Strain-invariant stretchable radio-frequency electronics.

Wireless modules that provide telecommunications and power-harvesting capabilities enabled by radio-frequency (RF) electronics are vital components of skin-interfaced stretchable electronics1-7. However, recent studies on stretchable RF components have demonstrated that substantial changes in electrical properties, such as a shift in the antenna resonance frequency, occur even under relatively low elastic strains8-15. Such changes lead directly to greatly reduced wireless signal strength or power-transfer efficiency in stretchable systems, particularly in physically dynamic environments such as the surface of the skin. Here we present strain-invariant stretchable RF electronics capable of completely maintaining the original RF properties under various elastic strains using a 'dielectro-elastic' material as the substrate. Dielectro-elastic materials have physically tunable dielectric properties that effectively avert frequency shifts arising in interfacing RF electronics. Compared with conventional stretchable substrate materials, our material has superior electrical, mechanical and thermal properties that are suitable for high-performance stretchable RF electronics. In this paper, we describe the materials, fabrication and design strategies that serve as the foundation for enabling the strain-invariant behaviour of key RF components based on experimental and computational studies. Finally, we present a set of skin-interfaced wireless healthcare monitors based on strain-invariant stretchable RF electronics with a wireless operational distance of up to 30 m under strain.

Fabrication and characterization of flower-like CuO-ZnO heterostructure nanowire arrays by photochemical deposition.

A simple two step solution-based method was applied to fabricate CuO-ZnO heterostructured nanowire (NW) arrays. First, ZnO nanowires were grown on a Si substrate using the ammonia solution hydrothermal reaction. Afterwards, flower-like CuO crystals were photochemically deposited on the tip of the ZnO NWs, using ultraviolet (UV) light (312 nm wavelength) irradiation at room temperature. The morphology of the CuO was controlled by reaction time, density of ZnO NWs, and concentration of the solution. Because the deposited CuO is p-type and has narrow band gap properties, CuO-ZnO heterostructured NWs exhibited a stable p-n junction property and good ability to absorb visible light. Through investigation of UV light-triggered reaction phenomena, we found that the production of OH(-) from the photocatalytic process on the surface of ZnO NWs plays a critical role in the CuO deposition mechanism.

Multifunctional transparent ZnO nanorod films.

Transparent ZnO nanorod (NR) films that exhibit extreme wetting states (either superhydrophilicity or superhydrophobicity through surface chemical modification), high transmittance, UV protection and antireflection have been prepared via the facile ammonia hydrothermal method. The periodic 1D ZnO NR arrays showed extreme wetting states as well as antireflection properties due to their unique surface structure and prevented the UVA region from penetrating the substrate due to the unique material property of ZnO. Because of the simple, time-efficient and low temperature preparation process, ZnO NR films with useful functionalities are promising for fabrication of highly light transmissive, antireflective, UV protective, antifogging and self-cleaning optical materials to be used for optical devices and photovoltaic energy devices.

Highly Integrated Elastic Island-Structured Printed Circuit Board with Controlled Young's Modulus for Stretchable Electronics.

A stretchable printed circuit board (PCB), which is an essential component of next-generation electronic devices, should be highly stretchable even at high levels of integration, as well as durable under repetitive stretching and patternable. Herein, an island-structured stretchable PCB composed of materials with controlled Young's modulus and viscosity by adding a reinforcing agent or controlling the degree of crosslinking is reported. Each material was fabricated with the most effective structures through a 3D printer. The PCB was able to stretch 71.3% even when highly integrated and was patterned so that various components could be mounted. When fully integrated, the stress applied to the mounted components was reduced by 99.9% even when stretched by over 70%. Consequently, a 4 × 4 array of capacitance sensors in a stretchable keypad demonstration using our PCB was shown to work, even at 50% stretching of the PCB.

Piezoresistive Behaviour of Additively Manufactured Multi-Walled Carbon Nanotube/Thermoplastic Polyurethane Nanocomposites.

