Effects of voltage and pressure on sludge electro-dewatering process and the dewatering mechanisms investigation.

Electro-dewatering technology shows a good application prospect because of its high efficiency in removing water from sludge and low energy consumption, but the potential mechanisms of sludge electro-dewatering have not been investigated in depth, which seriously limits the further development and application of electro-dewatering technology. In this study, the effects of voltage and pressure on sludge electro-dewatering performance, physicochemical characteristics and extracellular polymeric substances (EPS) compositions and distributions were investigated. The spatial distributions of EPS main components, including polysaccharide (PS) and protein (PN), were characterized by a confocal laser scanning microscopy (CLSM). The experimental results showed that under the conditions of a voltage of 40 V and a pressure of 90 kPa, the moisture content of sludge was reduced from 83.15% to 53.12%, and the bound water content of sludge in the anode layer, middle layer and cathode layer were decreased significantly from 1.16 g/g dry solid (DS) to 0.20, 0.47 and 0.35 g/g DS, respectively. The PN content of EPS in anode layer was significantly lower than that in cathode layer due to the electrochemical oxidation, while the variation of PS content showed the opposite trend, which agreed with the results visualized by CLSM. Pearson's correlation coefficient and hierarchical cluster analysis revealed that PN in TB-EPS was the major factor influencing the effect of sludge electro-dewatering. This work can be helpful to understand the potential mechanisms of electro-dewatering and provide theoretical support for the further popularization and application of electro-dewatering technology.

Buffer or boost? the role of openness to experience and knowledge sharing in the relationship between team cognitive diversity and members' innovative work behavior.

Although literature frequently argues that diversity stimulates innovative work behavior, theoretical perspectives and empirical findings on this relationship remain inconsistent. Based on self-category theory, this study aims to comprehensively investigate when and how team cognitive diversity benefits or inhibits innovative work behavior. We introduced a new context of research (i.e., virtual teams) during COVID-19 and tested a moderated mediation model using a two-wave survey of 238 employees from 56 virtual teams in China. The results indicated that team cognitive diversity negatively related to knowledge sharing, which in turn inhibited innovative work behavior. In addition, openness to experience moderated the relationship between team cognitive diversity and knowledge sharing, such that cognitive diversity positively related to knowledge sharing among employees with a high openness to experience, while it negatively related to knowledge sharing among those with low openness. These findings enrich the existing literature on innovation by clarifying the mechanisms and boundary conditions of team cognitive diversity and innovative work behavior.

When and why proactive employees get promoted: A trait activation perspective.

Although there is a consensus that workplace proactivity is vital for both employees and organizations, little is known as whether proactivity is beneficial for employees to develop leadership capabilities. Drawing from trait activation theory, we theorize that proactive personality could enhance employee promotability through taking charge behavior. We also propose that task structure determines the odds that proactive employees might be promoted. We tested the theoretical model with data from 226 employees and their direct leaders in 26 teams at three time points. The results of multi-level path analysis indicated that the positive relationship between proactive personality and taking charge was stronger in more organic work unit, which in turn, positively related to employees' promotability. These findings provide new knowledge in understanding the impacts of proactive personality and offers important empirical practices for proactivity management for organizations.

The Influence of Caerulomycin A on the Intestinal Microbiota in SD Rats.

Caerulomycin A (CRM A) is the first example of natural caerulomycins with a 2,2'-bipyridyl ring core and 6-aldoxime functional group from Streptomyces caeruleus and recently from marine-derived Actinoalloteichus cyanogriseus WH1-2216-6. Our previous study revealed that CRM A showed anti-tumor activity against human colorectal cancer (CRC) both in vitro and in vivo. Because some intestinal flora can affect the occurrence and development of CRC, the influence of CRM A on the intestinal flora is worthy of study in Sprague-Dawley (SD) rats. The high throughput sequencing of the V3-V4 hypervariable region in bacterial 16S rDNA gene results showed that the CRM A affected the diversity of intestinal flora of the SD rats treated with CRM A for 2, 3 and 4 weeks. Further analysis indicated that the abundance of genera Prevotella_1, Prevotellaceae_UCG-001, and Lactobacillus were increased while the that of genera Alloprevotella and Ruminiclostridium_1 were decreased. For the CRC related intestinal flora, the abundance of genera Bacteroides, Fusobacterium, Enterococcus, Escherichia-Shigella, Klebsiella, Streptococcus, Ruminococcus_2, and Peptococcus of SD rats treated with CRM A were decreased, while that of abundance of genera Bifidobacterium, Lactobacillus, Faecalibacterium, Blautia, Oscillibacter, and Clostridium were increased. The results indicated that CRM A could influence the intestinal flora by inhibiting some species of harmful flora and improving the beneficial bacteria in intestinal flora in the SD rats. The results may provide a new idea for revealing the mechanism of the anti-CRC activity of CRM A.

