, in agreement with the theoretical prediction of Sheinerman and Schmidt [J. Phys. B 30, 1677 (1997)] made on beryllium.
RESUMO
This paper reports the present stage of commissioning of the gas-phase photoemission beamline at Elettra, Trieste. The beamline is designed for atomic and molecular science experiments with high-resolution and high-flux synchrotron radiation. It consists of an undulator source, variable-angle spherical-grating monochromator and two experimental stations. The design value of the energy range is 20 to 800 eV with a specified resolving power of over 10000. The procedure adopted for calibration of this type of monochromator is discussed. At present a resolving power up to 20000 and a range up to 900 eV have been measured. Absorption spectra taken at the argon L(II,III)-edge and at the nitrogen, oxygen and neon K-edges are as sharp as, or sharper than, any reported in the literature. The instrumental broadening is well below the natural line-width making it difficult to quantify the resolution; this problem is discussed.