To develop highly sensitive flexible pressure sensors, the mechanical and piezoresistive properties of conductive thermoplastic materials produced via additive manufacturing technology were investigated. Multi-walled carbon nanotubes (MWCNTs) dispersed in thermoplastic polyurethane (TPU), which is flexible and pliable, were used to form filaments. Specimens of the MWCNT/TPU composite with various MWCNT concentrations were printed using fused deposition modelling. Uniaxial tensile tests were conducted, while the mechanical and piezoresistive properties of the MWCNT/TPU composites were measured. To predict the piezoresistive behaviour of the composites, a microscale 3D resistance network model was developed. In addition, a continuum piezoresistive model was proposed for large-scale simulations.

Lubricant-Added Conductive Composite for Direct Writing of a Stretchable Electrode.

Stretchable electrodes, which are essential components of next-generation electronic devices, should be highly conductive under multiaxial tensile strain, durable under repetitive stretching, and patternable for integrating stretchable devices. Herein, a lubricant-added stretchable conductive composite of a polydimethylsiloxane-based elastomer containing silver flakes is reported. The added lubricant minimizes changes in conductivity during stretching and maximizes elastic durability by reducing friction. The conductivity varies from 1933.3 S·cm-1 at 0% strain to 307.5 S·cm-1 at 300% uniaxial stretching and 1264.1 S·cm-1 at 50% biaxial stretching. Furthermore, the composite exhibits high durability, even after 1000 cycles of stretching at 200%, and the conductive composite paste can be applied to fine-linewidth direct writing.

Three-Dimensionally Printed Stretchable Conductors from Surfactant-Mediated Composite Pastes.

A stretchable conductor is a critical prerequisite to achieve various forms of stretchable electronics. In particular, directly printable stretchable conductors have gathered considerable attention with recent growing interest in a variety of large-area, deformable electronics. In this study, we have developed a chemical pathway of incorporating a surfactant with a moderate hydrophilic-lipophilic balance in formulating composite pastes for printed stretchable conductors, with a possibility of a vertically stackable, three-dimensional printing process. We demonstrate that the addition of a nonionic surfactant, sorbitane monooleate (commonly called SPAN 80) in Ag flake-based composite pastes, allows a critical reduction in resistance variation under an external strain. The four-layer stacked, surfactant-added composite conductors show a resistance variation of merely 1.6 at a strain of 0.6 and excellent cycling durability over 1000 cycles. The effectiveness of the methods suggested in this study is demonstrated with basic light-emitting diode circuits and the thermal heating characteristics of stretchable conductors.

Correction: 3D polymer objects with electronic components interconnected via conformally printed electrodes.

Correction for '3D polymer objects with electronic components interconnected via conformally printed electrodes' by Yejin Jo, et al., Nanoscale, 2017, 9, 14798-14803.

Ultrastretchable Conductor Fabricated on Skin-Like Hydrogel-Elastomer Hybrid Substrates for Skin Electronics.

Printing technology can be used for manufacturing stretchable electrodes, which represent essential parts of wearable devices requiring relatively high degrees of stretchability and conductivity. In this work, a strategy for fabricating printable and highly stretchable conductors are proposed by transferring printed Ag ink onto stretchable substrates comprising Ecoflex elastomer and tough hydrogel layers using a water-soluble tape. The elastic modulus of the produced hybrid film is close to that of the hydrogel layer, since the thickness of Ecoflex elastomer film coated on hydrogel is very thin (30 µm). Moreover, the fabricated conductor on hybrid film is stretched up to 1780% strain. The described transfer method is simpler than other techniques utilizing elastomer stamps or sacrificial layers and enables application of printable electronics to the substrates with low elastic moduli (such as hydrogels). The integration of printed electronics with skin-like low-modulus substrates can be applied to make wearable devices more comfortable for human skin.

3D polymer objects with electronic components interconnected via conformally printed electrodes.