Pressurized electro-osmotic dewatering treatment of sludge: focusing on the influences on nutrients for agricultural application.

Sewage sludge requires effective dewatering and high nutrients retention before disposal for agricultural application. Pressurized electro-osmotic dewatering (PEOD) process with low energy consumption can effectively remove water from sludge, but the influences of PEOD process on nutrients for agricultural application still lacks in-depth research. In this study, the influences of PEOD process on nutrients for agricultural application were investigated, including organic matter, nitrogen, phosphorus, potassium and silicon contents. Layered experiments were conducted to investigate the layered variation of nutrients in sludge and to understand the potential change mechanisms. The experimental results showed that PEOD process caused small losses (<10%) of organic matter and total phosphorus (TP) in sludge, but caused 11.2-18.4% loss of total nitrogen (TN). PEOD process also caused 18.6-27.0% loss of total potassium (TK) and over 80% loss of available potassium in sludge, and could weaken the potential salt damage during the agricultural application of sludge. Furthermore, the available phosphorus content of sludge in the anode area increased significantly after the PEOD process, indicating that PEOD process could enhance the phosphorus bioavailability of sludge in the anode area. Besides, PEOD process caused a slight loss of silicon components in sludge, but improved the long-term silicon dissolution and release ability of sludge. This work could expand the knowledge about the influences of PEOD process on sludge nutrients and provide scientific guidance for the agricultural application of PEOD sludge.

Long-term stability and toxicity effects of three-dimensional electrokinetic remediation on chromium-contaminated soils.

The three-dimensional electrokinetic remediation (3D EKR) achieved efficient removal of chromium (Cr) from the soil through mechanisms including electromigration, electroosmosis, and redox reactions. In this study, the long-term stability, leaching toxicity, bioavailability, and phytotoxicity of Cr in remediated soils were systematically analyzed to comprehensively evaluate the effectiveness of the 3D EKR method. The results showed that the concentration of hexavalent chromium (Cr (VI)) in the leachate of the 3D EKR system with sulfidated nano-scale zerovalent iron (S-nZVI) was more than 40% lower than those of the other 3D electrode groups, and the time required to reach the level III standard of groundwater quality criterion in China (0.05 mg/L, GB/T 14848-2017) was significantly shortened. The stabilization of Cr(VI) in contaminated soil after 3D EKR was maintained for 300 pore volumes (PVs), indicating that the treated Cr(VI) had good long-term stability. The leaching toxicity and bioaccessibility of Cr were assessed by the synthetic precipitation leaching procedure (SPLP), the toxicity characteristic leaching procedure (TCLP), and the physiologically based extraction test (PBET). The concentration of Cr(VI) in the SPLP, TCLP, and PBET leachates of the S-nZVI group decreased by more than 25% compared to the other 3D electrode groups, corresponding to the decrease in leaching toxicity and bioavailability of the treated Cr during the 15-day remediation period. In addition, the germination rate of wheat seeds and the average biomass of wheat seedlings in the S-nZVI group under alkaline conditions (EE) were higher than those in the non-polluting group (Blank-OH), indicating that the remediated soil had no obvious toxicity to wheat. In summary, 3D EKR achieved a satisfactory and stable remediation effect on Cr-contaminated soil, especially when using S-nZVI as the 3D electrode.

Synthesis of Nitrogen-Doped KMn8 O16 with Oxygen Vacancy for Stable Zinc-Ion Batteries.

