Artificial Channels Based on Bottlebrush Polymers: Enhanced Ion Transport Through Polymer Topology Control.

Synthetic structures mimicking the transport function of natural ion channel proteins have a wide range of applications, including therapeutic treatments, separation membranes, sensing, and biotechnologies. However, the development of polymer-based artificial channels has been hampered due to the limitation on available models. In this study, we demonstrate the great potential of bottlebrush polymers as accessible and versatile molecular scaffolds for developing efficient artificial ion channels. Adopting the bottlebrush configuration enhanced ion transport activity of the channels compared to their linear analogs. Matching the structure of lipid bilayers, the bottlebrush channel with a hydrophilic-hydrophobic-hydrophilic triblock architecture exhibited the highest activity among the series. Functionalized with urea groups, these channels displayed high anion selectivity. Additionally, we illustrated that the transport properties could be fine-tuned by modifying the chemistry of ion binding sites. This work not only highlights the importance of polymer topology control in channel design, but also reveals the great potential for further developing bottlebrush channels with customized features and diverse functionalities.

Carbon, energy and water footprints analysis of rapeseed oil production: A case study in China.

As the largest consumer of rapeseed oil in the world, China should consider the environmental effect of rapeseed oil production. However, only a few improvement measures have been proposed. To fill this gap, this study analyzed the energy, carbon and water footprints of rapeseed oil production based on the International Organization for Standardization standards using the framework of life cycle assessment. Results show that most of the energy, carbon, and water footprint of rapeseed oil production can be contributed to the direct processes of rapeseed cultivation, and the indirect processes of transport and fertilizer/diesel production. The value of energy and carbon footprints are calculated as 726.07 kg oil eq and 3889.75 kg CO2 eq, respectively. For the water footprint, the values of acidification, aquatic eutrophication, carcinogens, freshwater ecotoxicity, water scarcity, and non-carcinogens are 14.24 kg SO2 eq, 4.53 kg PO4-3 eq, 6.72 × 10-5Case, 5.43 × 104 PAF.m3.d, 437.62 m3 deprived, and 1.88 × 10-5 case, respectively. Spatial analysis shows that the total environmental impacts of rapeseed production are concentrated in Sichuan, Hunan, Hubei, and Jiangxi Provinces. Correlation analysis reveals the positive correlation of human health and ecosystem quality with fertilizer application and pesticide loss. In general, the environmental effect can be effectively reduced by adjusting the industrial layout to shorten the distance of transport, improve the fine cultivation degree in low-yield areas, and decrease the use of pesticides in the hilly region of southern China.

PET bottles recycling in China: An LCA coupled with LCC case study of blanket production made of waste PET bottles.

A large number of polyethylene terephthalate (PET) bottles are discarded daily after usage. Thus, plastic bottle recycling has elicited considerable attention in recent years. In this context, this study aims to quantify the environmental and economic impacts of blanket production from 100% recycled waste plastic bottles in China through a life cycle assessment coupled with life cycle costing method. In addition, the environmental impact of replacing coal with natural gas and solar energy was evaluated. Results show that impact categories of global warming and fossil depletion have significant influence on the overall environment. Carbon dioxide, water, iron, coal and chromium (VI) to water are the main contributors to the overall environmental burden. The internal and external costs are $6433/metric ton and $370/metric ton, respectively. Analysis results indicate that the optimization of organic chemicals, recycled polyester filament and steam production processes can reduce environmental and economic burdens substantially. Energy substitutions with natural gas and the use of solar photovoltaic in steam production and electricity generation are effective measures for decreasing environmental impacts. Finally, suggestions based on research results and the current status of waste plastic bottle recycling in China are proposed.

Water footprint coupled economic impact assessment for maize production in China.

Nowadays, agricultural production places an enormous burden on freshwater resources, and the environmental external cost caused by the restoration of water quality degradation has attracted great attention. Maize is regarded as one of the world's major food security crops, and China is the second-largest maize producer. Thus, this study conducts an impact-oriented water footprint coupled economic impact assessment to quantify the water-related environmental impacts and economic burden caused by China's maize production from 2008 to 2017. Results show that the overall damage to human health and ecosystem quality of China's maize production in 2017 were 4.32 × 104 DALY and 4.62 × 103 Species·yr, respectively. The total economic cost was $ 2.15 × 1011, which included an internal cost of $ 5.99 × 1010 and external cost of $ 1.55 × 1011. Key factor analysis demonstrates that diesel and fertilizer production dominated the reduction in ecological and external cost burdens. Direct water consumption and labor cost played leading roles in human health and internal cost, respectively. The spatiotemporal variation assessment indicates that Inner Mongolia and Heilongjiang were the hotspots for water footprint and economic impact assessment results after considering the yield factor. The national average water footprint and economic impact caused by producing 1 ton of maize showed an upward trend from 2008 to 2015, however, a significant decline transpired later. Overall, improving the resource efficiency (i.e., diesel and freshwater), scientific application of fertilizer and reducing labor input can further lessen the water footprint and economic impact of maize production. Developing the social environment can also generate indirect environmental and economic benefits to China's maize production.

Impact-oriented water footprint assessment of wheat production in China.

Water consumption and pollution in wheat production, which are worth paying attention in agricultural countries and arid regions, need to be assessed systematically and comprehensively. China, one of the largest wheat-producing country in the world, should be concerned about this issue. Thus, an impact-oriented water footprint assessment of wheat production in China was conducted based on the ISO 14046 standard to quantify water-related environmental impacts. We quantified the environmental impacts on human health and ecosystem quality categories of wheat production from 2009 to 2016 and evaluated the spatial variation of these categories in 2016. Results showed that the environmental impacts on human health and ecosystem quality categories in 2016 were 5.15 × 10-4 DALY/t and 37.17 PDF·m2·yr/t, respectively. Key factor analysis showed that the overall environmental impacts were primarily derived from fertilizer production, diesel production, and direct water consumption and emission. The dynamic analysis results revealed that the temporal variations in impacts were associated with water and fertilizer consumption. Areas with high potential impacts were mainly congregated in the North China Plain and Xinjiang Province due to their high wheat yields. Ecosystem quality was negatively correlated with wheat yield, and human health was positively correlated with crop water requirement. Therefore, on the basis of ensuring grain production, improving the utilization efficiency of irrigation water and reducing fertilizer and diesel consumption are the priorities for the management of agricultural water resources.