We report the fabrication of 3D polymer objects that contain electrical components interconnected by conductive silver/carbon nanotube inks printed conformally onto their surfaces and through vertical vias. Electrical components are placed within internal cavities and recessed surfaces of polymer objects produced by stereolithography. Conformally printed electrodes that interconnect each electrical component exhibit a conductivity of ∼2 × 104 S cm-1 upon annealing at temperatures below 100 °C. Multiple 3D objects were created to demonstrate this hybrid additive manufacturing approach, including those with an embedded circuit operated by an air-suspended switch and a 3D circuit board composed of microcontroller unit, resistor, battery, light-emitting diode and sensor.

3D printable composite dough for stretchable, ultrasensitive and body-patchable strain sensors.

The recent development of strain sensor devices which can actively monitor human body motion has attracted tremendous attention, for application in various wearable electronics and human-machine interfaces. In this study, as materials for strain sensor devices, we exploit the low-cost, carbon-based, 3-dimensional (3D) printable composite dough. The dough is prepared via a chemical method based on the formation of electrostatic assemblies between 1-dimensional, amine-functionalized, multi-walled carbon nanotubes and 2-dimensional graphene oxides. The resulting composite dough has an extremely high storage modulus, which allows a vertically-stackable, 3D printing process for fabricating strain sensor devices on various dense, porous and structured substrates. The device performance parameters, including gauge factor, hysteresis, linearity, and overshooting behavior are found to be adjustable by controlling the printing process parameters. The fabricated strain sensor devices demonstrate the ability to distinguish actual human body motions. A high gauge factor of over 70 as well as other excellent device performance parameters are achievable for the printed sensor devices, and even small strains, below 1%, are also detectable by the fabricated sensor devices.

3D-printable, highly conductive hybrid composites employing chemically-reinforced, complex dimensional fillers and thermoplastic triblock copolymers.

The use of 3-dimensional (3D) printable conductive materials has gained significant attention for various applications because of their ability to form unconventional geometrical architectures that cannot be realized with traditional 2-dimensional printing techniques. To resolve the major requisites in printed electrodes for practical applications (including high conductivity, 3D printability, excellent adhesion, and low-temperature processability), we have designed a chemically-reinforced multi-dimensional filler system comprising amine-functionalized carbon nanotubes, carboxyl-terminated silver nanoparticles, and Ag flakes, with the incorporation of a thermoplastic polystyrene-polyisoprene-polystyrene (SIS) triblock copolymer. It is demonstrated that both high conductivity, 22 939 S cm-1, and low-temperature processability, below 80 °C, are achievable with the introduction of chemically anchored carbon-to-metal hybrids and suggested that the highly viscous composite fluids employing the characteristic thermoplastic polymer are readily available for the fabrication of various unconventional electrode structures by a simple dispensing technique. The practical applicability of the 3D-printable highly conductive composite paste is confirmed with the successful fabrication of wireless power transmission modules on substrates with extremely uneven surface morphologies.

Electromechanical cardioplasty using a wrapped elasto-conductive epicardial mesh.

Heart failure remains a major public health concern with a 5-year mortality rate higher than that of most cancers. Myocardial disease in heart failure is frequently accompanied by impairment of the specialized electrical conduction system and myocardium. We introduce an epicardial mesh made of electrically conductive and mechanically elastic material, to resemble the innate cardiac tissue and confer cardiac conduction system function, to enable electromechanical cardioplasty. Our epicardium-like substrate mechanically integrated with the heart and acted as a structural element of cardiac chambers. The epicardial device was designed with elastic properties nearly identical to the epicardial tissue itself and was able to detect electrical signals reliably on the moving rat heart without impeding diastolic function 8 weeks after induced myocardial infarction. Synchronized electrical stimulation over the ventricles by the epicardial mesh with the high conductivity of 11,210 S/cm shortened total ventricular activation time, reduced inherent wall stress, and improved several measures of systolic function including increases of 51% in fractional shortening, ~90% in radial strain, and 42% in contractility. The epicardial mesh was also capable of delivering an electrical shock to terminate a ventricular tachyarrhythmia in rodents. Electromechanical cardioplasty using an epicardial mesh is a new pathway toward reconstruction of the cardiac tissue and its specialized functions.