The development of MnO2 as a cathode for aqueous zinc-ion batteries (AZIBs) is severely limited by the low intrinsic electrical conductivity and unstable crystal structure. Herein, a multifunctional modification strategy is proposed to construct N-doped KMn8 O16 with abundant oxygen vacancy and large specific surface area (named as N-KMO) through a facile one-step hydrothermal approach. The synergetic effects of N-doping, oxygen vacancy, and porous structure in N-KMO can effectively suppress the dissolution of manganese ions, and promote ion diffusion and electron conduction. As a result, the N-KMO cathode exhibits dramatically improved stability and reaction kinetics, superior to the pristine MnO2 and MnO2 with only oxygen vacancy. Remarkably, the N-KMO cathode delivers a high reversible capacity of 262 mAh g-1 after 2500 cycles at 1 A g-1 with a capacity retention of 91%. Simultaneously, the highest specific capacity can reach 298 mAh g-1 at 0.1 A g-1 . Theoretical calculations reveal that the oxygen vacancy and N-doping can improve the electrical conductivity of MnO2 and thus account for the outstanding rate performance. Moreover, ex situ characterizations indicate that the energy storage mechanism of the N-KMO cathode is mainly a H+ and Zn2+ co-insertion/extraction process.

Proportional Integral Derivative Control in Spark Plasma Sintering Simulations.

The prediction of microstructure evolution and densification behavior during the spark plasma sintering (SPS) process largely depends on accurate temperature regulation. A loop feedback control algorithm called proportional integral derivative (PID) control is a practical simulation tool, but its coefficients are often determined by an inefficient "trial and error" method. This paper is devoted to proposing a numerical method based on the principles of variable coefficients to construct an optimal linear PID controller in SPS electro-thermal simulations. Different types of temperature profiles were applied to evaluate the feasibility of the proposed method. Simulation results showed that, for temperature profiles conventionally used in SPS cycles, the PID output keeps pace with the desired profile. Characterized by an imperfect time delay and overshoot/undershoot, the constructed PID controller needs further advancement to provide a more satisfactory temperature regulation for non-continuous temperature profiles. The first step towards a numerical rule for the optimal PID controller design was undertaken in this work. It is expected to provide a valuable reference for the advanced electro-thermal modeling of SPS.

Chitosan derivatives as green corrosion inhibitors for P110 steel in a carbon dioxide environment.

Two chitosan derivatives were synthesized for the first time as green corrosion inhibitors for the carbon dioxide corrosion of P110 steel. The structures of the synthesized products were characterized by infrared spectroscopy. Electrochemical and weight-loss experiments were used to test the effect of corrosion inhibitors, while SEM-EDS, AFM and other analysis methods were used to study the protection mechanism of corrosion inhibitors. The experimental results show that synthetic corrosion inhibitors CHC and CAHC are all good corrosion inhibitors for carbon dioxide corrosion inhibition. Both chitosan derivatives can form hydrophobic protective films on the metal surface. For inhibition performance, CAHC is better than CHC, which is the same conclusion drawn from practical experiments and quantum chemical calculations. Investigation into chitosan inhibitors has opened up a new area of research of environmentally friendly corrosion inhibitors, which is of great significance for metal protection without toxicity and side effects.

Fast camera spatial characterization of photonic polarization entanglement.

Scalable technologies to characterize the performance of quantum devices are crucial to creating large quantum networks and quantum processing units. Chief among the resources of quantum information processing is entanglement. Here we describe the full temporal and spatial characterization of polarization-entangled photons produced by Spontaneous Parametric Down Conversions using an intensified high-speed optical camera, Tpx3Cam. This novel technique allows for precise determination of Bell inequality parameters with minimal technical overhead, and for new characterization methods for the spatial distribution of entangled quantum information. The fast-optical camera could lead to multiple applications in Quantum Information Science, opening new perspectives for the scalability of quantum experiments.

Cytotoxic and Optically Active Pyrisulfoxins From the Endophytic Streptomyces albolongus EA12432.

R-Pyrisulfoxin C (1), S-pyrisulfoxin D [(+)-2], R-pyrisulfoxin D [(-)-2], pyrisulfoxin E (13), S-pyrisulfoxin F [(+)-14], and R-pyrisulfoxin F [(-)-14], six new caerulomycin derivatives with a 2,2'-bipyridine skeleton, were obtained from the cultures of the endophytic Streptomyces albolongus EA12432 with Aconitum carmichaeli (Ranunculaceae). Additionally, the racemic pyrisulfoxins A [(±)-3] and B [(±)-4] were further purified as optically pure compounds and identified the configurations for the first time. The racemic pyrisulfoxin D [(±)-2] displayed significant cytotoxicity against a series of cancer cell lines with IC50 values ranging from 0.92 to 9.71 µM. Compounds 7, 8, and (±)-3 showed cytotoxicity against the HCT-116, HT-29, BXPC-3, P6C, and MCF-7 cell lines. Notably, compounds 7 and 8 have a strong inhibition both on the proliferation of human colon cancer cells HCT-116 and HT-29 with IC50 values ranging from 0.048 to 0.2 µM (doxorubicin, 0.21 and 0.16 µM), and compound 1 showed a selective inhibition on the proliferation of the gastric carcinoma cell lines, N87, with an IC50 value of 8.09 µM. Optically pure compounds R(-)-14 and S(+)-14 showed weak cytotoxicity against HCT-116 and MCF-7 cell lines with the IC50 values of 14.7 µM and 10.4 µM, respectively. Interestingly, compounds 1 and (±)-2 didn't show cytotoxic activity against two human normal cell lines, HEK-293F and L02, with IC50 values >100 µM.

