Fermi-surface reconstruction and complex phase equilibria in CaFe2As2.

Fermi-surface topology governs the relationship between magnetism and superconductivity in iron-based materials. Using low-temperature transport, angle-resolved photoemission, and x-ray diffraction, we show unambiguous evidence of large Fermi-surface reconstruction in CaFe2As2 at magnetic spin-density-wave and nonmagnetic collapsed-tetragonal (cT) transitions. For the cT transition, the change in the Fermi-surface topology has a different character with no contribution from the hole part of the Fermi surface. In addition, the results suggest that the pressure effect in CaFe2As2 is mainly leading to a rigid-band-like change of the valence electronic structure. We discuss these results and their implications for magnetism and superconductivity in this material.

Measurement of two low-temperature energy gaps in the electronic structure of antiferromagnetic USb2 using ultrafast optical spectroscopy.

Ultrafast optical spectroscopy is used to study the antiferromagnetic f-electron system USb(2). We observe the opening of two charge gaps at low temperatures (

Textured superconducting phase in the heavy fermion CeRhIn5.

When antiferromagnetism and unconventional superconductivity coexist in CeRhIn(5) there is a significant temperature difference between resistively and thermodynamically determined transitions into the superconducting state. In this state, anisotropic transport near the superconducting transition reveals the emergence of textured superconducting planes that appear without a change in translational symmetry of the lattice. CeRhIn(5) is not unique in exhibiting these behaviors, indicating that textured superconductivity may be a general consequence of coexisting orders in correlated electron materials.

Electronic tuning and uniform superconductivity in CeCoIn5.

We report a globally reversible effect of electronic tuning on the magnetic phase diagram in CeCoIn(5) driven by electron (Pt and Sn) and hole (Cd, Hg) doping. Consequently, we are able to extract the superconducting pair breaking component for hole and electron dopants with pressure and codoping studies, respectively. We find that these nominally nonmagnetic dopants have a remarkably weak pair breaking effect for a d-wave superconductor. The pair breaking is weaker for hole dopants, which induce magnetic moments, than for electron dopants. Furthermore, both Pt and Sn doping have a similar effect on superconductivity despite being on different dopant sites, arguing against the notion that superconductivity lives predominantly in the CeIn(3) planes of these materials. In addition, we shed qualitative understanding on the doping dependence with density functional theory calculations.

Anisotropic critical magnetic fluctuations in the ferromagnetic superconductor UCoGe.

We report neutron scattering measurements of critical magnetic excitations in the weakly ferromagnetic superconductor UCoGe. The strong non-Landau damping of the excitations we observe, although unusual, has been found in another related ferromagnet, UGe(2) at zero pressure. However, we also find that there is a significant anisotropy of the magnetic correlation length in UCoGe that contrasts with an almost isotropic length for UGe(2). The values of the magnetic correlation length and damping are found to be compatible with superconductivity on small Fermi-surface pockets. The anisotropy may be important to explain why UCoGe is a superconductor at zero pressure while UGe(2) is not.

Combination of thermal and electric properties' measurement techniques in a single setup suitable for radioactive materials in controlled environments and based on the 3ω approach.

We have designed and developed a new experimental setup, based on the 3ω method, to measure thermal conductivity, heat capacity, and electrical resistivity of a variety of samples in a broad temperature range (2-550 K) and under magnetic fields up to 9 T. The validity of this method is tested by measuring various types of metallic (copper, platinum, and constantan) and insulating (SiO2) materials, which have a wide range of thermal conductivity values (1-400 W m-1 K-1). We have successfully employed this technique for measuring the thermal conductivity of two actinide single crystals: uranium dioxide and uranium nitride. This new experimental approach for studying nuclear materials will help us to advance reactor fuel development and understanding. We have also shown that this experimental setup can be adapted to the Physical Property Measurement System (Quantum Design) environment and/or other cryocooler systems.

Tricritical point from high-field magnetoelastic and metamagnetic effects in UN.