Wearable Fall Detector using Integrated Sensors and Energy Devices.

Wearable devices have attracted great attentions as next-generation electronic devices. For the comfortable, portable, and easy-to-use system platform in wearable electronics, a key requirement is to replace conventional bulky and rigid energy devices into thin and deformable ones accompanying the capability of long-term energy supply. Here, we demonstrate a wearable fall detection system composed of a wristband-type deformable triboelectric generator and lithium ion battery in conjunction with integrated sensors, controllers, and wireless units. A stretchable conductive nylon is used as electrodes of the triboelectric generator and the interconnection between battery cells. Ethoxylated polyethylenimine, coated on the surface of the conductive nylon electrode, tunes the work function of a triboelectric generator and maximizes its performance. The electrical energy harvested from the triboelectric generator through human body motions continuously recharges the stretchable battery and prolongs hours of its use. The integrated energy supply system runs the 3-axis accelerometer and related electronics that record human body motions and send the data wirelessly. Upon the unexpected fall occurring, a custom-made software discriminates the fall signal and an emergency alert is immediately sent to an external mobile device. This wearable fall detection system would provide new opportunities in the mobile electronics and wearable healthcare.

Fabric-based integrated energy devices for wearable activity monitors.

A wearable fabric-based integrated power-supply system that generates energy triboelectrically using human activity and stores the generated energy in an integrated supercapacitor is developed. This system can be utilized as either a self-powered activity monitor or as a power supply for external wearable sensors. These demonstrations give new insights for the research of wearable electronics.

Reverse-micelle-induced porous pressure-sensitive rubber for wearable human-machine interfaces.

A novel method to produce porous pressure-sensitive rubber is developed. For the controlled size distribution of embedded micropores, solution-based procedures using reverse micelles are adopted. The piezosensitivity of the pressure sensitive rubber is significantly increased by introducing micropores. Using this method, wearable human-machine interfaces are fabricated, which can be applied to the remote control of a robot.

Stretchable silicon nanoribbon electronics for skin prosthesis.

Sensory receptors in human skin transmit a wealth of tactile and thermal signals from external environments to the brain. Despite advances in our understanding of mechano- and thermosensation, replication of these unique sensory characteristics in artificial skin and prosthetics remains challenging. Recent efforts to develop smart prosthetics, which exploit rigid and/or semi-flexible pressure, strain and temperature sensors, provide promising routes for sensor-laden bionic systems, but with limited stretchability, detection range and spatio-temporal resolution. Here we demonstrate smart prosthetic skin instrumented with ultrathin, single crystalline silicon nanoribbon strain, pressure and temperature sensor arrays as well as associated humidity sensors, electroresistive heaters and stretchable multi-electrode arrays for nerve stimulation. This collection of stretchable sensors and actuators facilitate highly localized mechanical and thermal skin-like perception in response to external stimuli, thus providing unique opportunities for emerging classes of prostheses and peripheral nervous system interface technologies.

Desmoplastic fibroma of the cranium in a young man.

Desmoplastic fibroma, which develops predominantly in long bones and the mandible, is a rare and benign but locally aggressive tumor. Desmoplastic fibroma of the cranium is extremely rare. We report a case of desmoplastic fibroma of the frontal bone in a young man. Because of its locally aggressive behavior, complete surgical excision with a safety margin is essential.

Fabrication of CuO-ZnO nanowires on a stainless steel mesh for highly efficient photocatalytic applications.

We report the photocatalytic activity of flower-like CuO-ZnO heterostructured nanowires (NWs) fabricated on a stainless steel mesh. The mesh provided an extensive surface area and facilitated efficient mass transfer. The composed NWs exhibited excellent photocatalytic activity and showed additional enhanced properties due to multilayered, dual light source effects during the photodecomposition of a non-biodegradable azo dye.