Enhancing Mechanical Properties of the Spark Plasma Sintered Inconel 718 Alloy by Controlling the Nano-Scale Precipitations.

The present study aimed to optimize the phase constituents and mechanical properties of the spark plasma sintered (SPS) Inconel 718 (IN718) alloy. A series of heat treatment routes were designed based on the phase relations in IN718 and performed for the optimization. The microstructure and phase compositions of the SPS IN718 alloys were examined by using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy disperse spectroscopy (EDS), and transmission electron microscopy (TEM). The mechanical properties of the samples were characterized at room temperature and at 650 °C. The results showed that large amounts of γ" (Ni3Nb) and γ' (Ni3(Al, Ti)) strengthening phases precipitated in the IN718 alloy after direct aging (DA) of the as-fabricated sample. Moreover, the mechanical properties of the DA sample were comparable to that of the best one of the solution-treated and aged counterparts. The analysis showed that the rapid sintering and solid solution treatment of the IN718 alloy were achieved simultaneously by SPS. In the case of the SPS IN718 material, the direct aging regime had the same heat treatment effect as the conventional solid solution and aging treatment. This contributes toward improving the production efficiency and reduces manufacturing costs in the actual production process.

Chitosan oligosaccharide derivatives as green corrosion inhibitors for P110 steel in a carbon-dioxide-saturated chloride solution.

Two chitosan oligosaccharide derivatives (PHC and BHC) were synthesized for use as corrosion inhibitors. They were characterized using Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR). The inhibition efficiency of PHC and BHC on P110 steel corrosion in a 3.5 wt.% NaCl CO2-saturated solution at 80℃ was studied using gravimetric measurement, scanning electron microscopy (SEM), atomic force microscopy (AFM), electrochemical analysis, and quantum chemical calculation. The results indicated that inhibition efficiency increased with increasing concentration of inhibitor. Energy dispersive X-ray (EDX), contact angle, and electrochemical impedance spectroscopy (EIS) measurements showed that the inhibitors had been successfully adsorbed to the surface of the P110 steel. The results of potentiodynamic polarization indicated that both compounds were mixed-type inhibitors.

Bi-layer Channel AZO/ZnO Thin Film Transistors Fabricated by Atomic Layer Deposition Technique.

This letter demonstrates bi-layer channel Al-doped ZnO/ZnO thin film transistors (AZO/ZnO TFTs) via atomic layer deposition process at a relatively low temperature. The effects of annealing in oxygen atmosphere at different temperatures have also been investigated. The ALD bi-layer channel AZO/ZnO TFTs annealed in dry O2 at 300 °C exhibit a low leakage current of 2.5 × 10-13A, I on/I off ratio of 1.4 × 107, subthreshold swing (SS) of 0.23 V/decade, and high transmittance. The enhanced performance obtained from the bi-layer channel AZO/ZnO TFT devices is explained by the inserted AZO front channel layer playing the role of the mobility booster.

The Manufacturing of High Porosity Iron with an Ultra-Fine Microstructure via Free Pressureless Spark Plasma Sintering.

High porosity (>40 vol %) iron specimens with micro- and nanoscale isotropic pores were fabricated by carrying out free pressureless spark plasma sintering (FPSPS) of submicron hollow Fe-N powders at 750 °C. Ultra-fine porous microstructures are obtained by imposing high heating rates during the preparation process. This specially designed approach not only avoids the extra procedures of adding and removing space holders during the formation of porous structures, but also triggers the continued phase transitions of the Fe-N system at relatively lower processing temperatures. The compressive strength and energy absorption characteristics of the FPSPS processed specimens are examined here to be correspondingly improved as a result of the refined microstructure.