Uranium nitride (UN) is one of the most studied actinide materials as it is a promising fuel for the next generation of nuclear reactors. Despite large experimental and theoretical efforts, some of the fundamental questions such as degree of 5 f-electron localization/delocalization and its relationship to magneto-vibrational properties are not resolved yet. Here we show that the magnetostriction of UN measured in pulsed magnetic fields up to 65 T and below the Néel temperature is large and exhibits complex behavior with two transitions. While the high field anomaly is a field-induced metamagnetic-like transition and affects both magnetisation and magnetostriction, the low field anomaly does not contribute to the magnetic susceptibility. Our data suggest a change in the nature of the metamagnetic transition from first to second order-like at a tricritical point at T tri ∼ 24 K and H tri ∼ 52 T. The induced magnetic moment at 60 T might suggest that only one subset of magnetic moments has aligned along the field direction. Using the results obtained here we have constructed a magnetic phase diagram of UN. These studies demonstrate that dilatometry in high fields is an effective method to investigate the magneto-structural coupling in actinide materials.

Piezomagnetism and magnetoelastic memory in uranium dioxide.

The thermal and magnetic properties of uranium dioxide, a prime nuclear fuel and thoroughly studied actinide material, remain a long standing puzzle, a result of strong coupling between magnetism and lattice vibrations. The magnetic state of this cubic material is characterized by a 3-k non-collinear antiferromagnetic structure and multidomain Jahn-Teller distortions, likely related to its anisotropic thermal properties. Here we show that single crystals of uranium dioxide subjected to strong magnetic fields along threefold axes in the magnetic state exhibit the abrupt appearance of positive linear magnetostriction, leading to a trigonal distortion. Upon reversal of the field the linear term also reverses sign, a hallmark of piezomagnetism. A switching phenomenon occurs at ±18 T, which persists during subsequent field reversals, demonstrating a robust magneto-elastic memory that makes uranium dioxide the hardest piezomagnet known. A model including a strong magnetic anisotropy, elastic, Zeeman, Heisenberg exchange, and magnetoelastic contributions to the total energy is proposed.The nuclear fuel uranium dioxide is of intrinsic interest due to its industrial applications but it also exhibits intriguing electronic and magnetic properties. Here, the authors demonstrate how its complex magnetic structure and interactions give rise to a strong piezomagnetic effect.

Quantum critical fluctuations in the heavy fermion compound Ce(Ni0.935Pd0.065)2Ge2.

Electric resistivity, specific heat, magnetic susceptibility, and inelastic neutron scattering experiments were performed on a single crystal of the heavy fermion compound Ce(Ni0.935Pd0.065)2Ge2 in order to study the spin fluctuations near an antiferromagnetic (AF) quantum critical point (QCP). The resistivity and the specific heat coefficient for T ⩽ 1 K exhibit the power law behavior expected for a 3D itinerant AF QCP (ρ(T) ∼ T(3/2) and γ(T) ∼ γ0 - bT(1/2)). However, for 2 ⩽ T ⩽ 10 K, the susceptibility and specific heat vary as log T and the resistivity varies linearly with temperature. Furthermore, despite the fact that the resistivity and specific heat exhibit the non-Fermi liquid behavior expected at a QCP, the correlation length, correlation time, and staggered susceptibility of the spin fluctuations remain finite at low temperature. We suggest that these deviations from the divergent behavior expected for a QCP may result from alloy disorder.

Thermal avalanches near a Mott transition.

We probe the volume collapse transition (ΔV/Vo âˆ¼ 15%) between the isostructural γ and α phases (T âˆ¼ 100 K) of Ce0.9Th0.1 using the Hall effect, three-terminal capacitive dilatometry, and electrical resistivity measurements. Hall effect measurements confirm the itinerant ground state as the carrier concentration increases by a factor of 7 in the α phase, γ phase (nH = 5.28 × 10(26) m(-3)), and the α phase (nH = 3.76 × 10(27) m(-3)). We were able to detect a noise spectrum consisting of avalanches while slowly varying the temperature through the hysteretic region. We surmise that the avalanches originate from intergranular stresses at the interfaces between partially transformed high-volume and low-volume phases. The statistical distribution of avalanches obey power laws with energy exponent ϵ ≃ 1.5. Hall effect measurements, combined with universal critical exponents, point to short electron mean-free percolation pathways and carrier localization at phase interfaces. Carrier localization was predicted many years ago for elemental cerium by Johansson (1974 Phil. Mag. 30 469).

