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1.
Sensors (Basel) ; 19(9)2019 May 02.
Artigo em Inglês | MEDLINE | ID: mdl-31052502

RESUMO

In a smart home linked to a smart grid (SG), demand-side management (DSM) has the potential to reduce electricity costs and carbon/chlorofluorocarbon emissions, which are associated with electricity used in today's modern society. To meet continuously increasing electrical energy demands requested from downstream sectors in an SG, energy management systems (EMS), developed with paradigms of artificial intelligence (AI) across Internet of things (IoT) and conducted in fields of interest, monitor, manage, and analyze industrial, commercial, and residential electrical appliances efficiently in response to demand response (DR) signals as DSM. Usually, a DSM service provided by utilities for consumers in an SG is based on cloud-centered data science analytics. However, such cloud-centered data science analytics service involved for DSM is mostly far away from on-site IoT end devices, such as DR switches/power meters/smart meters, which is usually unacceptable for latency-sensitive user-centric IoT applications in DSM. This implies that, for instance, IoT end devices deployed on-site for latency-sensitive user-centric IoT applications in DSM should be aware of immediately analytical, interpretable, and real-time actionable data insights processed on and identified by IoT end devices at IoT sources. Therefore, this work designs and implements a smart edge analytics-empowered power meter prototype considering advanced AI in DSM for smart homes. The prototype in this work works in a cloud analytics-assisted electrical EMS architecture, which is designed and implemented as edge analytics in the architecture described and developed toward a next-generation smart sensing infrastructure for smart homes. Two different types of AI deployed on-site on the prototype are conducted for DSM and compared in this work. The experimentation reported in this work shows the architecture described with the prototype in this work is feasible and workable.

2.
Inorg Chem ; 57(18): 11732-11737, 2018 Sep 17.
Artigo em Inglês | MEDLINE | ID: mdl-30179003

RESUMO

Although boron-containing radicals are promising materials for molecular electronic devices, the electronic effect of the σ-donating yet π-accepting boron center on the stability of open-shell species has been less discussed. In this work, the role of a tricoordinate boron center in π-conjugated radicals was explored through electron paramagnetic resonance measurement of several boron-linked bisphenol radicals and diradicals. Replacing the bridging methine fragment of a neutral Galvinoxyl radical with an arylboryl group led to the corresponding boron-linked radical anion that requires excessive steric protection at the boron center to be persistent in solution. Experimental and theoretical investigations revealed that the introduction of boron would diminish the quinoidal character of the phenoxyl radical and increase both the electrophilicity and nucleophilicity of the open-shell species. Therefore, it is important to consider the steric protection of the boron center in boron-containing π-conjugated organic radicals.

3.
Opt Lett ; 37(21): 4537-9, 2012 Nov 01.
Artigo em Inglês | MEDLINE | ID: mdl-23114355

RESUMO

We present a series of sub-wavelength annular aperture (SAA) structures with annular width equal to the tip of a tapered hollow tube, which was fabricated using a heat-pulled method. The light beams emitted from the SAA-like structures created by the tapered hollow tube produced light beams characteristic of Bessel beams. We obtained a sub-micrometer focal spot with a depth-of-focus larger than 7 µm and identified the proper structure parameters needed to generate Bessel-like light beams. Our new design has potential application to areas such as optical lithography, optical trapping, and the fabrication of high aspect ratio structures.

4.
ACS Appl Mater Interfaces ; 11(34): 31562-31572, 2019 Aug 28.
Artigo em Inglês | MEDLINE | ID: mdl-31373787

RESUMO

Multiferroic materials are strong candidates for reducing the energy consumption of voltage-controlled spintronic devices because of the coexistence of ferroelectric (FE) and magnetic orders in a single phase. In this article, we present a new multiferroic perovskite, GdNixFe1-xO3 (GFNO), produced via sputtering on a SrTiO3 substrate. The proposed GFNO is FE and canted antiferromagnetic (AFM) within a monoclinic framework at room temperature. The FE polarization of the GFNO is up to 37 µC/cm2. When capped with a Co layer, the resulting heterostructure exhibits voltage-controlled magnetism (VCM). The heterostructured device exhibits two distinct features. First, its VCM depends on the magnitude as well as the polarity of the applied bias, thereby doubling the number of available magnetic readout states under a fixed voltage. Furthermore, the magnetic order of the device can be controlled very effectively within ±1 V. These two characteristics satisfy the requirements for low-power and high-storage technology. Theoretical analysis and experimental results indicate the importance of Ni dopant in regulating the polarity-dependent multiferroicity of this gadolinium ferrite system.

5.
PLoS One ; 11(7): e0160031, 2016.
Artigo em Inglês | MEDLINE | ID: mdl-27459633

RESUMO

For rapid screening and quantification of an antisera antibody, a nanometer bithiophene-based conductive biolinker can enhanced signal performance and can be used to verify the interaction of an anti-IFN-γ antibody with an IFN-γ protein. The experimental measurements take a generic approach which takes advantage of the functionality of thiophene-based linkers for biosensors. Effects associated with using bithiophene as a biolinker for surface plasmon resonance (SPR) spectroscopy are examined in this paper. By using an atomic force microscope (AFM), it was observed that the morphology of the bithiophene modified gold sensor surface became smoother than the original gold surface. We compared the response and concentration of the anti-IFN-γ antibody on a bithiophene-coated and dextran-coated biochip as well as on different thickness-modified surfaces under SPR relevant conditions. The results indicate that a response to IFN-γ molecules immobilized on a sensor using a bithiophene biolinker improved more than 8-fold when compared to that of a sensor using a dextran biolinker. Furthermore, the regeneration ability of the sensor surface shows good repeatability as only less than a 1% decrease was found after repeating the experimental work over 6 cycles. The characteristics provided us with a good platform for rapid screening, real-time monitoring and quantitative concentration of the autoimmune antibody activities.


Assuntos
Anticorpos/imunologia , Técnicas Biossensoriais/métodos , Interferon gama/imunologia , Nanotecnologia/métodos , Animais , Anticorpos/análise , Dextranos/química , Ouro/química , Humanos , Proteínas Imobilizadas/imunologia , Camundongos , Sensibilidade e Especificidade , Tiofenos/química
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