1.
Chem Commun (Camb)
; 58(41): 6096-6099, 2022 May 20.
Artigo
em Inglês
| MEDLINE
| ID: mdl-35503035
RESUMO
Reaction between a carbazole-based mesoionic carbene ligand and manganese(II) iodide results in the formation of a rare air-stable manganese(IV) complex after aerobic workup. Cyclic voltammetry reveals the complex to be stable in five oxidation states. The electronic structure of all five oxidation states is elucidated chemically, spectroscopically (NMR, high-frequency EPR, UV-Vis, MCD), magnetically, and computationally (DFT, CASSCF).