Anisotropic thermal conductivity in uranium dioxide.

The thermal conductivity of uranium dioxide has been studied for over half a century, as uranium dioxide is the fuel used in a majority of operating nuclear reactors and thermal conductivity controls the conversion of heat produced by fission events to electricity. Because uranium dioxide is a cubic compound and thermal conductivity is a second-rank tensor, it has always been assumed to be isotropic. We report thermal conductivity measurements on oriented uranium dioxide single crystals that show anisotropy from 4 K to above 300 K. Our results indicate that phonon-spin scattering is important for understanding the general thermal conductivity behaviour, and also explains the anisotropy by coupling to the applied temperature gradient and breaking cubic symmetry.

Order-parameter coupling in the improper ferroelectric lawsonite.

Low-temperature specific heat and thermal expansion measurements are used to study the hydrogen-based ferroelectric lawsonite over the temperature range 1.8 K ≤ T ≤ 300 K. The second-order phase transition near 125 K is detected in the experiments, and the low-temperature phase is determined to be improper ferroelectric and co-elastic. In the ferroelectric phase T ≤ 125 K, the spontaneous polarization P(s) is proportional to (1) the volume strain e(s), and (2) the excess entropy ΔS(e). These proportionalities confirm the improper character of the ferroelectric phase transition. We develop a structural model that allows the off-centering of hydrogen positions to generate the spontaneous polarization. In the low-temperature limit we detect a Schottky anomaly (two-level system) with an energy gap of Δ âˆ¼ 0.5 meV.

Localized 5f electrons in superconducting PuCoIn5: consequences for superconductivity in PuCoGa5.

The physical properties of the first In analog of the PuMGa(5) (M = Co, Rh) family of superconductors, PuCoIn(5), are reported. With its unit cell volume being 28% larger than that of PuCoGa(5), the characteristic spin-fluctuation energy scale of PuCoIn(5) is three to four times smaller than that of PuCoGa(5), which suggests that the Pu 5f electrons are in a more localized state relative to PuCoGa(5). This raises the possibility that the high superconducting transition temperature T(c) = 18.5 K of PuCoGa(5) stems from the proximity to a valence instability, while the superconductivity at T(c) = 2.5 K of PuCoIn(5) is mediated by antiferromagnetic spin fluctuations associated with a quantum critical point.

Physical properties of polycrystalline Sm2PdGe6 and Sm2PtGe6.

The compounds Sm2TGe6 (T = Pd, Pt,) were synthesized and characterized by x-ray diffraction, magnetization, electrical resistivity, thermoelectric power, and specific heat measurements performed in the temperature range 2-300 K. Additional resistivity and thermoelectric power measurements performed down to 0.35 K have not indicated superconductivity. These compounds crystallize in the orthorhombic structure of Ce2NiGe6 type and order antiferromagnetically at 23(1) and 30(1) K, respectively, showing localized magnetism of a Sm(3+) ion with a crystal field doublet level being the ground state. Below T(N), the electrical resistivity, the thermoelectric power, and the specific heat are dominated by electron-magnon scattering with an antiferromagnetic spin-wave spectrum typical of anisotropic antiferromagnetic systems. The thermoelectric power, S, achieves medium positive values at high temperatures, indicating a hole domination in electrical transport in both samples. At low temperatures, S changes its sign and becomes negative. At about 10 K a small negative maximum in S(T) occurs for both studied compounds. All the measurements carried out point to well-localized 4f-electrons in these two compounds, being strongly influenced by the crystal-electric-field effect with a significant admixture of two J-multiplets (5/2 and 7/2), typical for Sm-containing compounds.